The Evolution, Chemistry and Applications of Homogeneous Liquid Redox Sulfur Recovery Techniques

References

• Kohl , A. L. and Riesenfeld , F. C. 1985 . Gas Purification , 4 edition , Houston, TX : Gulf Publishing Company .
   Google Scholar
• Lagas , J. A. , Borboom , J. , Berben , P. H. and Geus , J. W. Europen Patent Application . 02 42006 . 1985 .
   Google Scholar
• Berben , P. H. 1992 . Thesis Utrecht, , The Netherlands
   Google Scholar
• Lapersrix , E. , Costentin , G. , Guyen , N. N. , Saur , O. and Lavalley , J. C. 1999 . J. Catalysis , 187 : 385
   Google Scholar
• Kensell , W. and Leppin , D. Review of the H2S Direct Oxidation Process. GRI Sulfur Recovery Conference . Austin, Texas.
   Google Scholar
• Gowdy , H. W. , Bertram , R. V. and Sahlin , R. K. Review of the H2S Direct Oxidation Process . GRI Sulfur Recovery Conference . Austin, Texas.
   Google Scholar
• Adachi . US Patent . 3957691 . 1976 . Thompson, US Patent 1984, 4440874. Kim et al, US Patent 1986, 4591580. Wan et al. US Patent 1988, 4738947. Joy et al. US Patent 1988, 4760044. Kim et al, US Patent, 1988, 4780447. Rieek et al, US Patent 1990, 4916105
   Google Scholar
• Heisel , M. , Marold , J. F. and Gwinner , M. 1994 . CLINSULF- Do for Sulfur Recovery from H2S Containing Gas . Linde Reports on Science and Technology , 53 : 15
   Google Scholar
• Heisel , M. P. , Schwarz , C. and Schreiner , B. CLINSULF-Dofor Sulfur Recovery from Gasification Gas . GRI Sulfur Recovery Conference . Austin, Texas.
   Google Scholar
• Quinlan , M. P. 1992 . Technical and Economic Analysis of the Iron-Based Redox Process 215 In Proc. Annual G. P. A. Convention
   Google Scholar
• Leppin , D. and Wessels , J. GRI Sulfur Recovery Conference . GRI Sulfur Recovery Conferencew .
   Google Scholar
• Kohl , A. L. and Riesenfeld , F. C. 1960 . Gas Purification , New York : McGraw-Hill .
   Google Scholar
• Feld , W. 1911 . Uber die Bildung von Eidenbisufid in Losugen und die Entstehung der Naturlichen Pyritlager . Zeitschrift fur Angewanste Chemie , 24 : 97
   Google Scholar
• Overdieck , F. 1930 . Eine neue Technische Ausfuhrungstrom des Walter Feldschen . Polythionateverfahrens, Zeitschrift fur Angewandte Chemie , 43 : 1048
   Google Scholar
• McManus , D. and Martell , A. E. 1997 . J. Molecular Catalysis, A: Chemical , 17 : 289
   Google Scholar
• Pieters , H. A. J. and Krevelen , D. W. 1946 . The Wet Purification of Coal Gas and Similar Gases by the Staatsmijnen-Otto-Process , Elsevier .
   Google Scholar
• Hartley , W. , Craig , R. S. and Sapiro , R. H. British Patent . BP 855421 . 1960 .
   Google Scholar
• Gollmar , H. A. 1934 . Ind. Eng. Chem. , 26 : 130
   Google Scholar
• Jenett , E. 1962 . Oil & Gas Journal , 60 : 72
   Google Scholar
• Dalrymple , D. A. and Trofe , T. W. 1989 . Chem. Eng. Prog. , 85 : 43
   Google Scholar
• Dalrymple , D. A. , Trofe , T. W. and Leppin , D. 1994 . Oil & Gas Journal , 92 : 54
   Google Scholar
• Gollmar . US Patent . 2163169 . 1939 . Matheson, US Patent 1941, 2259901. Fetterly, US Patent 1949, 2472473. Patton, US Patent 1958, 2819950. Szombathy, US Patent 1959, 2911438. Hag, US Patent 1963, 3087793. Lida et al, US Patent 1969, 3459495. Redmer, US Patent 1973, 3764548. Nicklin, US Patent 1974, 3810833. Landrun et al, US Patent 1974, 3812243. Schulz, US Patent 1975, 3928535. Hasebe, US Patent 1976, 3937795. Espenscheid et al, US Patent 1976, 3959452. Fenton et al, US Patent 1976, 3972989. Frame, US Patent 1976, 3978137. Toyama et al, US Paten 1976, 3989810. Sonda et al, US Patent 1977, 4009251. Fenton et al, US Patent 1977, 4017594. Nicklin et al, US Patent 1977, 4049776. Fenton et al, US Patent 1977, 4060594. Fenton et al, US Patent 1978, 4083945. Sano et al, US Patent 1978, 4118467. Kawoda et al, US Patent 1980, 4199553. Fenton et al, US Patent 1980, 4206194. Marshall, US Patent 1981, 4251492. Gowdy et al, US Patent 1984, 4432962
   Google Scholar
• Wilson , B. M. and Newell , R. D. 1984 . Chem. Eng. Prog. , 313
   Google Scholar
• Hartley , W. , Craig , R. S. and Sapiro , R. H. US Patent . 3068065 . 1962 .
   Google Scholar
• McManus , D. and Martell , A. E. The Evolution, Chemistry an Application of Chelated Iron Hydrogen Sulfide Removal and Oxidation Processes . 6th International Symposium on the Activation of Dioxygen and Homogeneous Oxidation . Netherlands : Noordwijkerhout .
   Google Scholar
• Cabodi , A. 1982 . Oil & Gas Joural , 5
   Google Scholar
• Thompson . US Patent . 4189462 . 1990 . Hardison, US Patent 1992, 5139753. Hardison, US Patent 1992, 5160714. Naraghi, US Patent 1989, 4880609. Honna et al, US Patent 1995, 5391278. McManus, D., Kin, F. R. US Patent 1986, 4622212. Klecka, M. E. US Patent 1985, 4518577
   Google Scholar
• Martell , A. E. , Motekaitis , R. J. , Chen , D. , Hancock , R. D. and McManus , D. 1996 . Can. J. Chem. , 74 : 1872
   Web of Science ®Google Scholar
• Nagl , G. J. Gas Research Institutes (Chicago) . Sulfur Recovery Conference . 7th September . Austin, TX, , USA
   Google Scholar
• Diaz , Z. US Patent . 4400368 . 1983 .
   Google Scholar
• Bedell , S. International Patent . 90/01984 . 1990 .
   Google Scholar
• Thompon , R. B. US Patent . 4218342 . 1980 .
   Google Scholar
• McManus , D. and Reicher , M. AIChE Spring National Meeting . Houston, TX, USA. pp. 54a
   Google Scholar
• McManus , D. and Niemiec , W. J. AIChE Spring National Meeting . New Orleans, LA, USA. pp. 46b
   Google Scholar
• McManus , D. AIChE Spring National Meeting . Atlanta, GA, USA. pp. 276
   Google Scholar
• McManus , D. 1995 . Gas Research Institutes (Chicago) Sulfur Recovery Conference . 7th September 1995 , Austin, TX, USA.
   Google Scholar
• Wubs , H. J. and Beenackers , A. A.C.M. 1994 . AIChE J. , 40 : 433
   Web of Science ®Google Scholar
• Hardison , L. C. LO-CA T-II: A Big Step forward in Iron Redox Chemistry . GRI Liquid Redox Sulfur Recovery Conference . GRI .
   Google Scholar
• Hardison , L. C. and McManus , D. Chelon Degradation Mechanisms in Chelated Iron Redox Processes for H2S Removal . Annual Meeting AIChE, Miami Beach . Florida : AIChE .
   Google Scholar
• Hardison , L. C. US Patent . 5139753 . 1992 .
   Google Scholar
• Cantrall , R. LO-CAT and LO-CAT II Application of Technology Update In Sulfur Recovery Conference . GRI .
   Google Scholar
• Oostwouder , S. P. and Hodge , V. B. Sulferox Process Technology and Application Update In Sulfur Recovery Conference . GRI .
   Google Scholar
• Nagl , G. J. 1997 . Chem. Eng. , 125
   Google Scholar
• Nagl , G. J. 1995 . Gas Reseach Institutes (Chicago) 7th Sulfur Recovery Conference . September 1995 , Austin, TX, USA.
   Google Scholar
• McManus , D. and Niemiec , W. J. June 28 1998 . Application of Homogeneous, Catalytic, Chelated Iron Hydrogen Sulfide Advanced Oxidation Processes to Titanium Dioxide Manufacture June 28 , 1998 Pan-American Workshop on Commericallization of Advanced Oxidation Technologies
   Google Scholar
• Quinlan , M. P. Technical and Economic Analysis of the Iron-Based Redox Processs . Proc. Annual GPA . pp. 215 Covention
   Google Scholar
• Quinlan , M. P. and Echterhoff , L. W. Technical and Economic Comparison of LO-CAT II with Other Iron-Based Liquid Redox Processes In Sulfur Recovery Conference . GRI .
   Google Scholar
• Liu , X. , Sawyer , D. T. , Bedell , S. A. and Worley , C. M. 1995 . Gas Research Institutes (Chicago) 7th Sulfur Recovery Conference . September 1995 , Austin, TX, USA.
   Google Scholar
• DeBerry , D. W. and McManus , D. Private Communication
   Google Scholar
• Klein , G. W. , Bhatia , K. , Madhawan , V. and Schuler , R. H. 1975 . J. Phys. Chem. , 79 : 1767
   Google Scholar
• Chen , D. , Motekaitis , R. J. , Martell , A. E. and McManus , D. 1993 . Can. J. Chem. , 71 : 1524
   Google Scholar
• Chen , D. , Martell , A. E. and McManus , D. 1995 . Can. J. Chem. , 73 : 264
   Web of Science ®Google Scholar
• McManus , D. and Martell , A. E. unpublished work
   Google Scholar
• Diaz , Z. US Patent . 4388293 . 1983 .
   Google Scholar
• Diaz , Z. US Patent . 4382918 . 1983 .
   Google Scholar
• DeBerry , D. W. AIChE Spring National Meeting . New Orleans, LA, USA. pp. 46b
   Google Scholar
• Mehnert , R. , Brede , O. and Janovsky , I. 1984 . Radiat. Phys. Chem. , 23 : 463
   Google Scholar
• Sawyer . US Patent . 5273734 . 1993 .
   Google Scholar
• Hancock , R. D. , Martell , A. E. and Chen , D. 1997 . Can. J. Chem. , 75 : 591
   Web of Science ®Google Scholar
• Martell , A. E. , Motekaitis , R. J. , Chen , D. , Hancock , R. D. and McManus , D. New Fc(III)/Fe(II) Chelating Agents as Catalysts for the Oxidation of Hydrogen Sulfide in Sulfur by Air . AIChE Spring National Meeting .
   Google Scholar
• Hancock , R. D. , Martell , A. E. , Chen , D. and McManus , D. Design of Ligands For Complexation of Fe(III)/Fe(II) in the Catalytic Oxidation of Hydrogen Sulfide to Sulfur . AIChE Spring National Meeting, Sulfur Recovery from Gas Streams . New Orleans, LA.
   Google Scholar
• McManus , D. US Patent . 5686613 . 1997 .
   Google Scholar
• McManus , D. US Patent . 5591419 . 1997 .
   Google Scholar
• Chen , D. , Martell , A. E. , Motekaitis , R. J. and McManus , D. 1998 . Can. J. Chem. , 76 : 445 – 451 .
   Web of Science ®Google Scholar
• Peter , S. US Patent . 4892718 . 1990 .
   Google Scholar
• Ferm , B. , Freivald , W. A. , McManus , D. and Reicher , M. Sulfur Recovery Using Non-Aqueous, Chelated Iron, Redox Catalyst Solution . Sulfur Recovery Conference . Volume 8 , GRI .
   Google Scholar
• Eng , S. J. , Motekaitis , R. J. and Martell , A. E. 1998 . Inorg. Chem. Acta , 278 : 170
   Web of Science ®Google Scholar
• Eng , R. J. , Motekaitis , R. J. and Martell , A. E. 2000 . Inorg. Chem. Acta , 299 : 9
   Google Scholar
• Rehmat , A. and Yoshizawa , J. Bio-SR Technology Update . GRI Sulfur Recovery Conference . Austin, Texas. GRI .
   Google Scholar
• Wubs , H. J. and Beenackers , A. A.C.M. 1994 . AIChE. J. , 40 : 433
   Web of Science ®Google Scholar
• DeBerry , D. W. 1997 . Environ. Prog. , 16 : 193
   Google Scholar
• Tsonopoulos , C. , Coulson , D. M. and Inman , J. B. 1976 . J. Chem. Eng Data , 21 : 190
   Web of Science ®Google Scholar
• Sonta , H. and Shiratori , T. US Patent . 4931262 . 1990 .
   Google Scholar
• Pagella , C. , Perego , P. and Zilli , M. 1996 . Chem. Eng. Tech. , 19 : 79
   Google Scholar
• Pagella , C. , Zambelli , L. , Spilvestri , P. and Faveri , D. M. 1996 . Chem. Eng. Tech. , 19 : 378
   Google Scholar
• Rai , C. and Taylor , M. Improving Liquid Redox Processes by Microbial Redox Solution Reoxidation Rate Enhancement . sulfur Recovery Conference . Volume 8 , GRI .
   Google Scholar
• Rai , C. US Patent . 5508014 . 1996 .
   Google Scholar
• McManus , D. 1998 . Biologically Enhanced Redox Solution Oxidation: Evaluation in a LO-CAT Process Simulation Reactor . Gas Research Institutes Project Advisors Group Meeting . September 10 1998 , Chicago, IL.
   Google Scholar
• Rai , C. and McManus , D. 1999 . Biologically Enhanced Liquid Redox Process: Evaluation in Process Simulation Reactors . Sulfur ecovery Conference . October 1999 , San Antonio, TX. Gas Research Institutes .
   Google Scholar
• Buisman , C. J. N. Europen Patent . EP 451922B1 . 1991 .
   Google Scholar
• Tanji , Y. , Kanagawa , T. and Mikami , E. 1989 . J. Ferment. Bioeng. , 67 : 280
   Google Scholar
• Cho , K. S. , Hirai , M. and Shoda , M. 1991 . J. Ferment. Bioeng. , 71 : 384
   Google Scholar
• Moriarty , D. J. W. and Nicholas , D. J. D. 1969 . Biochem. Biophs. Acta , 184 : 114
   PubMedGoogle Scholar
• Moriarty , D. J. W. and Nicholas , D. J. D. 1970 . Biochem. Biophs. Acta , 197 : 143
   Google Scholar
• Moriarty , D. J. W. and Nicholas , D. J. D. 1970 . Biochem. Biophs. Acta , 216 : 130
   Google Scholar
• Sugio , T. , Mizunashi , W. , Inagaki , K. and Tano , T. 1987 . J. Nacteriol. , 169 : 4916
   PubMedGoogle Scholar
• Sugio , T. , Suzuki , H. , Oto , A. , Inagaki , K. and Tano , T. 1991 . Agric. Biol. Chem. , 55 : 2091
   Web of Science ®Google Scholar
• Kusai , K. and Yamanaka , T. 1973 . Biochem. Biophys. Acta , 325 : 304
   PubMedGoogle Scholar
• Fukumori , Y. and Yamanaka , T. 1979 . J. Biochem. , 85 : 1405
   PubMed Web of Science ®Google Scholar
• Zhang , L. , Hirai , M. and Shoda , M. 1991 . J. Ferment. Bioeng. , 72 : 392
   Google Scholar
• Cho , K. S. , Hirai , M. and Shoda , M. 1992 . Appl. Environ. Microbiol. , 58 : 1183
   PubMed Web of Science ®Google Scholar
• Nakada , Y. and Ohta , Y. 1999 . J. Biosci. Bioeng. , 87 : 452
   PubMed Web of Science ®Google Scholar
• Buisman , C. J. N. , Geraats , B. G. , Ijspeert , P. and Lettinga , G. 1990 . Biotech. Bioeng. , 35 : 50
   PubMed Web of Science ®Google Scholar
• Buisman , C. J. N. and Vegt , A. L. Thiopaq Bioscrubber: An Innovative Technology to Remove Hydrogen Sulfide from Air and Gaseous Streams . Liquid Sulfur Recovery Conference . Austin, Texas. GRI .
   Google Scholar
• Quinlan , M. P. and Echterhoff , L. W. Onshore/Offshore Sulfur Recovery Process Evaluation . Sulfur Recovery Conference . Volume 8 , GRI .
   Google Scholar
• Gadre , R. V. 1989 . Biotech. Bioeng. , 34 : 410
   PubMed Web of Science ®Google Scholar
• Cadenherd , P. and Sublette , K. L. 1990 . Biotech. Bioeng. , 35 : 1150
   Google Scholar
• Luinstra , E. 1996 . Sulfur , 37
   Google Scholar
• Mizuta , S. , Kondo , W. and Fuji , K. 1991 . Ind. Eng. Chem. Res. , 30 : 1601
   Google Scholar
• Luinstra , E. Hydrogen from H2S: A Review of the Leading Processes . GRI Sulfur Recovery Conference . Austin, Texas.
   Google Scholar
• Mark , H. F. , McKetta , J. J. Jr. and Othmer , D. F. 1983 . Kirk-Othmer Encyclopedia of Chemical Technology , 3rd edn. Vol. 22 , 267
   Google Scholar
• Kaloidas , V. E. and Papayannakos , N. G. 1989 . Chem. Eng. Sci. , 44 : 2493
   Web of Science ®Google Scholar
• Kaloidas , V. E. and Papayannakos , N. G. 1987 . Int. J. Hydrogen Energy , 12 : 403
   Web of Science ®Google Scholar
• Linkous , C. A. , Mingo , T. E. and Muradov , N. Z. 1994 . Int. J. Hydrogen Energy , 19 : 203
   Web of Science ®Google Scholar
• Traus , I. and Suhr , H. 1992 . Plasma Chem. Plasma Process , 12 : 275
   Google Scholar
• Alexander , S. R. and Winnick , J. 1994 . AIChE. J. , 40 : 613
   Web of Science ®Google Scholar
• Mao , Z. , Anani , A. A. , White , R. E. , Srinivasan , S. and Appleby , A. J. 1991 . J. Electrochem. Soc. , 137 : 1299
   Google Scholar
• Honna , K. , Noguehi , H. and Goto , M. European Patent . EP 612556 . 1994 .
   Google Scholar
• Sonta , H. and Shiratori , T. US Patent . 4931262 . 1990 .
   Google Scholar
• Plummer , M. A. and Beazly , P. M. US Patent . 4592905 . 1986 .
   Google Scholar
• Plummer , M. A. 1987 . Hydrocarbon Processing , 38
   Google Scholar
• Plummer , M. A. and Cowley , S. W. 1993 . Hydrogen Sulfide Decomposition into Hydrogen and Sulfur by Quinonc Cycles Gas Reserch Institute Final Report, Technical ReportP2/0400, GRI
   Google Scholar
• Plummer , M. A. US Patent . 5180572 . 1993 .
   Google Scholar
• Plummer , M. A. Int. Patent, Wo. . 94/12431 . 1994 .
   Google Scholar
• James , B. R. 1997 . Pure & Appl. Chem. , 69 : 2213
   Google Scholar
• Lee , C. L. , Besenyei , G. , James , B. R. , Nelson , D. A. and Lilga , M. A. 1985 . J. Chem. Soc., Chem. Commun. , 1175
   Google Scholar
• Shaver , A. , El-khateeb , M. and Lebuis , A. M. 1996 . Angew. Chem. Int. Ed. Engl. , 35 : 2362
   Google Scholar
• Wong , T. Y. H. , Barnabas , A. F. , Sallin , D. and James , B. R. 1995 . Inorg. Chem. , 34 : 2278
   Google Scholar
• Osakada , K. , Yamamoto , T. and Yamamoto , Y. 1984 . Inorg. Chim. Acta , 90 : L5
   Google Scholar
• Kuehn , G. C. and Taube , H. 1976 . J. Am. Chem. Soc. , 98 : 689
   Web of Science ®Google Scholar
• Morelli , D. , Segre , A. , Ugo , R. , Cenini , S. , Bonti , F. and Bonti , F. 1967 . J. Chem. Soc., Chem. Commun. , 524
   Google Scholar
• Ugo , R. , Monica , G. L. , Cenini , S. , Segre , A. and Conti , F. 1971 . J. Chem. Soc. A. , 522
   Google Scholar
• Howard , W. A. and Parkin , G. 1993 . Organometallics , 12 : 2363
   Google Scholar
• Rabinovich , D. and Parkin , G. 1991 . J. Am. Chem. Soc. , 113 : 5904
   Google Scholar
• McDonald , R. and Cowie , M. 1993 . Inorg. Chem. , 32 : 1671
   Google Scholar
• Antonelli , D. M. and Cowie , M. 1990 . Inorg. Chem. , 29 : 3339
   Google Scholar
• Mueting , A. M. , Boyle , P. D. and Pignolet , L. H. 1981 . Inorg. Chem. , 23 : 44
   Google Scholar