299
Views
22
CrossRef citations to date
0
Altmetric
Original Articles

The Effect of Acetohydroxamic Acid on Extraction and Speciation of Plutonium

&
Pages 2670-2683 | Received 25 Oct 2007, Accepted 29 Mar 2008, Published online: 06 Aug 2008

REFERENCES

  • Schulz , W.W. ; Navratil , J.D. ( 1984 ) Science and Technology of Tributyl Phosphate ; vol. I-IV, CRC Press : Boca Raton , FL .
  • Pereira , C. ; Vandegrift , G.F. ; Regabulto , M.C. ; Bakel , A.J. ; Bowers , D.L. ; Gelis , A.V. ; Hebden , A.S. ; Maggos , L.E. ; Stepinski , D. ; Tsai , Y. ; Laidler , J.J. (2007) Lab-scale demonstration of theUREX + 1a process using spent fuel , Waste Management, WM'07 Conference, Tucson, AZ, February 25-March 1.
  • Schroeder , N.C. ; Attrep , M. ; Marrero , T. Jr.. ( 2001 ) Technetium and iodine separations in the UREX process , Los Alamos National Laboratory (C-INC), Final Report for WBS 1.24.01.01 .
  • Tkac , P. ; Matteson , B. ; Bruso , J. ; Paulenova , A. ; ( 2008 ) Complexation of uranium (VI) with acetohydroxamic acid . J. Radioanal. Nucl. Chem. , 277 ( 1 ): accepted .
  • Butler , R.J. ; Sinkov , S. ; Renshaw , J.C. ; Collison , D. ; Livens , F.R. ; Taylor , R.J. ; Choppin , G.R. ( 2000 ) Reactions of plutonium with acetohydroxamic acid in aqueous solution: first results , Atalante 2000, Advances for future nuclear fuel cycles, October 24–26, Avignon, France, P2-09 .
  • Taylor , R.J. ; May , I. ; Wallwork , A.L. ; Denniss , I.S. ; Hill , N.J. ; Galkin , B.Y. ; Zilberman , B.Y. ; ( 1998 ) The applications of formo- and aceto-hydroxamic acids in nuclear fuel reprocessing . J. All. Comp. , 271 – 273 : 534 .
  • Colston , B.J. ; Choppin , G.R. ; Taylor , R.J. ( 2000 ) A preliminary study of the reduction of Np(VI) by formohydroxamic acid using stopped-flow near-infrared spectrophotometry . Radiochim. Acta , 88 : 329 .
  • Chung , D.Y. ; Lee , E.H. ( 2005 ) The reduction of Np(VI) by acetohydroxamic acid in nitric acid solution . Bull. Korean Chem. Soc. , 26 ( 11 ): 1692 .
  • Taylor , R.J. ; Dennis , I.S. ; May , I. ( 2000 ) Hydroxamic acids – novel agents for advanced PUREX process , Atalante 2000, Advances for future nuclear fuel cycles, October 24–26, Avignon, France, P2-15 .
  • Karraker , G. ( 2002 ) Radiation chemistry of acetohydroxamic acid in the UREX process , Westinghouse Savannah River Company, WSRC-TR-2002-00283 .
  • Gosh , K.K. ; Vaidya , Y. ; Sinha , D. ( 2004 ) Kinetics and mechanism of the mineral acid catalysed reactions of hydroxamic acids . Z. Phys. Chem. , 218 : 563 .
  • Chung , D.Y. ; Lee , E.H. ; ( 2006 ) Kinetics of the hydrolysis of acetohydroxamic acid solution . J. Ind. Eng. Chem. , 12 ( 6 ): 962 .
  • Alyapyshev , M. ; Paulenova , A. ; Cleveland , M.A. ; Bruso , J.E. ; Tkac , P. ( 2007 ) Hydrolysis of acetohydroxamic acid under UREX + conditions , GLOBAL 2007, Advanced Nuclear Fuel Cycles and Systems, September 9–13 , Boise , ID , USA , 1861 – 1864 .
  • Carrott , M.J. ; Fox , O.D. ; Jones , C.J. ; Mason , C. ; Taylor , R.J. ; Sinkov , S.I. ; Choppin , G.R. ; ( 2007 ) Solvent extraction behaviour of plutonium ions in the presence of simple hydroxamic acids . Solv. Extr. Ion Exch. , 25 ( 6 ): 723 .
  • Paulenova , A. ; Tkac , P. ; Matteson , B. ( 2007 ) Speciation of plutonium and other metals under UREX process conditions , GLOBAL 2007, Advanced Nuclear Fuel Cycles and Systems, September 9–13 , Boise , ID , USA , 723 – 727 .
  • Karraker , G. ; Rudisill , T.S. ; Thompson , M.C. ( 2001 ) Studies of the effect of acetohydroxamic acid on distribution of plutonium and neptunium by 30 vol% tributyl phosphate , Westinghouse Savannah River Company, WSRC-TR-2001-00509 .
  • Tkac , P. ; Paulenova , A. ; Gable , K. ( 2007 ) Spectroscopic study of the uranyl-acetohydroxamate adduct with tributyl phosphate . Appl. Spectrosc. , 61 ( 7 ): 772 .
  • Tkac , P. ; Paulenova , A. ( 2008 ) Speciation of molybdenum (VI) in aqueous and organic phase of selected extraction systems . Sep. Sci. Technol. , this volume .
  • Herbelin , A.L. ; Westall , J.C. ( 1999 ) FITEQL 4.0: A computer program for determination of chemical equilibrium constants from experimental data , Department of Chemistry, Oregon State University, Report 99–01 .
  • HYSS: Hyperquad Simulation and Speciation, http://www.hyperquad.co.uk/hyss.htm
  • Veirs , D.K. ; Smith , C.A. ; Berg , J.M. ; Zwick , B.D. ; Marsh , S.F. ; Allen , P. ; Conradson , S.D. ( 1994 ) Characterization of the nitrate complexes of Pu(IV) using absorption spectroscopy, 15NMR, and EXAFS . J. All. Comp. , 213/214 : 328 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.