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- The rate constant k3 can be neglected against k2 because only traces of diol 8 were present in a reaction mixture. Thus, the sum (k2 + k3) is actually k2.
- According to the initial rates of the formation of both 3 and 4 in the early stage of 1 deacetylation, the ratio k3/k2 can be estimated as 1.8. It means that k3 = 0.55 × 10−4 s−1 and k2 = 0.30×10−4 s−1.
- Although no rate constants are given in ref.,11 the half-time of the hydrolysis can be roughly estimated.
- The binding of hydrophobic groups must occur in the Hs area rather than in the HL site, but the cyclopentyl ring is marginally too large for optimum fit into Hs. It may extend partially into Hs pocket.5
- Moravcová , J. , Čapková , J. and Staněk , J. 1994 . Carbohydr. Res. , 263 : 61