199
Views
8
CrossRef citations to date
0
Altmetric
Articles

Extraction of Eu(III) and Am(III) by 1-phenyl-3-methyl-4-acetylpyrazol-5-one (HPMAP) and tri-n-octylphosphine oxide (TOPO) in a room-temperature ionic liquid

, , &
Pages 2318-2327 | Received 30 Sep 2016, Accepted 12 Jan 2017, Published online: 22 Feb 2017

References

  • IAEA TECDOC-1103. (1999) Status and Trends of Spent Fuel Reprocessing. IAEA, Vienna.
  • Magill, J.; Berthou, V.; Haas, D.; Galy, J.; Schenkel, R.; Wiese, H.W.; Heusener, G.; Tommasi, J.; Youinou, G. (2003) Impact limits of partitioning and transmutation scenarios on the radiotoxicity of actinides in radioactive waste. Nuclear Energy, 42: 263–277.
  • Nash, K.L.; Madic, C.; Mathur, J.N.; Lacquement, J. (2006) Actinide separation science and technology. In: Morss, L.R.; Edelstein, N.M.; Fuger, J.; Katz, J.J. (eds.) The Chemistry of the Actinide and Transactinide Element, 3rd edn, vol. 4. Springer: The Netherlands, p. 2622.
  • Bertrand, P.A.; Choppin, G.R. (1982) Separation of actinides in different oxidation states by solvent extraction. Radiochimica Acta, 31: 135–138.
  • Ramakrishna, V.V.; Patil, S.K.; Haraprakash, B. (1979) Solvent extraction and spectrophotometric studies on synergistic extraction of plutonium(1V) by mixtures of thenoyltrifluoroacetone (HTTA) and tri-n-butylphosphate. Separation Science and Technology, 14: 571–589.
  • Irving, H.; Edgington, D.N. (1961) Synergic effects in the solvent extraction of the actinides—II plutonium (VI) and neptunium (VI). Journal of Inorganic and Nuclear Chemistry, 20: 314–320.
  • Sivakumar, P.; Meenakshi, S.; Mohan, S.V.; Subba Rao, R.V.; Venkataraman, M. (2012) Modified TTA method for the determination of plutonium, J. Radioanal. Nucl. Chem., 294: 93–96.
  • Batzar, K.; Goldberg, D.E.; Newman, L. (1967) Effect of β-diketone structure on the synergistic extraction of uranyl ion by tributyl phosphate. Journal of Inorganic and Nuclear Chemistry 29: 1511–1518.
  • Banerjee, S.; Bhattacharyya, A.; Mohapatra, P.K.; Basu, S.; Manchanda, V.K. (2003) Extraction of the uranyl ion with 3-phenyl-4-benzoyl-5-isoxazolone (HPBI) and neutral donors from dilute nitric acid medium. Radiochimica Acta, 91: 729–736.
  • Jensen, B.S. (1959) Solvent extraction of metal chelates. Acta Chemica Scandinavica, 13: 1890–1896.
  • Coronel, F.; Mareva, S.; Yordanov, N. (1982) Extraction of uranium(IV) from phosphoric acid solutions with 1-phenyl-3-methyl-4-benzoyl pyrazolone-5 (PMBP). Talanta, 29: 119–123.
  • Arora, H.C.; Rao, G.N. (1982) Solvent extraction of Cu(II), Co(II), Ni(II) & Th(IV) with 1-phenyl-3-methyl-4-p-nitrobenzoyl-5-pyrazolone. Indian Journal of Chemistry, 21A: 335–338.
  • Umetani, S.; Matsui, M. (1983) Liquid-liquid distribution of 4-acyl-3-methyl-1-phenyl-5-pyrazolones and their zinc complexes. Bulletin of the Chemical Society of Japan, 56: 3426–3429.
  • Sasaki, Y.; Freiser, H. (1983) Mixed-Ligand Chelate Extraction of Lanthanides with l-Phenyl-3-methyl-4-acyl-5-pyrazolones. Inorganic Chemistry, 22: 2289–2292.
  • Bacher, W.; Keller, C. (1973) 4-Acyl substituierte 1-phenyl-3-methylpyrazolone-5 als chelatbildner fuer actinidenionen. Journal of Inorganic and Nuclear Chemistry, 35: 2945–2956.
  • Mathur, J.N.; Khopkar, P.K. (1987) Liquid-liquid extraction of trivalent actinides and lanthanides with 1-phenyl-3-methyl-4- trifluoroacetyl pyrazolone-5. Polyhedron, 6: 2099–2102.
  • Manchanda, V.K.; Mohapatra, P.K. (1993) Extraction of plutonium(IV) with 1-phenyl-3-methyl-4-benzoyl pyrazol-5-one and tri-n-octyl phosphine oxide. Radiochimica Acta, 60: 185–189.
  • Nagar, M.S.; Ruikar, P.B.; Subramanian, M.S. (1987) Synergistic complexes of uranyl ion with 1-phenyl-3-methyl-4-acetyl-pyrazolone-5 and some oxo-donors. Polyhedron, 6: 1913–1917.
  • Mohapatra P.K.; Manchanda V. K. (1992) Extraction of Am(III) and Cm(III) with 1-phenyl-3-methyl-4-acetyl pyrazolone-5, Radiochimica Acta, 57: 25–28.
  • Welton, T. (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chemical Reviews, 99: 2071–2083.
  • Binnemans, K. (2007) Lanthanides and actinides in ionic liquids. Chemical Reviews, 107: 2592–2614.
  • Ohno, H. (Ed.). (2005) Electrochemical Aspects of Ionic Liquids. Wiley-Interscience: Hoboken.
  • Baker, G.A.; Baker, S.N.; Pandey, S.; Bright, F.V. (2005) An analytical view of ionic liquids. Analyst, 130: 800–808.
  • Billard, I. (2013) Ionic liquids: New hopes for efficient lanthanide/actinide extraction and separation. In: Bunzli, J.C.G.; Pecharsky, V. (eds.), Handbook on the Physics and Chemistry of Rare Earths. Elsevier Science Pub. B.V.: Amsterdam, pp. 213–373.
  • Sun, X.; Luo, H.; Dai, S. (2012) Ionic liquids-based extraction: A promising strategy for the advanced nuclear fuel cycle. Chemical Reviews, 112: 2100–2128.
  • Mohapatra, P.K. (2015) Diglycolamide-based solvent systems in room temperature ionic liquids for actinide ion extraction: A review. Chemical Product and Process Modelling, 10: 135–145.
  • Vasudeva Rao, P.R.; Venkatesan, K.A.; Rout, A.; Srinivasan, T.G.; Nagarajan, K. (2012) Potential applications of room temperature ionic liquids for fission products and actinide separation. Separation Science and Technology 47: 204–222.
  • Panja, S.; Mohapatra, P.K.; Tripathi, S.C.; Gandhi, P.M. and Janardan, P. (2012) A highly efficient solvent system containing TODGA in room temperature ionic liquids for actinide extraction. Separation and Purification Technology, 96: 289–295.
  • Patil, A.B.; Pathak, P.N.; Shinde, V.S.; Godbole, S.V. and Mohapatra, P.K. (2013) Efficient solvent system containing malonamides in room temperature ionic liquids: actinide extraction, fluorescence and radiolytic degradation studies. Dalton Transactions, 42: 1519–1529.
  • Paramanik, M.; Raut, D.R.; Sengupta A.; Ghosh, S.K.; Mohapatra, P.K. (2016) A trialkyl phosphine oxide functionalized task specific ionic liquid for actinide ion complexation: Extraction and spectroscopic studies. RSC Advances, 6: 19763–19767.
  • Bhattacharyya, A.; Ansari, S.A.; Gadly, T.; Ghosh, S.K.; Mohapatra, M.; Mohapatra, P.K. (2015). A remarkable enhancement in Am3+/Eu3+selectivity by an ionic liquid based solvent containing bis-1,2,4-triazinyl pyridine derivatives: DFT validation of experimental results. Dalton Transactions, 44: 6193–6201.
  • Mohapatra, P.K.; Kandwal, P.; Iqbal, M.; Huskens, J.; Murali, M.S. and Verboom, W. (2013) A novel CMPO-functionalized task specific ionic liquid: Synthesis, extraction and spectroscopic investigations of actinide and lanthanide complexes. Dalton Transactions. 42: 4343–4347.
  • Billard, I.; Ouadi, A.; Gaillard, C. (2013) Is a universal model to describe liquid–liquid extraction of cations by use of ionic liquids in reach? Dalton Transactions, 42:6203–6212.
  • Atanassova, M.; Kurteva, V.; Lubenov, L.; Billard, I. (2014) Comparing extraction, synergism and separation of lanthanoids using acidic and neutral compounds in chloroform and one ionic liquid: is the latter always “better”? RSC Advances, 4: 38820–38829.
  • Petrova, M.A. (2016) Worthy extraction and uncommon selectivity of 4-f ions in ionic liquid medium: 4-acylpyrazolones and CMPO. ACS Sustainable Chemistry & Engineering, 4: 2366–2375.
  • Sukhbaatar, T.; Dourdain, S.; Turgis, R.; Rey, J.; Arrachart, G.; Pellet-Rostaing, S. (2015) Ionic liquids as diluents in solvent extraction: first evidence of supramolecular aggregation of a couple of extractant molecules. Chemical Communications, 51: 15960–15963.
  • Dai, S.; Ju, Y.H.; Barnes, C.E. (1999) Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids. J. Chem. Soc. Dalton Transactions, 1201–1202.
  • Kidani, K.; Hirayama, N.; Imura, H. (2008) Extraction behavior of divalent metal cations in ionic liquid chelate extraction systems using 1-alkyl-3-methyl imidazolium bis(trifluoromethanesulfonyl)imides and Thenoyltrifluoroacetone. Analytical Sciences, 24: 1251–1254.
  • Jensen, M.P.; Neuefeind, J.; Beitz, J.V.; Skanthakumar, S.; Soderholm, L. (2003) Mechanisms of metal ion transfer into room-temperature ionic liquids: The role of anion exchange. Journal of the American Chemical Society, 125: 15466–5473.
  • Patil, S.K.; Ramakrishna, V.V.; Kartha, P.K.S.; Gudi, N.M. (1980). Synergistic Extraction of Plutonium(IV) from nitric acid medium by mixtures of TOPO and HTTA. Separation Science and Technology 15:1459–1469.
  • Hirayama, N., Okamura, H., Kidani, K., Imura, H. (2008) Ionic liquid synergistic cation-exchange system for the selective extraction of lanthanum(III) using 2-thenoyltrifluoroacetone and 18-Crown-6. Analytical Sciences, 24, 697–699.
  • Gujar, R.B.; Ansari, S.A.; Sengupta, A.; Murali, M.S.; Mohapatra, P.K. (2016) Extractive complexation of lanthanides and Am(III) by 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone in ionic liquid: Solvent extraction and spectroscopic studies (2016). Inorganic Chemistry Communications, 73: 72–76.
  • Mohapatra, P.K. (1993) PhD Thesis, University of Bombay, Mumbai.
  • Okamura, H.; Sakae, H.; Kidani, K.; Hirayama,N.; Aoyagi, N.; Saito, T.; Shimojo, K.; Naganawa, H.; Imura, H. (2012) Laser-induced fluorescence and infrared spectroscopic studies on the specific solvation of tris(1-(2-thienyl)-4,4,4-trifluoro-1,3-butanedionato)europium(III) in an ionic liquid. Polyhedron, 31: 748–753.
  • Okamura, H.; Hirayama, N.; Morita, K.; Shimojo, K.; Naganawa, H.; Imura, H. (2010) Synergistic Effect of 18-Crown-6 Derivatives on Chelate Extraction of Lanthanoids(III) into an Ionic liquid with 2-thenoyltrifluoroacetone. Analytical Sciences, 26: 607–611.
  • Kumar, A.; Rai, D.K.; Rai, S.B. (2002) Optical studies of Eu3+ ions doped in tellurite glass Spectrochimica Acta A 58: 2115–2125.
  • Lin, H.; Yang, D.; Liu, G.; Ma, T.; Zhai, B.; An, Q.; Yu, J.; Wang, X.; Liu, X.; Pun, E.Y. (2005). Optical absorption and photoluminescence in Sm3+- and Eu3+-doped rare-earth borate glasses. Journal of Luminescence, 113: 121–128.
  • Horrocks, W.D.; Sudnick, D.R. (1979) Lanthanide ion probes of structure in biology. Laser-induced luminescence decay constants provide a direct measure of the number of metal-coordinated water molecules. Journal of the American Chemical Society, 101: 334−340.
  • Choppin, G.R.; Peterman, D.R. (1998) Applications of lanthanide luminescence spectroscopy to solution studies of coordination chemistry. Coordination Chemical Reviews 174: 283−299.
  • Zhang, P; Kimura, T. (2006) Complexation of Eu(III) with dibutyl phosphate and tributyl phosphate. Solvent Extraction and Ion Exchange, 24: 149–163.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.