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Extraction

The Influence of Alkyl Chain Length and Steric Effect on the Stability Constants and Extractability of Co(II) Complexes with 1-Alkyl-2-Methylimidazoles

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Pages 676-682 | Received 16 Sep 2013, Accepted 26 Aug 2014, Published online: 02 Mar 2015

REFERENCES

  • Sundberg, R. J.; Martin, R. B. (1974) Interactions of histidine and other imidazole derivatives with transition metal ions in chemical and biological system. Chemical Reviews, 74: 471–517.
  • Lenarcik, B.; Ojczenasz, P. (2002) The influence of the size and position of the alkyl groups in alkylimidazole molecules on their acid-base properties. Journal of Heterocyclic Chemistry, 39: 287–290.
  • Lenarcik, B.; Barszcz, B. (1980) Stability and structure of transition metal complexes with azoles in aqueous solutions. Part XXI. A comparison of complex-forming of 1,2-dimethylimidazole with that of other 1,3-diazoles. Journal of the Chemical Society Dalton Transactions, 24–28 (DOI:1039/DT9800000024).
  • Lenarcik, B.; Kulig, J.; Laider, P. (1974) Stability and structure of transition metal complexes with azoles in aqueous solutions. Part II. 2-methylimidazole complexes of Co(II), Cu(II) and Zn(II). Roczniki Chemii, 48: 1151–1158.
  • Lenarcik, B.; Kurdziel, K.; Czopek, R. (1991) Stability and structure of transition metal complexes with azoles in aqueous solutions. Part XXVIII. The steric effect in the complex formation of 2-n-propylimidazole and 2-isopropylimidazole. Polish Journal of Chemistry, 65: 815–820.
  • Lenarcik, B.; Kurdziel, K.; Czopek, R. (1991) Stability and structure of transition metal complexes with azoles in aqueous solutions. Part XXIX. The influence of the size and structure of the alkyl group on the formation of 2-alkylimidazole complexes. Polish Journal of Chemistry, 65: 1235–1241.
  • Lenarcik, B.; Kurdziel, K.; Czopek, R. (1991) Research of optimum conditions for extraction of metal complexes by alkylimidazole. Part IV. The influence of the steric effect on the extraction of the complexes of 2-ethylimidazole with Co(II), Ni(II), Zn(II) and Cd(II). Polish Journal of Chemistry, 65: 837–843.
  • Cuprey, M. E. U.S. Patent No. 3,843,667. October 22, N-Imidazole compounds and their complex metal derivatives. Washington, D.C.: U.S. Patent and Trademark Office, 1974.
  • Schaekers, J. M.; du Preez, J. G. H. U.S. Patent No 2004/0208808 A1. Solvent extraction mixture comprising substituted imidazole or benzimidazole for the purification of groups of base metals. Washington, D.C.; U.S. Patent and Trademark Office, 2004.
  • Gheaedi, M.; Niknam, K.; Shokrollahi, A.; Niknam, E.; Gheadi, H.; Soylak, M. (2008) A solid extraction procedure for Fe3+, Cu2+ and Zn2+ ions on 2-phenyl-1H-benzo[d] imidazole loaded on Triton Z-100 coated polyvinyl chloride. Journal of Hazardous Materials, 158: 131–136.
  • Ulewicz, M.; Radzyminska-Lenarcik, E. (2012) Application of supported and polymer membrane with 1 decyl-2-methylimidazole for separation of transition metal ions. Physicochemical Problems of Mineral Processing, 48: 91–102.
  • Radzyminska-Lenarcik, E.; Ulewicz, M. (2012) Selective transport of Cu(II) across a polymer inclusion membrane with 1-alkylimidazole from nitrate solutions. Separation Science and Technology, 47: 1113–1118.
  • Ulewicz, M.; Radzyminska-Lenarcik, E. (2012) Supported liquid (SLM) and polymer inclusion (PIM) membranes pertraction of copper(II) from aqueous nitrate solutions by 1-hexyl-2-methylimidazole. Separation Science and Technology, 47: 1383–1389.
  • Lenarcik, B.; Ojczenasz, P. (2004) Investigation of the stability constants of Co(II) complexes with a homologous series of 1-alkylimidazoles in aqueous solution by using a partition method with several solvents. Separation Science and Technology, 39: 199–226.
  • Lenarcik, B.; Rauckyte, T. (2004) The influence of alkyl length on extraction equilibria of Ni(II) complexes with 1-alkylimidazoles in aqueous solution/organic solvent systems. Separation Science and Technology, 39: 3353–3372.
  • Radzyminska-Lenarcik, E. (2007) The influence of the alkyl chain length on the extraction equilibrium of Cu(II) complexes with 1-alkylimidazoles in aqueous solution -organic solvent systems. Solvent Extraction and Ion Exchange, 25: 53–64.
  • Lenarcik, B.; Kierzkowska, A. (2004) The influence of alkyl length on stability constants of Zn(II) complexes with 1-alkylimidazoles in aqueous solutions and their partition between aqueous phase and organic solvent. Solvent Extraction and Ion Exchange, 22: 449–471.
  • Lenarcik, B.; Ojczenasz, P.; Kopkowski, A. (2006) The influence of the alkyl chain length and steric effect on stability constants and extractability of Co(II) complexes with 1-alkyl-4(5)-methylimidazoles. Separation Science and Technology, 41: 1697–1724.
  • Radzyminska-Lenarcik, E. (2010) The Influence of alkyl chain length and donor number of solvents on the extraction of copper(II) complexes with 1-alkyl-4-methylimidazoles. Solvent Extraction and Ion Exchange, 28: 636–652.
  • Lenarcik, B.; Kierzkowska, A. (2004) The influence of alkyl chain length and steric effect on stability constants and extractability of Zn(II) complexes with 1-alkyl-4(5)-methylimidazoles. Solvent Extraction and Ion Exchange, 39: 3485–3508.
  • Radzyminska-Lenarcik, E. (2007) Effect of alkyl chain length on the extraction of Copper(II) complexes with 1-alkyl-2-methylimidazoles. Separation Science and Technology, 42: 2661–2676.
  • Lenarcik, B.; Kierzkowska, A. (2006) The influence of alkyl chain length and steric effect on extraction of zinc(II) complexes with 1-alkyl-2-methylimidazoles. Solvent Extraction and Ion Exchange, 24: 433–445.
  • Pernak, J.; Krysinski, J.; Skrzypczak, A. (1987) Bakterizide wirkung von Iminiumverbindungen. A. Tenside. Surfactants Detergents, 24(5): 276–286.
  • Braibanti, A.; Ostacoli, G.; Paoletti, P.; Pettit, L. D.; Sammartano, S. (1987) Potentiometric apparatus and technique for the pH-metric measurement of metal-complex equilibrium constants. Pure and Applied Chemistry, 59: 1721–1728.
  • Rydberg, J. (1950) On the complex formation between thorium and acetylacetone. Acta Chemica Scandinavica, 4: 1503–1522.
  • Rossotti, F. J. C.; Rossotti, H. (1961) The Determination of Stability Constants;McGraw-Hill: New York.
  • Rydberg, J.; Musakis, C.; Choppin, G. R. (1992) Principles and Practices of Solvent Extraction; vol.1, 22–24. Marcel Dekker: New York
  • Barszcz, B.; Kulig, J. (1993) Comparison of the complexing processes of 1-butyl-2-hydroxymethylimidazole and 1-butyl-2-methylimidazole in aqueous solution. Journal of the Chemical Society Dalton Transactions, 1559–1562.
  • Marcus, Y. (1992) Principles of solubility and solutions. In: Principles and Practices of Solvent Extraction;Rydberg, J., Musikas, C., Choppin, G. R., eds.; Marcel Dekker: New York; vol. 1, pp 22–24.
  • van Panthaleon van Eck, C. L. (1953) On the mutual stability relationship of MeAn complexes consisting of a metal ion Me and a ligand A in aqueous solution, for consecutive values of n. Recueil des Travaux Chimiques des Pays-Bas, 72: 529–537.

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