A review on reaction mechanisms and catalysts of methanol to olefins process

References

• Abramova A. 2010. Synthesis of ethylene and propylene on a SAPO-34 silica—alumina—phosphate catalyst. Catal Ind. 2(1):29–37. doi:10.1134/S2070050410010058
   Google Scholar
• Aghaei E, Haghighi M. 2014. Enhancement of catalytic lifetime of nanostructured SAPO-34 in conversion of biomethanol to light olefins. Microporous Mesoporous Mater. 196:179–190. doi:10.1016/j.micromeso.2014.05.011
   Web of Science ®Google Scholar
• Aghaei E, Haghighi M. 2015. Effect of crystallization time on properties and catalytic performance of nanostructured SAPO-34 molecular sieve synthesized at high temperatures for conversion of methanol to light olefins. " Powder Technol. 269:358–370. doi:10.1016/j.powtec.2014.09.036
   Web of Science ®Google Scholar
• Aghamohammadi S, Haghighi M. 2015. Dual-template synthesis of nanostructured CoAPSO-34 used in methanol to olefins: Effect of template combinations on catalytic performance and coke formation. Chem Engin J. 264:359–375. doi:10.1016/j.cej.2014.11.102
   Web of Science ®Google Scholar
• Aghamohammadi S, Haghighi M. 2019. Spray-dried zeotype/clay nanocatalyst for methanol to light olefins in fluidized bed reactor: Comparison of active and non-active filler. Appl Clay Sci. 170:70–85. doi:10.1016/j.clay.2019.01.006
   Web of Science ®Google Scholar
• Aghamohammadi S, Haghighi M, Charghand M. 2014. Methanol conversion to light olefins over nanostructured CeAPSO-34 catalyst: thermodynamic analysis of overall reactions and effect of template type on catalytic properties and performance. Mater Res Bull. 50:462–475. doi:10.1016/j.materresbull.2013.11.014
   Web of Science ®Google Scholar
• Ahmad MS, Cheng CK, Bhuyar P, Atabani AE, Pugazhendhi A, Chi NTL, Witoon T, Lim JW, Juan JC. 2021. Effect of reaction conditions on the lifetime of SAPO-34 catalysts in methanol to olefins process–A review. Fuel. 283:118851. doi:10.1016/j.fuel.2020.118851
   Web of Science ®Google Scholar
• Ahmadpour J, Taghizadeh M. 2015. Catalytic conversion of methanol to propylene over high-silica mesoporous ZSM-5 zeolites prepared by different combinations of mesogenous templates. J Nat Gas Sci Eng. 23:184–194. doi:10.1016/j.jngse.2015.01.035
   Web of Science ®Google Scholar
• Ahmadpour J, Taghizadeh M. 2015. Selective production of propylene from methanol over high-silica mesoporous ZSM-5 zeolites treated with NaOH and NaOH/tetrapropylammonium hydroxide. CR Chim. 18(8):834–847. doi:10.1016/j.crci.2015.05.002
   Web of Science ®Google Scholar
• Ali MA, Al-Baghli NA, Nisar M, Malaibari ZO, Abutaleb A, Ahmed S. 2019. Selective production of propylene from methanol over monolith-supported modified ZSM-5 catalysts. Energy Fuels. 33(2):1458–1466. doi:10.1021/acs.energyfuels.8b04020
   Web of Science ®Google Scholar
• Al-Jarallah AM, El-Nafaty UA, Abdillahi MM. 1997. Effects of metal impregnation on the activity, selectivity and deactivation of a high silica MFI zeolite when converting methanol to light alkenes. Appl Catal, A. 154(1-2):117–127. doi:10.1016/S0926-860X(96)00379-1
   Web of Science ®Google Scholar
• Alwahabi SM, Froment GF. 2004. Conceptual reactor design for the methanol-to-olefins process on SAPO-34. Ind Eng Chem Res. 43(17):5112–5122. doi:10.1021/ie040042m
   Web of Science ®Google Scholar
• Alwahabi SM, Froment GF. 2004. Single event kinetic modeling of the methanol-to-olefins process on SAPO-34. Ind Eng Chem Res. 43(17):5098–5111. doi:10.1021/ie040041u
   Web of Science ®Google Scholar
• Arstad B, Kolboe S. 2001. The reactivity of molecules trapped within the SAPO-34 cavities in the methanol-to-hydrocarbons reaction. J Am Chem Soc. 123(33):8137–8138. doi:10.1021/ja010668t
   PubMed Web of Science ®Google Scholar
• Arstad B, Nicholas JB, Haw JF. 2004. Theoretical study of the methylbenzene side-chain hydrocarbon pool mechanism in methanol to olefin catalysis. J Am Chem Soc. 126(9):2991–3001. doi:10.1021/ja035923j
   PubMed Web of Science ®Google Scholar
• Auerbach SM, Carrado KA, et al. 2003. Handbook of zeolite science and technology, CRC press, Marcel Dekker Inc.
   Google Scholar
• Azarhoosh MJ, Halladj R, Askari S, Aghaeinejad-Meybodi A. 2019. Performance analysis of ultrasound-assisted synthesized nano-hierarchical SAPO-34 catalyst in the methanol-to-lights-olefins process via artificial intelligence methods. Ultrason Sonochem. 58(104646):104646. doi:10.1016/j.ultsonch.2019.104646
   PubMed Web of Science ®Google Scholar
• Baliban RC, Elia JA, Weekman V, Floudas CA. 2012. Process synthesis of hybrid coal, biomass, and natural gas to liquids via Fischer–Tropsch synthesis, ZSM-5 catalytic conversion, methanol synthesis, methanol-to-gasoline, and methanol-to-olefins/distillate technologies. Comput Chem Eng. 47:29–56. doi:10.1016/j.compchemeng.2012.06.032
   Web of Science ®Google Scholar
• Barakov R, Shcherban N, Yaremov P, Bezverkhyy I, Baranchikov A, Trachevskii V, Tsyrina V, Ilyin V. 2017. Synthesis of micro-mesoporous aluminosilicates on the basis of ZSM-5 zeolite using dual-functional templates at presence of micellar and molecular templates. Microporous Mesoporous Mater. 237:90–107. doi:10.1016/j.micromeso.2016.09.009
   Web of Science ®Google Scholar
• Behbahani RM, Mehr AS. 2014. Studying activity, product distribution and lifetime of Sr promoted alkali modified low Si ZSM-5 catalyst in MTO process. J Nat Gas Sci Eng. 18:433–438. doi:10.1016/j.jngse.2014.03.024
   Web of Science ®Google Scholar
• Beheshti MS, Behzad M, Ahmadpour J, Arabi H. 2020. Modification of H-[B]-ZSM-5 zeolite for methanol to propylene (MTP) conversion: Investigation of extrusion and steaming treatments on physicochemical characteristics and catalytic performance. Microporous Mesoporous Mater. 291(109699):109699. doi:10.1016/j.micromeso.2019.109699
   Web of Science ®Google Scholar
• Bjørgen M, Bonino F, Arstad B, Kolboe S, Lillerud K-P, Zecchina A, Bordiga S. 2005. Persistent methylbenzenium ions in protonated zeolites: The required proton affinity of the guest hydrocarbon. Chemphyschem. 6(2):232–235. doi:10.1002/cphc.200400422
   PubMed Web of Science ®Google Scholar
• Bjørgen M, Bonino F, Kolboe S, Lillerud K-P, Zecchina A, Bordiga S. 2003. Spectroscopic evidence for a persistent benzenium cation in zeolite H-beta. J Am Chem Soc. 125(51):15863–15868. doi:10.1021/ja037073d
   PubMed Web of Science ®Google Scholar
• Bjørgen M, Joensen F, Lillerud K-P, Olsbye U, Svelle S. 2009. The mechanisms of ethene and propene formation from methanol over high silica H-ZSM-5 and H-beta. Catal Today. 142(1-2):90–97. doi:10.1016/j.cattod.2009.01.015
   Web of Science ®Google Scholar
• Bjørgen M, Joensen F, Spangsberg Holm M, Olsbye U, Lillerud K-P, Svelle S. 2008. Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH. Appl Catal, A. 345(1):43–50. doi:10.1016/j.apcata.2008.04.020
   Web of Science ®Google Scholar
• Bjørgen M, Olsbye U, et al. 2003. Coke precursor formation and zeolite deactivation: mechanistic insights from hexamethylbenzene conversion. J Catal. 215(1):30–44. doi:10.1016/S0021-9517(02)00050-7
   Web of Science ®Google Scholar
• Bjørgen M, Olsbye U, et al. 2004. The methanol-to-hydrocarbons reaction: insight into the reaction mechanism from [12C] benzene and [13C] methanol coreactions over zeolite H-beta. J Catal. 221(1):1–10. doi:10.1016/S0021-9517(03)00284-7
   Web of Science ®Google Scholar
• Bjørgen M, Svelle S, Joensen F, Nerlov J, Kolboe S, Bonino F, Palumbo L, Bordiga S, Olsbye U. 2007. Conversion of methanol to hydrocarbons over zeolite H-ZSM-5: On the origin of the olefinic species. J Catal. 249(2):195–207. doi:10.1016/j.jcat.2007.04.006
   Web of Science ®Google Scholar
• Blaszkowski SR, van Santen RA. 1997. Theoretical study of C − C bond formation in the methanol-to-gasoline process. J Am Chem Soc. 119(21):5020–5027. doi:10.1021/ja963530x
   Web of Science ®Google Scholar
• Blaszkowski SR, van Santen RA. 1997. Theoretical study of the mechanism of surface methoxy and dimethyl ether formation from methanol catalyzed by zeolitic protons. J Phys Chem B. 101(13):2292–2305. doi:10.1021/jp962006+
   Web of Science ®Google Scholar
• Bos ANR, Tromp PJJ, Akse HN. 1995. Conversion of methanol to lower olefins. Kinetic modeling, reactor simulation, and selection. Ind Eng Chem Res. 34(11):3808–3816. doi:10.1021/ie00038a018
   Web of Science ®Google Scholar
• Chae H-J, Park SS, Shin YH, Park MB. 2018. Synthesis and characterization of nanocrystalline TiAPSO-34 catalysts and their performance in the conversion of methanol to light olefins. Microporous Mesoporous Mater. 259:60–66. doi:10.1016/j.micromeso.2017.09.035
   Web of Science ®Google Scholar
• Chaikittisilp W, Suzuki Y, Mukti RR, Suzuki T, Sugita K, Itabashi K, Shimojima A, Okubo T. 2013. Formation of hierarchically organized zeolites by sequential intergrowth. Angew Chem. 125(12):3439–3443. doi:10.1002/ange.201209638
   Google Scholar
• Chal R, Gérardin C, Bulut M, van Donk S. 2011. Overview and industrial assessment of synthesis strategies towards zeolites with mesopores. ChemCatChem. 3(1):67–81. doi:10.1002/cctc.201000158
   Web of Science ®Google Scholar
• Chang CD. 1980. A kinetic model for methanol conversion to hydrocarbons. Chem Eng Sci. 35(3):619–622. doi:10.1016/0009-2509(80)80011-X
   Web of Science ®Google Scholar
• Chang CD. 1983. Hydrocarbons from methanol. Catal Rev Sci Engin. 25(1):1–118. doi:10.1080/01614948308078874
   Web of Science ®Google Scholar
• Chang CD, Silvestri AJ. 1977. The conversion of methanol and other O-compounds to hydrocarbons over zeolite catalysts. J Catal. 47(2):249–259. doi:10.1016/0021-9517(77)90172-5
   Web of Science ®Google Scholar
• Charghand M, Haghighi M, Aghamohammadi S. 2014. The beneficial use of ultrasound in synthesis of nanostructured Ce-doped SAPO-34 used in methanol conversion to light olefins. Ultrason Sonochem. 21(5):1827–1838. doi:10.1016/j.ultsonch.2014.03.011
   PubMed Web of Science ®Google Scholar
• Charghand M, Haghighi M, Saedy S, Aghamohammadi S. 2014. Efficient hydrothermal synthesis of nanostructured SAPO-34 using ultrasound energy: Physicochemical characterization and catalytic performance toward methanol conversion to light olefins. Adv Powder Technol. 25(6):1728–1736. doi:10.1016/j.apt.2014.06.022
   Web of Science ®Google Scholar
• Chen D, Grønvold A, Moljord K, Holmen A. 2007. Methanol conversion to light olefins over SAPO-34: Reaction network and deactivation kinetics. Ind Eng Chem Res. 46(12):4116–4123. doi:10.1021/ie0610748
   Web of Science ®Google Scholar
• Chen J, Liang T, Li J, Wang S, Qin Z, Wang P, Huang L, Fan W, Wang J. 2016. Regulation of framework aluminum siting and acid distribution in H-MCM-22 by boron incorporation and its effect on the catalytic performance in methanol to hydrocarbons. ACS Catal. 6(4):2299–2313. doi:10.1021/acscatal.5b02862
   Web of Science ®Google Scholar
• Chen X-D, Li X-G, Li H, Han J-J, Xiao W-D. 2018. Interaction between binder and high silica HZSM-5 zeolite for methanol to olefins reactions. Chem Eng Sci. 192:1081–1090. doi:10.1016/j.ces.2018.08.047
   Web of Science ®Google Scholar
• Chen N, Reagan W. 1979. Evidence of autocatalysis in methanol to hydrocarbon reactions over zeolite catalysts. J Catal. 59(1):123–129. doi:10.1016/S0021-9517(79)80050-0
   Web of Science ®Google Scholar
• Chen H, Wang Y, Meng F, Li H, Wang S, Sun C, Wang S, Wang X. 2016. Conversion of methanol to propylene over nano-sized ZSM-5 zeolite aggregates synthesized by a modified seed-induced method with CTAB. RSC Adv. 6(80):76642–76651. doi:10.1039/C6RA14753D
   Web of Science ®Google Scholar
• Chen H, Wang Y, Meng F, Sun C, Li H, Wang Z, Gao F, Wang X, Wang S. 2017. Aggregates of superfine ZSM-5 crystals: the effect of NaOH on the catalytic performance of methanol to propylene reaction. Microporous Mesoporous Mater. 244:301–309. doi:10.1016/j.micromeso.2017.02.014
   Web of Science ®Google Scholar
• Chen H, Wang Y, Sun C, Wang X, Wang C. 2018. Organosilane surfactant-directed synthesis of hierarchical ZSM-5 zeolites with improved catalytic performance in methanol-to-propylene reaction. Industr Engin Chem Res. 112(32):10–10966. doi:10.1016/j.catcom.2018.04.017
   Web of Science ®Google Scholar
• Chen H, Wang Q, Zhang X, Wang L. 2014. Hydroconversion of jatropha oil to alternative fuel over hierarchical ZSM-5. Ind Eng Chem Res. 53(51):19916–19924. doi:10.1021/ie503799t
   Web of Science ®Google Scholar
• Cho HS, Ryoo R. 2012. Synthesis of ordered mesoporous MFI zeolite using CMK carbon templates. Microporous Mesoporous Mater. 151:107–112. doi:10.1016/j.micromeso.2011.11.007
   Web of Science ®Google Scholar
• Choi M, Cho HS, Srivastava R, Venkatesan C, Choi D-H, Ryoo R. 2006. Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity. Nat Mater. 5(9):718–723. doi:10.1038/nmat1705
   PubMed Web of Science ®Google Scholar
• Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. 2009. Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts. Nature. 461(7261):246–249. doi:10.1038/nature08288
   PubMed Web of Science ®Google Scholar
• Christensen CH, Johannsen K, Schmidt I, Christensen CH. 2003. Catalytic benzene alkylation over mesoporous zeolite single crystals: improving activity and selectivity with a new family of porous materials. J Am Chem Soc. 125(44):13370–13371. doi:10.1021/ja037063c
   PubMed Web of Science ®Google Scholar
• Corma A. 1997. From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem Rev. 97(6):2373–2420. doi:10.1021/cr960406n
   PubMed Web of Science ®Google Scholar
• Cui N, Guo H, Zhou J, Li L, Guo L, Hua Z. 2020. Regulation of framework Al distribution of high-silica hierarchically structured ZSM-5 zeolites by boron-modification and its effect on materials catalytic performance in methanol-to-propylene reaction. Microporous Mesoporous Mater. 306:110411. doi:10.1016/j.micromeso.2020.110411
   Web of Science ®Google Scholar
• Cui Z-M, Liu Q, Song W-G, Wan L-J. 2006. Insights into the mechanism of methanol-to-olefin conversion at zeolites with systematically selected framework structures. Angew Chem Int Ed Engl. 45(39):6512–6515. doi:10.1002/anie.200602488
   PubMed Web of Science ®Google Scholar
• Cui T-L, Lv L-B, Zhang W-B, Li X-H, Chen J-S. 2016. Programmable synthesis of mesoporous ZSM-5 nanocrystals as selective and stable catalysts for the methanol-to-propylene process. Catal Sci Technol. 6(14):5262–5266. doi:10.1039/C6CY00379F
   Web of Science ®Google Scholar
• Dahl IM, Kolboe S. 1993. On the reaction mechanism for propene formation in the MTO reaction over SAPO-34. Catal Lett. 20(3-4):329–336. doi:10.1007/BF00769305
   Web of Science ®Google Scholar
• Dahl IM, Kolboe S. 1994. On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: I. Isotopic labeling studies of the co-reaction of ethene and methanol. J Catal. 149(2):458–464. doi:10.1006/jcat.1994.1312
   Web of Science ®Google Scholar
• Dahl IM, Kolboe S. 1996. On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: 2. Isotopic labeling studies of the co-reaction of propene and methanol. J Catal. 161(1):304–309. doi:10.1006/jcat.1996.0188
   Web of Science ®Google Scholar
• Dehertog W, Froment G. 1991. Production of light alkenes from methanol on ZSM-5 catalysts. Appl Catal. 71(1):153–165. doi:10.1016/0166-9834(91)85012-K
   Google Scholar
• Deng Z, Zhang Y, Zhu K, Qian G, Zhou X. 2015. Carbon nanotubes as transient inhibitors in steam-assisted crystallization of hierarchical ZSM-5 zeolites. Mater Lett. 159:466–469. doi:10.1016/j.matlet.2015.07.062
   Web of Science ®Google Scholar
• Derouane EG. 1978. Elucidation of the mechanism of conversion of methanol and ethanol to hydrocarbons on a new type of synthetic zeolite. J Catal. 53(1):40–55. doi:10.1016/0021-9517(78)90006-4
   Web of Science ®Google Scholar
• Dessau R. 1986. On the H-ZSM-5 catalyzed formation of ethylene from methanol or higher olefins. J Catal. 99(1):111–116. doi:10.1016/0021-9517(86)90204-6
   Web of Science ®Google Scholar
• Devulapelli VG, Sahle-Demessie E. 2008. Catalytic oxidation of dimethyl sulfide with ozone: Effects of promoter and physico-chemical properties of metal oxide catalysts. Appl Catal, A. 348(1):86–93. doi:10.1016/j.apcata.2008.06.038
   Web of Science ®Google Scholar
• Ding J, Han L, Wen M, Zhao G, Liu Y, Lu Y. 2015. Synthesis of monolithic Al-fiber@ HZSM-5 core-shell catalysts for methanol-to-propylene reaction. Catal Commun. 72:156–160. doi:10.1016/j.catcom.2015.09.026
   Web of Science ®Google Scholar
• Ding J, Jia Y, Chen P, Zhao G, Liu Y, Lu Y. 2019. Thin-felt hollow-B-ZSM-5/SS-fiber catalyst for methanol-to-propylene: Toward remarkable stability improvement from mesoporosity-dependent diffusion enhancement. Chem Engin J. 361:588–598. doi:10.1016/j.cej.2018.12.108
   Web of Science ®Google Scholar
• Doering WvE, Saunders M, Boyton HG, Earhart HW, Wadley EF, Edwards WR, Laber G. 1958. The 1, 1, 2, 3, 4, 5, 6-heptamethylbenzenonium ion. " Tetrahedron. 4(1-2):178–185. doi:10.1016/0040-4020(58)88016-3
   Web of Science ®Google Scholar
• Dowdy TE. 1999. Coal gasification and hydrogen production system and method. Google Patents.
   Google Scholar
• Dubois DR, Obrzut DL, Liu J, Thundimadathil J, Adekkanattu PM, Guin JA, Punnoose A, Seehra MS. 2003. Conversion of methanol to olefins over cobalt-, manganese-and nickel-incorporated SAPO-34 molecular sieves. Fuel Process Technol. 83(1-3):203–218. doi:10.1016/S0378-3820(03)00069-9
   Web of Science ®Google Scholar
• Ebadzadeh E, Khademi MH, Beheshti M. 2021. A kinetic model for methanol-to-propylene process in the presence of co-feeding of C4-C5 olefin mixture over H-ZSM-5 catalyst. Chem Engin J. 405:126605. doi:10.1016/j.cej.2020.126605
   Web of Science ®Google Scholar
• Ebrahimi A, Haghighi M, Aghamohammadi S. 2020. Effect of calcination temperature and composition on the spray-dried microencapsulated nanostructured SAPO-34 with kaolin for methanol conversion to ethylene and propylene in fluidized bed reactor. Microporous Mesoporous Mater. 297:110046. doi:10.1016/j.micromeso.2020.110046
   Web of Science ®Google Scholar
• Fang Y, Hu H. 2006. An ordered mesoporous aluminosilicate with completely crystalline zeolite wall structure. J Am Chem Soc. 128(33):10636–10637. doi:10.1021/ja061182l
   PubMed Web of Science ®Google Scholar
• Feng R, Wang X, Lin J, Li Z, Hou K, Yan X, Hu X, Yan Z, Rood MJ. 2018. Two-stage glucose-assisted crystallization of ZSM-5 to improve methanol to propylene (MTP). Microporous Mesoporous Mater. 270:57–66. doi:10.1016/j.micromeso.2018.05.003
   Web of Science ®Google Scholar
• Feng R, Yan X, Hu X, Wu J, Yan Z. 2020. Direct synthesis of b-axis oriented H-form ZSM-5 zeolites with an enhanced performance in the methanol to propylene reaction. Microporous Mesoporous Mater. 302:110246. doi:10.1016/j.micromeso.2020.110246
   Web of Science ®Google Scholar
• Feng R, Yan X, Hu X, Yan Z, Lin J, Li Z, Hou K, Rood MJ. 2018. Surface dealumination of micro-sized ZSM-5 for improving propylene selectivity and catalyst lifetime in methanol to propylene (MTP) reaction. Catal Commun. 109:1–5. doi:10.1016/j.catcom.2018.02.005
   Web of Science ®Google Scholar
• Feng R, Yan X, Hu X, Zhang Y, Wu J, Yan Z. 2020. Phosphorus-modified b-axis oriented hierarchical ZSM-5 zeolites for enhancing catalytic performance in a methanol to propylene reaction. Appl Catal, A. 594:117464. doi:10.1016/j.apcata.2020.117464
   Web of Science ®Google Scholar
• Feng R, Yan X, Hu X, Zhang Y, Wu J, Yan Z. 2020. The effect of co-feeding ethanol on a methanol to propylene (MTP) reaction over a commercial MTP catalyst. Appl Catal, A. 592:117429. doi:10.1016/j.apcata.2020.117429
   Web of Science ®Google Scholar
• Fernández Y, Arenillas A, Díez MA, Pis JJ, Menéndez JA. 2009. Pyrolysis of glycerol over activated carbons for syngas production. J Anal Appl Pyrolysis. 84(2):145–150. doi:10.1016/j.jaap.2009.01.004
   Web of Science ®Google Scholar
• Fournier, J.-F., E. S. Wagner, et al. 2019. Recycling system and process of a methanol-to-propylene and steam cracker plant, Google Patents.
   Google Scholar
• Froment, G. (1992). Kinetics and reactor design in the thermal cracking for olefins production. Chem Engin Sci 47(9):2163–2177.
   Web of Science ®Google Scholar
• Fujitsuka H, Oshima S, et al. 2020. Synthesis of Rh nanoparticles encapsulated in ZSM-5 and its application for methanol to olefin over acid sites with simultaneous production of hydrogen over Rh. Catal Today. 375:360–368.
   Web of Science ®Google Scholar
• Fujiwara M, Mimura N, Sato O, Yamaguchi A. 2019. Surface modification of H-ZSM-5 with organo-disilane compound for propylene production from dimethyl ether. Microporous Mesoporous Mater. 280:219–226. doi:10.1016/j.micromeso.2019.02.005
   Web of Science ®Google Scholar
• Gao M, Li H, Liu W, Xu Z, Peng S, Yang M, Ye M, Liu Z. 2020. Imaging spatiotemporal evolution of molecules and active sites in zeolite catalyst during methanol-to-olefins reaction. Nat Commun. 11(1):1–11. doi:10.1038/s41467-020-17355-6
   PubMed Web of Science ®Google Scholar
• Gayubo AG, Aguayo AT, Alonso A, Atutxa A, Bilbao J. 2005. Reaction scheme and kinetic modelling for the MTO process over a SAPO-18 catalyst. Catal Today. 106(1-4):112–117. doi:10.1016/j.cattod.2005.07.133
   Web of Science ®Google Scholar
• Gayubo AG, Aguayo AT, Sánchez del Campo AE, Tarrío AM, Bilbao J. 2000. Kinetic modeling of methanol transformation into olefins on a SAPO-34 catalyst. Ind Eng Chem Res. 39(2):292–300. doi:10.1021/ie990188z
   Web of Science ®Google Scholar
• Gluhoi AC, Nieuwenhuys BE. 2007. Structural and chemical promoter effects of alkali (earth) and cerium oxides in CO oxidation on supported gold. Catal Today. 122(3-4):226–232. doi:10.1016/j.cattod.2007.01.066
   Web of Science ®Google Scholar
• Gorzin F, Towfighi Darian J, Yaripour F, Mousavi SM. 2019. Synthesis of highly crystalline nanosized HZSM-5 catalyst employing combined hydrothermal and sonochemical method: Investigation of ultrasonic parameters on physico-chemical and catalytic performance in methanol to propylene reaction. J Solid State Chem. 271:8–22. doi:10.1016/j.jssc.2018.12.016
   Web of Science ®Google Scholar
• Groen JC, Moulijn JA, Pérez-Ramírez J. 2006. Desilication: on the controlled generation of mesoporosity in MFI zeolites. J Mater Chem. 16(22):2121–2131. doi:10.1039/B517510K
   Web of Science ®Google Scholar
• Groen J, Sano T, Moulijn J, Perezramirez J. 2007. Alkaline-mediated mesoporous mordenite zeolites for acid-catalyzed conversions. J Catal. 251(1):21–27. doi:10.1016/j.jcat.2007.07.020
   Web of Science ®Google Scholar
• Guo W, Wu W, Luo M, Xiao W. 2013. Modeling of diffusion and reaction in monolithic catalysts for the methanol-to-propylene process. Fuel Process Technol. 108:133–138. doi:10.1016/j.fuproc.2012.06.005
   Web of Science ®Google Scholar
• Guo W, Xiao W, Luo M. 2012. Comparison among monolithic and randomly packed reactors for the methanol-to-propylene process. Chem Engin J. 207–208:734–745. doi:10.1016/j.cej.2012.07.046
   Web of Science ®Google Scholar
• Hadi N, Alizadeh R, Niaei A. 2017. Selective production of propylene from methanol over nanosheets of metal-substituted MFI zeolites. J Ind Eng Chem. 54:82–97. doi:10.1016/j.jiec.2017.05.021
   Web of Science ®Google Scholar
• Hadi N, Farzi A, Alizadeh R, Niaei A. 2020. Metal-substituted sponge-like MFI zeolites as high-performance catalysts for selective conversion of methanol to propylene. Microporous Mesoporous Mater. 306:110406. doi:10.1016/j.micromeso.2020.110406
   Web of Science ®Google Scholar
• Hadi N, Niaei A, et al. 2014. Development of a new kinetic model for methanol to propylene process on Mn/H-ZSM-5 catalyst. Chem Biochem Eng Q. 28(1):53–63.
   Web of Science ®Google Scholar
• Hadi N, Niaei A, Alizadeh R, Raeisipour J. 2018. Durable and highly selective tungsten-substituted MFI metallosilicate catalysts for the methanol-to-propylene process by designing a novel feed-supply technique. CR Chim. 21(5):523–540. doi:10.1016/j.crci.2018.01.001
   Web of Science ®Google Scholar
• Hadi N, Niaei A, Nabavi SR, Alizadeh R, Shirazi MN, Izadkhah B. 2016. "An intelligent approach to design and optimization of M-Mn/H-ZSM-5 (M: Ce, Cr, Fe, Ni) catalysts in conversion of methanol to propylene. J Taiwan Inst Chem Eng. 59:173–185. doi:10.1016/j.jtice.2015.09.017
   Web of Science ®Google Scholar
• Hadi N, Niaei A, Nabavi SR, Navaei Shirazi M, Alizadeh R. 2015. Effect of second metal on the selectivity of Mn/H-ZSM-5 catalyst in methanol to propylene process. J Ind Eng Chem. 29:52–62. doi:10.1016/j.jiec.2015.03.017
   Web of Science ®Google Scholar
• Hambali HU, Jalil AA, Triwahyono S, Jamian SF, Fatah NAA, Abdulrasheed AA, Siang TJ. 2021. Unique structure of fibrous ZSM-5 catalyst expedited prolonged hydrogen atom restoration for selective production of propylene from methanol. Int J Hydrogen Energy. 46(48):24652–24665. doi:10.1016/j.ijhydene.2019.11.236
   Web of Science ®Google Scholar
• Han Z, Zhou F, Liu Y, Qiao K, Ma H, Yu L, Wu G. 2019. Synthesis of gallium-containing ZSM-5 zeolites by the seed-induced method and catalytic performance of GaZSM-5 and AlZSM-5 during the conversion of methanol to olefins. J Taiwan Inst Chem Eng. 103:149–159. doi:10.1016/j.jtice.2019.07.005
   Web of Science ®Google Scholar
• Han Z, Zhou F, Zhao J, Liu Y, Ma H, Wu G. 2020. Synthesis of hierarchical GaZSM-5 zeolites by a post-treatment method and their catalytic conversion of methanol to olefins. Microporous Mesoporous Mater. 302:110194. doi:10.1016/j.micromeso.2020.110194
   Web of Science ®Google Scholar
• Hashemi F, Taghizadeh M, Rami MD. 2020. Polyoxometalate modified SAPO-34: A highly stable and selective catalyst for methanol conversion to light olefins. Microporous Mesoporous Mater. 295(109970):109970. doi:10.1016/j.micromeso.2019.109970
   Web of Science ®Google Scholar
• Haw JF. 2002. Zeolite acid strength and reaction mechanisms in catalysis. PCCP. 4(22):5431–5441. doi:10.1039/B206483A
   Web of Science ®Google Scholar
• Haw JF, Nicholas JB, Song W, Deng F, Wang Z, Xu T, Heneghan CS. 2000. Roles for cyclopentenyl cations in the synthesis of hydrocarbons from methanol on zeolite catalyst HZSM-5. J Am Chem Soc. 122(19):4763–4775. doi:10.1021/ja994103x
   Web of Science ®Google Scholar
• Haw JF, Song W, Marcus DM, Nicholas JB. 2003. The mechanism of methanol to hydrocarbon catalysis. Acc Chem Res. 36(5):317–326. doi:10.1021/ar020006o
   PubMed Web of Science ®Google Scholar
• Heracleous E, Lee A, Wilson K, Lemonidou A. 2005. Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene: structural characterization and reactivity studies. J Catal. 231(1):159–171. doi:10.1016/j.jcat.2005.01.015
   Web of Science ®Google Scholar
• Huang X, Aihemaitijiang D, Xiao W-D. 2016. Co-reaction of methanol and olefins on the high silicon HZSM-5 catalyst: A kinetic study. Chem Engin J. 286:150–164. doi:10.1016/j.cej.2015.10.045
   Web of Science ®Google Scholar
• Huang F, Cao J, Wang L, Wang X, Liu F. 2020. Enhanced catalytic behavior for methanol to lower olefins over SAPO-34 composited with ZrO2. Chem Engin J. 380:122626. doi:10.1016/j.cej.2019.122626
   Web of Science ®Google Scholar
• Huang X, Li H, Li H, Xiao W-D. 2016. A computationally efficient multi-scale simulation of a multi-stage fixed-bed reactor for methanol to propylene reactions. Fuel Process Technol. 150:104–116. doi:10.1016/j.fuproc.2016.05.008
   Web of Science ®Google Scholar
• Huang X, Li X-G, Li H, Xiao W-D. 2017. High-performance HZSM-5/cordierite monolithic catalyst for methanol to propylene reaction: A combined experimental and modelling study. Fuel Process Technol. 159:168–177. doi:10.1016/j.fuproc.2017.01.031
   Web of Science ®Google Scholar
• Huang X, Li H, Xiao W-D, Chen D. 2016. Insight into the side reactions in methanol-to-olefin process over HZSM-5: A kinetic study. Chem Engin J. 299:263–275. doi:10.1016/j.cej.2016.04.065
   Web of Science ®Google Scholar
• Huang H, Yu M, Zhang Q, Li C. 2020. Insights into NH4-SAPO-34 preparation procedure: Effect of the number of ammonium exchange times on catalytic performance of Zn-modified SAPO-34 zeolite for methanol to olefin reaction. Microporous Mesoporous Mater. 295:109971. doi:10.1016/j.micromeso.2019.109971
   Web of Science ®Google Scholar
• Hu S, Shan J, Zhang Q, Wang Y, Liu Y, Gong Y, Wu Z, Dou T. 2012. Selective formation of propylene from methanol over high-silica nanosheets of MFI zeolite. Appl Catal A 445–446:215–220.
   Web of Science ®Google Scholar
• Hu X, Yuan L, Cheng S, Luo J, Sun H, Li S, Li L, Wang C. 2019. GeAPSO-34 molecular sieves: Synthesis, characterization and methanol-to-olefins performance. Catal Commun. 123:38–43. doi:10.1016/j.catcom.2019.02.007
   Web of Science ®Google Scholar
• Hu Z, Zhang H, Wang L, Zhang H, Zhang Y, Xu H, Shen W, Tang Y. 2014. Highly stable boron-modified hierarchical nanocrystalline ZSM-5 zeolite for the methanol to propylene reaction. Catal Sci Technol. 4(9):2891–2895. doi:10.1039/C4CY00376D
   Web of Science ®Google Scholar
• Hwang A, Johnson BA, Bhan A. 2019. Mechanistic study of methylbenzene dealkylation in methanol-to-olefins catalysis on HSAPO-34. J Catal. 369:86–94. doi:10.1016/j.jcat.2018.10.022
   Web of Science ®Google Scholar
• Ilias S, Bhan A. 2012. Tuning the selectivity of methanol-to-hydrocarbons conversion on H-ZSM-5 by co-processing olefin or aromatic compounds. J Catal. 290:186–192. doi:10.1016/j.jcat.2012.03.016
   Web of Science ®Google Scholar
• Ilias S, Khare R, Malek A, Bhan A. 2013. A descriptor for the relative propagation of the aromatic-and olefin-based cycles in methanol-to-hydrocarbons conversion on H-ZSM-5. J Catal. 303:135–140. doi:10.1016/j.jcat.2013.03.021
   Web of Science ®Google Scholar
• Ivanova S, Lebrun C, Vanhaecke E, Pham-Huu C, Louis B. 2009. Influence of the zeolite synthesis route on its catalytic properties in the methanol to olefin reaction. J Catal. 265(1):1–7. doi:10.1016/j.jcat.2009.03.016
   Web of Science ®Google Scholar
• Izadkhah B, Nabavi SR, Niaei A, Salari D, Mahmuodi Badiki T, Çaylak N. 2012. Design and optimization of Bi-metallic Ag-ZSM5 catalysts for catalytic oxidation of volatile organic compounds. J Ind Eng Chem. 18(6):2083–2091. doi:10.1016/j.jiec.2012.06.002
   Web of Science ®Google Scholar
• Jang H-G, Min H-K, Hong SB, Seo G. 2013. Tetramethylbenzenium radical cations as major active intermediates of methanol-to-olefin conversions over phosphorous-modified HZSM-5 zeolites. J Catal. 299:240–248. doi:10.1016/j.jcat.2012.12.014
   Web of Science ®Google Scholar
• Jiao Y, Fan X, Perdjon M, Yang Z, Zhang J. 2017. Vapor-phase transport (VPT) modification of ZSM-5/SiC foam catalyst using TPAOH vapor to improve the methanol-to-propylene (MTP) reaction. Appl Catal, A. 545:104–112. doi:10.1016/j.apcata.2017.07.036
   Web of Science ®Google Scholar
• Jiao Y, Xu S, Jiang C, Perdjon M, Fan X, Zhang J. 2018. MFI zeolite coating with intrazeolitic aluminum (acidic) gradient supported on SiC foams to improve the methanol-to-propylene (MTP) reaction. Appl Catal, A. 559:1–9. doi:10.1016/j.apcata.2018.04.006
   Web of Science ®Google Scholar
• Jin Y, Asaoka S, Zhang S, Li P, Zhao S. 2013. Reexamination on transition-metal substituted MFI zeolites for catalytic conversion of methanol into light olefins. Fuel Process Technol. 115:34–41. doi:10.1016/j.fuproc.2013.03.047
   Web of Science ®Google Scholar
• Kaarsholm M, Joensen F, Nerlov J, Cenni R, Chaouki J, Patience GS. 2007. Phosphorous modified ZSM-5: Deactivation and product distribution for MTO. Chem Eng Sci. 62(18-20):5527–5532. doi:10.1016/j.ces.2006.12.076
   Web of Science ®Google Scholar
• Kaarsholm M, Rafii B, Joensen F, Cenni R, Chaouki J, Patience GS. 2010. Kinetic modeling of methanol-to-olefin reaction over ZSM-5 in fluid bed. Ind Eng Chem Res. 49(1):29–38. doi:10.1021/ie900341t
   Web of Science ®Google Scholar
• Kaeding WW, Butter SA. 1975. Conversion of methanol and dimethyl ether. Google Patents.
   Google Scholar
• Kazemi A, Beheshti M, et al. 2017. Influence of recycle streams of C5/C6 and C4 hydrocarbon cuts on the performance of methanol to propylene (PVM) reactors. Chem Engin Sci 172:385–394.
   Google Scholar
• Keil FJ. 1999. Methanol-to-hydrocarbons: process technology. Microporous Mesoporous Mater. 29(1-2):49–66. doi:10.1016/S1387-1811(98)00320-5
   Web of Science ®Google Scholar
• Khaledi K, Haghighi M, Sadeghpour P. 2017. On the catalytic properties and performance of core-shell ZSM-5@ MnO nanocatalyst used in conversion of methanol to light olefins. Microporous Mesoporous Mater. 246:51–61. doi:10.1016/j.micromeso.2017.03.022
   Web of Science ®Google Scholar
• Khanmohammadi M, Amani S, Garmarudi AB, Niaei A. 2016. Methanol-to-propylene process: perspective of the most important catalysts and their behavior. Chin J Catal. 37(3):325–339. doi:10.1016/S1872-2067(15)61031-2
   Web of Science ®Google Scholar
• Kim M, Chae H-J, Kim T-W, Jeong K-E, Kim C-U, Jeong S-Y. 2011. Attrition resistance and catalytic performance of spray-dried SAPO-34 catalyst for MTO process: Effect of catalyst phase and acidic solution. J Ind Eng Chem. 17(3):621–627. doi:10.1016/j.jiec.2011.05.009
   Web of Science ®Google Scholar
• Kim J, Choi M, Ryoo R. 2010. Effect of mesoporosity against the deactivation of MFI zeolite catalyst during the methanol-to-hydrocarbon conversion process. J Catal. 269(1):219–228. doi:10.1016/j.jcat.2009.11.009
   Web of Science ®Google Scholar
• Kim Y, Kim J-C, Jo C, Kim T-W, Kim C-U, Jeong S-Y, Chae H-J. 2016. Structural and physicochemical effects of MFI zeolite nanosheets for the selective synthesis of propylene from methanol. Microporous Mesoporous Mater. 222:1–8. doi:10.1016/j.micromeso.2015.09.056
   Web of Science ®Google Scholar
• Kim J, Kim W, Seo Y, Kim J-C, Ryoo R. 2013. n-Heptane hydroisomerization over Pt/MFI zeolite nanosheets: Effects of zeolite crystal thickness and platinum location. J Catal. 301:187–197. doi:10.1016/j.jcat.2013.02.015
   Web of Science ®Google Scholar
• Kim S-S, Shah J, Pinnavaia TJ. 2003. Colloid-imprinted carbons as templates for the nanocasting synthesis of mesoporous ZSM-5 zeolite. Chem Mater. 15(8):1664–1668. doi:10.1021/cm021762r
   Web of Science ®Google Scholar
• Koempel H, Liebner W. 2007. Lurgi's Methanol To Propylene (MTP®) Report on a successful commercialisation. Stud Surf Sci Catal. 167:261–267.
   Google Scholar
• Lee S-G, Kim H-S, Kim Y-H, Kang E-J, Lee D-H, Park C-S. 2014. Dimethyl ether conversion to light olefins over the SAPO-34/ZrO 2 composite catalysts with high lifetime. J Ind Eng Chem. 20(1):61–67. doi:10.1016/j.jiec.2013.04.026
   Web of Science ®Google Scholar
• Lee S-U, Lee Y-J, Kim J-R, Jeong K-E, Jeong S-Y. 2019. Cobalt-isomorphous substituted SAPO-34 via milling and recrystallization for enhanced catalytic lifetime toward methanol-to-olefin reaction. J Ind Eng Chem. 79:443–451. doi:10.1016/j.jiec.2019.07.020
   Web of Science ®Google Scholar
• Lesthaeghe D, Van der Mynsbrugge J, Vandichel M, Waroquier M, Van Speybroeck V. 2011. Full theoretical cycle for both ethene and propene formation during methanol‐to‐olefin conversion in H‐ZSM‐5. ChemCatChem. 3(1):208–212. doi:10.1002/cctc.201000286
   Web of Science ®Google Scholar
• Lesthaeghe D, Van Speybroeck V, Marin GB, Waroquier M. 2007. The rise and fall of direct mechanisms in methanol-to-olefin catalysis: An overview of theoretical contributions. Ind Eng Chem Res. 46(26):8832–8838. doi:10.1021/ie0613974
   Web of Science ®Google Scholar
• Li Z. 2014. New micro and mesoporous materials for the reaction of methanol to olefins. [Tesis doctoral no publicada]. Universitat Politècnica de València. doi:10.4995/Thesis/10251/44229
   Google Scholar
• Liang T, Chen J, Qin Z, Li J, Wang P, Wang S, Wang G, Dong M, Fan W, Wang J. 2016. Conversion of methanol to olefins over H-ZSM-5 zeolite: reaction pathway is related to the framework aluminum siting. ACS Catal. 6(11):7311–7325. doi:10.1021/acscatal.6b01771
   Web of Science ®Google Scholar
• Li X-G, Huang X, Zhang Y-L, Li H, Xiao W-D, Wei Z. 2020. Effect of n-butanol cofeeding on the deactivation of methanol to olefin conversion over high-silica HZSM-5: A mechanism and kinetic study. Chem Eng Sci. 226:115859. doi:10.1016/j.ces.2020.115859
   Web of Science ®Google Scholar
• Li S, Li J, Dong M, Fan S, Zhao T, Wang J, Fan W. 2019. Strategies to control zeolite particle morphology. Chem Soc Rev. 48(3):885–907. doi:10.1039/c8cs00774h
   PubMed Web of Science ®Google Scholar
• Li J, Liu M, Guo X, Dai C, Song C. 2018. Fluoride-mediated nano-sized high-silica ZSM-5 as an ultrastable catalyst for methanol conversion to propylene. J Energy Chem. 27(4):1225–1230. doi:10.1016/j.jechem.2017.08.018
   Web of Science ®Google Scholar
• Li J, Liu M, Guo X, Dai C, Xu S, Wei Y, Liu Z, Song C. 2018. In situ aluminum migration into zeolite framework during methanol-to-propylene reaction: An innovation to design superior catalysts. Ind Eng Chem Res. 57(24):8190–8199. doi:10.1021/acs.iecr.8b00513
   Web of Science ®Google Scholar
• Li J, Ma H, Chen Y, Xu Z, Li C, Ying W. 2018. Conversion of methanol to propylene over hierarchical HZSM-5: the effect of Al spatial distribution. Chem Commun (Camb). 54(47):6032–6035. doi:10.1039/c8cc02042f
   PubMed Web of Science ®Google Scholar
• Liu J, Zhang C, Shen Z, Hua W, Tang Y, Shen W, Yue Y, Xu H. 2009. Methanol to propylene: Effect of phosphorus on a high silica HZSM-5 catalyst. Catal Commun. 10(11):1506–1509. doi:10.1016/j.catcom.2009.04.004
   Web of Science ®Google Scholar
• Li J, Wei Y, Chen J, Tian P, Su X, Xu S, Qi Y, Wang Q, Zhou Y, He Y, et al. 2012. Observation of heptamethylbenzenium cation over SAPO-type molecular sieve DNL-6 under real MTO conversion conditions. J Am Chem Soc. 134(2):836–839. doi:10.1021/ja209950x
   PubMed Web of Science ®Google Scholar
• Li J, Wei Y, Chen J, Xu S, Tian P, Yang X, Li B, Wang J, Liu Z. 2015. Cavity controls the selectivity: insights of confinement effects on MTO reaction. ACS Catal. 5(2):661–665. doi:10.1021/cs501669k
   Web of Science ®Google Scholar
• Li J, Wei Y, Liu G, Qi Y, Tian P, Li B, He Y, Liu Z. 2011. Comparative study of MTO conversion over SAPO-34, H-ZSM-5 and H-ZSM-22: Correlating catalytic performance and reaction mechanism to zeolite topology. Catal Today. 171(1):221–228. doi:10.1016/j.cattod.2011.02.027
   Web of Science ®Google Scholar
• Li J, Wei Y, Qi Y, Tian P, Li B, He Y, Chang F, Sun X, Liu Z. 2011. Conversion of methanol over H-ZSM-22: The reaction mechanism and deactivation. Catal Today. 164(1):288–292. doi:10.1016/j.cattod.2010.10.095
   Web of Science ®Google Scholar
• Li D, Xing B, Wang B, Li R. 2020. Activity and selectivity of methanol-to-olefin conversion over Zr-modified H-SAPO-34/H-ZSM-5 zeolites-A theoretical study. Fuel Process Technol. 199:106302. doi:10.1016/j.fuproc.2019.106302
   Web of Science ®Google Scholar
• Losch P, Boltz M, Louis B, Chavan S, Olsbye U. 2015. Catalyst optimization for enhanced propylene formation in the methanol-to-olefins reaction. CR Chim. 18(3):330–335. doi:10.1016/j.crci.2014.06.007
   Web of Science ®Google Scholar
• Lucrédio AF, Jerkiewicz G, Assaf EM. 2008. Cobalt catalysts promoted with cerium and lanthanum applied to partial oxidation of methane reactions. Appl Catal, B. 84(1-2):106–111. doi:10.1016/j.apcatb.2008.03.008
   Web of Science ®Google Scholar
• Ma M, Zhao X, Wang X, Gong F, Yuan F, Li Z, Zhu Y. 2020. Synthesis of small-sized SAPO-34 assisted by pluronic F127 nonionic surfactant and its catalytic performance for methanol to olefins (MTO). Catal Commun. 133:105839. doi:10.1016/j.catcom.2019.105839
   Web of Science ®Google Scholar
• Machoke AG, Knoke IY, Lopez-Orozco S, Schmiele M, Selvam T, Marthala VRR, Spiecker E, Unruh T, Hartmann M, Schwieger W. 2014. Synthesis of multilamellar MFI-type zeolites under static conditions: The role of gel composition on their properties. Microporous Mesoporous Mater. 190:324–333. doi:10.1016/j.micromeso.2014.02.026
   Web of Science ®Google Scholar
• Mei C, Wen P, Liu Z, Liu H, Wang Y, Yang W, Xie Z, Hua W, Gao Z. 2008. Selective production of propylene from methanol: Mesoporosity development in high silica HZSM-5. J Catal. 258(1):243–249. doi:10.1016/j.jcat.2008.06.019
   Web of Science ®Google Scholar
• Meng L, Mezari B, Goesten MG, Hensen EJM. 2017. One-step synthesis of hierarchical ZSM-5 using cetyltrimethylammonium as mesoporogen and structure-directing agent. Chem Mater. 29(9):4091–4096. doi:10.1021/acs.chemmater.7b00913
   PubMed Web of Science ®Google Scholar
• Mier D, Aguayo AT, Gayubo AG, Olazar M, Bilbao J. 2010. Synergies in the production of olefins by combined cracking of n-butane and methanol on a HZSM-5 zeolite catalyst. Chem Engin J. 160(2):760–769. doi:10.1016/j.cej.2010.04.016
   Web of Science ®Google Scholar
• Mihail R, Straja S, Maria G, Musca G, Pop G. 1983. A kinetic model for methanol conversion to hydrocarbons. Chem Eng Sci. 38(9):1581–1591. doi:10.1016/0009-2509(83)80094-3
   Web of Science ®Google Scholar
• Mirza K, Ghadiri M, Haghighi M, Afghan A. 2018. Hydrothermal synthesize of modified Fe, Ag and K-SAPO-34 nanostructured catalysts used in methanol conversion to light olefins. Microporous Mesoporous Mater. 260:155–165. doi:10.1016/j.micromeso.2017.10.045
   Web of Science ®Google Scholar
• Mol J. 2004. Industrial applications of olefin metathesis. J Mol Catal A: Chem. 213(1):39–45. doi:10.1016/j.molcata.2003.10.049
   Web of Science ®Google Scholar
• Mole T, Bett G, et al. 1983. Conversion of methanol to hydrocarbons over ZSM-5 zeolite: An examination of the role of aromatic hydrocarbons using 13carbon-and deuterium-labeled feeds. J Catal. 84(2):435–445. doi:10.1016/0021-9517(83)90014-3
   Web of Science ®Google Scholar
• Mole T, Whiteside JA, et al. 1983. Aromatic co-catalysis of methanol conversion over zeolite catalysts. J Catal. 82(2):261–266. doi:10.1016/0021-9517(83)90192-6
   Web of Science ®Google Scholar
• Na K, Choi M, Park W, Sakamoto Y, Terasaki O, Ryoo R. 2010. Pillared MFI zeolite nanosheets of a single-unit-cell thickness. J Am Chem Soc. 132(12):4169–4177. doi:10.1021/ja908382n
   PubMed Web of Science ®Google Scholar
• Na K, Choi M, Ryoo R. 2013. Recent advances in the synthesis of hierarchically nanoporous zeolites. Microporous Mesoporous Mater. 166:3–19. doi:10.1016/j.micromeso.2012.03.054
   Web of Science ®Google Scholar
• Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger RJ, Chmelka BF, Ryoo R. 2011. Directing zeolite structures into hierarchically nanoporous architectures. Science. 333(6040):328–332. doi:10.1126/science.1204452
   PubMed Web of Science ®Google Scholar
• Nakagawa K, Yasumura Y, Thongprachan N, Sano N. 2011. Freeze-dried solid foams prepared from carbon nanotube aqueous suspension: Application to gas diffusion layers of a proton exchange membrane fuel cell. Chem Eng Process. 50(1):22–30. doi:10.1016/j.cep.2010.10.010
   Web of Science ®Google Scholar
• Nesterenko N, Aguilhon J, et al. 2016. Methanol to olefins: An insight into reaction pathways and products formation. Zeolites and Zeolite-Like Materials, Elsevier: 1:189–263. doi:10.1016/B978-0-444-63506-8.00006-9
   Google Scholar
• Olsbye U, Bjørgen M, Svelle S, Lillerud K-P, Kolboe S. 2005. Mechanistic insight into the methanol-to-hydrocarbons reaction. Catal Today. 106(1-4):108–111. doi:10.1016/j.cattod.2005.07.135
   Web of Science ®Google Scholar
• Olsbye U, Svelle S, Bjørgen M, Beato P, Janssens TVW, Joensen F, Bordiga S, Lillerud KP. 2012. Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity. Angew Chem Int Ed Engl. 51(24):5810–5831. doi:10.1002/anie.201103657
   PubMed Web of Science ®Google Scholar
• Ono Y, Mori T. 1981. Mechanism of methanol conversion into hydrocarbons over ZSM-5 zeolite. J Chem Soc, Faraday Trans 1. 77(9):2209–2221. doi:10.1039/f19817702209
   Google Scholar
• Pajaie HS, Taghizadeh M. 2015. Optimization of nano-sized SAPO-34 synthesis in methanol-to-olefin reaction by response surface methodology. J Ind Eng Chem. 24:59–70. doi:10.1016/j.jiec.2014.09.009
   Web of Science ®Google Scholar
• Panahi PN, Salari D, Niaei A, Mousavi SM. 2013. NO reduction over nanostructure M-Cu/ZSM-5 (M: Cr, Mn, Co and Fe) bimetallic catalysts and optimization of catalyst preparation by RSM. J Ind Eng Chem. 19(6):1793–1799. doi:10.1016/j.jiec.2013.02.022
   Web of Science ®Google Scholar
• Papari S, Mohammadrezaei A, Asadi M, Golhosseini R, Naderifar A. 2011. Comparison of two methods of iridium impregnation into HZSM-5 in the methanol to propylene reaction. Catal Commun. 16(1):150–154. doi:10.1016/j.catcom.2011.09.024
   Web of Science ®Google Scholar
• Park T-Y, Froment GF. 2001. Kinetic modeling of the methanol to olefins process. 1. Model formulation. Ind Eng Chem Res. 40(20):4172–4186. doi:10.1021/ie0008530
   Web of Science ®Google Scholar
• Park W, Yu D, Na K, Jelfs KE, Slater B, Sakamoto Y, Ryoo R. 2011. Hierarchically structure-directing effect of multi-ammonium surfactants for the generation of MFI zeolite nanosheets. Chem Mater. 23(23):5131–5137. doi:10.1021/cm201709q
   Web of Science ®Google Scholar
• Parlett CMA, Wilson K, Lee AF. 2013. Hierarchical porous materials: catalytic applications. Chem Soc Rev. 42(9):3876–3893. doi:10.1039/c2cs35378d
   PubMed Web of Science ®Google Scholar
• Peng S, Gao M, Li H, Yang M, Ye M, Liu Z. 2020. Control of surface barriers in mass transfer to modulate methanol‐to‐olefins reaction over SAPO‐34 Zeolites. Angew Chem. 132(49):22129–22132. doi:10.1002/ange.202009230
   Google Scholar
• Pérez-Ramírez J, Abelló S, Bonilla A, Groen JC. 2009. Tailored mesoporosity development in zeolite crystals by partial detemplation and desilication. Adv Funct Mater. 19(1):164–172. doi:10.1002/adfm.200800871
   Web of Science ®Google Scholar
• Pérez-Uriarte P, Ateka A, Aguayo AT, Gayubo AG, Bilbao J. 2016. Kinetic model for the reaction of DME to olefins over a HZSM-5 zeolite catalyst. Chem Engin J. 302:801–810. doi:10.1016/j.cej.2016.05.096
   Web of Science ®Google Scholar
• Primo A, Garcia H. 2014. Zeolites as catalysts in oil refining. Chem Soc Rev. 43(22):7548–7561. doi:10.1039/c3cs60394f
   PubMed Web of Science ®Google Scholar
• Prinz D, Riekert L. 1988. Formation of ethene and propene from methanol on zeolite ZSM-5: I. Investigation of rate and selectivity in a batch reactor. Appl Catal. 37:139–154. doi:10.1016/S0166-9834(00)80757-5
   Google Scholar
• Qi G, Xie Z, Yang W, Zhong S, Liu H, Zhang C, Chen Q. 2007. Behaviors of coke deposition on SAPO-34 catalyst during methanol conversion to light olefins. Fuel Process Technol. 88(5):437–441. doi:10.1016/j.fuproc.2006.11.008
   Web of Science ®Google Scholar
• Rahimi K, Towfighi J, Sedighi M, Masoumi S, Kooshki Z. 2016. The effects of SiO2/Al2O3 and H2O/Al2O3 molar ratios on SAPO-34 catalysts in methanol to olefins (MTO) process using experimental design. J Ind Eng Chem. 35:123–131. doi:10.1016/j.jiec.2015.12.015
   Web of Science ®Google Scholar
• Rahmani M, Taghizadeh M. 2017. Synthesis optimization of mesoporous ZSM-5 through desilication-reassembly in the methanol-to-propylene reaction. Reac Kinet Mech Cat. 122(1):409–432. doi:10.1007/s11144-017-1204-0
   Web of Science ®Google Scholar
• Roohollahi G, Kazemeini M, Mohammadrezaee A, Golhosseini R. 2013. The joint reaction of methanol and i-butane over the HZSM-5 zeolite. J Ind Eng Chem. 19(3):915–919. doi:10.1016/j.jiec.2012.10.032
   Web of Science ®Google Scholar
• Rostami RB, Ghavipour M, Di Z, Wang Y, Behbahani RM. 2015. Study of coke deposition phenomena on the SAPO_34 catalyst and its effects on light olefin selectivity during the methanol to olefin reaction. RSC Adv. 5(100):81965–81980. doi:10.1039/C5RA11288E
   Web of Science ®Google Scholar
• Rostamizadeh M, Taeb A. 2015. Highly selective Me-ZSM-5 catalyst for methanol to propylene (MTP). J Ind Eng Chem. 27:297–306. doi:10.1016/j.jiec.2015.01.004
   Web of Science ®Google Scholar
• Rostamizadeh M, Yaripour F. 2016. Bifunctional and bimetallic Fe/ZSM-5 nanocatalysts for methanol to olefin reaction. Fuel. 181:537–546. doi:10.1016/j.fuel.2016.05.019
   Web of Science ®Google Scholar
• Rostamizadeh M, Yaripour F, Hazrati H. 2018. Ni-doped high silica HZSM-5 zeolite (Si/Al= 200) nanocatalyst for the selective production of olefins from methanol. J Anal Appl Pyrolysis. 132:1–10. doi:10.1016/j.jaap.2018.04.003
   Web of Science ®Google Scholar
• Ryoo R, Park I-S, Jun S, Lee CW, Kruk M, Jaroniec M. 2001. Synthesis of ordered and disordered silicas with uniform pores on the border between micropore and mesopore regions using short double-chain surfactants. J Am Chem Soc. 123(8):1650–1657. doi:10.1021/ja0038326
   PubMed Web of Science ®Google Scholar
• Sadeghpour P, Haghighi M. 2015. DEA/TEAOH templated synthesis and characterization of nanostructured NiAPSO-34 particles: Effect of single and mixed templates on catalyst properties and performance in the methanol to olefin reaction. Particuology. 19:69–81. doi:10.1016/j.partic.2014.04.012
   Web of Science ®Google Scholar
• Sadeghpour P, Haghighi M. 2018. High-temperature and short-time hydrothermal fabrication of nanostructured ZSM-5 catalyst with suitable pore geometry and strong intrinsic acidity used in methanol to light olefins conversion. Adv Powder Technol. 29(5):1175–1188. doi:10.1016/j.apt.2018.02.009
   Web of Science ®Google Scholar
• Sadeghpour P, Haghighi M, Khaledi K. 2018. High-temperature efficient isomorphous substitution of boron into ZSM-5 nanostructure for selective and stable production of ethylene and propylene from methanol. Mater Chem Phys. 217:133–150. doi:10.1016/j.matchemphys.2018.06.048
   Web of Science ®Google Scholar
• Salmasi M, Fatemi S, Taheri Najafabadi A. 2011. Improvement of light olefins selectivity and catalyst lifetime in MTO reaction; using Ni and Mg-modified SAPO-34 synthesized by combination of two templates. J Ind Eng Chem. 17(4):755–761. doi:10.1016/j.jiec.2011.05.031
   Web of Science ®Google Scholar
• Sang S, Chang F, Liu Z, He C, He Y, Xu L. 2004. Difference of ZSM-5 zeolites synthesized with various templates. Catal Today. 93–95:729–734. doi:10.1016/j.cattod.2004.06.091
   Web of Science ®Google Scholar
• Santhosh Kumar M, Chen D, Holmen A, Walmsley JC. 2009. Dehydrogenation of propane over Pt-SBA-15 and Pt-Sn-SBA-15: Effect of Sn on the dispersion of Pt and catalytic behavior. Catal Today. 142(1-2):17–23. doi:10.1016/j.cattod.2009.01.002
   Web of Science ®Google Scholar
• Sassi A, Wildman MA, Ahn HJ, Prasad P, Nicholas JB, Haw JF. 2002. Methylbenzene chemistry on zeolite HBeta: Multiple insights into methanol-to-olefin catalysis. J Phys Chem B. 106(9):2294–2303. doi:10.1021/jp013392k
   Web of Science ®Google Scholar
• Sastre G. 2016. Confinement effects in methanol to olefins catalysed by zeolites: A computational review. Front Chem Sci Eng. 10(1):76–89. doi:10.1007/s11705-016-1557-3
   Web of Science ®Google Scholar
• Schick J, Daou TJ, Caullet P, Paillaud J-L, Patarin J, Mangold-Callarec C. 2011. Surfactant-modified MFI nanosheets: a high capacity anion-exchanger. Chem Commun (Camb). 47(3):902–904. doi:10.1039/c0cc03604h
   PubMed Web of Science ®Google Scholar
• Schipper P, Krambeck F. 1986. A reactor design simulation with reversible and irreversible catalyst deactivation. Chem Eng Sci. 41(4):1013–1019. doi:10.1016/0009-2509(86)87187-1
   Web of Science ®Google Scholar
• Schmidt I, Boisen A, Gustavsson E, Ståhl K, Pehrson S, Dahl S, Carlsson A, Jacobsen CJH. 2001. Carbon nanotube templated growth of mesoporous zeolite single crystals. Chem Mater. 13(12):4416–4418. doi:10.1021/cm011206h
   Web of Science ®Google Scholar
• Schwarz S, Kojima M, O'Connor CT. 1991. Effect of tetraalkylammonium, alcohol and amine templates on the synthesis and high pressure propene oligomerisation activity of ZSM-type zeolites. Appl Catal. 73(2):313–330. doi:10.1016/0166-9834(91)85144-K
   Google Scholar
• Sedran U, Mahay A, De Lasa HI. 1990. Modelling methanol conversion to hydrocarbons: revision and testing of a simple kinetic model. Chem Eng Sci. 45(5):1161–1165. doi:10.1016/0009-2509(90)87109-6
   Web of Science ®Google Scholar
• Serrano DP, Aguado J, Escola JM, Rodríguez JM, Peral Á. 2006. Hierarchical zeolites with enhanced textural and catalytic properties synthesized from organofunctionalized seeds. Chem Mater. 18(10):2462–2464. doi:10.1021/cm060080r
   Web of Science ®Google Scholar
• Serrano DP, Escola JM, Pizarro P. 2013. Synthesis strategies in the search for hierarchical zeolites. Chem Soc Rev. 42(9):4004–4035. doi:10.1039/c2cs35330j
   PubMed Web of Science ®Google Scholar
• Sheldon RA. 2011. Utilisation of biomass for sustainable fuels and chemicals: Molecules, methods and metrics. Catal Today. 167(1):3–13. doi:10.1016/j.cattod.2010.10.100
   Web of Science ®Google Scholar
• Shetti V, Kim J, Srivastava R, Choi M, Ryoo R. 2008. Assessment of the mesopore wall catalytic activities of MFI zeolite with mesoporous/microporous hierarchical structures. J Catal. 254(2):296–303. doi:10.1016/j.jcat.2008.01.006
   Web of Science ®Google Scholar
• Song W, Marcus DM, Fu H, Ehresmann JO, Haw JF. 2002. An oft-studied reaction that may never have been: Direct catalytic conversion of methanol or dimethyl ether to hydrocarbons on the solid acids HZSM-5 or HSAPO-34. J Am Chem Soc. 124(15):3844–3845. doi:10.1021/ja016499u
   PubMed Web of Science ®Google Scholar
• Song W, Nicholas JB, Sassi A, Haw JF. 2002. Synthesis of the heptamethylbenzenium cation in zeolite-β: In situ NMR and theory. Catal Lett. 81(1/2):49–53. doi:10.1023/A:1016003905167
   Web of Science ®Google Scholar
• Song W, Wei Y. 2016. Chemistry of the Methanol to Olefin Conversion. Zeolites in Sustainable Chemistry, Springer: 299–346. Green Chemistry and Sustainable Technology, Springer, Berlin, Heidelberg. doi:10.1007/978-3-662-47395-5_9
   Google Scholar
• Standl S, Kirchberger FM, Kühlewind T, Tonigold M, Sanchez-Sanchez M, Lercher JA, Hinrichsen O. 2020. Single-event kinetic model for methanol-to-olefins (MTO) over ZSM-5: Fundamental kinetics for the olefin co-feed reactivity. Chem Engin J. 402:126023. doi:10.1016/j.cej.2020.126023
   Web of Science ®Google Scholar
• Stöcker M. 1999. Methanol-to-hydrocarbons: catalytic materials and their behavior. Microporous Mesoporous Mater. 29(1–2):3–48. doi:10.1016/S1387-1811(98)00319-9
   Web of Science ®Google Scholar
• Sullivan RF, Egan CJ, Langlois GE, Sieg RP. 1961. A new reaction that occurs in the hydrocracking of certain aromatic hydrocarbons. J Am Chem Soc. 83(5):1156–1160. doi:10.1021/ja01466a036
   Web of Science ®Google Scholar
• Sun C, Du J, Liu J, Yang Y, Ren N, Shen W, Xu H, Tang Y. 2010. A facile route to synthesize endurable mesopore containing ZSM-5 catalyst for methanol to propylene reaction. Chem Commun (Camb). 46(15):2671–2673. doi:10.1039/b925850g
   PubMed Web of Science ®Google Scholar
• Sun C, Wang Y, Chen H, Wang X, Wang C, Zhang X. 2020. Seed-assisted synthesis of hierarchical SAPO-18/34 intergrowth and SAPO-34 zeolites and their catalytic performance for the methanol-to-olefin reaction. Catal Today. 355:188–198. doi:10.1016/j.cattod.2019.04.038
   Web of Science ®Google Scholar
• Sun C, Wang Y, Wang Z, Chen H, Wang X, Li H, Sun L, Fan C, Wang C, Zhang X, et al. 2018. Fabrication of hierarchical ZnSAPO-34 by alkali treatment with improved catalytic performance in the methanol-to-olefin reaction. CR Chim. 21(1):61–70. doi:10.1016/j.crci.2017.11.006
   Web of Science ®Google Scholar
• Sun C, Wang Y, Zhao A, Wang X, Wang C, Zhang X, Wang Z, Zhao J, Zhao T. 2020. Synthesis of nano-sized SAPO-34 with morpholine-treated micrometer-seeds and their catalytic performance in methanol-to-olefin reactions. Appl Catal, A. 589:117314. doi:10.1016/j.apcata.2019.117314
   Web of Science ®Google Scholar
• Suttipat D, Saenluang K, Wannapakdee W, Dugkhuntod P, Ketkaew M, Pornsetmetakul P, Wattanakit C. 2021. Fine-tuning the surface acidity of hierarchical zeolite composites for methanol-to-olefins (MTO) reaction. Fuel. 286:119306. doi:10.1016/j.fuel.2020.119306
   Web of Science ®Google Scholar
• Svelle S, Joensen F, Nerlov J, Olsbye U, Lillerud K-P, Kolboe S, Bjørgen M. 2006. Conversion of methanol into hydrocarbons over zeolite H-ZSM-5: Ethene formation is mechanistically separated from the formation of higher alkenes. J Am Chem Soc. 128(46):14770–14771. doi:10.1021/ja065810a
   PubMed Web of Science ®Google Scholar
• Svelle S, Olsbye U, Joensen F, Bjørgen M. 2007. Conversion of methanol to alkenes over medium-and large-pore acidic zeolites: Steric manipulation of the reaction intermediates governs the ethene/propene product selectivity. J Phys Chem C. 111(49):17981–17984. doi:10.1021/jp077331j
   Web of Science ®Google Scholar
• Takahashi A, Xia W, Wu Q, Furukawa T, Nakamura I, Shimada H, Fujitani T. 2013. Difference between the mechanisms of propylene production from methanol and ethanol over ZSM-5 catalysts. Appl Catal, A. 467:380–385. doi:10.1016/j.apcata.2013.07.064
   Web of Science ®Google Scholar
• Tanaka S, Fukui R, Kosaka A, Nishiyama N. 2020. Development of hierarchical and phosphorous-modified HZSM-5 zeolites by sequential alkaline/acid treatments and their catalytic performances for methanol-to-olefins. Mater Res Bull. 130:110958. doi:10.1016/j.materresbull.2020.110958
   Web of Science ®Google Scholar
• Taniguchi T, Nakasaka Y, Yoneta K, Tago T, Masuda T. 2016. Size-controlled synthesis of metallosilicates with MTW structure and catalytic performance for methanol-to-propylene reaction. Catal Lett. 146(3):666–676. doi:10.1007/s10562-015-1683-4
   Web of Science ®Google Scholar
• Tanizume S, Maehara S, Ishii K, Onoki T, Okuno T, Tawarayama H, Ishikawa S, Nomura M. 2021. Reaction of methanol to olefin using a membrane contactor on a silica substrate. Sep Purif Technol. 254:117647. doi:10.1016/j.seppur.2020.117647
   Web of Science ®Google Scholar
• Tao Y, Kanoh H, Kaneko K. 2003. ZSM-5 monolith of uniform mesoporous channels. J Am Chem Soc. 125(20):6044–6045. doi:10.1021/ja0299405
   PubMed Web of Science ®Google Scholar
• Tian S, Ji S, Lü D, Bai B, Sun Q. 2013. Preparation of modified Ce-SAPO-34 catalysts and their catalytic performances of methanol to olefins. J Energy Chem. 22(4):605–609. doi:10.1016/S2095-4956(13)60079-0
   Web of Science ®Google Scholar
• Tian P, Wei Y, Ye M, Liu Z. 2015. Methanol to olefins (MTO): from fundamentals to commercialization. ACS Catal. 5(3):1922–1938. doi:10.1021/acscatal.5b00007
   Web of Science ®Google Scholar
• Tosheva L, Valtchev VP. 2005. Nanozeolites: synthesis, crystallization mechanism, and applications. Chem Mater. 17(10):2494–2513. doi:10.1021/cm047908z
   Web of Science ®Google Scholar
• Triantafillidis CS, Vlessidis AG, Nalbandian L, Evmiridis NP. 2001. Effect of the degree and type of the dealumination method on the structural, compositional and acidic characteristics of H-ZSM-5 zeolites. Microporous Mesoporous Mater. 47(2–3):369–388. doi:10.1016/S1387-1811(01)00399-7
   Web of Science ®Google Scholar
• Valecillos J, Epelde E, Albo J, Aguayo AT, Bilbao J, Castaño P. 2020. Slowing down the deactivation of H-ZSM-5 zeolite catalyst in the methanol-to-olefin (MTO) reaction by P or Zn modifications. Catal Today. 348:243–256. doi:10.1016/j.cattod.2019.07.059
   Web of Science ®Google Scholar
• Valero-Romero MJ, Márquez-Franco EM, Bedia J, Rodríguez-Mirasol J, Cordero T. 2014. Hierarchical porous carbons by liquid phase impregnation of zeolite templates with lignin solution. Microporous Mesoporous Mater. 196:68–78. doi:10.1016/j.micromeso.2014.04.055
   Web of Science ®Google Scholar
• Valle B, Alonso A, Atutxa A, Gayubo AG, Bilbao J. 2005. Effect of nickel incorporation on the acidity and stability of HZSM-5 zeolite in the MTO process. Catal Today. 106(1–4):118–122. doi:10.1016/j.cattod.2005.07.132
   Web of Science ®Google Scholar
• Védrine JC, Auroux A, et al. 1982. Catalytic and physical properties of phosphorus-modified ZSM-5 zeolite. J Catal. 73(1):147–160.
   Web of Science ®Google Scholar
• Verma D, Kumar R, Rana BS, Sinha AK. 2011. Aviation fuel production from lipids by a single-step route using hierarchical mesoporous zeolites. Energy Environ Sci. 4(5):1667–1671. doi:10.1039/c0ee00744g
   Web of Science ®Google Scholar
• Vinek H, Rumplmayr G, et al. 1989. Catalytic properties of postsynthesis phosphorus-modified H-ZSM5 zeolites. J Catal. 115(2):291–300. doi:10.1016/0021-9517(89)90033-X
   Web of Science ®Google Scholar
• Voltz SE, Wise J. 1976. Development studies on conversion of methanol and related oxygenates to gasoline.: Report, Energy Research and Development Administration. Quarterly Progress Report, May - Jul. 1976 Mobil Research and Development Corp., Paulsboro, NJ.
   Google Scholar
• Wang S, Chen Y, Qin Z, Zhao T-S, Fan S, Dong M, Li J, Fan W, Wang J. 2019. Origin and evolution of the initial hydrocarbon pool intermediates in the transition period for the conversion of methanol to olefins over H-ZSM-5 zeolite. J Catal. 369:382–395. doi:10.1016/j.jcat.2018.11.018
   Web of Science ®Google Scholar
• Wang S, Chen Y, Wei Z, Qin Z, Ma H, Dong M, Li J, Fan W, Wang J. 2015. Polymethylbenzene or alkene cycle? theoretical study on their contribution to the process of methanol to olefins over H-ZSM-5 zeolite. J Phys Chem C. 119(51):28482–28498. doi:10.1021/acs.jpcc.5b10299
   Web of Science ®Google Scholar
• Wang C, Chu Y, Zheng A, Xu J, Wang Q, Gao P, Qi G, Gong Y, Deng F. 2014. New Insight into the hydrocarbon-pool chemistry of the methanol-to-olefins conversion over zeolite H-ZSM-5 from GC-MS, solid-state NMR spectroscopy, and DFT calculations. Chemistry. 20(39):12432–12443. doi:10.1002/chem.201403972
   PubMed Web of Science ®Google Scholar
• Wang S, Li Z, Qin Z, Dong M, Li J, Fan W, Wang J. 2021. Catalytic roles of the acid sites in different pore channels of H-ZSM-5 zeolite for methanol-to-olefins conversion. Chin J Catal. 42(7):1126–1136. doi:10.1016/S1872-2067(20)63732-9
   Web of Science ®Google Scholar
• Wang H, Pinnavaia TJ. 2006. MFI zeolite with small and uniform intracrystal mesopores. Angew Chem Int Ed Engl. 45(45):7603–7606. doi:10.1002/anie.200602595
   PubMed Web of Science ®Google Scholar
• Wang C-M, Wang Y-D, Du Y-J, Yang G, Xie Z-K. 2016. Computational insights into the reaction mechanism of methanol-to-olefins conversion in H-ZSM-5: nature of hydrocarbon pool. Catal Sci Technol. 6(9):3279–3288. doi:10.1039/C5CY01419K
   Web of Science ®Google Scholar
• Wang S, Wang P, Qin Z, Chen Y, Dong M, Li J, Zhang K, Liu P, Wang J, Fan W, et al. 2018. Relation of catalytic performance to the aluminum siting of acidic zeolites in the conversion of methanol to olefins, viewed via a comparison between ZSM-5 and ZSM-11. ACS Catal. 8(6):5485–5505. doi:10.1021/acscatal.8b01054
   Web of Science ®Google Scholar
• Wang C-M, Wang Y-D, Xie Z-K. 2018. Elucidating the dominant reaction mechanism of methanol-to-olefins conversion in H-SAPO-18: A first-principles study. Chin J Catal. 39(7):1272–1279. doi:10.1016/S1872-2067(18)63064-5
   Web of Science ®Google Scholar
• Wang Q, Xu S, Chen J, Wei Y, Li J, Fan D, Yu Z, Qi Y, He Y, Xu S, et al. 2014. Synthesis of mesoporous ZSM-5 catalysts using different mesogenous templates and their application in methanol conversion for enhanced catalyst lifespan. RSC Adv. 4(41):21479–21491. doi:10.1039/C4RA02695K
   Web of Science ®Google Scholar
• Wang L, Zhang Z, Yin C, Shan Z, Xiao F-S. 2010. Hierarchical mesoporous zeolites with controllable mesoporosity templated from cationic polymers. Microporous Mesoporous Mater. 131(1–3):58–67. doi:10.1016/j.micromeso.2009.12.001
   Web of Science ®Google Scholar
• Wei R, Li C, Yang C, Shan H. 2011. Effects of ammonium exchange and Si/Al ratio on the conversion of methanol to propylene over a novel and large partical size ZSM-5. J Nat Gas Chem. 20(3):261–265. doi:10.1016/S1003-9953(10)60198-3
   Google Scholar
• Wen M, Ding J, Wang C, Li Y, Zhao G, Liu Y, Lu Y. 2016. High-performance SS-fiber@ HZSM-5 core–shell catalyst for methanol-to-propylene: A kinetic and modeling study. Microporous Mesoporous Mater. 221:187–196. doi:10.1016/j.micromeso.2015.09.039
   Web of Science ®Google Scholar
• Wen M, Wang X, Han L, Ding J, Sun Y, Liu Y, Lu Y. 2015. Monolithic metal-fiber@ HZSM-5 core–shell catalysts for methanol-to-propylene. Microporous Mesoporous Mater. 206:8–16. doi:10.1016/j.micromeso.2014.12.007
   Web of Science ®Google Scholar
• White RJ, Fischer A, Goebel C, Thomas A. 2014. A sustainable template for mesoporous zeolite synthesis. J Am Chem Soc. 136(7):2715–2718. doi:10.1021/ja411586h
   PubMed Web of Science ®Google Scholar
• Wijnen PWJG, Beelen TPM, de Haan JW, Rummens CPJ, van de Ven LJM, van Santen RA. 1989. Silica gel dissolution in aqueous alkali metal hydroxides studied by 29Si— NMR. J Non-Cryst Solids. 109(1):85–94. doi:10.1016/0022-3093(89)90446-8
   Web of Science ®Google Scholar
• Wilhelm DJ, Simbeck DR, Karp AD, Dickenson RL. 2001. Syngas production for gas-to-liquids applications: technologies, issues and outlook. Fuel Process Technol. 71(1–3):139–148. doi:10.1016/S0378-3820(01)00140-0
   Web of Science ®Google Scholar
• Wu W, Guo W, Xiao W, Luo M. 2011. Dominant reaction pathway for methanol conversion to propene over high silicon H-ZSM-5. Chem Eng Sci. 66(20):4722–4732. doi:10.1016/j.ces.2011.06.036
   Web of Science ®Google Scholar
• Wu X, Xu S, Zhang W, Huang J, Li J, Yu B, Wei Y, Liu Z. 2017. Direct mechanism of the first carbon–carbon bond formation in the methanol‐to‐hydrocarbons process. Angew Chem. 129(31):9167–9171. doi:10.1002/ange.201703902
   Google Scholar
• Xing A, Yuan D, Tian D, Sun Q. 2019. Controlling acidity and external surface morphology of SAPO-34 and its improved performance for methanol to olefins reaction. Microporous Mesoporous Mater. 288:109562. doi:10.1016/j.micromeso.2019.109562
   Web of Science ®Google Scholar
• Xu T, Barich DH, Goguen PW, Song W, Wang Z, Nicholas JB, Haw JF. 1998. Synthesis of a benzenium ion in a zeolite with use of a catalytic flow reactor. J Am Chem Soc. 120(16):4025–4026. doi:10.1021/ja973791m
   Web of Science ®Google Scholar
• Xue Y, Li J, Wang S, Cui X, Dong M, Wang G, Qin Z, Wang J, Fan W. 2018. Co-reaction of methanol with butene over a high-silica H-ZSM-5 catalyst. J Catal. 367:315–325. doi:10.1016/j.jcat.2018.09.008
   Web of Science ®Google Scholar
• Xue Y, Li J, Wang P, Cui X, Zheng H, Niu Y, Dong M, Qin Z, Wang J, Fan W, et al. 2021. Regulating Al distribution of ZSM-5 by Sn incorporation for improving catalytic properties in methanol to olefins. Appl Catal, B. 280:119391. doi:10.1016/j.apcatb.2020.119391
   Web of Science ®Google Scholar
• Xu A, Ma H, Zhang H, Weiyong D, Fang D. 2013. Effect of boron on ZSM-5 catalyst for methanol to propylene conversion. Polish J Chem Technol. 15(4):95–101. doi:10.2478/pjct-2013-0075
   Web of Science ®Google Scholar
• Xu S, Zheng A, Wei Y, Chen J, Li J, Chu Y, Zhang M, Wang Q, Zhou Y, Wang J, et al. 2013. Direct observation of cyclic carbenium ions and their role in the catalytic cycle of the methanol-to-olefin reaction over chabazite zeolites. Angew Chem Int Ed Engl. 52(44):11564–11568. doi:10.1002/anie.201303586
   PubMed Web of Science ®Google Scholar
• Yalcin BK, Ipek B. 2020. Fluoride-free synthesis of mesoporous [Al]-[B]-ZSM-5 using cetyltrimethylammonium bromide and methanol-to-olefin activity with high propene selectivity. Appl Catal, A: 610:117915.
   Web of Science ®Google Scholar
• Yang G, Han J, Huang Y, Chen X, Valtchev V. 2020. Busting the efficiency of SAPO-34 catalysts for the MTO conversion by post-synthesis methods. Chin J Chem Eng. 28(8):2022–2027. doi:10.1016/j.cjche.2020.05.028
   Web of Science ®Google Scholar
• Yang Y, Sun C, Du J, Yue Y, Hua W, Zhang C, Shen W, Xu H. 2012. The synthesis of endurable B–Al–ZSM-5 catalysts with tunable acidity for methanol to propylene reaction. Catal Commun. 24:44–47. doi:10.1016/j.catcom.2012.03.013
   Web of Science ®Google Scholar
• Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A. 2015. Conventional hydrothermal synthesis of nanostructured H-ZSM-5 catalysts using various templates for light olefins production from methanol. J Nat Gas Sci Eng. 22:260–269. doi:10.1016/j.jngse.2014.12.001
   Web of Science ®Google Scholar
• Yarulina I, Chowdhury AD, Meirer F, Weckhuysen BM, Gascon J. 2018. Recent trends and fundamental insights in the methanol-to-hydrocarbons process. Nat Catal. 1(6):398–411. doi:10.1038/s41929-018-0078-5
   Web of Science ®Google Scholar
• Yarulina I, De Wispelaere K, Bailleul S, Goetze J, Radersma M, Abou-Hamad E, Vollmer I, Goesten M, Mezari B, Hensen EJM, et al. 2018. Structure-performance descriptors and the role of Lewis acidity in the methanol-to-propylene process. Nat Chem. 10(8):804–812. doi:10.1038/s41557-018-0081-0
   PubMed Web of Science ®Google Scholar
• Yu Q, Meng X, Liu J, Li C, Cui Q. 2013. A fast organic template-free, ZSM-11 seed-assisted synthesis of ZSM-5 with good performance in methanol-to-olefin. Microporous Mesoporous Mater. 181:192–200. doi:10.1016/j.micromeso.2013.07.034
   Web of Science ®Google Scholar
• Zang K, Zhang W, Huang J, Feng P, Ding J. 2019. First molecule with carbon–carbon bond in methanol-to-olefins process. Chem Phys Lett. 737:136844. doi:10.1016/j.cplett.2019.136844
   Web of Science ®Google Scholar
• Zhang W, Chen J, Xu S, Chu Y, Wei Y, Zhi Y, Huang J, Zheng A, Wu X, Meng X, et al. 2018. Methanol to olefins reaction over cavity-type zeolite: cavity controls the critical intermediates and product selectivity. ACS Catal. 8(12):10950–10963. doi:10.1021/acscatal.8b02164
   Web of Science ®Google Scholar
• Zhang C, Chen H, Zhang X, Wang Q. 2017. TPABr-grafted MWCNT as bifunctional template to synthesize hierarchical ZSM-5 zeolite. Mater Lett. 197:111–114. doi:10.1016/j.matlet.2017.03.085
   Web of Science ®Google Scholar
• Zhang S, Gong Y, Zhang L, Liu Y, Dou T, Xu J, Deng F. 2015. Hydrothermal treatment on ZSM-5 extrudates catalyst for methanol to propylene reaction: finely tuning the acidic property. Fuel Process Technol. 129:130–138. doi:10.1016/j.fuproc.2014.09.006
   Web of Science ®Google Scholar
• Zhang Y, Li M, Xing E, Luo Y, Shu X. 2019. Coke evolution on mesoporous ZSM-5 during methanol to propylene reaction. Catal Commun. 119:67–70. doi:10.1016/j.catcom.2018.10.009
   Web of Science ®Google Scholar
• Zhang H, Ning Z, Shang J, Liu HYan, Han SHua, Qu W, Jiang Y, Guo Y. 2017. A durable and highly selective PbO/HZSM-5 catalyst for methanol to propylene (MTP) conversion. Microporous Mesoporous Mater. 248:173–178. doi:10.1016/j.micromeso.2017.04.031
   Web of Science ®Google Scholar
• Zhang K, Ostraat ML. 2016. Innovations in hierarchical zeolite synthesis. Catal Today. 264:3–15. doi:10.1016/j.cattod.2015.08.012
   Web of Science ®Google Scholar
• Zhang C, Wang F, et al. 2020. Numerical exploration of hydrodynamic features in a methanol-to-olefins fluidized bed reactor with two parallel reaction zones. Powder Technol. 372:336–350.
   Web of Science ®Google Scholar
• Zhang L, Wang S, Shi D, Qin Z, Wang P, Wang G, Li J, Dong M, Fan W, Wang J, et al. 2020. Methanol to olefins over H-RUB-13 zeolite: regulation of framework aluminum siting and acid density and their relationship to the catalytic performance. Catal Sci Technol. 10(6):1835–1847. doi:10.1039/C9CY02419K
   Web of Science ®Google Scholar
• Zhang M, Xu S, Li J, Wei Y, Gong Y, Chu Y, Zheng A, Wang J, Zhang W, Wu X, et al. 2016. Methanol to hydrocarbons reaction over Hβ zeolites studied by high resolution solid-state NMR spectroscopy: Carbenium ions formation and reaction mechanism. J Catal. 335:47–57. doi:10.1016/j.jcat.2015.12.007
   Web of Science ®Google Scholar
• Zhang M, Xu S, Wei Y, Li J, Wang J, Zhang W, Gao S, Liu Z. 2016. Changing the balance of the MTO reaction dual-cycle mechanism: Reactions over ZSM-5 with varying contact times. Chin J Catal. 37(8):1413–1422. doi:10.1016/S1872-2067(16)62466-X
   Web of Science ®Google Scholar
• Zhang S, Zhang B, et al. 2010. Ca modified ZSM-5 for high propylene selectivity from methanol. Reaction Kinetics, Mech Catal. 99(2):447–453.
   Web of Science ®Google Scholar
• Zhang W, Zhi Y, Huang J, Wu X, Zeng S, Xu S, Zheng A, Wei Y, Liu Z. 2019. Methanol to olefins reaction route based on methylcyclopentadienes as critical intermediates. ACS Catal. 9(8):7373–7379. doi:10.1021/acscatal.9b02487
   Web of Science ®Google Scholar
• Zhao X, Hong Y, Wang L, Fan D, Yan N, Liu X, Tian P, Guo X, Liu Z. 2018. External surface modification of as-made ZSM-5 and their catalytic performance in the methanol to propylene reaction. Chin J Catal. 39(8):1418–1426. doi:10.1016/S1872-2067(18)63117-1
   Web of Science ®Google Scholar
• Zhao T-S, Takemoto T, Tsubaki N. 2006. Direct synthesis of propylene and light olefins from dimethyl ether catalyzed by modified H-ZSM-5. Catal Commun. 7(9):647–650. doi:10.1016/j.catcom.2005.11.009
   Web of Science ®Google Scholar
• Zhong J, Han J, Wei Y, Liu Z. 2021. Catalysts and shape selective catalysis in the methanol-to-olefin (MTO) reaction. J Catal. 396:23–31. doi:10.1016/j.jcat.2021.01.027
   Web of Science ®Google Scholar
• Zhong J, Han J, Wei Y, Tian P, Guo X, Song C, Liu Z. 2017. Recent advances of the nano-hierarchical SAPO-34 in the methanol-to-olefin (MTO) reaction and other applications. Catal Sci Technol. 7(21):4905–4923. doi:10.1039/C7CY01466J
   Web of Science ®Google Scholar
• Zhong J, Han J, Wei Y, Xu S, He Y, Zheng Y, Ye M, Guo X, Song C, Liu Z, et al. 2018. Increasing the selectivity to ethylene in the MTO reaction by enhancing diffusion limitation in the shell layer of SAPO-34 catalyst. Chem Commun (Camb). 54(25):3146–3149. doi:10.1039/C7CC09239C
   PubMed Web of Science ®Google Scholar
• Zhou J, Gao M, et al. 2021. Directed transforming of coke to active intermediates in methanol-to-olefins catalyst to boost light olefins selectivity. Nat Commun. 12(1):1–11.
   PubMed Web of Science ®Google Scholar
• Zhou J, Zhi Y, Zhang J, Liu Z, Zhang T, He Y, Zheng A, Ye M, Wei Y, Liu Z, et al. 2019. Presituated “coke”-determined mechanistic route for ethene formation in the methanol-to-olefins process on SAPO-34 catalyst. J Catal. 377:153–162. doi:10.1016/j.jcat.2019.06.014
   Web of Science ®Google Scholar
• Zhuang S, Hu Z, Huang L, Qin F, Huang Z, Sun C, Shen W, Xu H. 2018. Synthesis of ZSM-5 catalysts with tunable mesoporosity by ultrasound-assisted method: A highly stable catalyst for methanol to propylene. Catal Commun. 114:28–32. doi:10.1016/j.catcom.2018.06.001
   Web of Science ®Google Scholar
• Zhu K, Egeblad K, Christensen CH. 2007. Mesoporous carbon prepared from carbohydrate as hard template for hierarchical zeolites. Eur J Inorg Chem. 2007(25):3955–3960. doi:10.1002/ejic.200700218
   Web of Science ®Google Scholar
• Zhu X, Goesten MG, Koekkoek AJJ, Mezari B, Kosinov N, Filonenko G, Friedrich H, Rohling R, Szyja BM, Gascon J, et al. 2016. Establishing hierarchy: the chain of events leading to the formation of silicalite-1 nanosheets. Chem Sci. 7(10):6506–6513. doi:10.1039/C6SC01295G
   PubMed Web of Science ®Google Scholar
• Zhu Y, Hua Z, Zhou J, Wang L, Zhao J, Gong Y, Wu W, Ruan M, Shi J. 2011. Hierarchical mesoporous zeolites: Direct self‐assembly synthesis in a conventional surfactant solution by kinetic control over the zeolite seed formation. Chem Eur J. 17(51):14618–14627. doi:10.1002/chem.201101401
   PubMed Web of Science ®Google Scholar
• Zhu Q, Kondo JN, Setoyama T, Yamaguchi M, Domen K, Tatsumi T. 2008. Activation of hydrocarbons on acidic zeolites: superior selectivity of methylation of ethene with methanol to propene on weakly acidic catalysts. Chem Commun. 1(41):5164–5166. doi:10.1039/b809718f
   PubMed Web of Science ®Google Scholar
• Zhu Q, Kondo JN, Tatsumi T. 2018. Co-reaction of methanol and ethylene over MFI and CHA zeolitic catalysts. Microporous Mesoporous Mater. 255:174–184. doi:10.1016/j.micromeso.2017.07.030
   Web of Science ®Google Scholar