212
Views
6
CrossRef citations to date
0
Altmetric
Original Articles

Separation of Americium (III) and Lanthanide (III) Ions using TPEN Analogs

, &
Pages 2619-2629 | Received 25 Oct 2007, Accepted 31 Mar 2008, Published online: 06 Aug 2008

REFERENCES

  • Jensen , M.P. ; Morss , L.R. ; Beitz , J.V. ; Ensor , D.D. ( 2000 ) Aqueous complexation of trivalent lanthanide and actinide cations by N,N,N′,N′-tetrakis(2-methylpyridyl)ethylenediamine . J. Alloys Compds. , 303–304 : 137 – 141 .
  • Watanabe , M. ; Mirvaliev , R. ; Tachimori , S. ; Takeshita , K. ; Nakano , Y. ; Morikawa , K. ; Mori , R. ( 2002 ) Separation of americium(III) from lanthanide by encapsulating hexadentate-ligand . Chem. Lett , 32 ( 12 ): 1230 – 1231 .
  • Watanabe , M. ; Mirvaliev , R. ; Tachimori , S. ; Takeshita , K. ; Nakano , Y. ; Morikawa , K. ; Chikazawa , T. ; Mori , R. ( 2004 ) Selective extraction of americium(III) over macroscopic concentrations of lanthanides(III) by synergistic system of TPEN and D2EHPA in 1-octonal . Solv. Extr. Ion Exch. , 22 ( 3 ): 377 – 390 .
  • Mirvaliev , R. ; Watanabe , M. ; Matsumura , T. ; Tachimori , S. ; Takeshita , K. ( 2004 ) Selective separation of Am(III) from Ln(III) with a novel synergistic extraction system, N, N, N′, N′-tetrakis(2-methylpyridyl)ethylenediamine (TPEN) and carboxylic acid in 1-octonal . J. Nucl. Sci. Tech. , 41 ( 11 ): 1122 – 1124 .
  • Mandel , J.B. ; Maricondi , C. ; Douglas , B.E. ( 1988 ) Synthesis and characterization of cobalt(II) and copper(II) complexes of hexadentate and tetradentate ligands containing pyridyl arms . Inorg. Chem. , 27 ( 17 ): 2990 – 2996 .
  • Hirayama , N. ; Iimuro , S. ; Kubono , K. ; Kokusen , H. ; Honjo , T. ( 1997 ) Ion-pair extraction behavior of transition metal(II) cations as charged complexes with ethylenediamine derivatives having heterocyclic pendant arms . Anal. Chem. Acta , 339 ( 1–2 ): 115 – 121 .
  • Takeshita , K. ; Tanaka , M. ; Nakano , Y. ; Seida , Y. ( 2003 ) Thermal-swing extraction of Cd(II) by thermosensitive gel cross-linked with nitrogen-donor ligands . J. Chem. Eng. Jap. , 36 ( 10 ): 1253 – 1258 .
  • Takeshita , K. ; Watanabe , K. ; Nakano , Y. ; Wantanabe , M. ( 2004 ) Extraction separation of Cd(II) and Zn(II) with Cyanex301 and aqueous nitrogen-donor ligand TPEN . Solvent Extr. Ion Exch. , 22 ( 2 ): 203 – 218 .
  • Matsumura , T. ; Takeshita , K. ( 2006 ) Extraction behavior of Am(III) from Eu(III) with hydrophobic derivatives of N,N,N′,N′-tetrakis(2-methylpyridyl)ethylenediamine (TPEN) . J. Nucl. Sci. Tech. , 43 ( 7 ): 824 – 827 .
  • Pandiyan , T. ; Consuelo-Estrada , V.M. ; Moreno-Esparza , R. ; Ruiz-Ramirez , L. ( 2003 ) Mercaptoethanesulfonic acid studies with nickel(II) complexes of tetra- and hexadentate ligands containing pyridul groups: synthesis, structure, spectra and redox behavior . Inorg. Chem. Acta , 343 : 79 – 89 .
  • Karmazin , L. ; Mazzanti , M. ; Gateau , C. ; Hill , C. ; Pecaut , J. ( 2002 ) The important effect of ligand architecture on the selectivity of metal ions recognition in An(III)/Ln(III) separation with N-donor extractants . Chem. Commun. , 23 : 2892 – 2893 .
  • Unpublished work in Takeshita group .
  • Sato , M. ; Mori , Y. ; Iida , T. ( 1992 ) Convenient synthesis of N,N,N′,N′-tetrakis(2-pyridylmethyl)-α,ω-alkanediamines using a phase-transfer catalyst . Synthesis , 6 : 539 – 540 .
  • Morss , L.R. ; Rogers , R.D. ( 1997 ) Synthesis and crystal structure of [M(NO3)2(tpen)]NO3 · 3H2O (M = La, Tb), rare earth complexes with strong M-N bonds . Inorg. Chim. Acta , 255 : 193 – 197 .
  • ∗Work was performed on sabbatical from Savannah River National Laboratory, Aiken, SC, USA.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.