160
Views
10
CrossRef citations to date
0
Altmetric
SUPPORTED LIQUID MEMBRANE

Carrier Facilitated Transport of Europium(III) Across Supported Liquid Membranes Containing N,N,N′,N′-tetra-2-ethylhexyl-3-oxapentane-diamide (T2EHDGA) as the Extractant

, , &
Pages 1941-1949 | Received 30 Nov 2010, Accepted 08 Apr 2011, Published online: 03 Oct 2011

REFERENCES

  • Baisden , P.A. ; Choppin , G.R. ( 2007 ). Nuclear Waste Management and the Nuclear Fuel Cycle . In: Radiochemistry and Nuclear Chemistry , Nagyl , S. , ed.; Encyclopedia of Life Support Systems (EOLSS) , Eolss Publishers , Oxford , U.K.
  • Baestle , L.H. ( 1992 ) Burning of Actinides: A complementary waste management option? IAEA Bulletin , 34 : 32 .
  • Mathur , J.N. ; Murali , M.S. ; Nash , K.L. ( 2001 ) Actinide Partitioning – A Review . Solv. Extr. Ion Exch. , 19 : 357 .
  • Paiva , A.P. ; Malik , P. ( 2004 ) Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes . J. Radioanal. Nucl. Chem. , 261 : 485 – 496 .
  • Serrano-Purroy , D. ; Christiansen , B. ; Malmbeck , R. ; Glatz , J.P. ; Baron , P. ( 2003 ) Partitioning of minor actinides from HLW using DIAMEX Process. Proc. Global 2003, New Orleans, USA, November 16–20 .
  • Zhu , Y. ; Jiao , R. (1994) Chinese experience in the removal of actinides from high active waste by tri alkyl phosphine oxide extraction. Nucl. Technol. , 108: 361–369.
  • Morita , Y. ; Glatz , J.P. ; Kubota , M. ; Koch , L. ; Pagliosa , G. ; Roemer , K. ; Nicholl , A. ( 1996 ) Actinide partitioning from HLW in a continuous DIDPA extraction process by means of centrifugal extractors . Solv. Extr. Ion Exch. , 14 : 385 – 400 .
  • Sasaki , Y. ; Choppin , G.R. ( 1998 ) Solvent extraction of Eu, Th, U, Np and Am with N, N′-dimethyl-N,N′-dihexyl-3-oxapentanediamide and its analogous compounds . Anal. Sci. , 12 : 225 .
  • Sasaki , Y. ; Zhu , Z.X. ; Sugo , Y. ; Kimura , T. ( 2007 ) Extraction of various metal ions from nitric acid to n-dodecane by diglycolamide (DGA) compounds . J. Nucl. Sci. Technol. , 44 : 405 .
  • Sasaki , Y. ; Sugo , Y. ; Suzuki , S. ; Tachimori , S. ( 2001 ) The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3-n-dodecane system . Solv. Extr. Ion Exch. , 19 : 91 .
  • Modolo , G. ; Asp Hanna , Schreinemachers , C. ; Vijgen , H. ( 2007 ) Development of a TODGA based process for partitioning of actinides from a PUREX Raffinate Part I: Batch extraction optimization studies and stability tests . Solv. Extr. Ion Exch. , 25 : 703 .
  • Zhu , Z. ; Sasaki , Y. ; Suzuki , H. ; Suzuki , S. ; Kimura , T. ( 2004 ) Cumulative study on solvent extraction of elements by N,N,N′, N′-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane . Anal. Chim. Acta , 527 : 163 – 168 .
  • Ansari , S.A. ; Pathak , P.N. ; Husain , M. ; Prasad , A.K. ; Parmar , V.S. ; Manchanda , V.K. ( 2005 ) N,N,N′,N′-Tetraoctyl diglycolamide (TODGA): A promising extractant for actinide-partitioning from high-level waste (HLW) . Solv. Extr. Ion Exch. , 23 : 463 – 479 .
  • Ansari , S.A. ; Mohapatra , P.K. ; Prabhu , D.R. ; Manchanda , V.K. ( 2007 ) Evaluation of N,N,N′,N′-tetraoctyl-3-oxapentane-diamide (TODGA) as a mobile carrier in remediation of nuclear waste using supported liquid membrane . J. Membr. Sci. , 298 : 169 – 174 .
  • Ansari , S.A. ; Mohapatra , P.K. ; Manchanda , V.K. ( 2009 ) Recovery of actinides and lanthanides from high-level waste using hollow-fiber supported liquid membrane with TODGA as the carrier . Ind. Eng. Chem. Res. , 48 : 8605 – 8612 .
  • Panja , S. ; Mohapatra , P.K. ; Tripathi , S.C. ; Manchanda , V.K. ( 2009 ) Studies on uranium(VI) pertraction across a N,N,N′,N′-tetraoctyldiglycolamide (TODGA) supported liquid membrane . J. Membr. Sci. , 337 : 274 – 281 .
  • Sharma , J.N. ; Ruhela , R. ; Harindaran , K.N. ; Mishra , S.L. ; Tangri , S.K. ; Suri , A.K. ( 2008 ) Separation studies of uranium and thorium using tetra(2-ethylhexyl) diglycolamide (TEHDGA) as an extractant . J. Radioanal. Nucl. Chem. , 278 : 173 – 177 .
  • Manohar , S. ; Sharma , J.N. ; Shah , B.V. ; Wattal , P.K. ( 2007 ) Process development for bulk separation of trivalent actinides and lanthanides from radioactive high-level liquid waste . Nucl. Sci. Eng. , 156 : 96 – 102 .
  • Boyadzhiev , L. ; Lazarova , Z. ( 1995 ) In: Membrane Separations Technology: Principles And Applications , Noble , R.D. ; Stern , S.A. eds.; Elsevier Science B.V. , 283 – 300 .
  • Bartsch , R.A. ; Way , J.D. ; Chrisstoffels , L.A.J. ; de Jong , F. ; Reinhouldt , D.N. ( 1996 ) In: Chemical Separations With Liquid Membranes , Bartsch , R.A. ; Way , J.D. ; eds.; ACS symposium series number 642, ACS : Washington , DC .
  • Mohapatra , P.K. ; Manchanda , V.K. ( 2003 ) Liquid membrane based separations of actinides and fission products . Indian J. Chem. , 42A : 2925 – 2939 .
  • Kocherginsky , N.M. ; Yang , Q. ; Seelam , L. ( 2007 ) Recent advances in supported liquid membrane technology . Sep. Purif. Technol. , 53 : 171 – 177 .
  • Panja , S. ; Ruhela , R. ; Misra , S.K. ; Sharma , J.N. ; Tripathi , S.C. ; Dakshinamoorthy , A. ( 2008 ) Facilitated transport of Am(III) through a flat-sheet supported liquid membrane (FSSLM) containing tetra(2-ethyl hexyl) diglycolamide (T2EHDGA) as carrier . J. Membr. Sci. , 325 : 158 – 165 .
  • Gujar , R.B. ; Ansari , S.A. ; Murali , M.S. ; Mohapatra , P.K. ; Manchanda , V.K. ( 2010 ) Comparative evaluation of tetra-2-ethylhexyl diglycolamide (T2EHDGA) for actinide partitioning . J. Radioanal. Nucl. Chem. , 284 : 377 – 385 .
  • Sriram , S. ; Mohapatra , P.K. ; Pandey , A.K. ; Manchanda , V.K. ; Badheka , L.P. ( 2000 ) Facilitated transport of americium(III) from nitric acid media using dimethyldibutyltetradecyl-1,3-malonamide . J. Membr. Sci. , 177 : 163 – 175 .
  • Ansari , S.A. ; Mohapatra , P.K. ; Prabhu , D.R. ; Manchanda , V.K. ( 2006 ) Transport of Americium(III) through a supported liquid membrane containing N,N,N′,N′-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier . J. Membr. Sci. , 282 : 133 – 141 .
  • Hofman , D.L. ; Craig , W.M. ; Buchalter , E.M. ; Birkill , R.S. ; Smit , J.J. Supported liquid membrane technology applied to the recovery of useful isotopes from reactor pool water, I. Chem. E. Symposium Series No. 103, Extraction ’87, EFCE Publication Series No. 347, pp. 180–182 .
  • Jensen , M.P. ; Yaita , T. ; Chiarizia , R. ( 2007 ) Reverse-micelle formation in the partitioning of trivalent f-element cations by biphasic systems containing a tetraalkyl diglycolamide . Langmuir , 23 : 4765 .
  • Gujar , R.B. ; Ansari , S.A. ; Mohapatra , P.K. ; Manchanda , V.K. ( 2010 ) Development of T2EHDGA based process for actinide partitioning Part-I: Batch studies for process optimization . Solv. Extr. Ion Exch. , 28 : 350 – 366 .
  • Babcock , W.C. ; Baker , R.W. ; LaChapelle , E.D. ; Smith , K.L. ( 1980 ) Coupled transport membranes III: The rate limiting step in uranium transport with a tertiary amine . J. Membr. Sci. , 7 : 89 .
  • Panja , S. ; Mohapatra , P.K. ; Tripathi , S.C. ; Manchanda , V.K. ( 2011 ) Controlled pertraction of plutonium(III) under reducing conditions from acidic feeds using TODGA as the carrier extractant . Sep. Sci. Technol. , 46 : 96 – 104 .
  • Wlike , C.R. ; Chang , P. ( 1955 ) Correlation of diffusion coefficients in dilute solutions . A. I. Ch. E. Journal , 1 : 264 – 270 .
  • Schotte , W. ( 1992 ) Prediction of the molar volume at the normal boiling point . Chem. Eng. J. , 48 : 167 – 172 .
  • Nakamura , S. ; Sato , A. ; Akiba , K. ( 1994 ) Application of europium(III) extraction with organophosphinic acid to liquid membrane transport . J. Radioanal. Nucl. Chem., Articles , 178 : 63 – 71 .
  • Lee , C.-J. ; Yang , B.-R. ( 1995 ) Extraction of trivalent europium via a supported liquid membrane containing PC-MA as a mobile carrier . Chem. Eng. J. , 57 : 253 – 260 .
  • Kemperman , A.J.B. ; Bargeman , D. ; van den Boomgaard , T. ; Strathmann , H. ( 1996 ) Stability of supported liquid membranes: State of the art . Sep. Sci. Technol. , 31 : 2733 – 2762 .
  • Kemperman , A.J.B. ; Rolevink , H.H.M. ; van den Boomgaard , T. ; Strathmann , H. ( 1997 ) Hollow-fiber supported liquid membranes with improved stability for nitrate removal . Sep. Purif. Technol. , 12 : 119 – 134 .
  • Neplenbroek , A.M. ; Bargeman , D. ; Smolder , C.A. ( 1992 ) Supported liquid membranes: Stabilization by gelation . J. Membr. Sci. , 67 : 149 – 165 .
  • Mohapatra , P.K. ; Lakshmi , D.S. ; Mohan , D. ; Manchanda , V.K. ( 2006 ) Uranium pertraction across a PTFE flatsheet membrane containing Aliquat 336 as the carrier . Sep. Purif. Technol. , 51 : 24 – 30 .
  • Mohapatra , P.K. ; Lakshmi , D.S. ; Mohan , D. ; Manchanda , V.K. ( 2004 ) Selective transport of cesium using a supported liquid membrane containing di-tert-butylbenzo 18 crown 6 as the carrier . J. Membr. Sci. , 232 : 133 – 139 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.