2,2’-bipyridine as a masking agent of ruthenium in the PUREX process

References

• Seddon, E. A.; Seddon, R. The Chemistry of Ruthenium; Elsevier, Amsterdam, The Netherland, 1984.
   Google Scholar
• Bush, R. P. Recovery of Platinum Group Metals from High Level Radioactive Waste. Platinum Met. Rev. 1991, 35(4), 202.
   Google Scholar
• Motojima, K. Removal of Ruthenium from PUREX Process. J. Nucl. Sci. Technol. 1989, 26(3), 358. DOI: 10.1080/18811248.1989.9734317.
   Web of Science ®Google Scholar
• Scargill, D.; Lyon, C. E.; Large, N. R.; Fletcher, J. M. Nitratoaquo Complexes of Nitrosylruthenium III. J. Inorg. Nucl. Chem. 1965, 27(1), 161. DOI: 10.1016/0022-1902(65)80206-8.
   Web of Science ®Google Scholar
• Fletcher, J. M.; Lyon, C. E.; Wain, A. G. The Partition Coefficients of Nitratonitrosylruthenium Complexes between Nitric Acid and TBP Phases. J. Inorg. Nucl. Chem. 1965, 27(7), 1841. DOI: 10.1016/0022-1902(65)80328-1.
   Web of Science ®Google Scholar
• Boswell, G. G. J.; Soentono, S. Ruthenium Nitrosyl Complexes in Nitric Acid Solutions. J. Inorg. Nucl. Chem. 1981, 43(7), 1625. DOI: 10.1016/0022-1902(81)80350-8.
   Web of Science ®Google Scholar
• Swain, P.; Annapoorani, S.; Srinivasan, R. Separation and Recovery of Ruthenium from Nitric Acid Medium by Electro-oxidation. J. Radioanal. Nucl. Chem. 2015, 303(3), 1865.
   Web of Science ®Google Scholar
• Brown, P. G. M. Nitro Complexes of Nitrosylruthenium. J. Inorg. Nucl. Chem. 1960, 13(1–2), 73. DOI: 10.1016/0022-1902(60)80238-2.
   Web of Science ®Google Scholar
• Fletcher, J. M.; Brown, P. G. M.; Gardner, E. R.; Hardy, C. J.; Wain, A. G.; Woodhead, J. L. Nitrosylruthenium Nitrato Complexes in Aqueous Nitric Acid. J. Inorg. Nucl. Chem. 1959, 12(1–2), 154. DOI: 10.1016/0022-1902(59)80106-8.
   Web of Science ®Google Scholar
• Fletcher, J. M.; Jenkins, I. L.; Lever, F. M.; Martin, F. S.; Powell, A. R.; Todd, R. Nitrato and Nitro Complexes of Nitrosylruthenium. J. Inorg. Nucl. Chem. 1955, 1(6), 378. DOI: 10.1016/0022-1902(55)80048-6.
   Web of Science ®Google Scholar
• Siczek, A. A.; Steindler, M. T. Chemistry of Ruthenium and Zirconium in the PUREX Solvent-extraction Process. At. Energy Rev. 1978, 16(4), 575.
   Google Scholar
• Pruett, D. J. The Solvent Extraction Behaviour of Ruthenium I – The Nitric Acid-tri-n-butyl Phosphate System. Radiochim. Acta. 1980, 27(2), 115.
   Web of Science ®Google Scholar
• Kulkarni, P. G.; Gupta, K. K.; Gurba, P. B.; Janardan, P.; Changrani, R. D.; Dey, P. K.; Manchanda, V. K. Solvent Extraction Behaviour of Some Fission Product Elements with N,N-dihexyl Octanamide and Tri-n-butyl Phosphate under Simulated PUREX Process Conditions. Radiochim. Acta. 2006, 94(7), 325. DOI: 10.1524/ract.2006.94.6.325.
   Web of Science ®Google Scholar
• Natarajan, R.; Dhamodharan, K.; Sharma, P. K.; Pugazhendi, S.; Vijayakumar, V.; Pandey, N. K.; Subba Rao, R. B. Optimization of Flowsheet for Scrubbing of Ruthenium during the Reprocessing of Fast Reactor Spent Fuel. Radiochim. Acta. 2013, 48(5–6), 2494.
   Google Scholar
• Moeyaert, P.; Miguirditchian, M.; Masson, M.; Dinh, B.; Hérès, X.; Sio, S. D.; Sorel, C. Experimental and Modelling Study of Ruthenium Extraction with Tri-n-butylphosphate in the Purex Process. Chem. Eng. Sci. 2017, 158(1), 580. DOI: 10.1016/j.ces.2016.10.035.
   Web of Science ®Google Scholar
• Lefebvre, C.; Dumas, T.; Charbonnel, M.-C.; Solari, P. L. Speciation of Ruthenium in Organic TBP/TPH Organic Phases: A Study about Acidity of Nitric Solutions. Procedia Chem. 2016, 21(1), 54. DOI: 10.1016/j.proche.2016.10.008.
   Google Scholar
• Lefebvre, C.; Dumas, T.; Tamain, C.; Ducres, T.; Solari, P. L.; Charbonnel, M.-C. Addressing Ruthenium Speciation in Tri-n-butyl-phosphate Solvent Extraction Process by Fourier Transform Infrared, Extended X-ray Absorption Fine Structure and Single Crystal X-ray Diffraction. Ind. Eng. Chem. Res. 2017, 56(39), 11292. DOI: 10.1021/acs.iecr.7b02973.
   Web of Science ®Google Scholar
• Dirks, T.; Dumas, T.; Solari, P. L.; Charbonnel, M.-C. Ruthenium Nitrosyl Structure in Solvent Extraction Systems: A Comparison of Tributyl Phosphate, Tetrabutyl Urea, N-methyl, N-octyl Ethylhexanamide, and N,N,N,N-tetraoctyl Diglycolamide. Ind. Eng. Chem. Res. 2019, 58(32), 14938. DOI: 10.1021/acs.iecr.9b02555.
   Web of Science ®Google Scholar
• Maya, L. Ruthenium(IV) in Nitric Acid Media. J. Inorg. Nucl. Chem. 1979, 41(1), 67. DOI: 10.1016/0022-1902(79)80396-6.
   Web of Science ®Google Scholar
• Anderson, J. S.; McConnell, J. D. M. Ruthenium(IV) Nitrates. J. Inorg. Nucl. Chem. 1955, 1(6), 371. DOI: 10.1016/0022-1902(55)80047-4.
   Web of Science ®Google Scholar
• Verma, P. K.; Gujar, R. B.; Mohapatra, P. K. An Efficient Method for Radio-ruthenium Separation from Acidic Feeds: Extraction, Transport and Spectroscopic Studies. J. Environ. Chem. Eng. 2018, 6(5), 5830. DOI: 10.1016/j.jece.2018.08.062.
   Web of Science ®Google Scholar
• Swain, P.; Mallika, C.; Srinivasan, R.; Mudali, U. K.; Natarajan, R. Separation and Recovery of Ruthenium: A Review. J. Radioanal. Nucl. Chem. 2013, 298(2), 781. DOI: 10.1007/s10967-013-2536-5.
   Web of Science ®Google Scholar
• Richards, J. M.; Mincher, B. J. Selective Partitioning of Ruthenium from Nitric Acid Media. Solv. Extr. Ion Exch. 2017, 35(1), 49. DOI: 10.1080/07366299.2017.1279923.
   Web of Science ®Google Scholar
• Aneheim, E.; Ekberg, C.; Foreman, M. R. S. Aqueous Complexation of Palladium to Prevent Precipitation and Extraction in a Group Actinide Extraction System. Hydrometallurgy. 2012, 115–116(1), 71. DOI: 10.1016/j.hydromet.2011.12.018.
   Web of Science ®Google Scholar
• Sasaki, Y.; Morita, K.; Shimazaki, S.; Tsubata, Y.; Ozawa, M. Masking Effects for Mo, Re, Pd and Ru by S and N-donor Reagents through MIDOA and Ntaamide Extraction. Solvent Extr. Dev. Jpn. 2016, 23(1), 161. DOI: 10.15261/serdj.23.161.
   Google Scholar
• Thevenet, A.; Marie, C.; Tamain, C.; Amendola, V.; Miljkovic, A.; Guillaumont, D.; Boubals, N.; Guilbaud, P. Perrhenate and Pertechnetate Complexation by an Azacryptand in Nitric Acid Medium. Dalton Trans. 2020, 49(5), 1446. DOI: 10.1039/C9DT04314D.
   PubMed Web of Science ®Google Scholar
• Sasaki, Y.; Suzuki, T.; Morita, K.; Tsubata, Y. Complexing Agents for Oxonium Anions of Mo and Re and Their Masking Effects on Extraction Using N-donor Extractants. Chem. Lett. 2014, 43(10), 1538. DOI: 10.1246/cl.140502.
   Web of Science ®Google Scholar
• Blasius, E.; Luxenburger, H. J.; Neumann, W. Ruthenium Nitrosyl Complexes in Radioactive Waste Solutions of Reprocessing Plants. Radiochim. Acta. 1981, 29(1), 159. DOI: 10.1524/ract.1981.29.23.159.
   Google Scholar
• Ahrland, S.; Chatt, J.; Davies, N. R. The Relative Affinities of Ligand Atoms for Acceptor Molecules and Ions. Q. Rev. 1958, 12(3), 265. DOI: 10.1039/qr9581200265.
   Google Scholar
• Alozy, J.-P. Thesis report, Ecole centrale des Arts et Manufactures, 1982.
   Google Scholar
• Bruker. SAINTPlus. Data Processing Software for the CCD Detector System. Version 6.22, Bruker Analytical X-Ray Systems; Madison, WI, 2001.
   Google Scholar
• G. M. Sheldrick. SADABS. Version 2.03, Bruker Analytical X-ray Systems; Madison, WI, 2001.
   Google Scholar
• G. M. Sheldrick. SHELX-97. Program for Crystal Structure Solution and Refinement; University of Göttingen: Göttingen, Germany, 1997.
   Google Scholar
• Lai, S.-H.; Ling, J.-W.; Huang, Y.-M.; Huang, M.-J.; Cheng, C. H.; Chen, I.-C. Characterization of Ir(ppy)3 and [Ir(ppy)2bpy]+ by Infrared, Raman Spectra and Surface-enhanced Raman Scattering. J. Raman Spectrosc. 2011, 42(3), 332. DOI: 10.1002/jrs.2719.
   Web of Science ®Google Scholar
• Bradley, P. G.; Kress, N.; Homberger, B. A.; Dallinger, R. F.; Woodruff, W. H. Vibrational Spectroscopy of the Electronically Excited State. 5. Time-resolved Resonance Raman Study of tris(bipyridine)ruthenium(II) and Related Complexes. Definitive Evidence for the “Localized” MLCT State. J. Am. Chem. Soc. 1981, 103(25), 7441. DOI: 10.1021/ja00415a007.
   Web of Science ®Google Scholar
• Mallick, P. K.; Danzer, G. D.; Strommen, D. P.; Kincaid, J. R. Vibrationnal Spectra and Normal-coordinate Analysis of tris(bipyridine)ruthenium(II). J. Phys. Chem. 1988, 92(20), 5628. DOI: 10.1021/j100331a018.
   Web of Science ®Google Scholar
• Strommen, D. P.; Mallick, P. K.; Danzer, G. D.; Lumpkin, R. S.; Kincaid, J. R. Normal-coordinate Analyses of the Ground and 3MLCT Excited States of tris(bipyridine)ruthenium(II). J. Phys. Chem. 1990, 94(4), 1357. DOI: 10.1021/j100367a031.
   Web of Science ®Google Scholar
• Omberg, K. M.; Schoonover, J. R.; Treadway, J. A.; Leasure, R. M.; Dyer, R. B.; Meyer, T. J. Mid-infrared Spectrum of [Ru(bpy)3]2+*. J. Am. Chem. Soc. 1997, 119(30), 7013. DOI: 10.1021/ja970511u.
   Web of Science ®Google Scholar
• Janiak, C. A Critical Account on π-π Stacking in Metal Complexes with Aromatic Nitrogen-containing Ligand. J. Chem. Soc. Dalton Trans. 2000, 29(21), 3885. DOI: 10.1039/b003010o.
   Google Scholar
• Hunter, C. A.; Sanders, J. K. M. The Nature of Pi – Pi Interactions. J. Am. Chem. Soc. 1990, 112(14), 5525. DOI: 10.1021/ja00170a016.
   Web of Science ®Google Scholar
• Charushnikova, I. A.; Auwer, C. D. Crystal Structures of Molecular Adducts between Uranyl Nitrate and 2,2ʹ:6ʹ,2”-terpyridine or 2,2ʹ-bipyridyl. Russ. J. Coord. Chem. 2004, 30(7), 511. DOI: 10.1023/B:RUCO.0000034793.14795.72.
   Web of Science ®Google Scholar
• Berger, C.; Marie, C.; Guillaumont, D.; Tamain, C.; Dumas, T.; Dirks, T.; Boubals, N.; Acher, E.; Laszczyk, M.; Berthon, L. Coordination Structures of uranium(VI) and plutonium(IV) in Organic Solutions with Amide Derivatives. Inorg. Chem. 2020, 59(3), 1823. DOI: 10.1021/acs.inorgchem.9b03024.
   PubMed Web of Science ®Google Scholar