Removal of cesium by countercurrent solvent extraction with a calix[4]crown derivative

References

• Dam, H.H.; Reinhoudt, D.N.; Verboom, W. (2007) Multicoordinate ligands for actinide/lanthanide separations. Chemical Society Reviews, 36: 367–377.
   PubMed Web of Science ®Google Scholar
• Kolarik, Z. (2008) Complexation and separation of lanthanides(III) and actinides(III) by heterocyclic N-donors in solutions. Chemical Reviews, 108: 4208–4252.
   PubMed Web of Science ®Google Scholar
• Ekberg, C.; Fermvik, A.; Retegan, T. (2008) An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III). Radiochimica Acta, 96: 225–233.
   Web of Science ®Google Scholar
• Choppin, G.R.; Nash, K.L. (1995) Actinide separation science. Radiochimica Acta, 70–71: 225–236.
   Web of Science ®Google Scholar
• Mathur, J.M.; Murali, M.S.; Nash, K.L. (2001) Actinides partitioning–A review. Solvent Extraction and Ion Exchange, 19: 357–390.
   Web of Science ®Google Scholar
• Zhang, A.; Xiao, C.; Chai, Z. (2011) Development of silica-based supramolecular recognition materials in spent nuclear fuel reprocessing. Progress in Chemistry, 23: 1355–1365.
   Web of Science ®Google Scholar
• Christiansen, B.; Apostolidis, C.; Carlos, R. (2004) Advanced aqueous reprocessing in P&T strategies: Process demonstrations on genuine fuels and targets. Radiochimica Acta, 92: 475–480.
   Web of Science ®Google Scholar
• Warin, D.; Boullis, B.; Mouney, H. (2001) Status of French programme on partitioning and transmutation for nuclear waste management. Proc. Int. Conf. (Global 2001), September 9–13: 2001, Paris, France, 59–66.
   Google Scholar
• Collins, E.D.; Renier, J.P. (2005) Systems studies of actinide partitioning-transmutation recycle methods, Proc. Int. Conf. (Global 2005), 9–13 Oct., Japan, 235–236.
   Google Scholar
• Oigawa, H.; Minato, K.; Kimura, T.; Morita, Y.; Arai, Y.; Nakayama, S.; Nishihara, K. (2005) Present status and future perspective of research and development on partitioning and transmutation technology at JAERI. Proc. Int. Conf. (Global 2005), 9–13 Oct., Japan, 207–209.
   Google Scholar
• Herbst, R.S.; Law, J.D.; Todd, T.A.; Romanovskiy, V.N.; Babain, V.A.; Esimantovskiy, V.M.; Smirnov, I.V.; Zaitsev, B.N. (2002) Universal solvent extraction (UNEX) flowsheet testing for the removal of cesium, strontium, and actinides elements from radioactive, acidic dissolved waste. Solvent Extraction and Ion Exchange, 20: 429–445.
   Web of Science ®Google Scholar
• Romanovskiy, V.N.; Smirnov, I.V.; Babain, V.A.; Todd, T.A.; Law, J.D.; Herbst, R.S.; Brewer, K.N. (2001) The Universal solvent extraction (UNEX) process. I. Development of the UNEX process solvent for the separation of cesium, strontium, and the actinides from acidic radioactive waste. Solvent Extraction and Ion Exchange, 19: 1–21.
   Web of Science ®Google Scholar
• Law, J.D.; Herbst, R.S.; Todd, T.A.; Romanovskiy, V.N.; Babain, V.A.; Esimantovskiy, V.M.; Smirnov, I.V.; Zaitsev, B.N. (2001) The universal solvent extraction (UNEX) process. II. Flow sheet development and demonstration of the UNEX process for the separation of cesium, strontium, and actinides from actual acidic radioactive waste. Solvent Extraction and Ion Exchange, 19: 23–36.
   Web of Science ®Google Scholar
• Apichaibukol, A.; Sasaki, Y.; Morita, Y. (2004) Effect of DTPA on the extractions of actinides (III) and lanthanides(III) from nitrate solution into TODGA/n-dodecane. Solvent Extraction and Ion Exchange, 22: 997–1012.
   Web of Science ®Google Scholar
• Koma, Y.; Watanabe, M.; Nemoto, S.; Tanaka, Y. (1998) A counter current experiment for the separation of trivalent actinides and lanthanides by the SETFICS process. Solvent Extraction and Ion Exchange, 16: 1357–1367.
   Web of Science ®Google Scholar
• Schulz, W.W.; Horwitz, E.P. (1988) The TRUEX process and the management of liquid TRU waste. Separation Science and Technology, 23: 1191–1210.
   Web of Science ®Google Scholar
• Madic, C. (2002) Overview of the hydrometallurgical and pyrometallurgical processes studied world-wide for the partitioning of high active nuclear wastes. International Symposium NUCEF 2001, Japan Atomic Energy Research Institute, Tokai, Ibaraki, Japan, 27–37.
   Google Scholar
• Koma, Y.; Watanabe, M.; Nemoto, S.; Tanaka, Y. (1998) Trivalent f-element intra-group separation by solvent extraction with CMPO–complexant system. Journal of Nuclear Science and Technology, 35: 130–136.
   Web of Science ®Google Scholar
• Asfari, Z.; Bressot, C.; Vicens, J.; Hill, C.; Dozol, J.F.; Rouquette, H.; Eymard, S.; Lamare, V.; Tournois, B. (1995) Doubly crowned calix[4]arenes in the 1,3-alternate conformation as cesium-selective carriers in supported liquid membranes. Analytical Chemistry, 67: 3133–3139.
   Web of Science ®Google Scholar
• Baron, P.; Lecomte, M.; Boullis, B.; Simon, N.; Warin, D. (2003) Separation of the long lived radionuclides: Current status and future R&D program in France. Proc. Int. Conf. (Global 2003), New Orleans, the United States of America, 565–574.
   Google Scholar
• Dybal, J.; Makrlik, E.; Vanura, P.; Budka, J. (2008) Protonation of 25,27-bis(1-octyloxy) calix[4]arene-crown-6 in the 1,3-alternate conformation. Analytical Chemistry, 139: 1175–1178.
   Google Scholar
• Asfari, Z.; Böhmer, V.; Harrowfield, J.; Vicens, J. (2001) Calixarenes 2001. 3300 AA Dordrecht; Kluwer Academic Publishers: The Netherlands, 312–333.
   Google Scholar
• Asfari, Z.; Wenger, S.; Vicens, J. (1994) Calixcrowns and related molecules. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 19 (1–4): 137–148.
   Web of Science ®Google Scholar
• Ludwing, R.; Dzung, N.T. K. (2002) Calixarene-based molecules for cation recognition. Sensors, 2: 397–416.
   Web of Science ®Google Scholar
• Ji, H.; Dabestani, R.; Brown, G.M.; Hettich, R.L. (2001) Synthesis and sensing behavior of cyanoanthracene modified 1,3-alternate calix[4]benzocrown-6: A new class of Cs+ selective optical sensors. Journal of the Chemical Society, Perkin Transactions, 2: 585–591.
   Google Scholar
• Asfieri, C.; Dradi, E.; Pochina, A.; Ungaro, R.; Andreetti, G.D. (1983) Synthesis, X-ray crystal and molecular structure of a novel macro-bicyclic ligand: Crowned p-t-butyl-calix[4] arene. Journal of the Chemical Society, Chemical Communications, 19: 1075–1077.
   Google Scholar
• Sachleben, R.A.; Urvoas, A.; Bryan, J.C.; Haverlock, T.J.; Hay, B.P.; Moyer, B.A. (1999) Dideoxygenated calix[4]arenecrown-6 ethers enhanced selectivity for caesium over potassium and rubidium. Chemical Communications, 17: 1751–1752.
   Web of Science ®Google Scholar
• Sieffert, N.; Chaumont, A.; Wipff, G. (2009) Importance of the liquid-liquid interface in assisted ion extraction: New molecular dynamics studies of cesium picrate extraction by a calix[4]arene. The Journal of Physical Chemistry, 113: 10610–10622.
   Web of Science ®Google Scholar
• Simon, N.; Eymard, S.; Tournois, B.; Dozol, J.F. (2004) Cs selective extraction from high level liquid wastes with crown Calixarenes: Where are we today. The Atalante-2004 Int. Conf., June 21–24, 2004, France, 1–57.
   Google Scholar
• Simon, N.; Eymard, S.; Tournois, B.; Dozol, J.F. Caesium extraction from acidic high level liquid wastes with functionalized calixarenes. Int. Conf. Atalante 2000, Scientific Research on the Back-End of the Fuel Cycle for 21th Century, Avignon, France, October 24–26, 2000, 1–8.
   Google Scholar
• Ansari, S.A.; Mohapatra, P.K.; Raut, D.R.; Manchanda, V.K. (2011) Extraction of caesium from HNO3 medium using room temperature ionic liquid containing calix[4]crown ligands as the selective extractants. Radiochimica Acta, 99: 713–720.
   Web of Science ®Google Scholar
• Zhang, A.; Hu, Q.; Chai, Z. (2009) SPEC: A new process for strontium and cesium partitioning utilizing two macroporous silica-based supramolecular recognition agents impregnated polymeric composites. Separation Science and Technology, 44 (9): 2146–2168.
   Web of Science ®Google Scholar
• Riddle, C.L.; Baker, J.D.; Law, J.D.; McGrath, C.A.; Meikrantz, D.H.; Peterman, D.R.; Todd, T.A. (2005) Fission product extraction (FPEX): Development of a novel solvent for the simultaneous separation of strontium and cesium from acidic solutions. Solvent Extraction and Ion Exchange, 23 (3): 449–461.
   Web of Science ®Google Scholar
• Bonnesen, P.V.; Delmau, L.H.; Haverlock, T.J.; Moyer, B.A. Alkaline-side extraction of cesium from Savannah River tank waste using a calixarene-crown ether extractant. Chemical and Analytical Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, U.S.A., Report ORNL/TM-13704, December, 1998, 1–103.
   Google Scholar
• Bazelarire, E.; Gobunova, M.G.; Bonnesen, P.V.; Moyer, B.A.; Delmau, L.H. (2004) pH- switchable cesium nitrate extraction with calix[4]arene mono and bis(benzo-crown-6) ethers bearing amino functionalities. Solvent Extraction and Ion Exchange, 22: 637–661.
   Web of Science ®Google Scholar
• Bonnesen, P.V.; Delmau, L.H.; Moyer, B.A.; Lumetta, G.J. (2003) Development of effective solvent modifiers for the solvent extraction of cesium from alkaline high-level tank waste. Solvent Extraction and Ion Exchange, 21 (2): 141–170.
   Web of Science ®Google Scholar