Publication Cover
Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 40, 2018 - Issue 4
665
Views
29
CrossRef citations to date
0
Altmetric
Original Articles

Free Radical and Direct Ozone Reaction Competition to Remove Priority and Pharmaceutical Water Contaminants with Single and Hydrogen Peroxide Ozonation Systems

ORCID Icon & ORCID Icon
Pages 251-265 | Received 08 Sep 2017, Accepted 19 Jan 2018, Published online: 01 Feb 2018

References

  • Astarita, G. 1967. Mass Transfer With Chemical Reaction. Amsterdam: Elsevier Publ.
  • Beltrán, F.J. 1999. “Estimation of the Relative Importance of Free Radical Oxidation and Direct ozonation/UV Radiation Rates of Micripollutants in Water.” Ozone Science. & Engineering 21:207–28.
  • Beltrán, F.J. 2004. Ozone Reaction Kinetics for Water and Wastewater Systems. Boca Ratón, Florida, USA: Lewis Publish. CRC Press.
  • Beltrán, F.J., A. Aguinaco, and J.F. García-Araya. 2009. “Mechanism and Kinetics of Sulfamethoxazole Photocatalytic Ozonation in Water.” Water Research 43:1359–69.
  • Beltrán, F.J., J.M. Encinar, and M.A. Alonso. 1998a. “Nitroaromatic Hydrocarbon Ozonation in Water. 1. Single Ozonation.” Industrial & Engineering Chemistry Research 37:25–31.
  • Beltrán, F.J., J.M. Encinar, and M.A. Alonso. 1998b. “Nitroaromatic Hydrocarbon Ozonation in Water. 2 Combined Ozonation.” Industrial & Engineering Chemistry Research 37:32–40.
  • Beltrán, F.J., J.M. Encinar, and J.F. García-Araya. 1992a. “Absorption Kinetics of Ozone in Aqueous O-Cresol Solutions.” Canadian Journal of Chemical Engineering 70:141–47.
  • Beltrán, F.J., J.F. García-Araya, and B. Acedo. 1994. “Advanced Oxidation of Atrazine in Water I. Ozonation.” Water Research 28:2153–64.
  • Beltrán, F.J., J.F. García-Araya, P.M. Álvarez, and J. Rivas. 1998c. “Aqueous Degradation of Atrazine and Some of Its Main By-Products with Ozone/Hydrogen Peroxide.” Journal of Chemical Technology & Biotechnology 71:345–55.
  • Beltrán, F.J., J.F García-Araya, F.J. Rivas, P. Álvarez, and E. Rodríguez. 2000a. “Kinetics of Simazine Advanced Oxidation in Water.” Journal of Environmental Science and Health, Part B B35:439–54.
  • Beltrán, F.J., V. Gómez-Serrano, and A. Durán. 1992b. “Degradation Kinetics of P-Nitrophenol Ozonation in Water.” Water Research 26:9–17.
  • Beltrán, F.J., M. González, F. J. Rivas, and B. Acedo. 2000b. “Determination of Kinetic Parameters of Ozone during Oxidations of Alachlor in Water.” Water Environment Research 72:689–97.
  • Beltrán, F.J., M. González, F.J. Rivas, and M. Marín. 1994. “Oxidation of Mecoprop in Water with Ozone and Ozone Combined with Hydrogen Peroxide.” Industrial & Engineering Chemistry Research 33:125–36.
  • Beltrán, F.J., G. Ovejero, and B. Acedo. 1993. “Oxidation of Atrazine in Water by Ultraviolet Radiation Combined with Hydrogen Peroxide.” Water Research 27:1013–21.
  • Beltrán, F.J., G. Ovejero, J.M. Encinar, and J. Rivas. 1995. “Oxidation of Polynuclear Aromatic Hydrocarbons in Water. 1 Ozonation.” Industrial & Engineering Chemistry Research 34:1596–606.
  • Beltrán, F.J., G. Ovejero, and F.J. Rivas. 1996a. “Oxidation of Polynuclear Aromatic Hydrocarbons in Water. 3. UV Radiation Combined with Hydrogen Peroxide.” Industrial & Engineering Chemistry Research 35:883–90.
  • Beltrán, F.J., G. Ovejero, and F.J. Rivas. 1996b. “Oxidation of Polynuclear Aromatic Hydrocarbons in Water. 4. Ozonation Combined with Hydrogen Peroxide.” Industrial & Engineering Chemistry Research 35:891–98.
  • Benitez, F.J., J.L. Acero, F.J Real, and J. García. 2003. “Kinetics of Photodegradation and Ozonation of Pentachlorophenol.” Chemosphere 51:651–62.
  • Benitez, F.J., F.J. Real, J.L. Acero, and C. Garcia. 2007. “Kinetics of the Transformation of Phenyl-Urea Herbicides during Ozonation of Natural Waters: Rate Constants and Model Predictions.” Water Research 41:4073–84.
  • Buxton, G.V., C.L. Greenstock, W.P. Helman, and A.B. Ross. 1988. “Critical Review of Data Constants for Reactions of Hydrated Electrons, Hydrogen Atoms and Hydroxyl Radicals (.OH/.O-) in Aqueous Solution.” Journal of Physical and Chemical Reference Data 17:513–886.
  • Cain, M., and Y.P. Lin. 2016. “Effects of Effluent Organic Matter (Efom) on the Removal of Emerging Contaminants by Ozonation.” Chemosphere 151:332–38.
  • Charpentier, J.C. 1981. Mass Transfer Rates in Gas Liquid Absorbers and Reactors, in Advances in Chemical Engineering, vol. 11, 3–133. New York: Academic Press.
  • Chelme-Ayala, P., M. G. El-Din, and D.W. Smith. 2010. “Kinetics and Mechanism of the Degradation of Two Pesticides in Aqueous Solutions by Ozonation.” Chemosphere 78:557–62.
  • Chen, W.R., C. Wu, M.S. Elovitz, K.G. Linden, and I.H. Suffet. 2008. “Reactions of Thiocarbamate, Triazine and Urea Herbicides, RDX and Benzenes on EPA Contaminant Candidate List with Ozone and with Hydroxyl Radicals.” Water Research 42:137–44.
  • Christensen, H.S., H. Sehensted, and H. Corfitzan. 1982. “Reactions of Hydroxyl Radicals with Hydrogen Peroxide at Ambient and Elevated Temperatures.” Journal of Physical Chemistry 86:55–68.
  • Deborde, M., S. Rabouan, J.P. Duguet, and B. Legube. 2005. “Kinetics of Aqueous Ozone-Induced Oxidation of Some Endocrine Disruptors.” Environmental Science and Technology 39:6086–92.
  • Dodd, M., M.O. Buffle, and U. Von Gunten. 2006. “Oxidation of Antibacterial Molecules by Aqueous Ozone: Moiety-Specific Reaction Kinetics and Application to Ozone-Based Wastewater Treatment.” Environmental Science & Technology 40:1969–77.
  • Farhataziz,, and A.B. Ross. 1977. “Selected Specific Rates of Reactions of Transients for Water in Aqueous Solution: III Hydroxyl Radical and Perhydroxyl Radical and Their Radical Ions.” Natural Std Ref Data Series US Natural Bur of Std 59:p59.
  • Gimeno, O., J.F. García-Araya, F.J. Beltrán, F.J. Rivas, and A. Espejo. 2016. “Removal of Emerging Contaminants from a Primary Effluent of Municipal Wastewater by Means of Sequential Biological Degradation-Solar Photocatalytic Oxidation Processes.” Chemical Engineering Journal 290:12–20.
  • Glaze, W.H., F.J. Beltrán, T. Tuhkanen, and J.W. Kang. 1992. “Chemical Models of Advanced Oxidation Processes.” Water Pollution Research Journal of Canada 27:23–42.
  • Glaze, W.H., and J.H. Kang. 1989. “Advanced Oxidation Processes. Description of a Kinetic Model for the Oxidation of Hazardous Materials in Aqueous Media with Ozone and Hydrogen Peroxide in a Semibatch Reactor.” Industrial & Engineering Chemistry Research 28:1573–80.
  • Gracia-Lor, E., J.V. Sancho, R. Serrano, and F. Hernández. 2012. “Occurrence and Removal of Pharmaceuticals in Wastewater Treatment Plants at the Spanish Mediterranean Area of Valencia.” Chemosphere 87:453–62.
  • Haag, W.R., and J. Hoigné. 1985. “Photo-Sensitized Oxidation in Natural Water via Oh Radicals.” Chemosphere 14:1659–71.
  • Hoigné, J., and H. Bader. 1983. “Rate Constants of the Reactions of Ozone with Organic and Inorganic Compounds. II. Dissociating Organic Compounds.” Water Research 17:185–94.
  • Huber, M., S. Canonica, G.Y. Park, and U. Von Gunten. 2003. “Oxidation of Pharmaceuticals during Ozonation and Advanced Oxidation Processes.” Environmental Science & Technology 37:1016–24.
  • Ikehata, K., N.J. Naghashkar, and M.G. El-Din. 2006. “Degradation of Aqueous Pharmaceuticals by Ozonation and Advanced Oxidation Processes: A Review” Ozone Science & Engineering 28:353–414.
  • Jiménez, M., N. Dietrich, J.R. Grace, and G. Hebrard. 2014. “Oxygen Mass Transfer and Hydrodynamic Behaviour in Wastewater: Determination of Local Impact of Surfactants by Visualization Techniques.” Water Research 58:111–21.
  • Jin, X., S. Peldszus, and P.M. Huck. 2012. “Reaction Kinetics of Selected Micropollutants in Ozonation and Advanced Oxidation Processes.” Water Research 46:6519–30.
  • Legube, B., H. Sugimitsu, S. Guyon, and M. Doré. 1986. “Ozonation of Naphthalene in Aqueous solution—II.” Kinetic Studies of the Initial Reaction Step.” Water Research 20:209–14.
  • Lin, A.Y.C., C.F. Lin, J.M. Chiou, and P.K.A. Hong. 2000. “O3 and O3/H2O2 Treatment of Sulfonamide and Macrolide Antibiotics in Wastewater.” Journal of Hazardous Materials 171:452–58.
  • Márquez, G., E.M. Rodríguez, F.J. Beltrán, and P.M. Álvarez. 2013. “Determination of Rate Constants for Ozonation of Ofloxacin in Aqueous Solution.” Ozone Science & Engineering 35:186–95.
  • Nöthe, T., H. Fahlemkamp, and C. Von Sonntag. 2009. “Ozonation of Wastewater: Rate of Ozone Consumption and Hydroxyl Radical Yield.” Environmental Science & Technology 43:5990–95.
  • Qiang, C., C. Adams, and R. Surampalli. 2004. “Determination of Ozonation Rate Constants for Lincomycin and Spectinomycin.” Ozone Science & Engineering 26:525–37.
  • Reisz, E., W. Schmidt, H.P. Schuchmann, and C. Von Sonntag. 2003. “Photolysis of Ozone in Aqueous Solutions in the Presence of Tertiary Butanol.” Environmental Science & Technology 37:1941–48.
  • Rivas, F.J., J. Sagasti, A. Encinas, and O. Gimeno. 2011. “Contaminants Abatement by Ozone in Secondary Effluents. Evaluation of Second Order Rate Constants.” Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire : 1986) 86:1058–66.
  • Rosal, R., A. Rodríguez, J.A. Perdigón-Melón, M. Mezcua, M.D. Hernando, P. Letón, E. García-Calvo, A. Agüera, and A.R. Fernández-Alba. 2008. “Removal of Pharmaceuticals and Kinetics of Mineralization by O3/H2O2 in a Biotreated Municipal Wastewater.” Water Research 42:3719–28.
  • Rosal, R., A. Rodríguez, J.A. Perdigón-Melón, A. Petre, and E. García-Calvo. 2009. “Oxidation of Dissolved Organic Matter in the Effluent of a Sewage Treatment Plant Using Ozone Combined with Hydrogen Peroxide (O3/H2O2).” Chemical Engineering Journal 149:311–18.
  • Solís, R.R., F.J. Rivas, O. Gimenoand, J.L. Pérez-Bote. 2016. “Photocatalytic Ozonation of Clopyralid, Picloram and Triclopyr. Kinetics, Toxicity and Influence of Operational Parameters.” Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire : 1986) 91:51–58.
  • Staehelin, S., and J. Hoigné. 1982. “Decomposition of Ozone in Water: Rate of Initiation by Hydroxyde Ions and Hydrogen Peroxide.” Environmental Science & Technology 16:666–81.
  • Stuart, M., D. Lapworth, E. Crane, and H. Hart. 2011. “Review of Risk from Potential Emerging Contaminants in UK Groundwater.” The Science of the Total Environment 416:1–21.
  • Ternes, T.A., J. Stüber, N. Herrmann, D. McDowella, A. Ried, M. Kampmann, and B. Teiser. 2003. “Ozonation: A Tool for Removal of Pharmaceuticals, Contrast Media and Musk Fragrances from Wastewater?” Water Research 37:1976–82.
  • Vel Leitner, N.K., and B. Roshani. 2010. “Kinetics of Benzotriazole Oxidation by Ozone and Hydroxyl Radical.” Water Research 44:2058–66.
  • Zhao, Y., J. Kuanga, S. Zhang, X. Li, B. Wang, J. Huang, S. Deng, Y. Wang, and G. Yu. 2017. “Ozonation of Indomethacin: Kinetics, Mechanisms and Toxicity.” Journal of Hazardous Materials 323:460–70.
  • Zwiener, C., and F.H. Frimmel. 2000. “Oxidative Treatment of Pharmaceuticals in Water.” Water Research 34:181–1885.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.