Novel Polysilsesquioxane Hybrid Membranes for Proton Exchange Membrane Fuel Cell (PEMFC) Applications

REFERENCES

• Laramie , J. ; Dicks , A. ( 2000 ) Fuel Cell Systems Explained. , 2nd ed.; John Wiley & Sons .
   Google Scholar
• Sankir , M. ; Seung , Y. ; Pivovar , B.S. ; McGrath , J.E. ( 2007 ) Proton exchange membrane for DMFC and H2/air fuel cells: Synthesis and characterization of partially fluorinated disulfonated poly(arylene ether benzonitrile) copolymers . J. Membr. Sci. , 299 : 8 – 18 .
   Google Scholar
• Osborn , S.J. ; Hassan , M.K. ; Divoux , G.M. ; Rhoades , D.W. ; Mauritz , K.A. ; Moore , R.B. ( 2007 ) Glass transition temperature of perfluorosulfonic acid ionomers . Macromolecules , 40 : 3886 – 3890 .
   Google Scholar
• Depre , L. ; Ingram , M. ; Poinsignon , C. ; Popall , M. ( 2000 ) Proton conducting sulfon/sulfonamide functionalized materials based on inorganic–organic matrices . Electrochim. Acta , 45 : 1377 – 1383 .
   Web of Science ®Google Scholar
• Kreuer , K. ( 2001 ) D. On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells . J. Membr. Sci. , 185 : 29 – 39 .
   Web of Science ®Google Scholar
• Honma , I. ; Nakajima , H. ; Nishikawa , O. ; Sugimoto , T. ; Nomura , S. ( 2002 ) Amphiphilic organic/inorganic nanohybrid macromolecules for intermediate-temperature proton conducting electrolyte membranes . J. Electrochem. Soc. , 149 : 10 , A1389–A1392 .
   Google Scholar
• Chen , N. ; Hong , L. ( 2002 ) Proton-conducting membrane composed of sulfonated polystyrene microspheres, poly(vinylpyrrolidone) and poly(vinylidene fluoride) . Solid State Ionics , 146 : 377 – 385 .
   Web of Science ®Google Scholar
• Surampudi , S. ; Narayanan , S.R. ; Vamos , E. ; Frank , G.H. ; Halpert , A. ; LaConti , J. ; Kosek , G. ; Surya Prakash , K. ; Olah , G.A. ( 1994 ) Advances in direct oxidation methanol fuel cells . J. Power Source , 47 : 377 – 385 .
   Google Scholar
• Appleby , A.J. ; Foulkes , F.R. (eds.). ( 1993 ) Fuel Cell Handbook , Krieger : Malabar , FL .
   Google Scholar
• Tsuruhara , K. ; Rikukawa , M. ; Sanui , K. ; Ogata , N. ; Nagasaki , Y. ; Kato , M. ( 2000 ) Synthesis of proton conducting polymer based on poly(silamine) . Electrochim. Acta , 45 : 1391 – 1394 .
   Google Scholar
• Watanabe , M. ; Uchida , H. ; Emori , M. ( 1998 ) Polymer electrolyte membranes incorporated with nanometer-size particles of Pt and/or metal-oxides: experimental analysis of the self-humidification and suppression of gas-crossover in fuel cells . J. Phys. Chem. B , 102 : 3129 – 3137 .
   Web of Science ®Google Scholar
• Wang , H. ; Holmberg , B.A. ; Huang , L. ; Wang , Z. ; Mitra , A. ; Norbeck , J.M. ; Yan , Y. ( 2002 ) Nafion-bifunctional silica composite proton conductive membranes . J. Mater. Chem. , 12 : 834 – 837 .
   Web of Science ®Google Scholar
• Wainwright , J.S. ; Wang , J.T. ; Weng , D. ; Savinell , R.F. ; Lit , R.F. ( 1995 ) Acid-doped polybenzimidazoles: a new polymer electrolyte . J. Electrochem. Soc. , 142 : L121 – L123 .
   Google Scholar
• Schechter , A. ; Savinell , R. (2002) Imidazole and 1-methyl imidazole in phosphoric acid doped polybenzimidazole, electrolyte for fuel cells. Solid State Ionics , 147: 181–187.
   Web of Science ®Google Scholar
• Rikukawa , M. ; Sanui , K. ( 2000 ) Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers . Prog. Polym. Sci. , 25 : 1463 – 1502 .
   Web of Science ®Google Scholar
• Matsuda , A. ; Kanzaki , T. ; Yoshinori , Y. ; Tatsuminago , M. ; Minami , T. ( 2001 ) Proton conductivity and structure of phosphosilicate gels derived from tetraethoxysilane and phosphoric acid or triethylphosphate . Solid State Ionics , 139 : 113 – 119 .
   Google Scholar
• Hirata , K. ; Matsuda , A. ; Hirata , T. ; Tatsuminago , M. ; Minami , T. ( 2000 ) Preparation and characterization of highly proton-conductive composites composed of phosphoric acid-doped silica gel and styrene-ethylene-butylene-styrene elastomer . J. Sol-Gel Sci. Tech. , 17 : 61 – 69 .
   Google Scholar
• Matsuda , A. ; Kanzaki , T. ; Tatsuminago , M. ; Minami , T. ( 2001 ) Comparison of structure and proton conductivity of phosphosilicate gels derived from several kinds of phosphorus-containing compounds . Solid State Ionics , 145 : 161 – 166 .
   Google Scholar
• Popall , M. ; Du , X.M. ( 1995 ) Inorganic-organic copolymers as solid state ionic conductors with grafted anions . Electrochim. Acta , 40 : 2305 – 8 .
   Google Scholar
• Aparicio , M. ; Duran , A. ( 2004 ) Hybrid organic/inorganic sol-gel materials for proton conducting membranes . J. Sol-Gel Sci. Tech. , 31 : 103 – 107 .
   Google Scholar
• Aparicio , M. ; Damay , F. ; Klein , L.C. ( 2003 ) Characterization of SiO2–P2O5–ZrO2 Sol-Gel/NAFIONTM composite membranes . J. Sol-Gel Sci. Tech. , 26 : 1055 – 1059 .
   Web of Science ®Google Scholar
• Khiterer , M. ; Loy , D. A. ; Cornelius , C.J. ; Fujimoto , C.H. ; Small , J.H. ; McIntire , T. M. ; Shea , K.J. ( 2006 ) Hybrid polyelectrolyte materials for fuel cell applications: design, synthesis and evaluation of proton-conducting bridged polysilsesquioxanes . Chem. Mater. , 18 : 3665 – 3673 .
   Google Scholar
• (a) Saito , M. ; Arimura , K. ; Hayamizuo , K. ; Okada , T. ( 2004 ) Mechanisms of ion and water transport in perfluorosulfonated ionomer membranes for fuel cells . J. Phys. Chem. B , 108 : 16064 – 16070 . (b) Saito, M.; Hayamizuo, K.; Okada, T. (2005) Temperature dependence of ion and water transport in perfluorinated ionomer membranes for fuel cells. J. Phys. Chem. B. 109: 3112–3119. (c) Zawodzinsk, Jr. T.A.; Neeman, M.; Sillerud, L.O.; Gottesfield, S. (1991) Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes. J. Phys. Chem., 95: 6040–6044 .
   Web of Science ®Google Scholar
• James , P.J. ( 2000 ) Hydration of Nafion® studied by AFM and X-ray scattering . J. Mat. Sci. , 35 : 5111 – 5119 .
   Google Scholar
• Alberti , G. ; Casciola , M. ; Massinelli , L. ; Bauer , B. ( 2001 ) Polymeric proton conducting membranes for medium temperature fuel cells (110–160°C) . J. Memb. Sci. , 185 : 73 – 81 .
   Web of Science ®Google Scholar
• Gao , Y. ; Choudhury , N.R. ; Dutta , N. ; Delmotte , L. ( 2005 ) Ionomer-silica hybrids via sol-gel reaction . Polymer , 46 : 4013 – 4022 .
   Google Scholar
• Herring , A. ( 2006 ) Inorganic-polymer composite membranes for proton exchange membrane fuel cells . J. Macromolecular Sci., Polym. Rev. , 46 : 245 – 296 .
   Web of Science ®Google Scholar
• Gaowen , Z. ; Zhentao , Z. (2005) Organic/inorganic composite membranes for application in DMFC. J. Membr. Sci. , 261: 107–113.
   Web of Science ®Google Scholar
• Li , S. ; Zhou , Z. ; Abernathy , H. ; Liu , M. ; Li , W. ; Ukai , J. ; Hase , K. ; Nakanishi , M. ( 2006 ) Synthesis and properties of phosphonic acid-grafted hybrid inorganic-organic polymer membranes . J. Mater. Chem ., 16 : 858 – 864 .
   Web of Science ®Google Scholar
• Rikukawa , M. ; Sanui , K. ( 2000 ) Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers . Prog. Polym. Sci. , 25 : 1463 – 1502 .
   Web of Science ®Google Scholar
• Xiong , C. ; Kim , M.J. ; Balkus , Jr. K.J. ( 2006 ) TiO2 nanofibers and core–shell structures prepared using mesoporous molecular sieves as templates . Small , 2 : 52 – 55 .
   Google Scholar
• Boston , D.R. ; Bailar , Jr. , J.C. ( 1972 ) Phthalocyanine derivatives from 1,2,4,5-tetracyanobenzene or pyromellitic dianhydride and metal salts . Inorg. Chem. , 11 : 1578 – 1583 .
   Web of Science ®Google Scholar
• (a) www.bekktech.com/train.html(accessed January 2008); (b) Honma , I. ; Nishikawa , O. ; Sugimoto , T. ; Nomura , S. ; Nakajima , H. (2002) A sol-gel derived organic/inorganic hybrid membrane for intermediate temperature PEFC, 2002. Fuel Cells, 2 (1): 52–58 .
   Google Scholar
• Shea , K.J. ; Loy , D.A. ( 2001 ) A mechanistic investigation of gelation. The sol-gel polymerization of precursors to bridged polysilsesquioxanes . Acc. Chem. Res. , 34 : 707 – 716 .
   Google Scholar
• Brinker, C. Jeffrey ; Scherer , G.W. ( 2005 ) Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing . Academic Press : New York . 1989 .; Klein, L.C.; Daiko, Y.; Aparicio, M.; Damay, F. Methods for modifying proton exchange membranes using the sol-gel process, Polymer, 46: 4504–4509 .
   Google Scholar
• Loy , D.A. ; Jamison , G.M. ; Baugher , B.M. ; Myers , S.A. ; Assink , R.A. ; Shea , K.J. ( 1996 ) Sol-gel synthesis of hybrid organic-inorganic materials. Hexylene- and phenylene-bridged polysiloxanes . Chem. Mater. , 8 : 656 – 663 .
   Google Scholar
• (a) Yang , Z. (2004) Novel polymer andinorganic/organic hybrid composite materials for proton exchange membrane applications, Ph.D. Thesis. University of Texas at Dallas; (b) Mo, Y.; Szlufarska, I. (2007) Simultaneous enhancement of toughness, ductility, and strength of nanocrystalline ceramics at high strain-rates . Appl. Phys. Lett. , 90 : 181926 .
   Google Scholar
• Chalkova , E. ; Fedkin , M.V. ; Wesolowski , D.J. ; Lvov , S.N. ( 2005 ) Effect of TiO2 surface properties on performance of Nafion-based composite membranes in high temperature and low relative humidity PEM fuel cells . J. Electrochem. Soc. , 152 : 9 , A1742–A1747 .
   Google Scholar
• Aparicio , M. ; Mosa , J. ; Duran , A. ( 2006 ) Hybrid organic-inorganic nanostructured membranes for high temperature proton exchange membranes fuel cells . J. Sol-Gel Sci. Techn. , 40 : 309 – 315 .
   Google Scholar
• Lin , C.W. ; Fan , K.C. ; Thangamuthu , R. ( 2006 ) Preparation and characterization of high selectivity organic-inorganic hybrid-laminated Nafion® 115 membranes for DMFC . J. Membr. Sci. , 278 : 437 – 446 .
   Web of Science ®Google Scholar
• Wakizoe , M. ; Velev , A.A. ; Srinivasan , S. ( 1995 ) Analysis of proton exchange membrane fuel cell performance with alternate membranes . Electrochim. Acta , 40 ( 3 ): 335 – 344 .
   Google Scholar
• Haubold , H.G. ; Vad , T. ; Jungbluth , H. ; Hiller , P. (2001) Nanostructure of NAFION: a SAXS study. Electrochim. Acta , 46: 1559–1563.
   Web of Science ®Google Scholar
• Eikerling , M. ; Kornyshev , A.A. ; Kunetzsov , A.M. ; Ulstrup , J. ; Walbran , S. ( 2001 ) Mechanisms of proton conductance in polymer electrolye membranes . J. Phys. Chem. B , 105 : 3646 – 3662 .
   Web of Science ®Google Scholar
• Sondheimer , S.J. ; Bunce , N.J. ; Fyfe , C.A. ( 1986 ) Structure and chemistry of Nafion-H: a fluorinated sulfonic acid polymer . J. Macromol. Sci., Polym. Rev. , 351 : C26 – 28 .
   Google Scholar
• Burton , D.J. ; Sprague , L.G. ( 1989 ) Allylations of [(diethoxyphosphinyl)difluoromethyl]zinc bromide as a convenient route to 1,1-difluoro-3-alkenephosphonates . J. Org. Chem. , 54 : 613 – 617 .
   Web of Science ®Google Scholar
• Dippel , Th. ; Kreuer , K.D. ; Lassegues , J.C. ; Rodriguez , D. ( 1993 ) Proton conductivity in fused phosphoric acid; A 1H/31P PFG-NMR and QNS study . Solid State Ionics , 61 : 41 – 46 .
   Google Scholar
• Hickner , M.A. ; Pivovar , B.S. ( 2005 ) The chemical and structural nature of proton exchange membrane fuel cell properties . Fuel Cells , 5 : 213 – 229 .
   Google Scholar
• Klein , L.C. ; Daiko , Y. ; Aparicio , M. ; Damay , F. ( 2005 ) Methods for modifying proton exchange membranes using the sol-gel process . Polymer , 46 : 4504 – 4509 .
   Web of Science ®Google Scholar
• Uchida , H. ; Mizuno , Y. ; Watanabe , Y. ( 2002 ) Suppression of methanol crossover and distribution of ohmic resistance in Pt-Dispersed PEMs under DMFC operation . J. Electrochem. Soc. , 149 : A682 – A687 .
   Google Scholar