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Original Articles

Selective Removal of Uranium from High‐Level Waste Solution Employing Tri‐n‐Butyl Phosphate as the Extractant

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Pages 663-675 | Received 12 Oct 2004, Accepted 31 May 2005, Published online: 15 Feb 2007

References

  • 1999 . “ Status and Trends of Spent Fuel Reprocessing ” . IAEA TECDOC‐1103
  • Baestle , L. H. 1992 . Burning of actinides: A complementary waste management option? IAEA Bulletin , 34 ( 3 ) : 32
  • Kapoor , S. S. 2001 . “Nuclear Technology Challenges in the 21st Century”, held at the Centre for Advanced Technology . October 10–12 2001 , Indore, India. Proceedings of Indian Nuclear Society Twelfth Annual Conference (INSAC–2001) , Vol. 2 , pp. 17 during
  • Raj , K. 2003 . “Nuclear Fuel Cycle Technologies: Closing the Fuel Cycle” held at Indira Gandhi Centre for Atomic Research . December 17–19 2003 , Kalpakkam, India. Proceedings of Indian Nuclear Society of Fourteenth Annual Conference (INSAC–2003) and First BRNS Conference of Nuclear Fuel Cycle , pp. Paper no. IT‐20
  • Horwitz , E. P. , Martin , K. A. , Diamond , H. and Kaplan , L. 1985 . Extraction of Am from nitric acid by carbamoyl‐phosphoryl extractants: The influence of substituents on the selectivity of Am over Fe and selected fission products . Solv. Extr. and Ion Exch. , 4 ( 3 ) : 449 – 494 .
  • Schulz , W. W. and Horwitz , E. P. 1988 . The TRUEX process and the management of liquid TRU waste . Sep. Sci. and Tech. , 23 ( 12&13 ) : 1191 – 1210 .
  • Mathur , J. N. 1993 . Partitioning of actinides from high level waste streams of PUREX process using mixtures of CMPO and TBP in n‐dodecane . Waste Management , 13 : 317 – 325 .
  • Mahajan , G. R. , Prabhu , D. R. , Manchanda , V. K. and Badheka , L. P. 1998 . Substituted malonamides as extractants for partitioning of actinides from nuclear waste solutions . Waste Management , 18 : 125 – 133 .
  • Mohapatra , P. K. , Sriram , S. , Manchanda , V. K. and Badheka , L. P. 2000 . Uptake of metal ions by extraction chromatography using dimethyl dibutyl tetradecyl‐1,3‐malonamide (DMDBTDMA) as the stationary phase. Sep . Sci. and Tech. , 35 ( 1 ) : 39 – 55 .
  • Cuillerdier , C. , Musikas , C. and Hoel , P. 1991 . New Techniques for Radioactive Waste and Other Specific Applications Edited by: Cecille , L. , Cesarci , M. and Pietrelli , L. 41 London : Elsevier Applied Science .
  • Cuillerdier , C. , Musikas , C. , Hoel , P. , Nigond , L. and Vitart , X. 1991 . Malonamides as new extractants for nuclear waste solutions . Sep. Sci. and Tech. , 26 ( 9 ) : 1229 – 1244 .
  • Baudin , G. , Lefevre , J. , Prunier , C. and Salvatores , M. 1993 . Proceedings of Technical Committee on Safety and Environmental Aspects of Partitioning and Transmutation of Actinides and Fission Products Vienna : IAEA . TECDOC‐783, 1995, 37
  • Taylor , R. J. 1998 . Kinetic and Solvent extraction studies of the selective reduction of Np(VI) by new salt free reducing agents . Radiochim. Acta , 81 : 149 – 156 .
  • Koltunov , V. S. , Taylor , R. J. , Baranov , S. M. and Mezhov , E. A. 1999 . May, I. The reduction of plutonium(IV) and neptunium(VI) ions by N,N-ethyl(hydroxyethyl) hydroxyl amine in nitric acid . Radiochim. Acta , 86 : 115 – 121 .
  • Anyun , Z. , Jingxin , Hu. , Xianye , Z. and Fangding , W. 2001 . Hydroxyl amine derivative in PUREX process,VI. Study on the partition of uranium/neptunium and uranium/plutonium with N,N-diethyl hydroxyl amine in the purification cycle of uranium contactor . Solv. Ext. and Ion Exch. , 19 ( 6 ) : 965 – 979 .
  • Yarbro , S. L. , Schreiber , S. B. , Ortiz , E. M. and Ames , R. L. 1998 . Reducing Pu(IV) to Pu(III) with hydroxyl amine in nitric acid solution . J. Radioanal. Nucl. Chem. , 235 ( 1,2 ) : 21 – 24 .
  • Barney , G. S. 1976 . A kinetic study of the reaction of plutonium(IV) with hydroxyl amine . J. Inorg. Nucl. Chem. , 38 : 1677 – 1681 .
  • Anyun , Z. and Ying , L. 2000 . Hydroxyl amine derivative in PUREX process, III. Study on the kinetics of oxidation–reduction reaction between N,N-diethyl hydroxyl amine and neptunium(VI) . J. Radioanal. Nucl. Chem. , 245 ( 2 ) : 357 – 364 .
  • Sze , Yu‐Keung; , Gosselin and Joseph , A. Valance control in the separation of actinides by liquid–liquid extraction . International Solvent Extraction Conference, ISEC‐80 . pp. 80 – 150 . Liege, , Belgium paper no
  • Anyun , Z. , Jingxin , H. , Xianye , Z. and Fangding , W. 2002 . Hydroxyl amine derivative in the purex process, part V. The single‐stage reduction extraction and back extraction of neptunium with N,N‐diethylhydroxyl amine . J. Radioanal. Nucl. Chem. , 253 ( 1 ) : 107 – 113 .
  • Anyun , Z. , Xioa , G. , Jingxin , H. , Xianye , Z. and He , H. 2003 . Hydroxyl amine derivative in the purex process, part V. The redox reactive kinetics and mechanism of dimethylhydroxylamine and vanadium(V) in nitric acid medium . J. Radioanal. Nucl. Chem. , 256 ( 3 ) : 587 – 592 .
  • Grossi , G. Organic soluble hydroquinones as reducing agents for plutonium and neptunium, and utilisation of hydroxyl amine nitrate for the stripping of plutonium from organic solutions of long chain tertiary amines . International Solvent Extraction Conference, ISEC‐77 . pp. 634 – 639 . Toronto, , Canada CIM special volume‐21
  • Taylor , R. J. 1998 . The applications of formo‐ and aceto-hydroxamic acids in nuclear fuel reprocessing . J. Alloy and Comp. , : 271 – 273 . 534 – 537 .
  • Grant , G. R. , Morgan , W. W. , Mehta , K. K. and Sargent , F. P. 1980 . “ Heavy element separation for thorium‐uranium‐plutonium fuels, Actinide Separation, ACS Symposium Series 117 ” . Edited by: Navratil , J. D. and Schulz , W. W. Washington, D.C.
  • Sajun , M. S. , Ramakrishna , V. V. and Patil , S. K. 1981 . The effect of temperature on the extraction of plutonium(VI) from nitric acid by tri‐n‐butyl phosphate . Thermochim. Acta , 47 ( 3 ) : 277 – 286 .
  • Moore , F. L. 1957 . Separation and determination of neptunium . Liquid–liquid extraction. Anal. Chem. , 29 ( 6 ) : 941 – 944 .
  • Srinivasan , N. , Nadkarni , M. N. , Balasubramanian , G. R. , Chitnis , R. T. and Siddiqui , H. R. 1972 . Mumbai, , India : Bhabha Atomic Research Centre . H.R. Report
  • Tachimori , S. , Nakashima , Z. , Karlsruhe , Schuler , R. and Karlsruhe . 1983 . Report . KfK–3637
  • Jeffery , G. H. , Bassett , J. , Mendham , J. and Denney , R. C. 1996 . Vogel's Textbook of Quantitative Chemical Analysis , 5th Edn. ELBS Edition 834 Addison Wesley Longman .
  • Johnson , D. A. and Florence , T. M. 1975 . A study of some pyridalazo dye stuffs as chromogenic reagents and the elucidation of the nature of their metal complexes spectra . Talanta , 22 : 253 – 265 .
  • Divakar , D. S. , Parikh , K. J. , Pandit , S. S. , Singh , S. K. , Jambunathan , U. and Ramanujam , A. 2001 . Sensitive method for the determination of micro quantities of 233U in the presence of large amounts of thorium. In the . “Nuclear Technology Challenges in the 21st Century”, held at Centre for Advanced Technology . October 10–12 2001 , Indore, India. Proceedings of Indian Nuclear Society Twelfth Annual Conference (INSAC–2001) , Vol. 1 , pp. 295 during
  • Schulz , W. W. , Burger , L. L. , Navratil , J. D. and Bender , K. P. 1990 . Science and Technology of Tributyl Phosphate Volume III 11 – 54 . Boca Raton, FL : CRC Press .
  • Sagar , V. , Chetty , K. V. and Sood , D. D. 2000 . Extraction of Pu(III) by TBP in presence of uranium . Solv. Ext. and Ion Exch. , 18 ( 2 ) : 307 – 317 .

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