Implication of counter-cations for polyoxometalate-based nano-electronics

References

• Pope, M. T.; Kortz, U. Polyoxometalates. In Encyclopedia Inorg. Chem.; Scott, R. A., Ed.; John Wiley & Sons, Ltd, 2012.
   Google Scholar
• Misra, A.; Kozma, K.; Streb, C.; Nyman, M. Beyond Charge Balance: Counter-Cations in Polyoxometalate Chemistry. Angew. Chem. Int. Ed. 2020, 59(2), 596–612.
   Web of Science ®Google Scholar
• Laurans, M.; Trinh, K.; Dalla Francesca, K.; Izzet, G.; Alves, S.; Derat, E.; Humblot, V.; Pluchery, O.; Vuillaume, D.; Lenfant, S., et al. Covalent Grafting of Polyoxometalate Hybrids onto Flat Silicon/Silicon Oxide: Insights from POMs Layers on Oxides. ACS Appl. Mater. Interfaces. 2020, 12(42), 48109–48123. DOI: 10.1021/acsami.0c12300.
   PubMed Web of Science ®Google Scholar
• Glöß, M.; Pütt, R.; Moors, M.; Kentzinger, E.; Karthäuser, S.; Monakhov, K. Y. Exploring the Ligand Functionality, Electronic Band Gaps, and Switching Characteristics of Single Wells–Dawson-type Polyoxometalates on Gold. Adv. Mater. Interfaces. 2022, 9(21), 2200461.
   Web of Science ®Google Scholar
• Werner, I.; Griebel, J.; Masip-Sánchez, A.; López, X.; Załęski, K.; Kozłowski, P.; Kahnt, A.; Börner, M.; Warneke, Z.; Warneke, J., et al. Hybrid Molecular Magnets with Lanthanide- and Countercation-Mediated Interfacial Electron Transfer between Phthalocyanine and Polyoxovanadate. Inorg. Chem. 2023. DOI: 10.1021/acs.inorgchem.2c03599.
   Web of Science ®Google Scholar
• Grigoriev, V. A.; Cheng, D.; Hill, C. L.; Weinstock, I. A. Role of Alkali Metal Cation Size in the Energy and Rate of Electron Transfer to Solvent-Separated 1:1 [(M+)(acceptor)] (M+ = Li+, Na+, K+) Ion Pairs. J. Am. Chem. Soc. 2001, 123(22), 5292–5307. DOI: 10.1021/ja010074q.
   PubMed Web of Science ®Google Scholar
• Glöß, M.; Pütt, R.; Moors, M.; Kentzinger, E.; Pyckhout-Hintzen, W.; Monakhov, K. Y. Interplaying the Amphipathic Polyoxometalate Interactions in Solution and at Solid–Liquid Interfaces: A Toolbox for the Technical Application. Nanoscale. 2019, 11(10), 4267–4277. DOI: 10.1039/C8NR08008A.
   PubMed Web of Science ®Google Scholar
• Piot, M.; Abécassis, B.; Brouri, D.; Troufflard, C.; Proust, A.; Izzet, G. Control of the Hierarchical Self-Assembly of Polyoxometalate-Based Metallomacrocycles by Redox Trigger and Solvent Composition. PNAS. 2018, 115(36), 8895–8900. DOI: 10.1073/pnas.1808445115.
   PubMed Web of Science ®Google Scholar
• Cameron, J. M.; Guillemot, G.; Galambos, T.; Amin, S. S.; Hampson, E.; Mall Haidaraly, K.; Newton, G. N.; Izzet, G. Supramolecular Assemblies of Organo-Functionalised Hybrid Polyoxometalates: From Functional Building Blocks to Hierarchical Nanomaterials. Chem. Soc. Rev. 2022, 51(1), 293–328. DOI: 10.1039/D1CS00832C.
   PubMed Web of Science ®Google Scholar
• Rahman, T.; Martin, N. P.; Jenkins, J. K.; Elzein, R.; Fast, D. B.; Addou, R.; Herman, G. S.; Nyman, M. Nb2O5, LiNbO3, and (Na,K)NbO3 Thin Films from High-Concentration Aqueous Nb-polyoxometalates. Inorg. Chem. 2022, 61(8), 3586–3597. DOI: 10.1021/acs.inorgchem.1c03638.
   PubMed Web of Science ®Google Scholar
• Cherevan, A. S.; Nandan, S. P.; Roger, I.; Liu, R.; Streb, C.; Eder, D. Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives. Adv. Sci. 2020, 7(8), 1903511. DOI: 10.1002/advs.201903511.
   Web of Science ®Google Scholar
• Moors, M.; An, Y.; Kuc, A.; Monakhov, K. Y. TiOx/Pt3Ti(111) Surface-Directed Formation of Electronically Responsive, Supramolecular Assemblies of Tungsten Oxide Clusters. Beilstein J. Nanotechnol. 2021, 12, 203–212. DOI: 10.3762/bjnano.12.16.
   PubMed Web of Science ®Google Scholar
• Linnenberg, O.; Moors, M.; Notario-Estévez, A.; López, X.; De Graaf, C.; Peter, S.; Baeumer, C.; Waser, R.; Monakhov, K. Y. Addressing Multiple Resistive States of Polyoxovanadates: Conductivity as a Function of Individual Molecular Redox States. J. Am. Chem. Soc. 2018, 140(48), 16635–16640. DOI: 10.1021/jacs.8b08780.
   PubMed Web of Science ®Google Scholar
• Linnenberg, O.; Moors, M.; Solé-Daura, A.; López, X.; Bäumer, C.; Kentzinger, E.; Pyckhout-Hintzen, W.; Monakhov, K. Y. Molecular Characteristics of a Mixed-Valence Polyoxovanadate {VIV/V18O42} in Solution and at the Liquid–Surface Interface. J. Phys. Chem. C. 2017, 121(19), 10419–10429. DOI: 10.1021/acs.jpcc.7b02138.
   Web of Science ®Google Scholar
• Guest, M.; Mir, R.; Foran, G.; Hickson, B.; Necakov, A.; Dudding, T. Trisaminocyclopropenium Cations as Small-Molecule Organic Fluorophores: Design Guidelines and Bioimaging Applications. J. Org. Chem. 2020, 85(21), 13997–14011. DOI: 10.1021/acs.joc.0c02026.
   PubMed Web of Science ®Google Scholar
• Le Maguerès, P.; Hubig, S. M.; Lindeman, S. V.; Veya, P.; Kochi, J. K. Novel Charge-Transfer Materials via Cocrystallization of Planar Aromatic Donors and Spherical Polyoxometalate Acceptors. J. Am. Chem. Soc. 2000, 122(41), 10073–10082. DOI: 10.1021/ja0019878.
   Web of Science ®Google Scholar
• Fay, N.; Bond, A. M.; Baffert, C.; Boas, J. F.; Pilbrow, J. R.; Long, D. L.; Cronin, L. Structural, Electrochemical, and Spectroscopic Characterization of a Redox Pair of Sulfite-Based Polyoxotungstates: α-[W18O54(SO3)2]4– And α-[W18O54(SO3)2]5–. Inorg. Chem. 2007, 46(9), 3502–3510. DOI: 10.1021/ic062067e.
   PubMed Web of Science ®Google Scholar
• Lapham, P.; Vilà-Nadal, L.; Cronin, L.; Georgiev, V. P. Influence of the Contact Geometry and Counterions on the Current Flow and Charge Transfer in Polyoxometalate Molecular Junctions: A Density Functional Theory Study. J. Phys. Chem. C. 2021, 125(6), 3599–3610. DOI: 10.1021/acs.jpcc.0c11038.
   PubMed Web of Science ®Google Scholar
• Sorokina, A.; Rydnyk, D. A.; Monakhov, K. Y.; Heine, T. What Is the Maximum Charge Uptake of Lindqvist-type Polyoxovanadates in Organic–Inorganic Heterostructures? Phys. Chem. Chem. Phys. 2022, 24(43), 26848–26852. DOI: 10.1039/D2CP04687C.
   PubMed Web of Science ®Google Scholar
• Solé-Daura, A.; Notario-Estévez, A.; Carbó, J. J.; Poblet, J. M.; de Graaf, C.; Monakhov, K. Y.; López, X. How Does the Redox State of Polyoxovanadates Influence the Collective Behavior in Solution? A Case Study with [I@V18O42]q− (q = 3, 5, 7, 11, and 13). Inorg. Chem. 2019, 58(58), 3881–3894. DOI: 10.1021/acs.inorgchem.8b03508.
   PubMed Web of Science ®Google Scholar
• Gumerova, N. I.; Rompel, A. Polyoxometalates in Solution: Speciation under Spotlight. Chem. Soc. Rev. 2020, 49(21), 7568–7601. DOI: 10.1039/D0CS00392A.
   PubMed Web of Science ®Google Scholar
• Watfa, N.; Melgar, D.; Haouas, M.; Taulelle, F.; Hijazi, A.; Naoufal, D.; Bonet Avalos, J.; Floquet, S.; Bo, C.; Cadot, E. Hydrophobic Effect as a Driving Force for Host–Guest Chemistry of a Multi-Receptor Keplerate-Type Capsule. J. Am. Chem. Soc. 2015, 137, 5845–5851.
   PubMed Web of Science ®Google Scholar
• Ding, J.; Yan, G.; Adamu-Lema, F.; Dou, Y.; Chen, Y.; Ding, B.; Georgiev, V. P.; Asenov, A. The Extraction of Polyoxometalate Flash Compact Model and Corresponding Circuit Simulation. J. Nanoelectron. Optoelectron. 2021, 16(6), 884–890. DOI: 10.1166/jno.2021.3027.
   Web of Science ®Google Scholar
• Moors, M.; Warneke, J.; López, X.; de Graaf, C.; Abel, B.; Monakhov, K. Y. Insights from Adsorption and Electron Modification Studies of Polyoxometalates on Surfaces for Molecular Memory Applications. Acc. Chem. Res. 2021, 54(17), 3377–3389. DOI: 10.1021/acs.accounts.1c00311.
   PubMed Web of Science ®Google Scholar
• Laskin, J.; Johnson, G. E.; Warneke, J.; Prabhakaran, V. From Isolated Ions to Multilayer Functional Materials Using Ion Soft Landing. Angew. Chem. Int. Ed. 2018, 57(50), 16270–16284. DOI: 10.1002/anie.201712296.
   PubMed Web of Science ®Google Scholar
• Yang, F.; Moors, M.; Hoang, D. A.; Schmitz, S.; Rohdenburg, M.; Knorke, H.; Charvat, A.; Wang, X.-B.; Monakhov, K. Y.; Warneke, J. On-Surface Single-Molecule Identification of Mass-Selected Cyclodextrin-Supported Polyoxovanadates for Multistate Resistive-Switching Memory Applications. ACS Appl. Nano Mater. 2022, 5(10), 14216–14220. DOI: 10.1021/acsanm.2c03025.
   Web of Science ®Google Scholar
• Christensen, D. V.; Dittmann, R.; Linares-Barranco, B.; Sebastian, A.; Le Gallo, M.; Redaelli, A.; Slesazeck, S.; Mikolajick, T.; Spiga, S.; Menzel, S., et al. 2022 Roadmap on Neuromorphic Computing and Engineering. Neuromorph. Comput. Eng. 2022, 2, 022501.
   Google Scholar
• Huez, C.; Guérin, D.; Lenfant, S.; Volatron, F.; Calame, M.; Perrin, M. L.; Proust, A.; Vuillaume, D. Redox-Controlled Conductance of Polyoxometalate Molecular Junctions. Nanoscale. 2022, 14(37), 13790–13800. DOI: 10.1039/D2NR03457C.
   PubMed Web of Science ®Google Scholar
• Chen, X.; Zhou, Y.; Roy, V. A. L.; Han, S. T. Evolutionary Metal Oxide Clusters for Novel Applications: Toward High‐density Data Storage in Nonvolatile Memories. Adv. Mater. 2018, 30(3), 1703950. DOI: 10.1002/adma.201703950.
   Web of Science ®Google Scholar
• Gillet, A.; Cher, S.; Tasse, M.; Blon, T.; Alves, S.; Izzet, G.; Chaudret, B.; Proust, A.; Demont, P.; Volatron, F., et al. Polarizability Is a Key Parameter for Molecular Electronics. Nanoscale. Horiz. 2021, 6(3), 271–276. DOI: 10.1039/D0NH00583E.
   PubMed Web of Science ®Google Scholar
• Yi, X.; Izarova, N. V.; Stuckart, M.; Guérin, D.; Thomas, L.; Lenfant, S.; Vuillaume, D.; van Leusen, J.; Duchoň, T.; Nemšák, S., et al. Probing Frontier Orbital Energies of {Co9(P2W15)3} Polyoxometalate Clusters at Molecule–Metal and Molecule–Water Interfaces. J. Am. Chem. Soc. 2017, 139(41), 14501–14510. DOI: 10.1021/jacs.7b07034.
   PubMed Web of Science ®Google Scholar