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Original Articles

Mesomorphic properties of orthopalladated complexes of laterally substituted azobenzene derivatives, 2-alkoxycarbonyl-4-(4-ethoxyphenylazo)phenyl 4-methoxybenzoates

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Pages 267-276 | Received 05 Jun 1990, Accepted 15 Sep 1990, Published online: 24 Sep 2006

References

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  • Adams , H. , Bailey , N. A. , Bruce , D. W. , Dhillon , R. , Dunmur , D. A. , Hunt , S. E. , Lalinde , E. , Maggs , A. A. , Orr , R. , Styring , P. , Wragg , M. S. and Maitlis , P. M. 1989 . Polyhedron , 7 : 1861
  • Ghedini , M. , Longeri , M. and Bartolino , R. 1982 . Molec. Crystals liq. Crystals , 84 : 207 For synthetic work with azobenzene derivatives: (a)
  • Ghedini , M. , Licoccia , S. , Armentano , S. and Bartolino , R. 1984 . Molec. Crystals liq. Crystals , 108 : 269 With Schiff base derivatives:
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  • Small satellite peaks are observed for these protons but not for the three protons attached to the central ring in L, and they continue to appear up to the highest measured temperature of 50[ddot] C.
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  • Solubility of the crude solid of lower complex homologues, n = 4, 2 and 1, in dichloromethane was very low, the last one being practically insoluble. Purification could not be completed in this case but a precipitate obtained by cooling its solution in 1:1 DMF:ethanol, gave a sufficiently definable melting point.

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