Publication Cover
Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 14, 1993 - Issue 2-3
13
Views
10
CrossRef citations to date
0
Altmetric
Original Articles

Stereochemistry and Steric Effects in the Photosubstitutions of Chromium(III) Complexes, and Their Utility as Probes of Mechanism

Pages 89-121 | Received 10 Aug 1992, Published online: 04 Oct 2006

References

  • Bjerrum , N. and Anorg , Z. 1921 . Allgem. Chemie , 118 : 131
  • Balzani , V. and Carassiti , V. 1970 . Photochemistry of Coordination Compounds , London and New York : Academic Press . Chapt. 7.
  • Zinato , E. 1975 . Concepts of Inorganic Chemistry , Edited by: Adamson , A. W. and Fleischauer , P. New York : Wiley . Chapt. 4. (b) M. A. Jamieson, N. Serpone and M. Z. Hoffman, Coord. Chem. Rev., 39, 121 (1981). (c) B. R. Hollebone, C. H. Langford and N. Serpone, Coord. Chem. Rev., 77, 1 (1981). (d) A. D. Kirk, Coord. Chem. Rev., 39, 225 (1981).
  • Forster , L. S. 1990 . Chem. Rev. , 90 : 331 (b) J. F. Endicott, T. Ramasami, R. Tamilarasan, R. B. Lessard and G. R. Brubaker, Coord. Chem. Rev., 77, 1 (1987).
  • Adamson , A. W. 1967 . J. Phys. Chem. , 71 : 798
  • Manfrin , M. F. , Moggi , L. and Balzani , V. 1977 . Inorg. Chem. , 10 : 207
  • Chen , S. N. and Porter , G. B. 1970 . J. Am. Chem. Soc. , 92 : 3196
  • Rojas , G. E. , Dupuy , C. , Sexton , D. A. and Magde , D. 1986 . J. Phys. Chem. , 90 : 87
  • Kirk , A. D. and Ibrahim , A. M. 1990 . Inorg. Chem. , 29 : 4848
  • CrL5X species have C4 v and trans CrL4X2 species have D4 h symmetry. Cis-CrL4X2 species can be considered to be trans-CrZ4L2, species with D4 h symmetry where Z is a hypothetical ligand with a ligand field strength equal to the mean of L and X. Fac-CrL3X3 are quasi-Oh , CrZ6 species. Mer-CrL3Z6 species. etc., have lower symmetries.
  • Kirk , A. D. , Frederick , L. A. and Glover , S. G. 1980 . J. Am. Chem. Soc. , 102 : 7170
  • Yamatera , H. 1958 . Bull. Chem. Soc. Jpn. , 31 : 95
  • Wilson , R. B. and Solomon , E. I. 1978 . Inorg. Chem. , 17 : 1729
  • Wrighton , M. , Gray , H. B. and Hammond , G. S. 1973 . Mol. Photochem. , 5 : 165
  • Vanquickenborne , L. G. and Ceulemans , A. 1983 . Coord. Chem. Rev. , 48 : 157
  • Kirk , A. D. , Namasivayam , C. and Ward , T. 1986 . Inorg. Chem. , 25 : 2225 (b) A. D. Kirk and S. R. L. Fernando, Inorg. Chem., 31, 656 (1992).
  • Zink , J. I. 1974 . J. A. Chem. Soc. , 96 : 4464
  • But not exclusvely; such “axial labilization” is often accompanied by “equatorial labilization”.
  • Angermann , K. , van Eldik , R. , Kelm , H. and Wasgestian , F. 1981 . Inorg. Chem. , 20 : 955
  • Friesen , D. A. , Lee , S. H. , Lilie , J. , Waltz , W. L. and Vincze , L. 1975, 1991 . Inorg. Chem. , 30
  • Kirk , A. D. , Moss , K. C. and Valentin , J. G. 1971 . Can. J. Chem. , 48 : 1524
  • Moensted , L. and Moensted , O. 1989 . Coord. Chem. Rev. , 94 : 109
  • Ricceri , P. and Zinato , E. 1981 . Inorg. Chim. Acta , 52 : 133
  • Kirk , A. D. 1971 . J. Am. Chem. Soc. , 93 : 283
  • Kirk , A. D. 1973 . Mol. Photochem. , 5 : 127
  • Kirk , A. D. 1985 . Inorg. Chem. , 24 : 720
  • Wong , C. F. C. and Kirk , A. D. 1976 . Inorg. Chem. , 15 : 1519
  • Unfortunately, for this mode, little stereochemical information is obtainable because of the lack of stereochemical markers and difficulties of product identification.
  • Wong , C. F. C. and Kirk , A. D. 1977 . Inorg. Chem. , 16 : 3148
  • Kirk , A. D. , Frederick , L. A. and Wong , C. F. C. 1979 . Inorg. Chem. , 18 : 448
  • Kirk , A. D. 1979 . Inorg. Chem. , 18 : 2326
  • Kutal , C. and Adamson , A. W. 1973 . Inorg. Chem. , 12 : 1990
  • Kane-Maguire , N. A. P. , Wallace , K. C. and Miller , D. B. 1985 . Inorg. Chem. , 24 : 597
  • Kirk , A. D. and Guedel , H. U. 1992 . Inorg. Chem. , 31
  • Vincze , L. , Friesen , D. A. , Mezyk , S. P. and Waltz , W. L. to be published.
  • Fernando , S. R. L. and Kirk , A. D. work in progress.
  • Kirk , A. D. and Frederick , L. A. 1981 . Inorg. Chem. , 20 : 60
  • Vanquickenborne , L. G. , Coussens , B. , Postelmans , D. , Ceulemans , A. and Pierloot , K. 1992 . Inorg. Chem. , 31 : 539
  • Riccieri , P. and Zinato , E. 1980 . Inorg. Chem. , 19 : 3279
  • Zinato , E. , Riccieri , P. and Prelati , M. 1981 . Inorg. Chem. , 20 : 1432
  • Because of experimental difficulties, small changes might not have been observed.
  • Krause , H. H. and Wasgestian , F. 1981 . Inorg. Chim. Acta , 49 : 231
  • Namasivayam , C. and Kirk , A. D. work in progress.
  • Kirk , A. D. and Ibrahim , A. M. 1988 . Inorg. Chem. , 27 : 4567
  • Cimolino , M. C. and Linck , R. G. 1981 . Inorg. Chem. , 20 : 3499
  • Kirk , A. D. and Heyd , D. 1991 . Inorg. Chem. , 30 : 2453
  • Riccieri , P. , Zinato , E. and Damiani , A. 1987 . Inorg. Chem. , 26 : 2667
  • Ceulemans , A. , Bongaerts , N. and Vanquickenborne , L. G. 1987 . Inorg. Chem. , 26 : 1566
  • The ligand labilization aspect of the VC model appears to be less universally obeyed than the stereochemical change. It has been found that ligand loss can be influenced by steric factors and that competitive loss can occur from the plane of excitation. The bonding factors considered in the model are therefore not the sole influences to be considered in predicting the leaving ligand.
  • Wong , C. F. C. and Kirk , A. D. 1975 . Can. J. Chem. , 53 : 419
  • Riccieri , P. and Zinato , E. 1975 . J. Am. Chem. Soc. , 97 : 6071
  • Rosebush , W. J. and Kirk , A. D. 1976 . Can. J. Chem. , 54 : 2335
  • Gandolfi , M. T. , Manfrin , M. F. , Juris , A. , Moggi , L. and Balzani , V. 1974 . Inorg. Chem. , 13 : 1342
  • Bifano , C. and Linck , R. G. 1974 . Inorg. Chem. , 13 : 609
  • Sandrini , D. , Gandolfi , M. T. , Moggi , L. and Balzani , V. 1978 . J. Am. Chem. Soc. , 100 : 1463
  • Kirk , A. D. and Wong , C. F. C. 1979 . Inorg. Chem. , 18 : 593
  • Wirth , G. and Linck , R. G. 1973 . J. Am. Chem. Soc. , 95 : 5913
  • Pyke , S. C. and Linck , R. G. 1971 . J. Am. Chem. Soc. , 93 : 5281
  • Kirk , A. D. and Porter , G. B. 1980 . Inorg. Chem. , 19 : 445
  • Walters , R. T. and Linck , R. G. 1975 . Inorg. Chem. , 14 : 2098
  • Thompson , M. S. and Sheridan , P. S. 1979 . Inorg. Chem. , 18 : 375
  • Saliby , M. J. , Sheridan , P. S. and Madan , S. K. 1980 . Inorg. Chem. , 19 : 1291
  • Wasgestian , H. F. and Schlaefer , H. L. 1968 . Z. Phys. Chem. (Frankfurt a. M.) , 62 : 127
  • Riccieri , P. and Schlaefer , H. L. 1970 . Inorg. Chem. , 9 : 727
  • Zinato , E. , Lindholm , R. and Adamson , A. W. 1969 . J. Am. Chem. Soc. , 91 : 1076
  • Zinato , E. and Riccieri , P. 1973 . Inorg. Chem. , 12 : 1551
  • Wright , R. E. and Adamson , A. W. 1977 . Inorg. Chem. , 16 : 3360
  • Kirk , A. D. and Kelly , T. L. 1974 . Inorg. Chem. , 13 : 1613

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.