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Original Articles

Application of Mixture Models to Solubility Calculations, Using Sodium Oxalate as an Example

Pages 2872-2886 | Received 01 Oct 2007, Accepted 01 Apr 2008, Published online: 06 Aug 2008

REFERENCES

  • Scheffe , H. ( 1958 ) Experiments with mixtures . J. R. Stat. Soc. , B20 : 344 .
  • Cox , D.R. ( 1971 ) A note on polynomial response functions for mixtures . Biometrika , 58 : 155 .
  • Kim , D. ; Hrma , P. ( 1994 ) Models for liquidus temperature of nuclear waste glasses . Ceram. Transactions. , 45 : 327 .
  • Mika , M. ; Schweiger , M.J. ; Vienna , J.D. ; Hrma , P. ( 1997 ) Liquidus temperature of spinel precipitating high-level waste glasses . Mat. Res. Soc. Symp. Proc. , 465 : 71 .
  • Hrma , P. ; Vienna , J.D. ( 2002 ) Relationship between liquidus temperature and solubility . Ceramic Transactions , 143 : 159 .
  • Piepel , G.F. ( 2007 ) A component slope linear model for mixture experiments . Quality Technology Quantitative Management , 4 : 331 .
  • Reynolds , J.G. ( 2005 ) Spinel structure and liquidus temperature relationships in nuclear waste glass . J. Materials Sci. , 40 : 3987 .
  • Zemaitis , J.F. ; Clark , D.M. ; Rafal , M. ; Scrivner , C.N. ( 1986 ) Handbook of Aqueous Electrolyte Thermodynamics . AICHE : New York , NY .
  • Hobbs , D.T. ; Karraker , D.G. ( 1996 ) Recent results on the solubility of uranium and plutonium in Savannah River Site waste supernatant . Nucl. Tech. , 114 : 318 .
  • Choi , A.S. ; Pierce , R.A. ; Edwards , T.B. ; Calloway , T.B. ( 2007 ) Physical property modeling of concentrated cesium eluate solutions: Part I–derivation of models . Nucl. Tech. , 160 : 361 .
  • Reynolds , J.G. ( 2006 ) A simplified gibbsite solubility equation for modeling the caustic leaching of aluminum-bearing sludge . Proceedings of Waste Management ’06. Feb. 26-Mar. 02. 2006. Tucson, Az. (Published on CD) .
  • Romagnoli , J.A. ; Sanchez , M.C. ( 2000 ) Data Processing and Reconciliation for Chemical Process Operations . l Academic Press : San Diago , CA , U. S. A .
  • Kol'ba , V.I. ; Zhikharev , M.I. ; Sukhanov , L.P. ( 1980 ) The Na2C2O4-NaNO3-H2O system at 50 and 75°C . Russ. J. Inorg. Chem. , 25 : 1583 .
  • Gorman , J.W. ; Cornell J.A. ( 1985 ) A note on fitting equations to freezing-point data exhibiting eutectics for binary and ternary mixture systems . Technometrics , 27 : 229 .
  • Fluegel , A. ( 2007 ) Statistical regression modeling of glass properties-A tutorial . Glass Technol.-Europ. J. Glass Sci. Technol. , (in press) .
  • Sharma , A.K. ; Clauss , S.A. ; Mong , G.M. ; Wahl , K.L. ; Campbell , J.A. ( 1998 ) Analysis and quantification of organic acids in simulated Hanford tank waste and Hanford tank waste . J. Chromatography , A805 : 101 .
  • Qafoku , O. ; Felmy , A.R. ( 2007 ) Development of accurate chemical equilibrium models for oxalate species to high ionic strength in the system: Na-Ba-Ca-Mn-Sr-Cl-NO3-PO4-SO4-H2O at 25°C . J. Solution Chem. , 36 : 81 .
  • Hrma , P. (1998) “Empirical models” and thermodynamic constitutive functions for high-level nuclear waste glass properties. Ceramic Transactions , 87: 245.
  • Denbigh , K.G. ( 1966 ) The Principles of Chemical Equilibrium, , 2nd Ed. ; Cambridge University Press : Cambridge , UK .
  • Cornell , J.A. ( 2002 ) Experiments with Mixtures: Designs, Models, and the Analysis of Mixture Data, , 3rd Ed. ; Wiley-Interscience : New York , NY , USA .
  • Ott , R.L. ( 1993 ) An Introduction to Statistical Methods and Data Analysis, , 4th Ed. ; Duxbury Press : Belmont , CA , USA .
  • Freedman , D.A. ( 1983 ) A note on screening regression equations . American Statistician , 37 : 152 .
  • Piepel , G.F. ( 2006 ) A note comparing component-slope, Scheffe and Cox parameterizations of the linear mixture experiment model . J. Appl. Stat. , 33 : 397 .
  • Marquardt , D.W. ; Snee , R.D. ( 1974 ) Test statistic for mixture models . Technometrics , 16 : 533 .
  • Gorman , J.W. ; Cornell , J.A. ( 1982 ) A note on model reduction for experiments with both mixture components and process variables . Technometrics , 24 : 243 .
  • Norris , W.H.H. ( 1951 ) The system oxalic acid-sodium hydroxide-water . J. Chem. Soc. , 1708 .
  • Bouzat , G. ; Philipponneau , G. ( 1991 ) Physical Chemistry Models of Oxalate and Gibbsite Solubility in Bayer Solutions . In: Light Metals 1991 , Rooy , E.L. , ed.; The Minerals, Metals & Materials Society : Warrendal , PA , U. S. A .
  • Toghiani , R.K. ; Smith , L.T. ; Lindner , J.S. ; Tachiev , G. ; Yaari G. ; ( 2006 ) Modeling of Pilot Scale Salt-Cake Dissolution . Proceedings of Waste Management ’06 . Feb. 26-Mar. 02. 2006. Tucson, Az. (Published on CD) .
  • Zhikharev , M.I. ; Kol'ba , V.I. ; Sukhanov , L.P. ( 1979 ) The Na2C2O4-NaNO3-H2O system at 20°C . Russ. J. Inorg. Chem. , 24 : 469 .
  • Reynolds , J.G. ; Bernards , J.K. , Carter , R. ( 2007 ) Model For Calculating the Density of Hanford Waste Treatment Plant Supernatants . Waste Management ’07 Proceedings , Feb-March, 2007, Tucson, Az. (Published on CD) .
  • Menczel , B. ; Apelblat , A. ; Korin , E. ( 2004 ) The molar enthalpies of solution and solubilities of ammonium, sodium and potassium oxalates in water . J. Chem. Thermo. , 36 : 41 .
  • Marcos-Arroyo , M.M. ; Khoshkbarchi , M.K. ; Vera , J.H. ( 1996 ) Activity coefficients of sodium, potassium, and nitrate ions in aqueous solutions of NaNO3, KNO3, NaNO3 + KNO3 at 25°C . J. Solution Chem. , 25 : 983 .
  • Kettler , R.M. ; Palmer , D.A. ; Wesolowski , D.J. ( 1991 ) Dissociation quotients of oxalic acid in aqueous sodium chloride media to 175°C . J. Solution Chem. , 20 : 905 .

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