USING PHOSPHONATES TO PROBE STRUCTURAL DIFFERENCES BETWEEN TRANSURANIUM ELEMENTS AND THEIR PROPOSED SURROGATES

REFERENCES

• Choppin , G. R. 1983 . Solution chemistry of the actinides . Radiochim. Acta. , 32 : 43 – 53 .
   Web of Science ®Google Scholar
• Albright , D. , F. Berkhout , and W. Walker . 1997 . Plutonium and Highly Enriched Uranium 1996: World Inventories, Capabilities, and Policies: Stockholm International Peace Research Institute , Oxford University Press , New York .
   Google Scholar
• Wilson , P. D. , ed. 1996 . The Nuclear Fuel Cycle: From Ore to Waste , Oxford University Press , New York .
   Google Scholar
• Draganic , I. G. , Z. D. Draganic , and J.-P. Adloff . 1990 . 1973 . Radiation and Radioactivity on Earth and Beyond , CRC Press , Boca Raton , FL .
   Google Scholar
• Clark , D. L. , D. E. Hobart , and M. P. Neu . 1995. Actinide carbonate complexes and their importance in actinide environmental chemistry. Chem. Rev. , 95: 25–48.
   Web of Science ®Google Scholar
• Bhattacharyya , M. H. , B. D. Breitenstein , H. Metivier , B. A. Muggenburg , G. N. Stradling , and V. Volf . 1992 . Guidebook for the treatment of accidental internal radionuclide contamination of workers . Radiat. Prot. Dosim. , 41 : 1 – 49 .
   Web of Science ®Google Scholar
• Sutcliffe , W. G. , R. H. Condit , W. G. Mansfield , D. S. Myers , D. W. Layton , and P. W. Murphy . 1995 . A Perspective on the Dangers of Plutonium , Lawrence Livermore National Laboratory , Livermore , CA .
   Google Scholar
• Stradling , G. N. 1998 . Decorporation of actinides: A review of recent research . J. Alloys Compd. , 271–273 : 72 – 77 ; a) Humphreys , E. R. and V. A. Stones . 1978 . The relationship between iron-59 uptake in marrow and plutonium-239 deposition in bone . Chem. Med. , 33 : 571 – 5 .
   Web of Science ®Google Scholar
• a) Runde , W. , A. C. Bean , T. E. Albrecht-Schmitt , and B. L. Scott . 2003 . Structural characterization of the first hydrothermally synthesized plutonium compound, PuO2(IO3)2 H2O . Chem. Commun. , 4 : 478 – 479 ; b) Bean , A. C. , B. L. Scott , T. E. Albrecht-Schmitt , and W. Runde . 2003 . Structural and spectroscopic trends in actinyl iodates of uranium, neptunium, and plutonium . Inorg. Chem. , 42 : 5632 – 5636 ; c) Weigel , F. and L. W. H. Engelhardt . 1983 . Preparation and properties of uranyl bromate monohydrate . J. Less-Common Met. , 91 : 339 – 350 ; d) Bean , A. C. , S. M. Peper , and T. E. Albrecht-Schmitt . 2001 . Structural relationships, interconversion, and optical properties of the uranyl iodates, UO2(IO3)2 and UO2(IO3)2(H2O): A comparison of reactions under mild and supercritical conditions . Chem. Mater. , 13 : 1266 – 1272 ; e) Gorden , A. E. V. , D. K. Shuh , B. E. F. Tiedemann , R. E. Wilson , J. Xu , and K. N. Raymond . 2005 . Sequestered plutonium: [PuIV{5LIO(Me-3,2-HOPO)}2]—the first structurally characterized plutonium hydroxypyridonate complex . Chemistry , 11 : 2842 – 2848 ; f) Gorden , A. E. V. , J. Xu , and K. N. Raymond . 2003 . Rational design of sequestering agents for plutonium and other actinides . Chem. Rev. , 103 : 4207 – 4282 ; g) Xu , J. , E. Radkov , M. Ziegler , and K. N. Raymond . 2000 . Plutonium(IV) sequestration: Structural and thermodynamic evaluation of the extraordinarily stable cerium(IV) hydroxypyridinonate complexes . Inorg. Chem. , 39 : 4156 – 4164 ; h) Raymond , K. N. and G. Szigethy . 2008 . In Shuh, D. K., Chung, B. W., Albrecht-Schmitt, T. E., Gouder, T., and J. D. Thompson (eds.), Actinides 2008--Basic Science, Applications and Technology: Symposium Held March 25–28, 2008, San Francisco, California, U.S.A. (Materials Research Society Symposium Proceedings), Vol. 1104, Materials Research Society, San Francisco, CA; i) Penneman , R. A. , R. R. Ryan and A. Rosenzweig . 1973 . Structural systematics in actinide fluoride complexes . Struct. Bonding. , 13 : 1 – 52 ; j) Brandel , V. and N. Dacheux . 2004 . Chemistry of tetravalent actinide phosphates–Part II . J. Solid State Chem. , 177 : 4755 – 4767 ; k) Brandel , V. and N. Dacheux . 2004 . Chemistry of tetravalent actinide phosphates-Part I . J. Solid State Chem. , 177 : 4743 – 4754 ; l) Dacheux , N. , R. Podor , V. Brandel , and M. Genet . 1998 . Investigations of systems ThO2-MO2-P2O5 (M=U, Ce, Zr, Pu). Solid solutions of thorium-uranium (IV) and thorium-plutonium (IV) phosphate-diphosphates . J. Nucl. Mater. , 252 : 179 – 186 ; m) Dacheux , N. , S. Grandjean , J. Rousselle , and N. Clavier . 2007 . Hydrothermal method of preparation of actinide(IV) phosphate hydrogenphosphate hydrates and study of their conversion into actinide(IV) phosphate diphosphate solid solutions . Inorg. Chem. , 46 : 10390 – 10399 ; n) Dacheux , N. , A. C. Thomas , V. Brandel , and M. Genet . 1998 . Investigation of the system ThO2-NpO2-P2O5. Solid solutions of thorium-neptunium (IV) phosphate-diphosphate . J. Nucl. Mater. , 257 : 108 – 117 ; o) Keller , C. and K. H. Walter . 1965 . Preparation, lattice constants, and chemical properties of certain ternary oxides of plutonium, americium, and curium of the type MIIIXVO4 . J. Inorg. Nucl. Chem. , 27 : 1253 – 1260 ; p) Dacheux , N. , N. Clavier , G. Wallez , and M. Quarton . 2007 . Crystal structures of Th(OH)PO4, U(OH)PO4 and Th2O(PO4)2. Condensation mechanism of MIV(OH)PO4 (M = Th, U) into M2O(PO4)2 . Solid State Sci. , 9 : 619 – 627 .
   Google Scholar
• Bray , T. H. , A.-G. D. Nelson , G. B. Jin , R. G. Haire , and T. E. Albrecht-Schmitt . 2007. In situ hydrothermal reduction of neptunium(VI) as a route to neptunium(IV) phosphonates. Inorg. Chem. , 46: 10959–10961.
   Google Scholar
• Bray , T. H. , J. Ling , E.-S. Choi , J. S. Brooks , J. V. Beitz , R. E. Sykora , R. G. Haire , D. M. Stanbury , and T. E. Albrecht-Schmitt . 2007 . Critical role of water content in the formation and reactivity of uranium, neptunium, and plutonium iodates under hydrothermal conditions: Implications for the oxidative dissolution of spent nuclear fuel . Inorg. Chem. , 46 : 3663 – 3668 .
   Google Scholar
• Cowan , R. L. and R. W. Staehle . 1971 . The thermodynamic and electrode kinetic behavior of nickel in acid solution in the temperature range 25° to 300°C . J. Electrochem. Soc. , 118 : 557 – 568 .
   Web of Science ®Google Scholar
• Nelson , A.-G. D. , T. H. Bray , W. Zhan , R. G. Haire , and T. E. Albrecht-Schmitt . 2008 . Further examples of the failure of surrogates to properly model the structural and hydrothermal chemistry of transuranium elements: insights provided by uranium and neptunium diphosphonates . Inorg. Chem. , 47 : 4945 – 4951 .
   Google Scholar
• Nelson , A.-G. D. , T. H. Bray , and T. E. Albrecht-Schmitt . 2008 . Capitalizing on differing coordination environments and redox potentials to prepare an ordered heterobimetallic U(VI)/Np(IV) diphosphonate . Angew. Chem. Int. Ed. , 47 : 6252 – 6254 .
   Google Scholar
• (a) Clearfield , A. 1998 . Metal phosphonate chemistry . In Progress of Inorganic Chemistry , Karlin, Kenneth D. (ed.) 47 , 371 – 510 ; (b) Clearfield , A. 2003 . Recent advances in metal phosphonate chemistry. II . Curr. Opin. Solid State Mater. Sci. , 6 : 495 – 506 ; (c) Mao , J.-G. 2007 . Structures and luminescent properties of lanthanide phosphonates . Coord. Chem. Rev. , 251 : 1493 – 1520 .
   Web of Science ®Google Scholar
• Nelson , A.-G. D. , T. H. Bray , F. A. Stanley , and T. E. Albrecht-Schmitt . 2009. Periodic trends in actinide phosphonates: Divergence and convergence between thorium, uranium, neptunium, and plutonium systems. Inorg. Chem. , 48: 4530–4535.
   PubMed Web of Science ®Google Scholar
• Miguirditchian , M. , D. Guillaneux , D. Guillaumont , P. Moisy , C. Madic , M. P. Jensen , and K. L. Nash . 2005 . Thermodynamic study of the complexation of trivalent actinide and lanthanide cations by ADPTZ, a tridentate N-donor ligand . Inorg. Chem. , 44 : 1404 – 1412 .
   PubMed Web of Science ®Google Scholar
• a) Nash , K. L. 1997 . f-element complexation by diphosphonate ligands . J. Alloy and Cmpd. , 249 : 33 – 40 ; b) Jensen , M. P. , J. V. Beitz , R. D. Rogers , and K. L. Nash . 2000 . Thermodynamics and hydration of the europium complexes of a nitrogen heterocycle methane-1,1-diphosphonic acid . Dalton Trans. , 18 : 3058 – 3064 ; c) Chiarizia , R. , E. P. Horwitz , S. D. Alexandratos , and M. J. Gula . 1997 . Diphonix resin: A review of its properties and applications . Sep. Sci. Tech. , 32 : 1 – 35 .
   Web of Science ®Google Scholar
• a) Nash , K. L. 1991 . Thermodynamics of formation of complexes between thorium(IV) and substituted methane diphosphonic acids in acidic solutions . Radiochim. Acta. , 54 : 171 – 179 ; b) Nash , K. L. 1993 . Stability and stoichiometry of uranyl phosphonate coordination compounds in acidic aqueous solutions . Radiochim. Acta. , 61 : 147 – 154 .
   Web of Science ®Google Scholar