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Original Articles

Molecular dynamics of 4-cyano-3-fluorophenyl 4-butylbenzoate (4CFPB) glass-forming liquid crystal in unidirectional silicon nanopores

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Pages 1073-1079 | Received 14 Jan 2014, Accepted 01 Mar 2014, Published online: 26 Mar 2014

References

  • Aliev FM. Liquid crystals and polymers in pores. In: Zumer GP, Crawford W, editors. Liquid crystals in complex geometries. London: Taylor and Francis; 1996. p. 345–370.
  • Sinha GP, Aliev FM. Dielectric spectroscopy of liquid crystals in smectic, nematic and isotropic phases confined in random porous media. Phys Rev E. 1998;58:2001–2010. doi:10.1103/PhysRevE.58.2001
  • Frunza L, Frunza S, Kosslick H, Schönhals A. Phase behavior and molecular mobility of n-octylcyanobiphenyl confined to molecular sieves: dependence on the pore size. Phys Rev E. 2008;78:51701–517011. doi:10.1103/PhysRevE.78.051701
  • Brás AR, Frunza S, Guerreiro L, Fonseca IM, Corma A, Frunza L, Dionísio M, Schönhals A. Molecular mobility of nematic E7 confined to molecular sieves with a low filling degree. J Chem Phys. 2010;132:224508–224511. doi:10.1063/1.3432775
  • Aliev FM, Nazario Z, Sinha GP. Broadband dielectric spectroscopy of confined liquid crystals. J Non Crystalline Solids. 2002;305:218–225. doi:10.1016/S0022-3093(02)01095-5
  • Kremer F, Schoenhals A. Broadband dielectric spectroscopy. Berlin Heidelberg: Springer-Verlag; 2003. p. 171.
  • Lalowicz Z, Stoch G, Birczyński A, Pinkkihen M, Ylinen EE, Krzystyniak M, Góra-Marek K, Datka Z. Translational and rotational mobility of methanol-d4 molecules in NaX and NaY zeolite cages: a deuteron NMR investigation. J Solid State NMR. 2012;45–46: 66–74.
  • Finotello D, Iannacchione GS, Qian S. Phase transitions in restricted geometries. In: Zumer GP, Crawford W, editors. Liquid crystals in complex geometries. London: Taylor and Francis; 1996. p. 325–344.
  • Sinha G, Leys J, Glorieux C, Thoen J. Dielectric spectroscopy of aerosil-dispersed liquid crystal embedded in anopore membranes. Phys Rev E. 2005;72:51710–51719. doi:10.1103/PhysRevE.72.051710
  • Massalska-Arodź M, Gorbachev VYu, Krawczyk J, Hartmann L, Kremer F. Molecular dynamics of the liquid crystal 6O2OCB in nanopores. J Phys Condens Matter. 2002;14:8435–8443. doi:10.1088/0953-8984/14/36/303
  • Massalska-Arodź M, Krawczyk J, Procyk B, Kremer F. Dielectric relaxation studies of 4-(2-hexyloxyethoxy)4′-cyanobiphenyl (6O2OCB) enclosed in SiO2 nanopores. Phase Transitions. 2007;80:687–695. doi:10.1080/01411590701339989
  • Różański SA, Kremer F, Groothues H, Stannarius R. The dielectric properties of nematic liquid crystal 5CB confined to treated and untreated anopore membranes. Mol Cryst Liq Cryst Sci Technol Sect A Mol Cryst Liq Cryst. 1997;303:319–324. doi:10.1080/10587259708039441
  • Jasiurkowska M, Kossack W, Ene R, Iacob CW, Kipnusu WK, Papadopoulos P, Sangoro JR, Massalska-Arodź M, Kremer F. Molecular dynamics and morphology of confined 4-heptyl-4′-isothiocyanatobiphenyl liquid crystals. Soft Matter. 2012;8:5194–5200. doi:10.1039/c2sm07258k
  • Araki T, Buscaglia M, Bellini T, Tanaka H. Memory and topological frustration in nematic liquid crystals confined in porous materials. Nat Mater. 2011;10:303–309. doi:10.1038/nmat2982
  • Massalska Arodź M, Krawczyk J, Juszyńska E, Kocot A, Inaba A. Molecular dynamics of 4-cyano-3-fluorophenyl 4-butylbenzoate as studied by dielectric relaxation spectroscopy. Acta Phys Polonica A. 2010;117:332–337.
  • Rozwadowski T, Massalska-Arodź M, Krawczyk J, Juszyńska E, Wojnarowska Ż, Paluch M. Dielectric spectroscopy studies of 4-cyano-3-fluorophenyl 4-butylbenzoate liquid crystal at high pressure. Acta Phys Polonica A. 2012;122:378–381.
  • Rozwadowski T, Massalska-Arodź M, Wojnarowska Ż, Paluch M, Juszyńska E, Krawczyk J. Isothermal high pressure studies of 4-cyano-3-fluorophenyl 4-butylbenzoate dynamics near room temperature. Phys Rev E. 2012;86:51702–51707. doi:10.1103/PhysRevE.86.051702
  • Inaba A, Suzuki H, Massalska-Arodź M, Rozwadowski T. Polymorphism and thermodynamic functions of liquid crystalline material 4-cyano-3-fluorophenyl 4-butylbenzoate. J Chem Thermodyn. 2012;54:204–210. doi:10.1016/j.jct.2012.03.031
  • Jasiurkowska-Delaporte M, Juszyńska E, Kolek Ł, Krawczyk J, Massalska-Arodź M, Osiecka N, Rozwadowski T. Signatures of glass transition in partially ordered phases. Liq Cryst. 2013;40:1436–1442. doi:10.1080/02678292.2013.828330
  • Iacob C, Sangoro J, Papadopoulos P, Schubert T, Naumov S, Valiullin R, Kärger J, Kremer F. Charge transport and diffusion of ionic liquids in nanoporous silica membranes. Phys Chem Chem Phys. 2010;12:13798–13803. doi:10.1039/c004546b
  • Kipnusu WK, Kossack W, Iacob C, Jasiurkowska M, Sangoro JR, Kremer F. Molecular order and dynamics of tris(2-ethylhexyl)phosphate confined in uni-directional nanopores. Zeitschrift für Physikalische Chemie. 2012;226:797–805. doi:10.1524/zpch.2012.0287
  • Havriliak S, Negami S. A complex plane representation of dielectric and mechanical relaxation processes in some polymers. Polymer. 1967;8:161–210. doi:10.1016/0032-3861(67)90021-3
  • Böhmer R, Ngai KL, Angell CA, Plazek DL. Non-exponential relaxations in strong and fragile glass formers. J Chem Phys. 1993;99:4201–4209. doi:10.1063/1.466117
  • Massalska-Arodź M, Nakamoto T, Wasiutyński T, Mayer J, Krawczyk J, Sorai M. Thermal and relaxational properties of glass-forming material, 3,3-dimethyl-1-butanol. J Chem Thermodyn. 2004;36:877–888. doi:10.1016/j.jct.2004.06.007
  • Arndt M, Stannarius S, Gorbatschow W, Kremer F. Dielectric investigations of the dynamic glass transition in nanopores. Phys Rev Let. 1996;54:5377–5390.
  • Kremer F, Huwe A, Arndt M, Behrens P, Schwieger W. How many molecules form liquid? J Phys Condens Matter. 1999;11:A175–A188.
  • Huwe A, Kremer F, Behrens P, Schwieger W. Molecular dynamics in confining space: from the single molecule to the liquid state. Phys Rev Lett. 1999;82:2338–2341. doi:10.1103/PhysRevLett.82.2338
  • Fatkullin N, Kausik R, Kimmich R. Cooperative polymer dynamics under nanoscopic pore confinements probed by field-cycling NMR relaxometry. J Chem Phys. 2007;126:94904–94908. doi:10.1063/1.2646367
  • Almarza NG, Enciso E, Bermejo FJ. Monte Carlo simulation of liquid n-alkanes. I. Intramolecular structure and thermodynamics. J Chem Phys. 1992;96:4625–4632. doi:10.1063/1.462798
  • Williams G, Watts DC. Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function. Trans Faraday Soc. 1970;66:80–85. doi:10.1039/tf9706600080

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