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Original Article

Determination and Control of Pesticide Residues in Beverages: A Review of Extraction Techniques, Chromatography, and Rapid Detection Methods

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References

  • China State Bureau of Quality and Technical Supervision. (2007) National Standard of the People's Republic of China. General Standard for Beverage. GB 10789–2007.
  • U.S. Department of Agriculture. (2005) . Codes General Standard for Fruit Juices and Nectars. CODEX STAN 247–2005.
  • Tadeo, J.L., Sanchez-Brunete, C., and Albero, B. (2004) Analysis of pesticide residues in juice and beverages. Crit. Rev. Anal. Chem., 34: 165–175.
  • Martínez Vidal, J.L., Plaza-Bolaños, P., Romero-González, R., and Garrido Frenich, A. (2009) Determination of pesticide transformation products: A review of extraction and detection methods. J. Chromatogr. A., 1216: 6767–6788.
  • Nougadère, A., Sirot, V., Kadar, A., Truchot, E., Vergnet, C., Hommet, F., Baylé, J., Gros,P., and Leblanc, J.C. (2012) Total diet study on pesticide residues in France: Levels in food as consumed and chronic dietary risk to consumers. Environ. Int., 45: 135–150.
  • Du, J., Yan, H., She, D., Liu, B., and Yang, G. (2010) Simultaneous determination of cypermethrin and permethrin in pear juice by ultrasound-assisted dispersive liquid–liquid microextraction combined with gas chromatography. Talanta, 82: 698–703.
  • Fernandes, V.C., Domingues, V.F., Mateus, N., Delerue-Matos, C., and Mateus, N. (2011) Determination of pesticides in fruit and fruit juices by chromatographic methods. An overview. J. Chromatogr. Sci., 49: 715–730.
  • U.S. Department of Agriculture. (2012) FAO/WHO Food Standards - Pesticide Residues in Food and Feed Codex Pesticides Residues. Codex Alimentarius Commission. Available at: http://www.codexalimentarius.org/standards/pesticide-mrls/en/
  • U.S. Department of Agriculture. (2009) Food Code. U.S. Public Health Service. Available at: http://www.usda.gov
  • European Communities. (2008) Commission Regulation 149/2008/EC. Off. J. Eur. Commun., L 58: 1–398.
  • European Communities. (2006) Commission Directive 2006/125/EC. Off. J. Eur. Commun., L 339: 16–35.
  • Tekel, J., Hudecová, T., and Pecníková, K. (2001) Isolation and purification techniques for pesticide residue analyses in samples of plant or animal origin. Eur. Food Res. Technol., 213: 250–258.
  • Pylypiw, H.M., Jr. (1993) Rapid gas chromatographic method for the multiresidue screening of fruits and vegetables for organochlorine and organophosphate pesticides. J. AOAC, 76: 1369–1373.
  • Aguera, A., Contreras, M., and Fernandez Alba, A.R. (1993) Gas chromatographic analysis of organophosphorus pesticides of horticultural concern. J. Chromatogr. A, 665: 293–300.
  • U.S. Environmental Protection Agency. (2009) Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events, Revision 5.0. U.S. Environmental Protection Agency: Cincinnati, OH.
  • Lehotay, S. (1997) Supercritical fluid extraction of pesticides in foods. J. Chromatogr. A, 785: 289–312.
  • Bowadt, S. and Hawthorne, S.B. (1995) Supercritical fluid extraction in environmental analysis. J. Chromatogr. A, 703: 49–571.
  • Letellier, M., and Budzinski, H. (1999) Microwave assisted extraction of organic compounds. Analusis, 27: 259–271.
  • Tadeo, J.L., Sánchez-Brunete, C., Albero, B., and Garcia-Valcárcel, A. (2010) Application of ultrasound-assisted extraction to the determination of contaminants in food and soil samples. J. Chromatogr. A, 1217: 2415–2440.
  • Jia, C., Zhu, X., Chen, L., He, M., Yu, P., and Zhao, E. (2010) Extraction of organophosphorus pesticides in water and juice using ultrasound-assisted emulsification–microextraction. J. Sep. Sci., 33: 244–250.
  • Sachse, J. (1977) On the determination of chlorocholine chloride (CCC) in cereals. Z. Lebensm. Unters. Forsch., 163: 274–277.
  • Vahl, M., Graven, A., and Juhler, R.K. (1998) Analysis of Chlormequat residues in grain using liquid chromatography–mass spectrometry (LC-MS/MS). J. Anal. Chem., 361: 817–820.
  • Ahmed, F.E. (2001) Analyses of pesticides and their metabolites in foods and drinks. TrAC, Trends Anal. Chem., 20: 649–661.
  • Cserháti, T., Forgács, E., Deyl, Z., Miksik, I., and Eckhardt, A. (2004) Chromatographic determination of herbicide residues in various matrices. Biomed. Chromatogr., 18: 350–359.
  • Andruch, V., Balogh, I.S., Koc´rová, L., and Šandrejová, J. (2013) Five years of dispersive liquid–liquid microextraction. Appl. Spectrosc. Rev., 48: 161–259.
  • Lehotay, S.J. (1997) Supercritical fluid extraction of pesticides in foods. J. Chromatogr. A, 785: 289–312.
  • Pihlström, T., and Österdahl, B.G. (1999) Analysis of pesticide residues in fruit and vegetables after cleanup with solid phase microextraction using ENV+ (polystyrene–divinylbenzene) cartridges. J. Agric. Food Chem., 47: 2549–2552.
  • Picó, Y., Fernández, M., Ruiz, M.J., and Font, G. (2007) Current trends in solid-phase-based extraction techniques for the determination of pesticides in food and environment. J. Biochem. Biophys. Methods, 70: 117–131.
  • Ravelo-Pérez, L.M., Hernández-Borges, J., and Rodríguez-Delgado, M.Á. (2008) Multi-walled carbon nanotubes as efficient solid-phase extraction materials of organophosphorus pesticides from apple, grape, orange and pineapple fruit juices. J. Chromatogr. A, 1211: 33–42.
  • Ibrahim, W.A.W., Veloo, K.V., and Sanagi, M.M. (2012) Novel sol-gel hybrid methyl–trimethoxysilane–tetraethoxysilane as solid phase extraction sorbent for organophosphorus pesticides. J. Chromatogr. A, 1229: 55–62.
  • Tadeo, J.L., and Sanchez-Brunete, C. (2003) Analysis of pesticide residues in fruit juices by matrix–solid phase dispersion and gas chromatographic determination. Chromatographia, 57: 793–798.
  • Albero, B., Sánchez-Brunete, C., and Tadeo, J.L. (2003) Determination of organophosphorus pesticides in fruit juices by matrix solid-phase dispersion and gas chromatography. J. Agric. Food Chem., 51: 6915–6921.
  • Chua, X.-G., Hub, X.-Z., and Yao, H.-Y. (2005) Determination of 266 pesticide residues in apple juice by matrix solid-phase dispersion and gas chromatography–mass selective detection. J. Chromatogr. A, 1063: 201–210.
  • Arthur, C.L., and Pawliszyn, J. (1990) Solid phase microextraction with thermal desorption using fused silica optical fibers. Anal Chem., 62: 2145–2150.
  • Somenath, M. (2003) Sample Preparation Techniques in Analytical Chemistry. John Wiley & Sons.
  • Heaven, M.W., and Nash, D. (2012) Recent analyses using solid phase microextraction in industries related to food made into or from liquids. Food Control, 27: 214–227.
  • Beltran, J., López, F.J., and Hernández, F. (2000) Solid-phase microextraction in pesticide residue analysis. J. Chromatogr. A, 885: 389–404.
  • Wu, J., Tragas, Ch., Lord, H., and Pawliszyn, J. (2002) Analysis of polar pesticides in water and wine samples by automated in-tube solid-phase microextraction coupled with high-performance liquid chromatography–mass spectrometry. J. Chromatogr. A, 976: 357–367.
  • Zhang, K., Wong, J.W., Hayward, D.G. (2009) Multiresidue pesticide analysis of wines by dispersive solid-phase extraction and ultrahigh-performance liquid chromatography–tandem mass spectrometry. J. Agric. Food Chem., 57: 4019–4029.
  • Berrada, H., Font, G., and Moltó, J.C. (2004) Application of solid-phase microextraction for determining phenylurea herbicides and their homologous anilines from vegetables. J. Chromatogr. A, 1042: 9–14.
  • Natangelo, M., Tavazzi, S., and Benfenari, E. (2002) Evaluation of solid phase microextraction–gas chromatography in the analysis of some pesticides with different mass spectrometric techniques: Application to environmental waters and food samples. Anal. Lett., 35: 327–338.
  • Magdic, S., Boyd-Boland, A., Jinno, K., and Pawliszyn, J. (1996) Analysis of organophosphorus insecticides from environmental samples using solid-phase microextraction. J. Chromatogr. A, 736: 219–228.
  • Sng, M.T., Lee, F.K., and Lasko, H.A. (1997) Solid-phase microextraction of organophosphorus pesticides from water. J. Chromatogr. A, 759: 225–230.
  • Yu, J., Wu, C., and Xing, J. (2004) Development of new solid-phase microextraction fibers by sol-gel technology for the determination of organophosphorus pesticide multiresidues in food. J. Chromatogr. A, 1036: 101–111.
  • Zhang, Z., and Pawliszyn, J. (1993) Headspace solid-phase microextraction. Anal. Chem., 65 (14): 1843–1852.
  • Lambropoulou, D.A., and Albanis, T.A. (2002) Headspace solid phase microextraction applied to the analysis of organophosphorus insecticides in strawberry and cherry juices. J. Agric. Food Chem., 50: 3359–3365.
  • Psillakis, E., and Kalogerakis, N. (2001) Solid-phase microextraction versus single-drop microextraction for the analysis of nitroaromatic explosives in water samples. J. Chromatogr. A, 938: 113–120.
  • Palit, M., Pardasani, D., Gupta, A.K., and Dubey, D.K. (2005) Application of single drop microextraction for analysis of chemical warfare agents and related compounds in water by gas chromatography/mass spectrometry. Anal. Chem., 77: 711–717.
  • Anastassiades, M., Lehotay, S.J., and Stajnbaher, D. (2003) Fast and easy multiresidue method employing acetonitrile extraction/partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce. J. AOAO. Int., 86: 412–431.
  • Alcudia-León, M.C., Lucena, R., Cárdenas, S., and Valcárcel, M. (2009) Dispersive solid phase extraction for in-sorbent surface attenuated total reflection infrared detection. Anal. Chem., 81: 1184–1190.
  • Zhang, J. and Lee, H.K. (2006) Application of liquid-phase microextraction and on-column derivatization combined with gas chromatography–mass spectrometry to the determination of carbamate pesticides. J. Chromatogr. A, 1117: 31–37.
  • Barahona, F., Gjelstad, A., Pedersen-Bjergaard, S., and Rasmussen, K.E. (2010) Hollow fiber–liquid-phase microextraction of fungicides from orange juices. J. Chromatogr. A, 1217: 1989–1994.
  • Rezaee, M., Assadi, Y., Milani Hosseini, M.-R., Aghaee, E., Ahmadi, F., and Berijani, S. (2006) Determination of organic compounds in water using dispersive liquid–liquid microextraction. J. Chromatogr. A, 1116: 1–9.
  • Berijani, S., Assadi, Y., Anbia, M., Hosseini, M.M., and Aghaee, E. (2006) Dispersive liquid–liquid microextraction combined with gas chromatography–flame photometric detection: Very simple, rapid and sensitive method for the determination of organophosphorus pesticides in water. J. Chromatogr. A, 1123: 1–9.
  • Wang, S., Xiang, B., and Tang, Q. (2012) Trace determination of dichlorvos in environmental samples by room temperature ionic liquid–based dispersive liquid-phase microextraction combined with HPLC. J. Chromatogr. Sci., 50: 702–708.
  • Bidari, A., Ganjali, M.R., Norouzi, P., Hosseini, M.R., and Assadi, Y. (2011) Sample preparation method for the analysis of some organophosphorus pesticides residues in tomato by ultrasound-assisted solvent extraction followed by dispersive liquid–liquid microextraction. Food Chem., 126: 1840–1844.
  • Fattahi, N., Samadi, S., Assadi, Y., and Hosseini, M.R. (2007) Solid-phase extraction combined with dispersive liquid–liquid microextraction-ultra preconcentration of chlorophenols in aqueous samples. J. Chromatogr. A, 1169: 63–69.
  • Jeannot, M.A., and Cantwell, F.F. (1996) Solvent microextraction into a single drop. Anal. Chem., 68: 2236–2240.
  • Viñas, P., Martinez-Castillo, N., Campillo, N., and Hernández-Córdoba, M. (2010) Liquid–liquid microextraction methods based on ultrasound-assisted emulsification and single-drop coupled to gas chromatography–mass spectrometry for determining strobilurin and oxazole fungicides in juices and fruits. J. Chromatogr. A, 1217: 6569–6577.
  • Psillakis, E., and Kalogerakis, N. (2002) Developments in single-drop microextraction. TrAC, Trends Anal. Chem., 21: 54–64.
  • Farajzadeh, M.A., Djozan, D., and Khorram, P. (2011) Development of a new microextraction method based on a dynamic single drop in a narrow-bore tube: Application in extraction and preconcentration of some organic pollutants in well water and grape juice samples. Talanta, 85: 1135–1142.
  • Patel, K., Mehta, P., Sahoo, U., Sen, A., and Dhanya, B. (2010) A single drop micro extraction and future trends. Int. J. ChemTech Res., 2: 1638–1652.
  • Xu, L., Basheer, C., and Lee, H.K. (2007) Developments in single-drop microextraction. J. Chromatogr. A, 1152: 184–192.
  • Baltussen, E., Sandra, P., and David, F. (1999) Stir bar sorptive extraction (SBSE), a novel extraction technique for aqueous samples: Theory and principles. J. Microcolumn Separations, 1110: 737–747.
  • Sandra, P., Tienpont, B., and David, F. (2003) Multi-residue screening of pesticides in vegetables, fruits and baby food by stir bar sorptive extraction–thermal desorption–capillary gas chromatography–mass spectrometry. J. Chromatogr. A, 1000: 299–309.
  • Blasco, C., Fernández, M., Picó, Y., and Font, G. (2004) Comparison of solid-phase microextraction and stir bar sorptive extraction for determining six organophosphorus insecticides in honey by liquid chromatography–mass spectrometry. J. Chromatogr. A, 1030: 77–85.
  • Kawaguchi, M., Inoue, K., Yoshimura, M., Ito, R., Sakui, N., Okanouchi, N., and Nakazawa, H. (2006) Determination of bisphenol A in river water and body fluid samples by stir bar sorptive extraction with in situ derivatization and thermal desorption–gas chromatography–mass spectrometry. J. Chromatogr. A, 805: 41–48.
  • Barletta, J.Y., de Lima Gomes, P.C., and dos Santos-Neto, A,J. (2011) Development of a new stir bar sorptive extraction coating and its application for the determination of six pesticides in sugarcane juice. J. Sep. Sci., 34: 1317–1325.
  • Ochiai, N., Sasamoto, K., Kanda, H., Yamagami, T., David, F., Tienpont, B., and Sandra, P. (2005) Optimization of a multi-residue screening method for the determination of 85 pesticides in selected food matrices by stir bar sorptive extraction and thermal desorption GC-MS. J. Sep. Sci., 28: 1083–1092.
  • Hauser, B., and Popp, P. (2001) Membrane-assisted solvent extraction of organochlorine compounds in combination with large-volume injection/gas chromatography–electron capture detection. J. Sep. Sci., 24: 551.
  • Viñas, P., Aguinaga, N., Campillo, N., and Hernández-Córdoba, M. (2008) Comparison of stir bar sorptive extraction and membrane-assisted solvent extraction for the ultra-performance liquid chromatographic determination of oxazole fungicide residues in wines and juices. J. Chromatogr. A, 1194: 178–183.
  • Cheng, J., Xia, Y., Zhou, Y., Guo, F., and Chen, G. (2011) Application of an ultrasound-assisted surfactant-enhanced emulsification microextraction method for the analysis of diethofencarb and pyrimethanil fungicides in water and fruit juice samples. Anal. Chim. Acta, 701: 86–91.
  • Wu, J., Xiang, B., and Xia, J. (2009) Application of ultrasound-assisted emulsification–microextraction combined with high performance liquid chromatography to the determination of propoxur in environmental and beverage samples. Microchim. Acta, 166: 157–162.
  • Seebunrueng, K., Santaladchaiyakit, Y., Soisungnoen, P., and Srijaranai, S. (2011) Catanionic surfactant ambient cloud point extraction and high-performance liquid chromatography for simultaneous analysis of organophosphorus pesticide residues in water and fruit juice samples. Anal. Bioanal. Chem., 401: 1703–1712.
  • Bedendo, G.C., Jardim, I.C.S.F., and Carasek, E. (2012) Multiresidue determination of pesticides in industrial and fresh orange juice by hollow fiber microporous membrane liquid–liquid extraction and detection by liquid chromatography–electrospray–tandem mass spectrometry. Talanta, 88: 573–580.
  • Tan, G.H. and Chai, M.K. (2011) Sample preparation in the analysis of pesticides residue in food for chromatographic techniques. In Pesticides—Strategies for Pesticides Analysis, Stoytcheva, M., Ed. InTech: Rijeka, Croatia, pp. 28–59.
  • Tan, G.H., and Abdulra’uf, L.B. (2012) Recent Developments and Applications of Microextraction Techniques for the Analysis of Pesticide Residues in Fruits and Vegetables. Pesticides – Recent Trends in Pesticide Residue Assay, pp. 171–190. Available at: http://dx.doi.org/10.5772/46843
  • Sichilongo, K.F., Obuseng, V.C., and Okatch, H. (2012) Applications of gas chromatography– mass spectrometry (GC-MS): An examination of selected African cases. Chromatographia, 75: 1017–1037.
  • Chen, X.-H., Zhao, Y.-G., Shen, H.-Y., and Jin, M.C. (2012) Application of dispersive solid-phase extraction and ultra-fast liquid chromatography–tandem quadrupole mass spectrometry in food additive residue analysis of red wine. J. Chromatogr. A, 1263: 34–42.
  • Current literature in mass spectrometry. (2009) J. Mass Spectrom., 44: 151–162.
  • Hau, J., Riediker, S., Varga, N., and Stadler, R.H. (2000) Determination of the plant growth regulator chlormequat in food by liquid chromatography–electrospray ionisation tandem mass spectrometry. J. Chromatogr. A, 878: 77–86.
  • Picó, Y., Blasco, C., and Font, G. (2004) Environmental and food applications of LC-tandem mass spectrometry in pesticide-residue analysis: An overview. Mass Spectrom. Rev., 23: 45–85.
  • Malik, A.K., Blasco, C., and Picó, Y. (2010) Liquid chromatography–mass spectrometry in food safety. J. Chromatogr. A, 1217: 4018–4040.
  • Fernández-Alba, A.R., and García-Reyes, J.F. (2008) Large-scale multi-residue methods for pesticides and their degradation products in food by advanced LC-MS. TrAC, Trends Anal. Chem., 27: 973–990.
  • Soler, C., and smf Picó, Y. (2007) Recent trends in liquid chromatography–tandem mass spectrometry to determine pesticides and their metabolites in food. TrAC, Trends Anal. Chem., 26: 103–115.
  • Wode, F., Reilich, C., van Baar, P., Dünnbier, U., Jekel, M., and Reemtsma, T. (2012) Multiresidue analytical method for the simultaneous determination of 72 micropollutants in aqueous samples with ultra high performance liquid chromatography–high resolution mass spectrometry. J. Chromatogr. A, 1270: 118–126.
  • Wong, S.-K., Yu, K.-C., and Lam, C.-H. (2010) Isotope dilution gas chromatography/mass spectrometry method for determination of pyrethroids in apple juice. Anal. Bioanal. Chem., 396: 1877–1884.
  • Ruiz del Castillo, M.L., Rodriguez-Valenciano, M., and de la Peña Moreno, F. (2012) Evaluation of pesticide residue contents in fruit juice by solid-phase microextraction and multidimensional gas chromatography coupled with mass spectrometry. Talanta, 89: 77–83.
  • Cunha, S.C., Fernandes, J.O., and Oliveira, M.B.P.P. (2009) Fast analysis of multiple pesticide residues in apple juice using dispersive liquid–liquid microextraction and multidimensional gas chromatography–mass spectrometry. J. Chromatogr. A, 1216: 8835–8844.
  • Moreno-González, D., Gámiz-Gracia, L., García-Campaña, A.M., and Bosque-Sendra, J.M. (2011) Use of dispersive liquid–liquid microextraction for the determination of carbamates in juice samples by sweeping-micellar electrokinetic chromatography. Anal. Bioanal. Chem., 400: 1329–1338.
  • Schenck, F.J., and Lehotay, S.J. (2000) Does further clean-up reduce the matrix enhancement effect in gas chromatographic analysis of pesticide residues in food? J. Chromatogr. A, 868: 51–61.
  • Sánchez-Brunete, C., Albero, B., and Tadeo, J.L. (2004) Multiresidue determination of pesticides in soil by gas chromatography–mass spectrometry detection. J. Agric. Food Chem., 52: 1445–1451.
  • Sánchez-Brunete, C., Albero, B., Martín, G., and Tadeo, J.L. (2005) Determination of pesticide residues by GC-MS using analyte protectants to counteract the matrix effect. Anal. Sci., 21: 1291–1296.
  • Ferrer, I., García-Reyes, J.F., Mezcua, M., Thurman, E.M., and Fernández-Alba, A.R. (2005) Multi-residue pesticide analysis in fruits and vegetables by liquid chromatography–time-of-flight mass spectrometry. J. Chromatogr. A, 1082: 81–90.
  • Ferrer, I., Thurman, E.M., and Zweigenbaum, J.A. (2007) Screening and confirmation of 100 pesticides in food samples by liquid chromatography/tandem mass spectrometry. Rapid Commun. Mass Spectrom., 21: 3869–3882.
  • Greulich, K., and Alder, L. (2008) Fast multiresidue screening of 300 pesticides in water for human consumption by LC-MS/MS. Anal. Bioanal. Chem., 391: 183–197.
  • Ferrer, C., Martinez-Bueno, M.J., Ana Lozano, A.R., Lozano, A., and Fernández-Alba, A.R. (2011) Pesticide residue analysis of fruit juices by LC-MS/MS direct injection. One year pilot survey. Talanta, 83: 1552–1561.
  • Henniona, M.-C., and Barcelo, D. (1998) Strengths and limitations of immunoassays for effective and efficient use for pesticide analysis in water samples: A review. Anal. Chim. Acta, 362: 3–34.
  • Meulenberg, E.P., Mulder, W.H., and Stoks, P.G. (1995) Immunoassays for pesticides. Environ. Sci. Technol., 29: 553–561.
  • Le, H.T.M., Szurdoki, F., and Székács, A. (2003) Evaluation of an enzyme immunoassay for the detection of the insect growth regulator fenoxycarb in environmental and biological samples. Pest Manag. Sci., 59: 410–416.
  • Leng, S.X., McElhaney, J.E., Walston, J.D., Li, L., Larkin, K.A., and Young, B.S. (2008) ELISA and multiplex technologies for cytokine measurement in inflammation and aging research. J. Gerontol. A Biol. Sci. Med. Sci., 63: 879–884.
  • Bushway, R.J., Brandon, D.L., Bates, A.H., Li, L., Larkin, K.A., and Young, B.S. (1995) Quantitative determination of thiabendazole in fruit juices and bulk juice concentrates using a thiabendazole monoclonal antibody. J. Agric. Food Chem., 43: 1407–1412.
  • Watanabe, E., Kanzaki, Y., Tokumoto, H., Hoshino, R., Kubo, H., and Nakazawa, H. (2002) Enzyme-linked immunosorbent assay based on a polyclonal antibody for the detection of the insecticide Fenitrothion. Evaluation of antiserum and application to the analysis of water samples. J. Agric. Food Chem., 50: 53–58.
  • Watanabe, E., Baba, K., and Eun, H. (2007) Application of a commercial immunoassay to the direct determination of insecticide imidacloprid in fruit juices. Food Chem., 102: 745–750.
  • Lisa, M., Chouhan, R.S., Vinayaka, A.C., Manonmani, H.K., and Thakur, M.S. (2009) Gold nanoparticles based dipstick immunoassay for the rapid detection of dichlorodiphenyltrichloroethane: An organochlorine pesticide. Biosens. Bioelectron., 25: 224–227.
  • Özkana, S.A., Uslua, B., and Zuman, P. (2004) Electrochemical oxidation of sildenafil citrate (Viagra) on carbon electrodes. Anal. Chim. Acta, 501: 227–233.
  • Sreedhar, N.Y., Samatha, K., and Sujatha, D. (2000) An electrochemical approach to the determination of dinobuton: A study of water samples. Analyst, 125: 1645–1648.
  • Mercan, H., Yılmaz, E., and İnam, R. (2007) Determination of insecticide pymetrozine by differential pulse polarography/application to lake water and orange juice. J. Hazard. Mater., 141: 700–706.
  • De Souza, D., Machado, S.A.S., and Pi, R.C. (2006) Multiple square wave voltammetry for analytical determination of paraquat in natural water, food, and beverages using microelectrodes. Talanta, 69: 1200–1207.
  • Guziejewski, D., Skrzypek, S., and Ciesielski, W. (2012) Application of catalytic hydrogen evolution in the presence of neonicotinoid insecticide clothianidin. Food Anal. Methods, 5: 373–380.
  • Melo, L.C., De Souza, D., de Lima-Neto, P., and Nunes Correia, N. (2010) Sensitive determination of the diquat herbicide in fresh food samples on a highly boron-doped diamond electrode. Electroanalysis, 22: 2502–2510.
  • Monk, P.M.S., Turner, C., and Akhtar, S.P. (1999) Electrochemical behaviour of methyl viologen in a matrix of paper. Electrochim. Acta, 44: 4817–4826.
  • Lu, T.-H., and Sun, I.-W. (2000) Electrocatalytic determination of paraquat using a nafion film coated glassy carbon electrode. Talanta, 53: 443–451.
  • Tegeler, T. and El Rassi, Z. (2001) Capillary electrophoresis and electrochromatography of pesticides and metabolites. Electrophoresis, 22: 4281–4293.
  • García-Cañas, V. and Cifuentes, A. (2008) Recent advances in the application of capillary electromigration methods for food analysis. Electrophoresis, 29: 294–309.
  • Herrero, M., García-Cañas, V., Simo, C., and Cifuentes, A. (2010) Recent advances in the application of capillary electromigration methods for food analysis and foodomics. Electrophoresis, 31: 205–228.
  • Huang, X. and Ren, J. (2006) Chemiluminescence detection for capillary electrophoresis and microchip capillary electrophoresis. Trends Anal. Chem., 25: 155–166.
  • Erny, G.L., and Cifuentes, A. (2006) Liquid separation techniques coupled with mass spectrometry for chiral analysis of pharmaceuticals compounds and their metabolites in biological fluids. J. Pharm. Biomed., 40: 509–515.
  • Miao, Y., He, N., and Zhu, J.-J. (2010) History and new developments of assays for cholinesterase activity and inhibition. Chem. Rev., 110: 5216–5234.
  • Ni, Y., Caoa, D., and Kokot, S. (2007) Simultaneous enzymatic kinetic determination of pesticides, carbaryl and phoxim, with the aid of chemometrics. Anal. Chim. Acta, 588: 131–139.
  • Andreescu, S., and Marty, J.-L. (2006) Twenty years research in cholinesterase biosensors: From basic research to practical applications. Biomol. Eng., 23: 1–15.
  • Guo, X., Zhang, X., Cai, Q., Shen, T., and Zhu, S. (2013) Developing a novel sensitive visual screening card for rapid detection of pesticide residues in food. Food Control, 30: 15–23.
  • Liu, D., Chen, W., Wei, J., Li, X., Wang, Z., and Jiang, X. (2012) A highly sensitive, dual-readout assay based on gold nanoparticles for organophosphorus and carbamate pesticides. Anal. Chem., 84: 4185–4191.
  • Marty, J.-L., Garcia, D., and Rouillon, R. (1995) Biosensors: Potential in pesticide detection. Trends Anal. Chem., 14: 329–333.
  • Jaffrezic-Renault, N. (2001) New trends in biosensors for organophosphorus pesticides. Sensors, 1: 60–74.
  • March, C., Manclus, J.J., Jimenez, Y., Arnau, A., and Montoya, A. (2009) A piezoelectric immunosensor for the determination of pesticide residues and metabolites in fruit juices. Talanta, 78: 827–833.
  • Ivanov, A., Evtugyn, G., Budnikov, H., Ricci, F., Moscone, D., and Palleschi, G. (2003) Cholinesterase sensors based on screen-printed electrodes for detection of organophosphorus and carbamic pesticides. Anal. Bioanal. Chem., 377: 624–631.
  • Hossain, S.M., Luckham, R.E., McFadden, M.J., and Brennan, J.D. (2009) Reagentless bidirectional lateral flow bioactive paper sensors for detection of pesticides in beverage and food samples. Anal. Chem., 81: 9055–9064.
  • Wu, H.-Z., Lee, Y.-C., and Lin, T.-K. (2009) Development of an amperometric micro-biodetector for pesticide monitoring and detection. J. Taiwan Inst. Chem. Eng., 40: 113–122.
  • Hwang, E.-S., Cash, J.N., and Zabik, M.J. (2001) Postharvest treatments for the reduction of mancozeb in fresh apples. J. Agric. Food Chem., 49: 3127–3132.
  • Athanasopoulos, P.E., and Pappas, C. (2000) E.ects of fruit acidity and storage conditions on the rate of degradation of azinphos methyl on apples and lemons. Food Chem., 69: 69–72.
  • Pose-Juan, E., Cancho-Grande, B., Rial-Otero, R., and Simal-Gándara, J. (2006) The dissipation rates of cyprodinil, fludioxonil, procymidone and vinclozoline during storage of grape juice. Food Control, 17: 1012–1017.
  • Li, Y., Jiao, B., Zhao, Q., Wang, C., Gong, Y., Zhang, Y., and Chen, W. (2012) Effect of commercial processing on pesticide residues in orange products. Eur. Food Res. Technol., 234: 449–456.
  • Banerjee, T., Banerjee, D., Roy, S., Banerjee, H., and Pai, S. (2012) A comparative study on the persistence of imidacloprid and beta-cyfluthrin in vegetables. Bull. Environ. Contam. Toxicol., 89: 193–196.
  • Fernandes, V.C., Domingues Nuno Mateus, V.F., Domingues, V.F., Mateus, N., and Delerue-Matos, C. (2012) Pesticide residues in Portuguese strawberries grown in 2009–2010 using integrated pest management and organic farming. Environ. Sci. Pollut. Res., 19: 4184–4192.
  • Picó, Y., and Kozmutza, C. (2007) Evaluation of pesticide residue in grape juices and the effect of natural antioxidants on their degradation rate. Anal. Bioanal. Chem., 389: 1805–1814.
  • Köne, J.M., Köne, S., and Simunek, J. (2009) A review of model applications for structured soils: (b) Pesticide transport. J. Contam. Hydrol., 104: 36–60.
  • Xu, X.-M., Yu, S., Li, R., Fan, J., Chen, S.-H., Shen, H.-T., Han, J.-L., Huang, B.-F., and Ren, Y.-P. (2012) Distribution and migration study of pesticides between peel and pulp in grape by online gel permeation chromatography–gas chromatography/mass spectrometry. Food Chem., 135: 161–169.
  • Mohamed, K.A., Basfar, A.A., and Al-Shahrani, A.A. (2009) Gamma-ray induced degradation of diazinon and atrazine in natural groundwaters. J. Hazard. Mater., 166: 810–814.
  • Basfar, A.A., Mohamed, K.A., Al-Abduly, A.J., Al-Kuraiji, T.S., and Al-Shahrani, A.A. (2007) Degradation of diazinon contaminated waters by ionizing radiation. Radiat. Phys. Chem., 76: 1474–1479.
  • Getoff, N. (1995) Radiation-induced degradation of water pollutants: State of the art. Radiat. Phys. Chem., 46: 1079–1080.
  • Basfar, A.A., Khan, H.M., Al-Shahrani, A.A., and Cooper, W.J. (2005) Radiation induced decomposition of methyl tert-butyl ether in water in presence of chloroform: Kinetic modelling. Water Res., 39: 2085–2095.
  • Chiron, S., Fernandez-Alba, A., Rodriguez, A., and Garcia-Calvo, E. (2000) Pesticide chemical oxidation: State-of-the-art. Water Res., 34: 366–377.
  • Ormad, M.P., Miguel, N., Claver, A., Matesanz, J.M., and Ovelleiro, J.L. (2008) Pesticides removal in the process of drinking water production. Chemosphere, 71: 97–106.
  • Metz, D.H., Meyer, M., Dotson, A., Beerendok, E., and Dionysiou, D.D. (2011) The effect of UV/H2O2 treatment on disinfection by-product formation potential under simulated distribution system conditions. Water Res., 45: 3969–3980.
  • Orejuela, E., and smf Silva, M. (2003) Monitoring some phenoxyl-type N-methylcarbamate pesticide residues in fruit juices using high-performance liquid chromatography with peroxyoxalate–chemiluminescence detection. J. Chromatogr. A, 1007: 197–201.
  • Basfar, A.A., Mohamed, K.A., and Al-Saqer, O.A. (2012) De-contamination of pesticide residues in food by ionizing radiation. Rad. Phys. Chem., 81: 473–478.
  • Codex Alimentarius Commission. (2003) Residues of Pesticides in Foods and Animal Feeds. Joint FAO/WHO Food Standards Programme, Codex Committee on Pesticide Residues: The Hague, The Netherlands.
  • Senthilnathan, J., and Philip, L. (2011) Photodegradation of methyl parathion and dichlorvos from drinking water with N-doped TiO2 under solar radiation. Chem. Eng. J., 172: 678–688.
  • Fenoll, J., Flores, P., Hellín, P., Martínez, C.M., and Navarro, S. (2012) Photodegradation of eight miscellaneous pesticides in drinking water after treatment with semiconductor materials under sunlight at pilot plant scale. Chem. Eng. J., 204–206: 54–64.
  • Deng, X., Chen, X., Lin, K., Ding, G., and Yao, P. (2013) Rapid and selective determination of trace benzimidazole fungicides in fruit juices by magnetic solid-phase extraction coupled with high-performance liquid chromatography–fluorescence detection. Food Anal. Methods. doi: 10.1007/s12161-013-9572-1.
  • Farajzadeh, M.A., Khoshmaram, L., and Afshar, M.R. (2012) Combination of solid-phase extractionhollow fiber for ultra-preconcentration of some triazole pesticides followed by gas chromatography–flame ionization detection. J. Sep. Sci., 35: 121–127.
  • Albero, B., Sánchez-Brunete, C., and Tadeo, J.L. (2005) Multiresidue determination of pesticides in juice by solid-phase extraction and gas chromatography–mass spectrometry. Talanta, 66: 917–924.
  • Albero, B., Sanchez-Brunete, C., and Tadeo, J.L. (2003) Determination of endosulfan isomers and endosulfan sulfate in tomato juice by matrix solid-phase dispersion and gas chromatography. J. Chromatogr. A, 1007: 137–143.
  • Farajzadeh, M.A., and Hatami, M. (2004) Solid-phase microextraction gas chromatography for determination of some organophosphorus pesticides. Chromatographia, 59: 259–262.
  • Zambonin, C.G., Quinto, M., De Vietro, N., and Palmisano, F. (2004) Solid-phase microextraction–gas chromatography mass spectrometry: A fast and simple screening method for the assessment of organophosphorus pesticides residues in wine and fruit juices. Food Chem., 86: 269–274.
  • Cortés-Aguado, S., Sánchez-Morito, N., Arrebola, F.J., and Martínez Vidal, J.L. (2008) Fast screening of pesticide residues in fruit juice by solid-phase microextraction and gas chromatography–mass spectrometry. Food Chem., 107: 1314–1325.
  • Sagratini, G., Manes, J., Giardiná, D., Damiani, D., and Picó, Y. (2007) Analysis of carbamate and phenylurea pesticide residues in fruit juices by solid-phase microextraction and liquid chromatography–mass spectrometry. J. Chromatogr. A, 1147: 135–143.
  • Viñas, P., Campillo, N., Aguinaga, N., Martínez-Castillo, N., and Hernández-Córdoba, M. (2008) Solid-phase microextraction for the gas chromatography mass spectrometric determination of oxazole fungicides in malt beverages. Anal. Bioanal. Chem., 391: 1425–1431.
  • Cavaliere, B., Monteleone, M., Naccarato, A., Sindona, G., and Tagarelli, A. (2012) A solid-phase microextraction–gas chromatographic approach combined with triple quadrupole mass spectrometry for the assay of carbamate pesticides in water samples. J. Chromatogr. A, 1257: 149–157.
  • Carabias-Martínez, R., García-Hermida, C., Rodríguez-Gonzalo, E., and Ruano-Miguel, L. (2005) Behaviour of carbamate pesticides in gas chromatography and their determination with solid-phase extraction and solid-phase microextraction as preconcentration steps. J. Sep. Sci., 28: 2130–2138.
  • Cai, L., Gong, S., Chen, M., and Wu, C. (2006) Vinyl crown ether as a novel radical crosslinked sol-gel SPME fiber for determination of organophosphorus pesticides in food samples. Anal. Chim. Acta, 559: 89–96.
  • Robles-Molina, J., Gilbert-Lopez, B., and García-Reyes, J.F. (2011) Multiclass determination of pesticides and priority organic pollutants in fruit-based soft drinks by headspace solid-phase microextraction/gas chromatography tandem mass spectrometry. Anal. Methods, 3: 2221–2230.
  • Wang, J.-H., Zhang, Y.-B., and Wang, X.-L. (2006) Determination of multiclass pesticide residues in apple juice by gas chromatography–mass spectrometry with large-volume injection. J. Sep. Sci., 29: 2330–2337.
  • Nguyen, T.D., Yun, M.Y., and Lee, G.-H. (2009) A multiresidue method for the determination of 118 pesticides in vegetable juice by gas chromatography–mass spectrometry and liquid chromatography–tandem mass spectrometry. J. Agric. Food Chem., 57: 10095–10101.
  • Furlani, R.P.Z., Marcilio, K.M., Moralez Leme, F., and Tfouni, S.A.V. (2011) Analysis of pesticide residues in sugarcane juice using QuEChERS sample preparation and gas chromatography with electron capture detection. Food Chem., 126: 1283–1287.
  • Matsadiq, G., Hu, H.-L., Ren, H.-B., Zhou, Y.-W., Liu, L., and Cheng, J. (2011) Quantification of multi-residue levels in peach juices, pulps and peels using dispersive liquid–liquid microextraction based on floating organic droplet coupled with gas chromatography–electron capture detection. J. Chromatogr. B, 879: 2113–2118.
  • Fu, L., Liu, X., Hub, J., Zhao, X., Wang, H., and Wang, X. (2009) Application of dispersive liquid–liquid microextraction for the analysis of triazophos and carbaryl pesticides in water and fruit juice samples. Anal. Chim. Acta, 632: 289–295.
  • Farajzadeh, M.A., Djozan, D., and Khorram, P. (2012) Development of a new dispersive liquid–liquid microextraction method in a narrow-bore tube for preconcentration of triazole pesticides from aqueous samples. Anal. Chim. Acta, 713: 70–78.
  • Xiong, J., and Hu, B. (2008) Comparison of hollow fiber liquid phase microextraction and dispersive liquid–liquid microextraction for the determination of organosulfur pesticides in environmental and beverage samples by gas chromatography with flame photometric detection. J. Chromatogr. A, 1193: 7–18.
  • Frenich, A.G., Romero-González, R., Martínez Vidal, J.L., Ocana, R.M., and Feria, P.B. (2011) Comparison of solid phase microextraction and hollow fiber liquid phase microextraction for the determination of pesticides in aqueous samples by gas chromatography triple quadrupole tandem mass spectrometry. Anal. Bioanal. Chem., 399: 2043–2059.
  • Ochiai, N., Sasamoto, K., Kandaa, H., and Nakamura, S. (2006) Fast screening of pesticide multiresidues in aqueous samples by dual stir bar sorptive extraction–thermal desorption–low thermal mass gas chromatography–mass spectrometry. J. Chromatogr. A, 1130: 83–90.
  • Lavagnini, I., Urbani, A., and Magno, F. (2011) Overall calibration procedure via a statistically based matrix-comprehensive approach in the stir bar sorptive extraction–thermal desorption–gas chromatography–mass spectrometry analysis of pesticide residues in fruit-based soft drinks. Talanta, 83: 1754–1762.
  • Goto, T., Ito, Y., Ok, H., Oka, H., Saito, I., Matsumoto, H., Sugiyama, H., Ohkubo, C., Nakazawa, H., and Nagase, H. (2005) The high throughput analysis of N-methyl carbamate pesticides in wine and juice by electrospray ionization liquid chromatography tandem mass spectrometry with direct sample injection into a short column. Anal. Chim. Acta, 531: 79–86.
  • Romero-González, R., Garrido Frenich, A., and Martínez Vidal, J.L. (2008) Multiresidue method for fast determination of pesticides in fruit juices by ultra performance liquid chromatography coupled to tandem mass spectrometry. Talanta, 76: 211–225.
  • Marek, L.J., and Koskinen, W.C. (2007) Multiresidue analysis of seven anticoagulant rodenticides by high-performance liquid chromatography/electrospray/mass spectrometry. J. Agric. Food Chem., 55: 571–576.
  • Maldaner, L. and Jardim, I.C.S.F. (2012) Determination of some organic contaminants in water samples by solid-phase extraction and liquid chromatography–tandem mass spectrometry. Talanta, 100: 38–44.
  • Greulich, K., and Alder, L. (2008) Fast multiresidue screening of 300 pesticides in water for human consumption by LC-MS/MS. Anal. Bioanal. Chem., 391: 183–197.
  • Kowal, S., Balsaa, P., Werres, F., and Schmidt, T.C. (2009) Determination of the polar pesticide degradation product N,N-dimethylsulfamide in aqueous matrices by UPLC-MS/MS. Anal. Bioanal. Chem., 395: 1787–1794.
  • Demoliner, A., Caldas, S.S.P. Costa, F.P., Gonçalves, F.F., Clementin, R.M., Milani, M.R., and Prime, E.G. (2010) Development and validation of a method using SPE and LC-ESI-MS-MS for the determination of multiple classes of pesticides and metabolites in water samples. J. Braz. Chem. Soc., 21: 1424–1433.
  • Ibáñez, M., Sancho, J.V., and Hernández, F. (2009) Determination of melamine in milk-based products and other food and beverage products by ion-pair liquid chromatography–tandem mass spectrometry. Anal. Chim. Acta, 649: 91–97.
  • Deák, E., Gyepes, A., Stefanovits-Bányai, É., and Dernovics, M. (2010) Determination of ethyl carbamate in pálinka spirits by liquid chromatography–electrospray tandem mass spectrometry after derivatization. Food Res. Int., 43: 2452–2455.
  • Pérez-Ortega, P., Gilbert-López, B., García-Reyes, J.F., Ramos-Martos, N., and Molina-Díaz, A. (2012) Generic sample treatment method for simultaneous determination of multiclass pesticides and mycotoxins in wines by liquid chromatography–mass spectrometry. J. Chromatogr. A, 1249: 32–40.
  • Gilbert-López, B., García-Reyes, J.F., Mezcua, M., Ramos-Martos, N., Fernández-Alba, A.R., and Molina-Díaz, A. (2010) Multi-residue determination of pesticides in fruit-based soft drinks by fast liquid chromatography time-of-flight mass spectrometry. Talanta, 81: 1310–1321.
  • Gilbert-López, B., García-Reyes, J.F., Mezcua, M., Molina-Díaz, A., and Fernández-Alba, A.R. (2007) Determination of postharvest fungicides in fruit juices by solid-phase extraction followed by liquid chromatography electrospray time-of-flight mass spectrometry. J. Agric. Food Chem., 55: 10548–10556.
  • García-Reyes, J.F., Gilbert-López, B., and Molina-Díaz, A. (2008) Determination of pesticide residues in fruit-based soft drinks. Anal. Chem., 80: 8966–8974.
  • Gilbert-López, B., Jaén-Martos, L., García-Reyes, J.F., Villar-Pulido, M., Polgar, L., Ramos-Martos, N., and Molina-Díaz, A. (2012) Study on the occurrence of pesticide residues in fruit-based soft drinks from the EU market and morocco using liquid chromatography–mass spectrometry. Food Control, 26: 341–346.
  • Mancl´s, J.J., Moreno, M.J., Plana, E., and Montoya, Á. (2008) Development of monoclonal immunoassays for the determination of triazole fungicides in fruit juices. J. Agric. Food Chem., 56: 8793–8800.
  • Sun, J.-W., Liu, B., Zhang, Y., and Wang, S. (2009) Development of an enzyme-linked immunosorbent assay for metolcarb residue analysis and investigation of matrix effects from different agricultural products. Anal. Bioanal. Chem., 394: 2223–2230.

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