Morphology and kinetic mechanism of facile one-step preparing TiO₂/polyacrylate/TiO₂ multilayer core–shell hybrid emulsion via miniemulsion polymerization

References

• Pal M, Garcia Serrano J, Santiago P, et al. Size-controlled synthesis of spherical TiO2 nanoparticles: morphology, crystallization, and phase transition. J. Phys. Chem. C. 2007;111:96–102.10.1021/jp0618173
   Web of Science ®Google Scholar
• Veronovski N, Andreozzi P, La Mesa C, et al. Stable TiO2 dispersions for nanocoating preparation. Surf. Coat. Tech. 2010;204:1445–1451.10.1016/j.surfcoat.2009.09.041
   Web of Science ®Google Scholar
• Yang GD, Yan ZF, Xiao TC, et al. Low-temperature synthesis of alkalis doped TiO2 photocatalysts and their photocatalytic performance for degradation of methyl orange. J. Alloy. Compd. 2013;580:15–22.10.1016/j.jallcom.2013.05.074
   Web of Science ®Google Scholar
• Yu HT, Quan X. Nano-heterojunction photocatalytic materials in environmental pollution controlling. Prog. Chem. 2009;21:406–419.
   Web of Science ®Google Scholar
• Sharma SD, Saini KK, Kant C, et al. Photodegradation of dye pollutant under UV light by nano-catalyst doped titania thin films. Appl. Catal. B: Environ. 2008;84:233–240.10.1016/j.apcatb.2008.04.017
   Web of Science ®Google Scholar
• Hoffmann MR, Martin ST, Choi W. Environmental applications of semiconductor photocatalysis. Chem. Rev. 1995;95:69–96.10.1021/cr00033a004
   Web of Science ®Google Scholar
• Cappellrtti G, Ardizzone S, Bianchi CL. Photodegradation of pollutants in air: enhanced properties of nano-TiO2 prepared by ultrasound. Nanoscale Res. Lett. 2008;4:97–105.
   PubMed Web of Science ®Google Scholar
• Kong H, Song J, Jang J. Photocatalytic antibacterial capabilities of Tio2−biocidal polymer nanocomposites synthesized by a surface-initiated photopolymerization. Environ. Sci. Technol. 2010;44:5672–5676.10.1021/es1010779
   PubMed Web of Science ®Google Scholar
• Zhu AP, Rong QP, Chen R. The preparation of core–shell P(St-MMA)–SiO2 hybrid nanoparticles and filling in the styrene/n-butyl acrylate adhesive. J. Adhes. Sci. Techno. 2010;24:267–280.10.1163/016942409X12520502629551
   Web of Science ®Google Scholar
• Cao L, Tang F, Fang GY. Preparation and characteristics of microencapsulated palmitic acid with TiO2 shell as shape-stabilized thermal energy storage materials. Sol. Energy Mater Sol. C. 2014;123:183–188.10.1016/j.solmat.2014.01.023
   Web of Science ®Google Scholar
• Ma JZ, Liu YH, Bao Y, et al. Research advances in polymer emulsion based on “core–shell” structure particle design. Adv. Colloid. Interface Sci. 2013;197–198:118–131.10.1016/j.cis.2013.04.006
   PubMed Web of Science ®Google Scholar
• Che XC, Jin YZ, Lee YS. Preparation of nano-TiO2/polyurethane emulsions via in situ RAFT polymerization. Prog. Org. Coat. 2010;69:534–538.10.1016/j.porgcoat.2010.09.013
   Web of Science ®Google Scholar
• Yu YY, Chien WC, Tsai TW. Synthesis of soluble polyimide/silica-titania core–shell nanoparticle hybrid thin films for anti-reflective coatings. Mater. Chem. Phys. 2011;126:962–972.10.1016/j.matchemphys.2010.11.056
   Web of Science ®Google Scholar
• Li LY, Qin DB, Yang XL, et al. Controlling internal nanostructures of porous microspheres prepared via electrospraying. Colloid Polym. Sci. 2010;288:199–206.
   Web of Science ®Google Scholar
• Song XF, Gao L. Fabrication of hollow hybrid microspheres coated with silica/titania via sol-gel process and enhanced photocatalytic activities. J. Phys. Chem. C. 2007;111:8180–8187.10.1021/jp071142j
   Web of Science ®Google Scholar
• Peng B, Tang FQ, Chen D, et al. Preparation of PS/TiO2/UF multilayer core–shell hybrid microspheres with high stability. J. Colloid Interface Sci. 2009;329:62–66.10.1016/j.jcis.2008.09.069
   PubMed Web of Science ®Google Scholar
• Bach LG, Islam MR, Seo SY, et al. A novel route for the synthesis of poly(2-hydroxyethyl met hacrylate) grafted TiO2 nanoparticles via surface thiol-lactam initiated radical polymerization. J. Appl. Polym. Sci. 2013;127:261–269.10.1002/app.37879
   Web of Science ®Google Scholar
• Zhang JM, Gao JG, Sun XG, et al. Preparation and characterization of TiO2/poly(St-co-MAA) core/shell composite particles. Iran. Polym. J. 2007;16:39–46.
   Web of Science ®Google Scholar
• Yu D-G, An JH, Bae JY, et al. Preparation of titanium dioxide/poly(methyl methacrylate-co-n-butyl acrylate-co-methacrylic acid) hybrid composite particles via emulsion polymerization. J. Appl. Polym. Sci. 2005;97:72–79.10.1002/(ISSN)1097-4628
   Web of Science ®Google Scholar
• Caruso K, Guruswamy M, Dibaj Amir M. Photonic materials from self-assembly of “tolerant” core–shell coated colloids. Langmuir. 2002;18:4150–4154.
   Web of Science ®Google Scholar
• Caruso F, Shi XY, Caruso RA, et al. Hollow titania spheres from layered precursor deposition on sacrificial colloidal core particles. Adv. Mater. 2001;13:740–744.10.1002/1521-4095(200105)13:10<740::AID-ADMA740>3.0.CO;2-6
   Web of Science ®Google Scholar
• Landfester K. Miniemulsion polymerization and the structure of polymer and hybrid nanoparticles. Angew. Chem. Int. Ed. 2009;48:4488–4507.10.1002/anie.v48:25
   PubMed Web of Science ®Google Scholar
• Zhao YL, Wang HT, Song XM, et al. Fabrication of two kinds of polymer microspheres stabilized by modified titania during pickering emulsion polymerization. Macromol. Chem. Phys. 2010;211:2517–2529.10.1002/macp.v211.23
   Web of Science ®Google Scholar
• Karabacak RB, Erdem M, Yurdakal S, et al. Facile two-step preparation of polystyrene/anatase TiO2 core/shell colloidal particles and their potential use as an oxidation photocatalyst. Mater. Chem. Phys. 2014;144:498–504.10.1016/j.matchemphys.2014.01.026
   Web of Science ®Google Scholar
• Nguyen D, Such C, Hawkett B. Polymer-TiO2 composite nanorattles via RAFT-mediated emulsion polymerization. J. Polym. Sci., A Polym. Chem. 2012;50:346–352.10.1002/pola.v50.2
   Web of Science ®Google Scholar
• Liu HL, Wang D, Yang XL. Preparation of polymer@titania raspberry-like core–corona composite via heterocoagulated self-assembly based on hydrogen-bonding interaction. Colloid. Surf. A. 2012;397:48–58.10.1016/j.colsurfa.2012.01.028
   Web of Science ®Google Scholar
• Ai ZQ, Sun GL, Zhou QL, et al. Polyacrylate-core/TiO2-shell nanocomposite particles prepared by in situ emulsion polymerization. J. Appl. Polym. Sci. 2006;102:1466–1470.10.1002/(ISSN)1097-4628
   Web of Science ®Google Scholar
• Zhou WD, Xu T, Wang XW, et al. In situ polymerized nanocomposites of poly(butylene succinate)/TiO2 nanofibers: molecular weight, morphology, and thermal properties. J. Appl. Polym. Sci. 2013;127:733–739.10.1002/app.37724
   Web of Science ®Google Scholar
• Wu YF, Zhang Y, Xu JX, et al. One-step preparation of PS/TiO2 nanocomposite particles via miniemulsion polymerization. Colloid Interface Sci. 2010;343:18–24.10.1016/j.jcis.2009.11.022
   PubMed Web of Science ®Google Scholar
• Al-Ghamdi GH, Sudol ED, Dimonie VL, et al. Encapsulation of titanium dioxide in styrene/n-butyl acrylate copolymer by miniemulsion polymerization. J. Appl. Polym. Sci. 2006;101:3479–3486.10.1002/(ISSN)1097-4628
   Web of Science ®Google Scholar
• Zhang QH, Gao L, Xie HQ. Analysis of the structure of titanium tetrachloride derived precipitates. Mat. Sci. Eng. A. 2003;343:22–27.10.1016/S0921-5093(02)00329-5
   Web of Science ®Google Scholar
• Luo YD, Dai CA, Chiu WY. Nucleation mechanism and morphology of polystyrene/Fe3O4 latex particles via miniemulsion polymerization using AIBN as initiator. J. Appl. Polym. Sci. 2009;112:975–984.10.1002/app.v112:2
   Web of Science ®Google Scholar
• Zhang QH, Zhan XL, Chen FQ. Miniemulsion polymerization of a fluorinated acrylate copolymer: kinetic studies and nanolatex morphology characterization. J. Appl. Polym. Sci. 2007;104:641–647.10.1002/(ISSN)1097-4628
   Web of Science ®Google Scholar
• Dunn AS, Chong LC-H. Application of the theory of colloid stability to the problem of particle formation in aqueous solutions of vinyl acetate. Br. Polym. J. 1970;2:49–59.10.1002/(ISSN)1934-256X
   Google Scholar
• Unzué MJ, Asua JM. Semicontinuous miniemulsion terpolymerization: effect of the operation conditions. J. Appl. Polym. Sci. 1993;49:81–90.10.1002/app.1993.070490109
   Web of Science ®Google Scholar