Extraction of Trivalent Europium and Americium from Nitric Acid Solution with Bisdiglycolamides

REFERENCES

• Law, D.; Brewer, K. N.; Herbst, R. S.; Todd, T. A.; Wood, D. J. (1999) Development and demonstration of solvent extraction processes for the separation of radionuclides from acidic radioactive waste. Waste Manage., 1 (19): 27.
   Web of Science ®Google Scholar
• Schulz, W. W.; Bray, L. A. (1987) Solvent extraction recovery of byproduct 137Cs and 90Sr from HNO3 solutions: A technology review and assessment. Sep. Sci. Technol., 22 (2–3):191.
   Web of Science ®Google Scholar
• Mathur, J. N.; Murali, M. S.; Nash, K. L. (2001) Actinide portioning: A review. Solvent Extr. Ion. Exch., 19 (3):357.
   Web of Science ®Google Scholar
• Ravi, J.; Venkatesan, K. A.; Antony, M. P.; Srinivasan, T. G.; Vasudeva, Rao, P. R. (2012) Tuning the diglycolamides for modifier-free minor actinide partitioning. J. Radioanal. Nucl. Chem., 295 (3):1283.
   Google Scholar
• Morita, Y.; Glatz, J. P.; Kubota, M.; Koch, L.; Pagliosa, G.; Römer, K.; Nicholl, A. (1996) Actinide partioning from HLLW in a continuous DIDPA extraction process by means of centrifugal extractors. Solvent Extr. Ion. Exch., 14 (3):385.
   Web of Science ®Google Scholar
• Horwitz, E. P.; Kalina, D. G.; Diamond, H. D.; Vandergrift, G. F.; Schultz, W. W. (1985) The TRUEX process: A process for the extraction of the transuranic elements from nitric acid in wastes utilizing modified PUREX solvent. Solvent Extr. Ion. Exch., 3 (1–2):75.
   Web of Science ®Google Scholar
• Schultz, W. W.; Horwitz, E. P. (1988) The TRUEX process and the management of liquid transuranium waste. Sep. Sci. Technol., 23 (12–13):1191.
   Web of Science ®Google Scholar
• Courson, O.; Lebrun, M.; Malmbeck, R.; Pagliosa, G.; Römer, K.; Sätmark, B.; Glatz, J. P. (2000) Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process. Radiochim. Acta, 88 (12):857.
   Web of Science ®Google Scholar
• Malmbeck, R.; Courson, O.; Pagliosa, G.; Römer, K.; Sätmark, B.; Glatz, J. P.; Baron, P. (2000) Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 – “Hot” continuous counter-current experiment. Radiochim. Acta, 88 (12):865.
   Web of Science ®Google Scholar
• Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S. (2001) The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3-n-dodecane system. Solvent Extr. Ion. Exch., 19 (1):91.
   Web of Science ®Google Scholar
• Sasaki, Y.; Tachimori, S. (2002) Extraction of actinides(III), (IV), (V), (VI) and lanthanides(III) by structurally tailored diamides. Solvent Extr. Ion. Exch., 20 (1):21.
   Web of Science ®Google Scholar
• Tachimori, S.; Sasaki, Y.; Suzuki, S. (2002) Modification of TODGA-n-dodecane solvent with a monoamide for high loading of lanthanides(III) and actinides(III). Solvent Extr. Ion. Exch., 20 (6):687.
   Web of Science ®Google Scholar
• Deb, A. K. S.; Ilaiyaraja, P.; Ponraju, D.; Venkatraman, B. (2011) Diglycolamide functionalized multi-walled carbon nanotubes for removal of uranium from aqueous solution by adsorption. J. Radioanal. Nucl. Chem., 291 (3):877.
   Web of Science ®Google Scholar
• Vyas, C. K.; Joshirao, P. M.; Bagla, H.; Manchanda, V. K.; (2013) Distribution behavior of U(VI), Am(III) and Eu(III) on diglycolamide based extraction chromatographic resin in perchloric acid medium. J. Radioanal. Nucl. Chem., 298 (3):1643.
   Web of Science ®Google Scholar
• Modolo, G.; Vijgen, H.; Purroy, D. S.; Christiansen, B.; Malmbeck, R.; Sorel, C.; Baron, P. (2007) DIAMEX counter‐current extraction process for recovery of trivalent actinides from simulated high active concentrate. Sep. Sci. Technol., 42 (3):439.
   Web of Science ®Google Scholar
• Ansari, S. A.; Pathak, P. N.; Manchandaa, V. K.; Husain, M.; Prasad, A. K.; Parmar, V.S. N, N, N′, N′-Tetraoctyl Diglycolamide(TODGA): A Promising Extractant for Actinide‐Partitioning from High‐Level Waste (HLW), Solvent Extr. Ion. Exch, 23 (1–3):463.
   Google Scholar
• Suzuki, H.; Sasaki, Y.; Sugo, Y.; Apichaibukol, A.; Kimura, T. (2004) Extraction and separation of Am(III) and Sr(II) by N, N, N´, N´-tetraoctyl-3-oxapentanediamide (TODGA). Radiochim. Acta, 92 (8):463.
   Web of Science ®Google Scholar
• Tachimori, S.; Sasaki, Y.; Suzuki, S. (2002) Modification of TODGA-n-dodecane solvent with a monoamide for high loading of lanthanides(III) and actinides(III). Solvent. Extr. Ion. Exch., 20 (6):687.
   Web of Science ®Google Scholar
• Mohapatra, P. K.; Iqbal, M.; Raut, D. R.; Huskens, J.; Verboom, W. (2012) Unusual transport behaviour of actinide ions with a novel calix[4]arene-tetra-diglycolamide (C4DGA) extractant as the carrier. J. Membr. Sci., 411–412: 64.
   Google Scholar
• Ansari, S. A.; Mohapatra, P. K.; Iqbal, M.; Kandwal, P.; Huskens J.; Verboom, W. (2013) Novel diglycolamide-functionalized calix[4]arenes for actinide extraction and supported liquid membrane studies: Role of substituents in the pendent arms and mass transfer modeling. J. Membr. Sci., 430:304.
   Web of Science ®Google Scholar
• Mohapatra, P. K.; Sengupta, A.; Iqbal, M.; Huskens, J.; Verboom, W. (2013) Diglycolamide-functionalized calix[4]arenes showing unusual complexation of actinide ions in room temperature ionic liquids: Role of ligand structure, radiolytic stability, emission spectroscopy, and thermodynamic studies. Inorg. Chem., 52 (5): 2533.
   PubMed Web of Science ®Google Scholar
• Sengupta, A.; Mohapatra P. K.; Iqbal, M.; Huskens, J.; Verboom, W. (2012) A highly efficient solvent system containing functionalized diglycolamides and an ionic liquid for americium recovery from radioactive wastes. Dalton Trans., 41 (23):6970.
   PubMed Web of Science ®Google Scholar
• Mohapatra, P. K.; Rout, D. R.; Iqbal, M.; Huskens, J.; Verboom, W. (2013) A comparative evaluation of the liquid–liquid extraction and pertraction efficiency of a both-side diglycolamide-functionalized calix[4]arene with analogous upper and lower-rim calixarenes for actinide separations. J. Membr. Sci., 444:268.
   Web of Science ®Google Scholar
• Sharma, J. N.; Ruhela, R.; Manohar, S.; Wattal, P. K.; Suri, A. K. Dialkyldiaza-tetraalkyloctane diamide derivatives useful for the separation of trivalent actinides from lanthanides and process for the preparation thereof. US. Patent 0172626A1, July 5, 2012.
   Google Scholar
• Murillo, M. T., Espartero, A. G., Sánchez-Quesada, J., de Mendoza, J.; Prados, P. (2009) Synthesis of pre-organized bisdiglycolamides (BisDGA) and study of their extraction properties for Actinides (III) and Lanthanides (III). Solvent Extr. Ion Exch., 27(2),107–131.
   Web of Science ®Google Scholar
• Iqbala, M., Huskens, J.; Verboom, W.; Sypula, M.; Modolo, G. (2010) Synthesis and Am/Eu extraction of novel TODGA derivatives. Supramol. Chem., 22 (11–12): 827–837.
   Web of Science ®Google Scholar
• Zhang, P.; Wang, H. R.; Wang, J. C.; Chen, J. (2008) Synthesis and characterization of water-soluble oxa-amide compounds. Chin. J. Org. Chem., 28(2):335.
   Web of Science ®Google Scholar
• Mowafy, E. A.; Aly, H. F. (2007) Synthesis of some N, N, N′, N′-tetraalkyl-3-oxa-pentane-1,5-diamide and their applications in solvent extraction. Solvent Extr. Ion. Exch., 25 (2):205.
   Web of Science ®Google Scholar
• Guillaumont, R.; Fanghänel, T. H.; Fuger, J.; Grenthe, I.; Neck, V.; Palmer, D. A.; Rand, M. H. (2003) Chemical Thermodynamics; Elsevier: Amsterdam, N.L.
   Google Scholar
• Ansari, S. A.; Pathak, P.; Mohapatra, P. K.; Manchanda, V. K. (2012) Chemistry of diglycolamides: Promising extractants for actinide partitioning. Chem. Rev. 112(3): 1751–1772.
   PubMed Web of Science ®Google Scholar
• Iqbal, M.; Huskens, J.; Verboom, W.; Sypula, M.; Modolo, G. (2010) Synthesis and Am/Eu extraction of novel TODGA derivatives. Supramol. Chem., 22(11): 827–837.
   Web of Science ®Google Scholar
• Horwitz, E. P.; Muscatello, A. C.; Kalina, D. G.; Kaplan, L. (1981) The extraction of selected transplutonium(III) and lanthanide(III) ions by dihexyl-N, N-diethylcarbamoylmethylphosphonate from aqueous nitrate media. Sep. Sci. Technol., 16 (4):417.
   Web of Science ®Google Scholar
• Ansari, S. A.; Pathak, P. N.; Husain, M.; Prasad, A. K.; Parmar, V. S.; Manchanda, V. K. (2006) Extraction of actinides using N, N, N′, N′-tetraoctyl diglycolamide (TODGA): a thermodynamic study. Radiochim. Acta., 94 (6–7):307.
   Web of Science ®Google Scholar
• Lever, A. B. P., Mantovani, E., Ramaswamy, B. S. (1971) Infrared combination frequencies in coordination complexes containing nitrate groups in various coordination environments. A probe for the metal-nitrate interaction. Can. J. Chem., 49 (11):1957.
   Web of Science ®Google Scholar
• Curtis, N. F.; Curtis, Y. M. (1965) Some nitrato-amine nickel(II) compounds with monodentate and bidentate nitrate ions. Inorg. Chem., 4 (6): 804.
   Web of Science ®Google Scholar
• Nakamoto, K. (1978) Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed.; Wiley: NewYork.
   Google Scholar