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Original Articles

Effect of alcohol type and amount on the total energy consumption and yield of the free fatty acids esterification reaction with simultaneous adsorptive water removal

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References

  • Alcantara, R., Amores, J., Canoira, L., Fidalgo, E., Franco, M. J., and Navarro, A. (2000). Catalytic production of biodiesel from soy bean oil, used frying oil and tallow, Biomass Bioenerg., 18, 515–527.
  • Aranda, D. A. G., Santos, R. T. P., Tapanes, N. C. O., Ramos, A. L. D., and Antunes, O. A. C. (2008). Acid catalyzed homogeneous esterification reaction for biodiesel production from palm fatty acids, Catal. Lett., 122, 20–25.
  • Berrios, M., Gutierrez, M. C., Martin, M. A., and Martin, A. (2010). Obtaining biodiesel from spanish used frying oil: Issues in meeting the EN 14214 biodiesel standard, Biomass Bioenerg., 34, 312–318.
  • Berrios, M., Siles, J., Martin, M. A., and Martin, A. (2007). A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil, Fuel, 86, 2383–2388.
  • Canakci, M. (2007). The potential of restaurant waste lipids as biodiesel feedstocks, Bioresour. Technol., 98, 180–193.
  • Canakci, M., and Van Gerpen, J. (2001). Biodiesel production from oils and fats with high free fatty acids, Trans. ASAE, 44, 1429–1436.
  • Canakci, M., and Van Gerpen, J. (2003). A pilot plant to produce biodiesel from high free fatty acid feedstocks, Trans. ASAE, 46, 945–954.
  • Chongkhong, S., Tongurai, C., and Chetpattananondh, R. (2009). Continuous esterification for biodiesel production from palm fatty acid distillate using economical process, Renew. Energy, 34, 1059–1063.
  • EPA420-P-02–001 (2002). A comprehensive analysis of biodiesel impacts on exhaust emissions, Draft technical report. Air and radiation.
  • Freedman, B., Pryde, E. H., and Mounts, T. L. (1984). Variables affecting the yields of fatty esters from transesterified vegetable oils, J. Am. Oil Chem. Soc., 61, 1638–1643.
  • Ghadge, S. V., and Raheman, H. (2005). Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids, Biomass Bioenerg., 28, 601–605.
  • Hammond, E. G. (1998). Personal Communication, Department of Food Science, Iowa State University, Ames, Iowa.
  • Jalama, K. (2012). Waste oils pre-esterification for biodiesel synthesis: Effect of feed moisture contents, Int. J. Chem. Mol. Nucl. Mater. Metall. Eng., 6, 342–347.
  • Kaur, N., and Ali, A. (2014). One-pot transesterification and esterification of waste cooking oil via ethanolysis using Sr:Zr mixed oxide as solid catalyst, RSC Adv., 4(82), 43671–43681.
  • Kaur, M., and Ali, A. (2015). An efficient and reusable Li/NiO heterogeneous catalyst for ethanolysis of waste cottonseed oil, Eur. J. Lipid Sci. Technol., 117(4), 550–560.
  • Knothe, G., Van Gerpen, J., and Krahl, J. (2005). The Biodiesel Handbook, AOCS Press, Urbana, IL.
  • Kumar, D., and Ali, A. (2015). Direct synthesis of fatty acid alkanolamides and fatty acid alkyl esters from high free fatty acid containing triglycerides as lubricity improvers using heterogeneous catalyst, Fuel, 159, 845–853.
  • Leung, D. Y. C., Wu, X., and Leung, M. K. H. (2010). A review on biodiesel production using catalyzed transesterification, Appl. Energy, 87, 1083–1095.
  • Liu, Y., Lotero, E., and Goodwin Jr, J. G. (2006). Effect of water on sulfuric acid catalyzed esterification, J. Mol. Catal. A Chem., 245, 132–140.
  • Lucena, I. L., Saboya, R. M. A., Oliveira, J. F. G., Rodrigues, M. L., Torres, A. E. B., Cavalcante Jr, C. L., Parente Jr, E. J. S., Silva, G. F., and Fernandes, F. A. N. (2011). Oleic acid esterification with ethanol under continuous water removal conditions, Fuel, 90, 902–904.
  • Lucena, I. L., Silva, G. F., and Fernandes, F. A. N. (2008). Biodiesel production by esterification of oleic acid with methanol using a water adsorption apparatus, Ind. Eng. Chem. Res., 47, 6885–6889.
  • Ma, F., Clements, L. D., and Hanna, M. A. (1998). The effects of catalyst free fatty acids and water on transesterification of beef tallow, Trans. ASAE, 41, 1261–1264.
  • Ma, F., and Hanna, M. A. (1999). Biodiesel production: A review, Bioresour. Technol., 70, 1–15.
  • Marchetti, J. M., and Errazu, A. F. (2008). Esterification of free fatty acids using sulfuric acid as catalyst in the presence of triglycerides, Biomass Bioenerg., 32, 892–895.
  • Meher, L. C., Vidya Sagar, D., and Naik, S. N. (2006). Technical aspects of biodiesel production by transesterification - A review. Renew. Sustainable Energy Rev., 10, 248–268.
  • Nye, M. J., and Southwell, P. H. (1984). Conversion of rapeseed oil to esters for use as diesel fuel. Fifth Canadian bioenergy R and D seminar, Elsevier Applied Science, London, UK, pp. 487–490.
  • Oliveira, J. F. G., Lucena, I. L., Saboya, R. M. A., Rodrigues, M. L., Torres, A. E. B., Fernandes, F. A. N., Cavalcante Jr, C. L., and Parente Jr, E. J. S. (2010). Biodiesel production from waste coconut oil by esterification with ethanol: the effect of water removal by adsorption, Renew. Energy, 35, 2581–2584.
  • Pahl, C., Pasel, C., Luckas, M., and Bathen, D. (2012). Adsorptive water removal from primary alcohols and acetic acid esters in the ppm-region, J. Chem. Eng. Data, 57, 2465–2471.
  • Park, J. Y., Wang, Z. M., Kim, D. K., and Lee, J. S. (2010). Effects of water on the esterification of free fatty acids by acid catalysts, Renew. Energy, 35, 614–618.
  • Pisarello, M. L., Dalla Costa, B., Mendow, G., and Querini, C. A. (2010). Esterification with ethanol to produce biodiesel from high acidity raw materials kinetic studies and analysis of secondary reactions, Fuel Process. Technol., 91, 1005–1014.
  • Sabudak, T., and Yildiz, M. (2010). Biodiesel production from waste frying oils and its quality control, Waste Manag., 30, 799–803.
  • Sheehan, J., Camobreco, V., Duffield, J., Graboski, M., and Shapouri, H. (1998). Life cycle inventory of biodiesel and petroleum diesel for use in an urban bus, final report for U.S. Dept. of Energy’s Office of Fuel Development and the U.S. Dept. of Agriculture’s Office of Energy, by the National Renewable Energy Laboratory, NREL/SR-580–24089.
  • Singh, A., He, B., Thompson, J., and Van Gerpen, J. (2006). Process optimization of biodiesel production using alkaline catalysts, Appl. Eng. Agric., 22, 597–600.
  • Van Gerpen, J., Shanks, B., Pruszko, R., Clements, D., and Knothe, G. (2004). Biodiesel production technology. NREL/SR-510–36244.
  • Zhen, X., and Wang, Y. (2015). Numerical analysis on original emissions for a spark ignition methanol engine based on detailed chemical kinetics, Renew. Energy, 81, 43–51.

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