134
Views
0
CrossRef citations to date
0
Altmetric
Research Article

Exploring the nematic to twist-bend nematic phase transition: calorimetric and optical measurements

, , , , &
Received 28 Feb 2024, Accepted 02 May 2024, Published online: 16 May 2024

References

  • Chandrasekhar S. Cambridge University Press, Cambridge, second edition, chapter 1. Liq Cryst. 1992:8–10. doi: 10.1017/CBO9780511622496
  • Das B, Grande S, Weissflog W, et al. Structural and conformational investigations in SmA and different SmC phases of new hockey stick-shaped compounds. Liq Cryst. 2003;30(5):529–539. doi: 10.1080/0267829031000090832
  • Cometti G, Dalcanale E, Du Vosel A, et al. New bowl-shaped columnar liquid crystals. J Chem Soc, Chem Commun. 1990;(2):163–165. doi: 10.1039/C39900000163
  • Niori T, Sekine T, Watanabe J, et al. Distinct ferroelectric smectic liquid crystals consisting of banana shaped achiral molecules. J Mater Chem. 1996;6(7):1231–1233. doi: 10.1039/JM9960601231
  • Madsen LA, Dingemans TJ, Nakata M, et al. Thermotropic biaxial nematic liquid crystals. Phys Rev Lett. 2004;92(14):145505. doi: 10.1103/PhysRevLett.92.145505
  • Acharya BR, Primak A, Kumar S. Biaxial nematic phase in bent-core thermotropic mesogens. Phys Rev Lett. 2004;92(14):145506. doi: 10.1103/PhysRevLett.92.145506
  • Kim YK, Cukrov G, Vita F, et al. Search for microscopic and macroscopic biaxiality in the cybotactic nematic phase of new oxadiazole bent-core mesogens. Phys Rev E. 2016;93(6):062701. doi: 10.1103/PhysRevE.93.062701
  • Vaupotič N, Szydlowska J, Salamonczyk M, et al. Structure studies of the nematic phase formed by bent-core molecules. Phys Rev E. 2009;80(3):030701(R). doi: 10.1103/PhysRevE.80.030701
  • Vorländer D. Über die Natur der Kohlenstoffketten in kristallin-flüssigen Substanzen [On the nature of carbon chains in crystalline liquid substances]. Z Phys Chem. 1927;126U(1):449–472. German. doi: 10.1515/zpch-1927-12629
  • Imrie CT. Liquid crystal dimers. In: Mingos DMP, editor. Liquid crystals II. Structure and bonding. Vol. 95. Berlin, Heidelberg: Springer; 1999. p. 149–192. doi: 10.1007/3-540-68118-3_4
  • Panov VP, Nagaraj M, Vij JK, et al. Spontaneous periodic deformations in nonchiral planar-aligned bimesogens with a Nematic-Nematic Transition and a negative elastic constant. Phys Rev Lett. 2010;105(16):167801. doi: 10.1103/PhysRevLett.105.167801
  • Barnes PJ, Douglass AG, Heeks SK, et al. An enhanced odd-even effect of liquid crystal dimers orientational order in the α,ω-bis(4′-cyanobiphenyl-4-yl)alkanes. Liq Cryst. 1993;13(4):603–613. doi: 10.1080/02678299308026332
  • Panov VP, Balachandran R, Nagaraj M, et al. Microsecond linear optical response in the second nematic phase of achiral bimesogens. Appl Phys Lett. 2011;99(26):261903. doi: 10.1063/1.3671996
  • Panov VP, Balachandran R, Vij JK, et al. Field-induced periodic chiral pattern in the Nx phase of achiral bimesogens. Appl Phys Lett. 2012;101(23):234106. doi: 10.1063/1.4769458
  • Borshch V, Kim YK, Xiang J, et al. Nematic twist-bend phase with nanoscale modulation of molecular orientation. Nat Commun. 2013;4(1):2635–2643. doi: 10.1038/ncomms3635
  • Chen D, Porada JH, Hooper JB, et al. Chiral heliconical ground state of nanoscale pitch in a nematic liquid crystal of achiral molecular dimmers. Proc Natl Acad Sci. USA. 2013;110(40):15931–15936. doi: 10.1073/pnas.1314654110
  • Cestari M, Diez-Berart S, Dunmur DA, et al. Phase behavior and properties of the liquid-crystal dimer 1′′,7′′-bis(4-cyanobiphenyl-4′-yl) heptane: a twist-bend nematic liquid crystal. Phys Rev E. 2011;84(3):031704. doi: 10.1103/PhysRevE.84.031704
  • Meyer RB. Structural problems in liquid crystal physics. Proceedings of the Les Houches Summer School in theoretical physics, 1973. In: Balian R Weil G, editors. Molecular fluids. New York: Gordon and Breach; 1976. p. 271–343.
  • Dozov I. On the spontaneous symmetry breaking in the mesophases of achiral banana-shaped molecules. Europhys Lett. 2001;56(2):247–253. doi: 10.1209/epl/i2001-00513-x
  • Pociecha D, Crawford CA, Paterson DA, et al. Critical behavior of the optical birefringence at the nematic to twist-bend nematic phase transition. Phys Rev E. 2018;98(5):052706. doi: 10.1103/PhysRevE.98.052706
  • Shamid SM, Dhakal S, Selinger JV. Statistical mechanics of bend flexoelectricity and the twist-bend phase in bent-core liquid crystals. Phys Rev E. 2013;87(5):052503. doi: 10.1103/PhysRevE.87.052503
  • Memmer R. Liquid crystal phases of achiral banana-shaped molecules: a computer simulation study. Liq Cryst. 2002;29(4):483–496. doi: 10.1080/02678290110104586
  • Robles-Hernandez B, Sebastian N, de la Fuente MR, et al. Twist, tilt, and orientational order at the nematic to twist-bend nematic phase transition of 1″,9″-bis(4-cyanobiphenyl-4′-yl) nonane: a dielectric, H 2 NMR, and calorimetric study. Phys Rev E. 2015;92(6):062505. doi: 10.1103/PhysRevE.92.062505
  • Chakraborty A, Chakraborty S, Das MK. Effect of hockey-stick-shaped molecules on the critical behavior at the nematic to isotropic and smectic-A to nematic phase transitions in octylcyanobiphenyl. Phys Rev E. 2015;91(3):032503. doi: 10.1103/PhysRevE.00.002500
  • Das MK, Chakraborty S, Dabrowski R, et al. Birefringence in the vicinity of the smectic-A to smectic-C phase transition: crossover from XY critical to tricritical behavior. Phys Rev E. 2017;95(1):012705. doi: 10.1103/PhysRevE.95.012705
  • Mitra S, Chakraborty A, Das MK. Calorimetric study of critical behavior near the smectic-A to nematic phase transition in a polar-polar binary system. Phase Trans. 2020;93(10–11):1006–1015. doi: 10.1080/01411594.2020.1832226
  • Chakraborty S, Chakraborty A, Das MK, et al. Effect of hockey-shaped mesogen as an additive on the critical behavior at the smectic-A to nematic phase transition. J Mol Liq. 2016;219:608–613. doi: 10.1016/j.molliq.2016.04.002
  • Sied MB, Salud J, Lopez DO, et al. Binary mixtures of nCB and nOCB liquid crystals. Two experimental evidences for a smectic A–nematic tricritical point. Phys Chem Chem Phys. 2002;4(12):2587–2593. doi: 10.1039/b111485a
  • Cusmin P, de la Fuente MR, Salud J, et al. Critical behavior and scaling relationships at the SmAd−N and N−I transitions in Nonyloxycyanobiphenyl (9OCB). J Phys Chem B. 2007;111(30):8974–8984. doi: 10.1021/jp070689v
  • Perez-Jubindo MA, de la Fuente MR, Diez-Berart S, et al. Influence of cylindrical submicrometer confinement on the static and dynamic properties in Nonyloxycyanobiphenyl (9OCB). J Phys Chem B. 2008;112(21):6567–6577. doi: 10.1021/jp800119s
  • Prasad A, Das MK. Optical birefringence studies of a binary mixture with the nematic-smectic Ad-re-entrant nematic phase sequence. J Phys Condens Matter. 2010;22(19):195106. doi: 10.1088/0953-8984/22/19/195106
  • Challa PK, Borshch V, Parri O, et al. Twist-bend nematic liquid crystals in high magnetic fields. Phys Rev E. 2014;89(6):060501(R. doi: 10.1103/PhysRevE.89.060501
  • Parthasarathi S, Rao DSS, Palakurthy NB, et al. Binary system exhibiting the nematic to twist-bend nematic transition: behavior of permittivity and elastic constants. J Phys Chem B. 2016;120(22):5056–5062. doi: 10.1021/acs.jpcb.6b03048
  • Sebastian N, de la Fuente M R, Lopez DO, et al. Dielectric and thermodynamic study on the liquid crystal dimer α-(4-cyanobiphenyl-4′-oxy)-ω-(1-pyreniminebenzylidene-4′-oxy) undecane (CBO11O∙Py). J Phys Chem B. 2011;115(32):9766–9775. doi: 10.1021/jp202796y
  • Lopez DO, Robles-Hernandez B, Salud J, et al. Miscibility studies of two twist-bend nematic liquid crystal dimers with different average molecular curvatures. A comparison between experimental data and predictions of a landau mean-field theory for the NTB-N phase transition. Phys Chem Chem Phys. 2016;18(6):4394–4404. doi: 10.1039/C5CP07605F
  • Anisimov MA, Voronov VP, Kulkov AO, et al. High-resolution adiabatic calorimetry measurements in the vicinity of the liquid crystal phase transitions. Mol Cryst Liq Cryst. 1987;150(1):399–418. doi: 10.1080/00268948708074812
  • Meyer C, Luckhurst GR, Dozov I. The temperature dependence of the heliconical tilt angle in the twist-bend nematic phase of the odd dimer CB7CB. J Mater Chem C. 2015;3(2):318–328. doi: 10.1039/C4TC01927J
  • Sebastian N, Tamba MG, Stannarious R, et al. Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic–nematic transition. Phys Chem Chem Phys. 2016;18(28):19299–19308. doi: 10.1039/C6CP03899A
  • Haller I. Thermodynamic and static properties of liquid crystals. Prog Solid State Chem. 1975;10:103–118. doi: 10.1016/0079-6786(75)90008-4
  • Sreenilayam SP, Panov VP, Vij JK, et al. The NTB phase in an achiral asymmetrical bent-core liquid crystal terminated with symmetric alkyl chains. Liq Cryst. 2016:1–10. doi: 10.1080/02678292.2016.1253878
  • Meyer C, Luckhurst GR, Dozov I. Flexoelectrically driven electroclinic effect in the twist-bend nematic phase of achiral molecules with bent shapes. Phys Rev Lett. 2013;111(6):067801. doi: 10.1103/PhysRevLett.111.067801
  • Virga EG. Double-well elastic theory for twist-bend nematic phases. Phys Rev E. 2014;89(5):052502. doi: 10.1103/PhysRevE.89.052502
  • Kats EI, Lebedev VV. Landau theory for helical nematic phases. JETP Lett. 2014;100(2):110–113. doi: 10.1134/S0021364014140070
  • Cestari M, Frezza E, Ferrarini A, et al. Crucial role of molecular curvature for the bend elastic and flexoelectric properties of liquid crystals: mesogenic dimers as a case study. J Mater Chem. 2011;21(33):12303–12308. doi: 10.1039/C1JM12233A
  • Paterson DA, Gao M, Kim YK, et al. Understanding the twist-bend nematic phase: the characterisation of 1-(4-cyanobiphenyl-4′-yloxy)-6-(4-cyanobiphenyl-4′-yl)hexane (CB6OCB) and comparison with CB7CB. Soft Matter. 2016;12(32):6827–6840. doi: 10.1039/c6sm00537c
  • Tripathi CSP, Losada-Perez P, Glorieux C, et al. Nematic-nematic phase transition in the liquid crystal dimer CBC9CB and its mixtures with 5CB: a high-resolution adiabatic scanning calorimetric study. Phys Rev E. 2011;84(4):041707. doi: 10.1103/PhysRevE.84.041707

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.