Synthesis of Pre‐Organized Bisdiglycolamides (BisDGA) and Study of their Extraction Properties for Actinides(III) and Lanthanides(III)

REFERENCES

• McKay , H. A. C. 1984 . “ The PUREX Process, Part I, Introduction in science and technology of tributyl phosphate. ” . Edited by: Schulz , W. W and Navratil , J. D . Boca Raton : CRC Press .
   Google Scholar
• Miles , J. H. 1984 . “ The PUREX Process, Part II, Separation of plutonium and uranium in science and technology of tributyl phosphate. ” . Edited by: Schulz , W. W and Navratil , J. D . Boca Raton : CRC Press .
   Google Scholar
• Schulz , W. W. and Horwitz , E. P. 1987 . The TRUEX process: Removal/recovery of TRU elements from acidic waste solutions; I Chem E Symposium Series, No. 103
   Google Scholar
• Zhu , Y. and Jiao , R. 1994 . Chinese experience in the removal of actinides from highly active waste by trialkylphosphine‐oxide extraction. . Nucl. Tech. , 108 (3) : 361 – 369 .
   Web of Science ®Google Scholar
• Koma , Y. , Watanabe , M. , Nemoto , S. and Tanaka , Y. 1998 . Trivalent lanthanide and actinide intra‐group separation by solvent extraction with CMPO‐complexant system. . J. Nucl. Sci. Tech. , 35 (2) : 130 – 136 .
   Web of Science ®Google Scholar
• Mathur , J. N. , Murali , M. S. and Nash , K. L. 2001 . Actinide partitioning, a review. . Sol. Extr. Ion Exch. , 19 (3) : 357 – 390 .
   Web of Science ®Google Scholar
• Hubert , H. and Musikas , C. “ Process for recovering actinides and/or lanthanides. ” . US Patent 4572802 (February 25, 1986)
   Google Scholar
• Thiollet , G. , Lafosse , L. , Musikas , C. and Hoel , P. “ New propanediamides and processes for their preparation. ” . FR Patent 2585700 (February 6, 1987)
   Google Scholar
• Musikas , C. , Hoel , P. , Thiollet , G. and Lafosse , L. “ Method for the recovery of actinides and/or lanthanides using novel extraction agents, and novel propanediamides, and the preparation thereof. ” . US Patent 4938871 (July 3, 1990)
   Google Scholar
• Spjuth , L. , Liljenzin , J. O. , Hudson , M. J. , Drew , M. G. B. , Iveson , P. B. and Madic , C. 2000 . Comparison of extraction behavior and basicity of some substituted malonamides. . Solvent Extr. Ion Exch. , 18 (1) : 1 – 23 .
   Web of Science ®Google Scholar
• Madic , C. , Lecomte , M. , Baron , P. and Boullis , B. 2002 . Separation of long‐lived radionuclides from high active nuclear waste. . C.R. Physique , 3 : 797 – 811 .
   Web of Science ®Google Scholar
• Sasaki , Y. , Sugo , Y. , Suzuki , S. and Tachimori , S. 2001 . The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3‐n‐dodecane system. . Solv. Extr. Ion Exch. , 19 (1) : 91 – 103 .
   Web of Science ®Google Scholar
• Sasaki , Y. and Tachimori , S. 2002 . Extraction of actinides(III), (IV), (V), (VI); and lanthanides(III) by structurally tailored diamides. . Solv. Extr. Ion Exch. , 20 (1) : 21 – 34 .
   Web of Science ®Google Scholar
• Ansari , S. A. , Pathak , P. N. , Manchanda , V. K. , Husain , M. , Prasad , A. K. and Parmar , V. S. 2005 . N,N,N′,N′‐tetraoctyldiglycolamide (TODGA): A promising extractant for actinide‐partitioning from high‐level waste (HLW). . Solv. Extr. Ion Exch. , 23 (4) : 463 – 479 .
   Web of Science ®Google Scholar
• Sasaki , Y. , Sugo , Y. , Suzuki , S. and Kimura , T. 2005 . A method for the determination of extraction capacity and its application to N,N,N′,N′‐tetraalkylderivatives of diglycolamide‐monoamide/n‐dodecane media. . Anal. Chim. Acta , 543 : 31 – 37 .
   Web of Science ®Google Scholar
• Sugo , Y. , Sasaki , Y. and Tachimori , S. 2002 . Studies on hydrolysis and radiolysis of N,N,N′,N′‐tetraoctyl‐3‐oxopentane‐1,5‐diamide. . Radiochim. Acta , 90 : 161 – 165 .
   Web of Science ®Google Scholar
• Modolo , G. , Asp , H. , Schreinemachers , C. and Vijgen , H. 2007 . Development of a TODGA based process for partitioning of actinides from a PUREX raffinate Part I: Batch extraction optimization studies and stability tests. . Solv. Extr. Ion Exch. , 25 (6) : 703 – 721 .
   Web of Science ®Google Scholar
• Nave , S. , Modolo , G. , Madic , C. and Testard , F. 2004 . Aggregation properties of N,N,N′,N′‐tetraoctyl‐3‐oxapentanediamide (TODGA) in n‐dodecane. . Solv. Extr. Ion Exch. , 22 (4) : 527 – 551 .
   Web of Science ®Google Scholar
• Yaita , T. , Herlinger , A. W. , Thiyagarajan , P. and Jensen , M. P. 2004 . Influence of extractant aggregation on the extraction of trivalent f‐element cations by a tetraalkyldiglycolamide. . Solv. Extr. Ion Exch. , 22 (4) : 553 – 571 .
   Web of Science ®Google Scholar
• Murillo , M. T. , Espartero , A. G. , Almaraz , M. , Prados , P. , Sánchez‐Quesada , J. , Segura , M. , Iglesias‐Sánchez , J–C. and de Mendoza , J. 2008 . Bismalonamides (BISMA) as new extractants for Am(III) and Eu(III) from aqueous high‐level wastes. . Radiochim. Acta , 96 : 241 – 257 .
   Web of Science ®Google Scholar
• Janczewski , D. , Reinhoudt , D. N. , Verboom , W. , Hill , C. , Allignol , C. and Duchesne , M.‐T. 2008 . Tripodal diglycolamides as highly efficient extractants for f‐elements. . New J. Chem. , 32 (3) : 490 – 495 .
   Web of Science ®Google Scholar
• Murillo , M. T. , Sánchez‐Quesada , J. , Almaraz , M. , de Mendoza , J. , González‐Espartero , A. , Modolo , G. and Prados , P. “ Bis‐diglycolamides (BISDGA) as new extractants for lanthanides [Ln(III)] and actinides [An(III)] from aqueous high‐level wastes. ” . EP 1923473 (May 21, 2008)
   Google Scholar
• Sander , M. and Burmeister , D. 1962 . The preparation of N,N′‐dimethyl‐m‐ and N,N′‐dimethyl‐p‐xylylenediamine. . Chem. Ber. , 95 : 964 – 966 .
   Google Scholar
• Le Stang , S. , Meier , R. , Rocaboy , C. and Gladysz , J. A. 2003 . Convenient syntheses of fluorous phenols of the formula HOC6H5‐n((CH2)3(CF2)7CF3)n (n  =  1, 2) and the corresponding triaryl phosphites. . J. Fluorine Chem. , 119 (2) : 141 – 149 .
   Web of Science ®Google Scholar
• Stephan , H. , Gloe , K. , Beger , J. and Muehl , P. 1991 . Liquid‐liquid extraction of strontium with amido podands. . Solv. Extr. Ion Exch. , 9 (3) : 435 – 458 .
   Web of Science ®Google Scholar
• Kolarik , Z. 1991 . Separation of actinides and long‐lived fission products from high level radioactive wastes (a review), KfK 4945 Report
   Google Scholar
• Kolarik , Z. , Mullich , U. and Gassner , F. 1999 . Extraction of Am(III) and Eu(III) nitrates by 2,6‐di‐(5,6‐dipropyl‐1,2,4‐triazin‐3‐yl)pyridines. . Solv. Extr. Ion Exch. , 17 (5) : 1155 – 1170 .
   Web of Science ®Google Scholar
• Madic , C. , Boullis , B. , Baron , P. , Testard , F. , Hudson , M. J. , Liljenzin , J.‐O. , Christiansen , B. , Ferrando , M. , Facchini , A. , Geist , A. , Modolo , G. , Espartero , A. G. and de Mendoza , J. 2007 . Futuristic back‐end of the nuclear fuel cycle with the partitioning of minor actinides. . J. Alloys Compds. , 444–445 : 23 – 27 .
   Web of Science ®Google Scholar
• Modolo , G. and Odoj , R. 1999 . Synergistic selective extraction of actinides(III) over lanthanides from nitric acid using new aromatic diorganyldithiophosphinic acids and neutral organophosphorus compounds. . Solv. Extr. Ion Exch. , 17 (1) : 33 – 53 .
   Web of Science ®Google Scholar
• Sasaki , Y. , Zhu , Z.‐X. , Sugo , Y. and Kimura , T. 2007 . Extraction of various metal ions from nitric acid to n‐dodecane by diglycolamide (DGA) compounds. . J. Nucl. Sci. Tech. , 44 (3) : 405 – 409 .
   Web of Science ®Google Scholar