Publication Cover
Phase Transitions
A Multinational Journal
Volume 87, 2014 - Issue 1
80
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior

, , , , , , & show all
Pages 71-84 | Received 13 Dec 2012, Accepted 17 Mar 2013, Published online: 23 May 2013

References

  • Kirpichnikova LF, Shuvalov LA, Ivanov NR, Prasolov BN, Andreyev EF. Ferroelectricity in the dimethylaminaluminiumsulphate crystal. Ferroelectrics. 1989;96:313–317.
  • Behera JN, Gopalkrishnan KV, Rao CNR. Synthesis, structure, and magnetic properties of amine-templated open-framework nickel(II) sulfates. Inorg Chem. 2004;43:2636–2642.
  • Yuan Y-P, Wang R-Y, Kong D-Y, Mao J-G, Clearfield A. [H2en]2{La2M(SO4)6(H2O)2} (M ¼ Co, Ni): First organically templated 3d–4f mixed metal sulfates. J Solid State Chem. 2005;178:2030–2035.
  • Rao CNR, Behera JN, Dan M. Organically-templated metal sulfates, selenites and selenates. Chem Soc Rev. 2006;35:375–387.
  • Hajlaoui F, Yahyaoui S, Naïli H, Mhiri T, Bataille T. Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O. Polyhedron. 2009;28:2113–2118.
  • Hajlaoui F, Yahyaoui S, Naïli H, Mhiri T, Bataille T. Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation. Inorg Chim Acta. 2010;363:691–695.
  • Yahyaoui S, Rekik W, Naïli H, Mhiri T, Bataille T. Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): C6H14N2)[Fe(H2O)6](SO4)2. J Solid State Chem. 2007;180:3560–3570.
  • Sivashankar V, Siddheswaran R, Bharthasarathi T, Murugakoothan P. Growth and characterization of new semiorganic nonlinear optical zinc guanidinium sulfate single crystal. J Cryst Growth. 2009;311:2709–2713.
  • Bataille T, Louer DJ. New linear and layered amine-templated lanthanum sulfates. Solid State Chem. 2004;177:1235–1243.
  • Zhao X, Chen Z, Zhao B, Shi W, Cheng P. Crystal structures and luminescent properties of two novel coordination polymers containing Ln3+ and SO42-. Inorg Chem Commun. 2007;10:1433–1436.
  • Behera JN, Rao CNR. Organically-templated zinc and thorium sulfates with chain and layered structures. Anorg Allg Chem. 2005;631:3030–3036.
  • Doran MB, Norquist AJ, O’Hare D. Exploration of composition space in templated uranium sulfates. Inorg Chem. 2003;42:6989–6995.
  • Naïli H, Rekik W, Bataille T, Mhiri T. Crystal structure, phase transition and thermal behaviour of dabcodiium hexaaquacopper(II) bis(sulfate), (C6H14N2)[Cu(H2O)6](SO4)2. Polyhedron. 2006;25:3543–3554.
  • Rekik W, Naïli H, Bataille T, Mhiri T. Synthesis, crystal structure, phase transition and thermal behaviour of a new dabcodiium hexaaquanickel(II) bis(sulphate), (C6H14N2)[Ni(H2O)6](SO4)2. J Organomet Chem. 2006;691:4725–4732.
  • Rekik W, Naïli H, Mhiri T, Bataille T. A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition. J Chem Crystallogr. 2007;37:147–155.
  • Fleck M, Bohaty L, Tillmanns E. Structural characterisation of MII guanidinium sulphate hydrates (MII = Mn, Fe, Co, Ni, Cd, VO). Solid State Sci. 2004;6:469–477.
  • Wilson RE, Skanthakumar S, Knope KE, Cahill CL, Soderholm L. An open-framework thorium sulfate hydrate with 11.5 Å voids. Inorg Chem. 2008;47:9321–9326.
  • Cheetham AK, Ferey G, Loiseau T. Open-framework inorganic materials. Angew Chem Int Ed Engl. 1999;38:3268–3292.
  • Haushalter RC, Mundi LA. Reduced molybdenum phosphates: octahedral-tetrahedral framework solids with tunnels, cages, and micropores. Chem Mater. 1992;4:31–48.
  • Muller EA, Cannon RJ, Sarjeant AN, Ok KM, Halasyamani PS, Norquist AJ. Directed synthesis of noncentrosymmetric molybdates. Cryst Growth Des. 2005;5:1913–1917.
  • Hagrman D, Hammond RP, Haushalter R, Zubieta J. Organic/inorganic composite materials: hydrothermal syntheses and structures of the one-, two-, and three-dimensional copper(II) sulfate−organodiamine phases [Cu(H2O)3(4,4’-bipyridine)(SO4)]·2H2O, [Cu(bpe)2][Cu(bpe)(H2O)2(SO4)2]·2H2O, and [Cu(bpe)(H2O)(SO4)] (bpe =trans-1,2-Bis(4-pyridyl)ethylene). Chem Mater. 1998;10:2091–2100.
  • Chen C, Liu G. Recent advances in nonlinear optical and electro-optical materials. Annu Rev Mater Sci. 1986;16:203–243.
  • Evans OR, Lin W. Crystal engineering of NLO materials based on metal−organic coordination networks. Acc Chem Res. 2002;35:511–522.
  • Halasyamani PS. Asymmetric cation coordination in oxide materials: influence of lone-pair cations on the intra-octahedral distortion in d0 transition metals. Chem Mater. 2004;16:3586–3592.
  • Veltman TR, Stover AK, Sarjeant AN, Ok KM, Halasyamani PS, Norquist AJ. Directed synthesis of noncentrosymmetric molybdates using composition space analysis. Inorg Chem. 2006;45:5529–5537.
  • Lii K, Chen, C-Y. Synthesis and characterization of (R-C5H14N2)2[Ga4(C2O4)(H2PO4)2(PO4)4]·2H2O, a layered gallium phosphatooxalate containing a chiral amine. Inorg Chem. 2000;39:3374–3378.
  • De Meulenaer J, Tompa H. The absorption correction in crystal structure analysis. Acta Crystallogr. 1965;19:1014–1018.
  • Farrugia LJ. WinGX suite for small-molecule single-crystal crystallography. J Appl Crystallogr. 1999;32:837–838.
  • Sheldrick GM. SHELX-97, Programs for crystal structure solution. Göttingen: University of Göttingen; 1997.
  • Altomare A, Cascarano G, Giacovazzo C, Guagliardi A. Completion and refinement of crystal structures with SIR92. J Appl Crystallogr. 1993;26:343–350.
  • Rekik W, Naili H, Mhiri T, Bataille T. [NH3(CH2)2NH3][Co(SO4)2(H2O)4]: chemical preparation, crystal structure, thermal decomposition and magnetic properties. Mat Res Bul. 2008;43:2709–2718.
  • Glowiak T, Podgorska I. X-ray, spectroscopic and magnetic studies of hexaaquacopper(II) di(diphenylphosphate) diglycine. Inorg Chim Acta. 1986;125:83–88.
  • Blackburn AC, Gallucci JC, Gerkin RE. Structure of hexaaquacopper(II) bromate. Acta Cryst. 1991;C47:2019–2023.
  • Hajlaoui F, Yahyaoui S, Naïli H, Mhiri T, Bataille T. Synthesis and crystal structures of a new non-centrosymmetric hybrid materials intercalating a chiral organic group. J Struc Chem. 2012;53:359–365.
  • Hajlaoui F, Naïli H, Yahyaoui S, Turnbull Mark M, Mhiri T, Bataille T. Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni). J Dalton Trans. 2011;40:11613–11620.
  • Brown ID. VALENCE: a program for calculating bond valences. J Appl Crystallogr. 1996;29:479–480.
  • Choyke SJ, Blau SM, Larner AA, Narducci SA, Yeon J, Halasyamani PS, Norquist AJ. Noncentrosymmetry in new templated gallium fluorophosphates. Inorg Chem. 2009;48:11277–11282.
  • Hajlaoui F, Naïli H, Yahyaoui S, Norquist AJ, Mhiri T, Bataille T. Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine. J Organomet Chem. 2012;700:110–116.
  • Spek AL. Single-crystal structure validation with the program PLATON. J Appl Crystallogr. 2003;36:7–13.
  • Mahe N, Bataille T. Synthesis, crystal structure from single-crystal and powder X-ray diffraction data, and thermal behavior of mixed potassium lanthanide squarates: thermal transformations of layered [Ln(H2O)6]K(H2C4O4)(C4O4)2 into pillared LnK(C4O4)2 (Ln = Y, La, Gd, Er). Inorg Chem. 2004;43:8379–8386.
  • Nonius. Kappa CCD program software. Delft: Nonius BV; 1998.
  • Otwinowski Z, Minor W, Carter CW, Sweet RM. Methods in enzymology, 276. New York: Academic Press; 1997, p. 307.
  • Faber J, Fawcett T. The Powder Diffraction File: present and future. Acta Cryst. 2002;B58:325--332.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.