Solubility of Uranium and Plutonium in Alkaline Savannah River Site High Level Waste Solutions

REFERENCES

• Clark , D.L.; Hobart D.E. ; Neu , M.P. ( 1995 ) Actinide carbonate complexes and their importance in actinide environmental chemistry . Chem. Rev. , 95 : 25 (and references therein).
   Web of Science ®Google Scholar
• Allard , B. ( 1982 ) Actinides in Perspective ; Pergamon Press, Inc. : New York , 553 – 580 .
   Google Scholar
• King , W.D. ; Wilmarth , W.R. ; Hobbs , D.T. ; Edwards , T.B. ( 2008 ) Recent studies of uranium and plutonium chemistry in alkaline radioactive waste solutions . J. Alloys and Comp. , 458 : 158 .
   Google Scholar
• Hobbs , D.T. ; Karraker , D.G. ( 1996 ) Recent results on the solubility of uranium and plutonium in Savannah River Site waste supernate . Nuclear Technology , 114 : 318 .
   Web of Science ®Google Scholar
• Rudisill , T.S. ; Hobbs , D.T. ; Edwards , T.B. ( 2010 ) Plutonium solubility in simulated Savannah River Site waste solutions . Sep. Sci. Technol. , 45 : 1782 – 1792 .
   Web of Science ®Google Scholar
• Delegard , C.H. ( 1987 ) Solubility of PuO2 · xH2O in alkaline Hanford high-level waste solution . Radiochim. Acta , 41 : 11 .
   Google Scholar
• Yamamura , T. ; Kitamura , A. ; Fukui , A. ; Nishikawa , S. ; Yamamota , T. ; Moriyama , H. ( 1998 ) Solubility of U(VI) in highly basic solutions . Radiochim. Acta , 83 : 139 .
   Web of Science ®Google Scholar
• Clark , D.L. ; Conradson , S.D. ; Donohue , R.J. ; Webster Keogh , D. ; Morris , D.E. ; Palmer , P.D. ; Rogers , R.D. ; Tait , C.D. ( 1999 ) Chemical speciation of the uranyl ion under highly alkaline conditions. Synthesis, structures, and oxo ligand exchange dynamics . Inorg. Chem. , 38 : 1456 .
   Web of Science ®Google Scholar
• Wahlgren , U. ; Moll , H. ; Grenthe , I. ; Schimmelpfennig , B. ; Maron , L. ; Vallet , V. ; Gropen , O. ( 1999 ) Structure of uranium(VI) in strong alkaline solutions. A combined theoretical and experimental investigation . J. Phys. Chem. A , 103 : 8257 .
   Web of Science ®Google Scholar
• Budaventzeva , N.A. ; Tananaev , I.G. ; Fedoseev , A.M. ; Delegard , C.H. ( 1998 ) Behavior of plutonium(V) in alkaline media . J. Alloys Comp. , 271–273 : 813 .
   Google Scholar
• Guilaumont , R. ; Adloff , J.P. ( 1992 ) Stability of pentavalent plutonium . Radiochim. Acta , 58/59 : 45 .
   Google Scholar
• Katz , J.J. ; Seaborg , G.T. ; Morss , L.R. ( 1986 ) The Chemistry of the Actinide Elements, , 2nd Ed. ; Vol. 1 ; Chapman and Hall : New York .
   Google Scholar
• Zhou , P. ; Gu , B. (2005) Extraction of oxidized and reduced forms of uranium from contaminated soils: Effects of carbonate concentration and pH. Environ. Sci. Technol. , 39: 4435.
   PubMed Web of Science ®Google Scholar
• Giammar , D.E. ; Hering , J.E. ( 2004 ) Influence of dissolved sodium and cesium on uranyl oxide hydrate solubility . Environ. Sci. Technol. , 38 : 171 .
   PubMedGoogle Scholar
• Haschke , J.M. ; Allen , T.H. ( 2002 ) Equilibrium and thermodynamic properties of the PuO2+x solid solution . J. Alloys Comp. , 336 : 124 .
   Google Scholar
• Cinneide , S.O. ; Scanlan , J.P. ; Hynes , M.J. ( 1975 ) Equilbria in uranyl carbonate systems – I, The overall stability constant of . J. Inorg. Nucl. Chem. , 37 : 1013 .
   Web of Science ®Google Scholar
• Scanlan , J.P. ( 1977 ) Equilbria in uranyl carbonate systems – II, The overall stability constant of and the third formation constant of . J. Inorg. Nucl. Chem. , 39 : 635 .
   Web of Science ®Google Scholar
• Allen , P.G. ; Bucher , J.J. ; Clark , D.L. ; Edelstein , N.M. ; Ekberg , S.A. ; Gohdes , J.W. ; Hudson , E.A. ; Kaltsoyannis , N. ; Lukens , W.W. ; Neu , M.P. ; Palmer , P.D. ; Reich , T. ; Shuh , D.K. ; Tait , C.D. ; Zwick , B.D. ( 1995 ) Multinuclear NMR, Raman, EXAFS, and X-ray Diffraction studies of uranyl carbonate complexes in near-neutral aqueous solution. X-ray structure of [C(NH2)3]6[(UO2)3(CO3)6] · 6.5H2O . Inorg. Chem. , 34 : 4797 .
   Web of Science ®Google Scholar