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Research Article

Spontaneous polarisation due to flexoelectric effect in liquid crystalline elastomers prepared by cross-linking under splay distortion

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Pages 2051-2057 | Received 04 Jun 2022, Accepted 26 Jun 2022, Published online: 11 Jul 2022

References

  • Finkelmann H, Kock HJ, Rehage G. Liquid crystalline elastomers – a new type of liquid crystalline material. Makromol Chem, Rapid Commun. 1981;2:317–322.
  • Zentel R. Liquid crystalline elastomers. Angew Chem Adv Mater. 1989;101(10):1437–1445. and references therein. doi:10.1002/ange.19891011041.
  • Brand HR, Finkelmann H, Goodby J, et al. Physical properties of liquid crystalline elastomers. In: Demus D, editor. Handbook of liquid crystals. Vol. 3. Weinheim: Wiley-VCH; 1989. p. 277–302.
  • Warner M, Terentjev EM. Liquid crystal elastomers. Revised ed. Oxford:Clarendon Press; 2007. p. 1–46.
  • De Gennes PG. Un muscle artificiel semi-rapide. C R Acad Sci Paris. 1997;324(Série IIb):343–348.
  • Neufeld RAE, Shahsavan H, Zhao BX, et al. Simulation-Based design of thermally-driven actuators using liquid crystal elastomers. Liq Cryst. 2018;45:1010–1022.
  • Skačej G. Elastocaloric effect in liquid crystal elastomers from molecular simulations. Liq Cryst. 2018;45:1964–1969.
  • Ube T, Yoda T, Ikeda T. Fabrication of photomobile polymer materials with phase-separated structure of crosslinked azobenzene liquid-crystalline polymer and poly(dimethylsiloxane). Liq Cryst. 2018;45:2269–2273.
  • Braun LB, Zentel R. Functional liquid crystalline particles and beyond. Liq Cryst. 2019;46:2023–2041.
  • Lehmann W, Skulpin H, Tolksdorf C, et al. Giant lateral electrostriction in ferroelectric liquid-crystalline elastomers. Nature. 2001;410:447–450.
  • Köhler R, Stannarius R, Tolksdorf C, et al. Electroclinic effect in free-standing smectic elastomer films. Appl Phys A. 2005;80:381–388.
  • Spillmann CM, Ratna BR, Naciri J. Anisotropic actuation in electroclinic liquid crystal elastomers. Appl Phys Lett. 2007;90:021911.
  • Spillmann CM, Kapur AV, Bentrem FW, et al. Critical field strength in an electroclinic liquid crystal elastomer. Phys Rev Lett. 2010;104:227802.
  • Eckert T, Finkelmann H. Piezoelectricity of mechanically oriented Sc*-elastomers. Macromol Rapid Commun. 1996;17:767–773.
  • Adams JM, Warner M, Stenull O, et al. Smectic-A elastomers with weak director anchoring. Phys Rev E. 2008;78:011703.
  • Hiraoka K, Stein P, Finkelmann H. Electromechanics of a chiral smectic C elastomer: measurement of complex piezoelectric constant through successive phase transformation. Macromol Chem Phys. 2004;205:48–54.
  • Hiraoka K, Kobayashi M, Kazama R, et al. Electromechanics of monodomain chiral smectic C elastomer: mechanical response to electric stimulation. Macromolecules. 2009;42:5600–5604.
  • Hiraoka K, Kishimoto T, Kato M, et al. Electroclinic and electromechanical effects of a side-chain chiral smectic a elastomer. Liq Cryst. 2011;38:489–493.
  • Meyer RB. Piezoelectric effects in liquid crystals. Phys Rev Lett. 1969;22:918–921.
  • De Gennes PG, Prost J. The physics of liquid crystals. 2nd. Oxford:Oxford Science Publications;1993. p. 135–139.
  • Patel JS, Meyer RB. Flexoelectric electro-optics of a cholesteric liquid crystal. Phys Rev Lett. 1987;58:1538–1540.
  • Rudquist P, Komitov L, Lagerwall ST. Linear electro-optic effect in a cholesteric liquid crystal. Phys Rev E. 1994;50:4735–4743.
  • Popova EV, Kopeychenko EI, Krivoshey VV, et al. Piezoelectric and flexoelectric effects in ferroelectric liquid crystals. Phys Rev E. 2012;86:031705.
  • Meyer C, Luckhurst GR, Dozov I. Flexoelectrically driven electroclinic effect in the twist-bend nematic phase of achiral molecules with bent shapes. Phys Rev Lett. 2013;111:067801.
  • Sreenilayam S, Panarin Y, Vij JK, et al. Flexoelectric polarisation studies in bent-core nematic liquid crystals. Phys Rev E. 2015;92:022502.
  • Harden J, Chambers M, Verduzco R, et al. Giant flexoelectricity in bent-core nematic liquid crystal elastomers. Appl Phys Lett. 2010;96:102907.
  • Hiraoka K, Kashimura H, Tanaka S, et al. Electric-Field-Induced deformation of chiral smectic a liquid-crystalline elastomers composed of cholesterol derivative mesogens. Mol Cryst Liq Cryst. 2017;646:168–175.
  • Hiraoka K, Taira S, Hoshino Y, et al. Electric-Field-Induced deformation caused by electroclinic and flexoelectric effects in liquid-crystalline elastomer with wedge-shaped mesogens derived from cholesterol. Liq Cryst. 2021;47:1535–1545.
  • Mitchell GR, Windle AH. Orientation in liquid crystal polymers. In: Bassett D, editor. Developments in crystalline polymers-2, chapter 3. Essex: Elsevier Applied Science; 1988.
  • Rössle M, Braun L, Schollmeyer D, et al. Differences between smectic homo- and co-polysiloxanes as a consequence of microphase separation. Liq Cryst. 2005;32:533–538.
  • Frisch MJ, Trucks GW, Schlegel HB, et al. Gaussian 16, revision B.01. Wallingford CT: Gaussian Inc.; 2016.

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