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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 28, 2007 - Issue 5-6
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Original Articles

GILDED ORGANOMETALLICS

Pages 181-212 | Published online: 21 Dec 2007

REFERENCES

  • Forward , J. M. , J. P. Fackler , Jr. , and Z. Assefa , 1999 . Photophysical and photochemical properties of gold(I) complexes , In Optoelectronic Properties of Inorganic Compounds , Roundhill , D. M. and J. P. Fackler , Jr. (eds.), pp. 195 – 226 , Plenum Press , New York .
  • Fackler , J. P. , Jr. 2002 . Forty-five years of chemical discovery including a golden quarter-century . Inorg. Chem. , 41 , 6959 – 6972 .
  • Balch , A. L. 2007 . Remarkable luminescence behaviors and structural variations of two-coordinate gold(I) complexes . Struct. Bond. , 123 , 1 – 40 .
  • Fernández , E. J. , A. Laguna , and J. M. López-de-Luzuriaga , 2005 . Luminescence in complexes with Au(I)-Tl(I) interactions . Coord. Chem. Rev. , 249 , 1423 – 1433 .
  • Yam , V. W.-W. and E. C.-C. Cheng , 2001 . Design of luminescent sulfur-containing polynuclear gold(I) complexes for advanced nanomaterials and chemosensors . Gold Bull. , 34 , 20 – 23 .
  • Bowmaker , G. A. 1999 . Spectroscopic methods in gold chemistry , In Gold: Progress in Chemistry, Biochemistry and Technology , Schmidbaur , H. (ed.), pp. 841 – 881 , Wiley , Chichester .
  • Omary , M. A. , A. A. Mohamed , M. A. Rawashdeh-Omary , and J. P. Fackler , Jr. 2005 . Photophysics of supramolecular binary stacks consisting of electron-rich trinuclear Au(I) complexes and organic electrophiles . Coord. Chem. Rev. , 249 , 1372 – 1381 .
  • Arvapally , R. K. , P. Sinha , S. R. Hettiarachchi , N. L. Coker , C. E. Bedel , H. H. Patterson , R. C. Elder , A. K. Wilson , and M. A. Omary , 2007 . Photophysics of bis(thiocyanato)gold(I) complexes: Intriguing structure-luminescence relationships . J. Phys. Chem. C , 111 , 10689 – 10699 .
  • Grohman , A. and H. Schmidbaur , 1995 . Gold , In Comprehensive Organometallic Chemistry II , Abel , E. W. , F. G. A. Stone , and G. Wilkinson (eds.), Elsevier , Oxford .
  • Lai , S.-W. and C.-M. Che , 2004 . Luminescent cyclometalated diimine platinum(II) complexes: Photophysical studies and applications . Top. Curr. Chem. , 241 , 27 – 63 .
  • Ma , Y. , X. Zhou , J. Shen , H.-Y. Chao , and C.-M. Che , 1999 . Triplet luminescent dinuclear gold I complex-based light-emitting diodes with low turn-on voltage . Appl. Phys. Lett. , 74 , 1361 – 1363 .
  • Ma , Y. , C.-M. Che , H.-Y. Chao , X. Zhou , W.-H. Chan , and J. Shen , 1999 . High luminescence gold(I) and copper(I) complexes with a triplet excited state for use in light-emitting diodes . Adv. Mater. , 11 , 852 – 857 .
  • Yam , V. W.-W. , C.-L. Chan , S. W.-K. Choi , K. M.-C. Wong , E. C.-C. Cheng , S.-C. Yu , P.-K. Ng , W.-K. Chan , and K.-K. Cheung , 2000. Synthesis, photoluminescent and electroluminescent behaviour of four-coordinate tetrahedral gold(I) complexes. X-Ray crystal structure of [Au(dppn)2]Cl. Chem. Commun. , 53–54.
  • Barnard , P. J. , M. V. Baker , S. J. Berners-Price , B. W. Skelton , and A. H. White , 2004 . Dinuclear gold(I) complexes of bridging bidentate carbene ligands: Synthesis, structure and spectroscopic characterization . Dalton Trans. , 1038 – 1047 .
  • Barnard , P. , L. E. Wedlock , M. V. Baker , S. J. Berners-Price , D. A. Joyce , B. W. Skelton , and J. H. Steer , 2006 . Luminescence studies of the intracellular distribution of a dinuclear gold(I) n-heterocyclic carbene complex . Angew. Chem., Int. Ed. , 46 , 5966 – 5970 .
  • Yam , V. W.-W. , C.-K. Li , and C.-L. Chan , 1998 . Proof of potassium ions by luminescence signaling based on weak gold-gold interactions in dinuclear gold(I) complexes . Angew. Chem., Int. Ed. , 37 , 2857 – 2859 .
  • Mansour , M. A. , W. B. Connick , R. J. Lachicotte , H. J. Gysling , and R. Eisenberg , 1998 . Linear chain Au(I) dimer compounds as environmental sensors: A luminescent switch for the detection of volatile organic compounds . J. Am. Chem. Soc. , 120 , 1329 – 1330 .
  • Mills , A. , A. Lepre , B. R. C. Theobald , E. Slade , and B. A. Murrer , 1997 . Use of luminescent gold compounds in the design of thin-film oxygen sensors . Anal. Chem. , 69 , 2842 – 2847 .
  • Pyykkö , P. 2004 Theoretical chemistry of gold . Angew. Chem., Int. Ed. , 43 , 4412 – 4456 .
  • Pyykkö , P. 2005 . Theoretical chemistry of gold. II . Inorg. Chim. Acta. , 358 , 4113 – 4130 .
  • Schmidbaur , H. 2000 . The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts, and emerging applications . Gold Bull. , 33 , 3 – 10 .
  • Pyykkö , P. 1997 . Strong closed-shell interactions in inorganic chemistry . Chem. Rev. , 97 , 597 – 636 .
  • Elbjeirami , O. and M. A. Omary , 2007 . Photochemistry of neutral isonitrile gold(I) complexes: Modulation of photoreactivity by aurophilicity and π-acceptance ability . J. Am. Chem. Soc. , 139 , 11384 – 11393 .
  • Balch , A. L. 2004 . Polymorphism and luminescent behavior of linear, two-coordinate gold(I) complexes . Gold Bull. , 37 , 45 – 50 .
  • Fernández , E. J. , A. Laguna , and M. E. Olmos , 2005 . Recent developments in arylgold(I) chemistry . Adv. Organomet. Chem. , 52 , 77 – 141 .
  • Carvajal , M. A. , J. J. Novoa , and S. Alvarez , 2004 . Choice of coordination number in d10 complexes of group 11 elements . J. Am. Chem. Soc. , 126 , 1465 – 1477 .
  • Gimeno , M. C. and A. Laguna , 1997. Three- and four-coordinate gold(I) complexes. Chem. Rev. , 97, 511–522.
  • Sinha , P. , A. K. Wilson , and M. A. Omary , 2005 . Beyond a T-shape . J. Am. Chem. Soc. , 127 , 12488 – 12489 .
  • Fu , W.-F. , K.-C. Chan , V. M. Miskowski , and C.-M. Che , 1999 . The intrinsic 3[ds∗ps] emission of binuclear gold(I) complexes with two bridging diphosphane ligands lies in the near UV. Emissions in the visible region are due to exciplexes . Angew. Chem., Int. Ed. , 38 , 2783 – 2785 .
  • Fu , W.-F. , K.-C. Chan , and C.-M. Che , 2001 . Substrate-binding reactions of the 3[dσ∗pσ] excited state of binuclear gold(I) complexes with bridging bis(dicyclohexylphosphino)methane ligands: Emission and time-resolved absorption spectroscopic studies . Chem. Eur. J. , 7 , 4656 – 4664 .
  • Phillips , D. L. , C.-M. Che , K. H. Leung , Z. Mao , and M.-C. Tse , 2005 . A comparative study on metal-metal interaction in binuclear two- and three-coordinated d10-metal complexes. Spectroscopic investigation of M(I)-M(I) interaction in the 1[dσ∗pσ] excited state of [M2(dcpm)2]2+(dcpm = bis(dicyclohexylphosphino)methane) (M = Au, Ag, Cu) and [M2(dmpm)3]2+ (dmpm = bis(dimethylphosphino)methane) (M = Au, Ag, Cu) complexes . Coord. Chem. Rev. , 249 , 1476 – 1490 .
  • Catalano , V. J. and S. J. Horner , 2003 . Luminescent gold(I) and silver(I) complexes of 2-(diphenylphosphino)-1-methylimidazole (dpim): Characterization of a three-coordinate Au(I)-Ag(I) dimer with a short metal-metal separation . Inorg. Chem. , 42 , 8430 – 8438 .
  • Brandys , M.-C. and R. J. Puddephatt , 2001 . Strongly luminescent three-coordinate gold(I) polymers: 1D chain-link fence and 2D chickenwire structures . J. Am. Chem. Soc. , 123 , 4839 – 4840 .
  • Forward , J. M. , Z. Assefa , and J. P. Fackler , Jr. 1995 . Photoluminescence of gold(I) phosphine complexes in aqueous solution . J. Am. Chem. Soc. , 117 , 9103 – 9104 .
  • King , C. , M. N. I. Khan , R. J. Staples , and J. P. Fackler , Jr. 1992 . Luminescent mononuclear gold(I) phosphines . Inorg. Chem. , 31 , 3236 – 3238 .
  • McCleskey , T. M. and H. B. Gray , 1992 . Emission spectroscopic properties of 1,2-bis(dicyclohexylphosphino)ethane complexes of gold(I) . Inorg. Chem. , 31 , 1733 – 1734 .
  • Esswein , A. J. , J. L. Dempsey , and D. G. Nocera , 2007 . A RhII—AuII bimetallic core with a direct metal-metal bond . Inorg. Chem. , 46 , 2362 – 2364 .
  • Cook , T. R. , A. J. Esswein , and D. G. Nocera , 2007 . Metal-halide bond photoactivation from a PtIII—AuII complex . J. Am. Chem. Soc. , 129 , 10094 – 10095 .
  • Fernández , E. J. , A. Laguna , and J. M. López-de-Luzuriaga , 2007 . Gold–heterometal complexes. Evolution of a new class of luminescent materials . Dalton Trans. , 1969 – 1981 .
  • Che , C.-M. , H.-Y. Chao , V. M. Miskowski , Y. Li , and K.-K. Cheung , 2001. Luminescent μ-ethynediyl and μ-butadiynediyl binuclear gold(I) complexes: Observation of 3(ππ∗) emissions from bridging C n 2– Units. J. Am. Chem. Soc. , 123, 4985–4991.
  • Lu , W. , H.-F. Xiang , N. Zhu , and C.-M. Che , 2002 . The 3(ππ∗) emission of Cy3PAu(C ≡ C) n AuPCy3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ∗) emission . Organometallics , 21 , 2343 – 2346 .
  • Lu , W. , N. Zhu , and C.-M. Che , 2003 . Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au(PCy3)]4 ([TEE]H4 = tetraethynylethene) . J. Organomet. Chem. , 670 , 11 – 16 .
  • Irwin , M. J. , J. J. Vittal , and R. J. Puddephatt , 1997 . Luminescent gold(I) acetylides: From model compounds to polymers . Organometallics , 16 , 3541 – 3547 .
  • Yam , V. W.-W. , S. W.-K. Choi , and K.-K. Cheung , 1996 . Synthesis and design of novel tetranuclear and dinuclear gold(I) phosphine acetylide complexes. First X-ray crystal structures of a tetranuclear ([Au4(tppb)(C ≡ CPh)4]) and a related dinuclear ([Au2(dppb)(C ≡ CPh)2]) complex . Organometallics , 15 , 1734 – 1739 .
  • Allred , A. L. 1961 . Electronegativity values from thermochemical data . J. Inorg. Nucl. Chem. , 17 , 215 – 221 .
  • Pauling , L. 1960 . The Nature of the Chemical Bond, , 3rd ed. , Cornell University .
  • Griffith , J. S. 1964 . Theory of Transition Metal Ions , Cambridge University Press , Cambridge .
  • Friedrich , J. , F. Metz , and F. Dörr , 1975 . Influence of a heavy atom on the decay mechanisms of the lowest triplet state of aromatic hydrocarbons . Mol. Phys. , 30 , 289 – 312 .
  • See also : Mohamed , A. A. , M. A. Rawashdeh-Omary , M. A. Omary , and J. P. Fackler , Jr. 2005 . External heavy-atom effect of gold in a supramolecular acid-base π stack . Dalton Trans. , 2597 – 2602 .
  • For heavy-atom effects in luminescent copper(I) and silver(I) complexes, see : Omary , M. A. , M. A. Rawashdeh-Omary , H. V. K. Diyabalanage , and H. V. Rasika Dias , 2003 . Blue phosphors of dinuclear and mononuclear copper(I) and silver(I) complexes of 3,5-bis(trifluoromethyl)pyrazolate and the related bis(pyrazolyl)borate . Inorg. Chem. , 42 , 8612 – 8614 .
  • For heavy-atom effects in luminescent, supramolecular complexes of mercury(II), see : (a) Burress , C. N. , M. I. Bodine , O. Elbjeirami , J. H. Reibenspies , M. A. Omary , and F. P. Gabbaï , 2007 . Enhancement of external spin-orbit coupling effects caused by metal-metal cooperativity . Inorg. Chem. , 46 , 1388 – 1395 . (b) Elbjeirami , O. , C. N. Burress , F. P. Gabbaï , and M. A. Omary , 2007 . Simultaneous external and internal heavy-atom effects in binary adducts of 1-halonaphthalenes with trinuclear perfluoro-ortho-phenylene mercury(II): A structural and photophysical study . J. Phys. Chem. C , 111 , 9522 – 9529 .
  • Miyaura , N. and A. Suzuki , 1995. Palladium-catalyzed cross-coupling reactions of organoboron compounds. Chem. Rev. , 95, 2457–2483.
  • Suzuki , A. 1998 . Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998 . J. Organomet. Chem. , 576 , 147 – 168 .
  • Chemler , S. R. , D. Trauner , and S. J. Danishefsky , 2001 . The B-Alkyl suzuki–miyaura cross-coupling reaction: Development, mechanistic study, and applications in natural product synthesis . Angew. Chem., Int. Ed. , 40 , 4544 – 4568 .
  • Matos , K. and J. A. Soderquist , 1998 . Alkylboranes in the suzuki-miyaura coupling: Stereochemical and mechanistic studies . J. Org. Chem. , 63 , 461 – 470 .
  • Forward , J. M. , J. P. Fackler , Jr. , and R. J. Staples , 1995 . Synthesis and structural characterization of the luminescent gold(I) complex [(MeTPA)3AuI]I3. Use of NaBPh4 as a phenyl-transfer reagent to form [(MeTPA)AuPh](BPh4) and (TPA)AuPh . Organometallics , 14 , 4194 – 4198 .
  • For water-stable gold(I) alkynyl complexes see : Mohr , F. , E. Cerrada , and M. Laguna , 2006 . Organometallic gold(I) and gold(III) complexes containing 1,3,5-triaza-7-phosphaadamantane (TPA): Examples of water-soluble organometallic gold compounds . Organometallics , 25 , 644 – 648 .
  • Sladek , A. , S. Hofreiter , M. Paul , and H. Schmidbaur , 1995 . Sodium tetraphenylborate as a phenylating agent for gold(I) complexes . J. Organomet. Chem. , 501 , 47 – 51 .
  • Partyka , D. V. , M. Zeller , A. D. Hunter , and T. G. Gray , 2006 . Relativistic functional groups: Aryl carbon-gold bond formation by selective transmetallation of boronic acids . Angew. Chem., Int. Ed. , 45 , 8188 – 8191 .
  • Partyka , D. V. , A. J. Esswein , M. Zeller , A. D. Hunter , and T. G. Gray , 2007 . Gold(I) pyrenyls: Excited-state consequences of carbon-gold bond formation . Organometallics , 26 , 3279 – 3282 .
  • Murov , S. L. , I. Carmichael , and G. L. Hug , 1993 . Handbook of Photochemistry, , 2nd ed. , Dekker , New York .
  • Miertus S. , E. Scrocco , and J. Tomasi , 1981 . Electrostatic interaction of a solute with a continuum. A direct utilization of ab initio molecular potentials for the prevision of solvent effects . Chem. Phys. , 55 , 117 – 129 .
  • Cossi , M. , G. Scalmani , N. Rega , and V. Barone , 2002 . New developments in the polarizable continuum model for quantum mechanical and classical calculations on molecules in solution . J. Chem. Phys. , 117 , 43 – 54 .
  • Tomasi , J. , B. Mennucci , and R. Cammi , 2005 . Quantum mechanical continuum solvation models . Chem. Rev. , 105 , 2999 – 3093 .
  • Fackler , J. P. , Jr. 1971 . Symmetry in Coordination Chemistry , Academic , New York .
  • Mulliken , R. S. 1955. Electronic population analysis on LCAO-MO molecular wave functions. I. J. Chem. Phys. , 23, 1833–1840.
  • Killoran , J. , L. Allen , J. F. Gallagher , W. M. Gallagher , and D. F. O'Shea , 2002 . Synthesis of BF2 chelates of tetraarylazadipyrromethenes and evidence for their photodynamic therapeutic behaviour . Chem. Commun. , 1862 – 1863 .
  • Zhao , W. and E. M. Carreira , 2005 . Conformationally restricted aza-bodipy: A highly fluorescent, stable, near-infrared-absorbing dye . Angew. Chem., Int. Ed. , 44 , 1677 – 1679 .
  • Hall , M. J. , L. T. Allen , and D. F. O'Shea , 2006 . PET modulated fluorescent sensing from the BF2 chelated azadipyrromethene platform . Org. Biomol. Chem. , 4 , 776 – 780 .
  • McDonnell , S. O. and D. F. O'Shea , 2006 . Near-infrared sensing properties of dimethylamino-substituted BF2-azadipyrromethenes . Org. Lett. , 8 , 3493 – 3496 .
  • Coskun , A. , M. D. Yilmaz , and E. U. Akkaya , 2007 . Bis(2-pyridyl)-substituted boratriazaindacene as an NIR-emitting chemosensor for Hg(II) . Org. Lett. , 9 , 607 – 609 .
  • Gorman , A. , J. Killoran , C. O'Shea , T. Kenna , W. M. Gallagher , and D. F. O'Shea , 2004 . In vitro demonstration of the heavy-atom effect for photodynamic therapy . J. Am. Chem. Soc. , 126 , 10619 – 10631 .
  • Gallagher , W. M. , L. T. Allen , C. O'Shea , T. Kenna , M. Hall , A. Gorman , J. Killoran , and D. F. O'Shea , 2005 . A potent nonporphyrin class of photodynamic therapeutic agent: Cellular localization, cytotoxic potential, and influence of hypoxia . Br. J. Cancer , 92 , 1702 – 1710 .
  • Teets , T. S. , D. V. Partyka , A. J. Esswein , J. B. Updegraff III , M. Zeller , A. D. Hunter , and T. G. Gray , 2007 . Luminescent, three-coordinate azadipyrromethene complexes of d10 copper, silver, and gold . Inorg. Chem. , 46 , 6218 – 6220 .
  • Clegg , W. 1976 . 2,2′-Bipyridyltriphenylphosphinegold(I) hexafluorophosphate . Acta Crystallogr. , B32 , 2712 – 2714 .
  • Meiners , J. , J.-S. Herrmann , and P. W. Roesky , 2007 . Three-coordinated aminotroponiminate and aminotroponate complexes of gold(I) . Inorg. Chem. , 46 , 4599 – 4604 .
  • Teets , T. S. , D. V. Partyka , J. B. Updegraff III , and T. G. Gray , submitted for publication .

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