Actinide(III)/Lanthanide(III) Separation Via Selective Aqueous Complexation of Actinides(III) using a Hydrophilic 2,6-Bis(1,2,4-Triazin-3-Yl)-Pyridine in Nitric Acid

REFERENCES

• Magill , J. , Berthou , V. , Haas , D. , Galy , J. , Schenkel , R. , Wiese , H.W. , Heusener , G. , Thommasi , J. and Youinou , G. 2003 . Impact limits of partitioning and transmutation scenarios on the radiotoxicity of actinides in radioactive waste . J. Nucl. Eng. , 42 : 263 – 277 .
   Web of Science ®Google Scholar
• Salvatores , M. and Palmiotti , G. 2011 . Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges . Prog. Part. Nucl. Phys. , 66 : 144 – 166 .
   Web of Science ®Google Scholar
• Serrano-Purroy , D. , Baron , P. , Christiansen , B. , Malmbeck , R. , Sorel , C. and Glatz , J.P. 2005 . Recovery of minor actinides from HLLW using the DIAMEX process . Radiochim. Acta , 93 ( 6 ) : 351 – 355 .
   Web of Science ®Google Scholar
• Magnusson , D. , Christiansen , B. , Glatz , J.P. , Malmbeck , R. , Modolo , G. , Serrano-Purroy , D. and Sorel , C. 2009 . Demonstration of a TODGA based extraction process for the partitioning of minor actinides from a PUREX raffinate, Part III: Centrifugal contactor run using genuine fuel solution . Solvent Extr. Ion Exch. , 27 ( 1 ) : 26 – 35 .
   Web of Science ®Google Scholar
• Magnusson , D. , Christiansen , B. , Foreman , M.R.S. , Geist , A. , Glatz , J.P. , Malmbeck , R. , Modolo , G. , Serrano-Purroy , D. and Sorel , C. 2009 . Demonstration of a SANEX process in centrifugal contactors using the CyMe4-BTBP molecule on a genuine fuel solution . Solvent Extr. Ion Exch. , 27 ( 2 ) : 97 – 106 .
   Web of Science ®Google Scholar
• www.acsept.org (http://www.acsept.org)
   Google Scholar
• Weaver , B. and Kappelmann , F.A. 1964 . TALSPEAK: A new method of separating americium and curium from the lanthanides by extraction from an aqueous solution of an aminopolyacetic acid complex with a monoacidic organophosphate or phosphonate , USA : Oak Ridge National Laboratory . ORNL-3559
   Google Scholar
• Persson , G. , Svantesson , I. , Wingefors , S. and Liljenzin , J.O. 1984 . Hot test of a TALSPEAK procedure for separation of actinides and lanthanides using recirculating DTPA-lactic acid solutions . Solvent Extr. Ion Exch. , 2 ( 1 ) : 89 – 113 .
   Google Scholar
• Sasaki , Y. , Sugo , Y. , Suzuki , S. and Tachimori , S. 2001 . The novel extractants, diglycolamides, for the extraction of actinides and lanthanides in HNO3 – dodecane system . Solvent Extr. Ion Exch. , 19 ( 1 ) : 91 – 103 .
   Web of Science ®Google Scholar
• Modolo , G. , Asp , H. , Schreinemachers , C. and Vijgen , H. 2007 . Development of a TODGA based process for partitioning of actinides from a PUREX raffinate, part I: Batch extraction optimization studies and stability tests . Solvent Extr. Ion Exch. , 25 ( 6 ) : 703 – 721 .
   Web of Science ®Google Scholar
• Modolo , G. , Asp , H. , Vijgen , H. , Malmbeck , R. , Magnusson , D. and Sorel , C. 2008 . Demonstration of a TODGA bsed continuous counter-current extraction process for the partitioning of actinides from a simulated PUREX raffinate, part II: Centrifugal contactor runs . Solvent Extr. Ion Exch. , 26 ( 1 ) : 62 – 76 .
   Web of Science ®Google Scholar
• Hérès , X. , Baron , P. , Hill , C. , Ameil , E. , Martinez , I. and Rivalier , P. May 19–23 2008 . The Separation of Extractants Implemented in the DIAMEX-SANEX Process , May 19–23 , Montpellier , , France : Proceedings of the International Conference Atalante 2008 (Nuclear Fuel Cycles for a Sustainable Future) .
   Google Scholar
• Hérès , X. , Sorel , C. , Miguirditchian , M. , Camès , B. , Hill , C , Bisel , I. , Espinoux , D. , Eysseric , C. , Baron , P. and Lorrain , B. Sept. 6–11 2009 . Results of recent counter-current tests on An(III)/Ln(III) separation using TODGA extractant , Sept. 6–11 , 1127 – 1132 . Paris : Proceedings of the International Conference GLOBAL 2009 (The Nuclear Fuel Cycle: Sustainable Options & Industrial Perspectives) . Paper No. 9384
   Google Scholar
• Sypula , M. , Modolo , G. , Wilden , A. and Geist , A. Oct. 3–7 2011 . Innovative SANEX Process for Actinide (III) Separation from PUREX Raffinate using TODGA Based Solvents , Oct. 3–7 , Santiago , , Chile : Proceedings of the International Solvent Extraction Conference (ISEC 2011) .
   Google Scholar
• Kolarik , Z. , Müllich , U. and Gassner , F. 1999 . Extraction of Am(III) and Eu(III) nitrates by 2,6-di(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine . Solvent Extr. Ion Exch. , 17 ( 5 ) : 1155 – 1170 .
   Web of Science ®Google Scholar
• Hudson , M.J. , Boucher , C.E. , Braekers , D. , Desreux , J.F. , Drew , M.G.B. , Foreman , M.R.S. , Harwood , L.M. , Hill , C. , Madic , C. , Marken , F. and Youngs , T.G.A. 2006 . New bis(triazinyl) pyridines for selective extraction of americium(III) . New J. Chem. , 30 : 1171 – 1183 .
   Web of Science ®Google Scholar
• Trumm , S. , Geist , A. , Panak , P.J. and Th , Fanghänel . 2011 . An improved hydrolytically-stable bis-triazinyl-pyridine (BTP) for selective actinide extraction . Solvent Extr. Ion Exch. , 29 ( 2 ) : 213 – 229 .
   Web of Science ®Google Scholar
• Drew , M.G.B. , Foreman , M.R.S. , Hudson , M.J. and Madic , C. 2005 . 6,6′-bis(5,6-diethyl-[1,2,4]triazin-3-yl)-2,2′-bipyridyl the first example of a new class of quadridentate hetercyclic extraction reagents for the separation of americium(III) and europium(III) . Inorg. Chem. Commun. , 8 : 239 – 241 .
   Web of Science ®Google Scholar
• Geist , A. , Hill , C. , Modolo , G. , Foreman , M.R.S. , Weigl , M. , Gompper , K. , Hudson , M.J. and Madic , C. 2006 . 6,6' Bis(5,5,5,8-tetramethyl-5,6,7,8-tetrahydro-benzo[1,2,4]triazin-3-yl)[2,2'] bipyridine, an effective extraction agent for the separation of americium(III) and curium(III) from the lanthanides . Solvent Extr. Ion Exch. , 24 ( 4 ) : 463 – 483 .
   Web of Science ®Google Scholar
• Magnusson , D. , Christiansen , B. , Malmbeck , R. and Glatz , J.-P. 2009 . Investigation of the radiolytic stability of a CyMe4-BTBP based SANEX solvent . Radiochim. Acta , 97 ( 9 ) : 497 – 502 .
   Web of Science ®Google Scholar
• Fermvik , A. , Ekberg , C. , Englund , S. , Foreman , M.R.S. , Modolo , G. , Retegan , T. and Skarnemark , G. 2009 . Influence of dose rate on the radiolytic stability of a BTBP solvent for actinide(III)/lanthanide(III) separation . Radiochim. Acta , 97 ( 6 ) : 319 – 324 .
   Web of Science ®Google Scholar
• Aneheim , E. , Ekberg , C. , Fermvik , A. , Foreman , M.R.S. , Retegan , T. and Skarnemark , G. 2010 . A TBP/BTBP-based GANEX separation process. Part 1: Feasibility . Solvent Extr. Ion Exch. , 28 ( 4 ) : 437 – 458 .
   Web of Science ®Google Scholar
• Trumm , S. , Panak , P.J. , Geist , A. and Th , Fanghänel . 2010 . A TRLFS study on the complexation of Cm(III) and Eu(III) with 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine in water/methanol mixture . Eur. J. Inorg. Chem. , 19 : 3022 – 3028 .
   Web of Science ®Google Scholar
• Trumm , S. , Lieser , G. , Foreman , M.R.S. , Panak , P.J. , Geist , A. and Th , Fanghänel . 2010 . A TRLFS study on the complexation of Cm(III) and Eu(III) with 4-t-butyl-6,6'-bis-(5,6-diethyl-1,2,4-triazin-3-yl)-2,2'-bipyridine in a water/2-propanol mixture . Dalton Trans. , 39 : 923 – 929 .
   PubMed Web of Science ®Google Scholar
• Traister , G.L. and Schilt , A.A. 1976 . Water-soluble sulfonated chromogenic reagents of the ferroin type and determination of iron and copper in water, blood serum, and beer with the tetraammonium salt of 2,4-bis(5,6-diphenyl-1,2,4-triazin-3-yl)pyridinetetrasulfonic acid . Anal. Chem. , 48 : 1216 – 1220 .
   PubMed Web of Science ®Google Scholar
• Geist , A. , Müllich , U. , Modolo , G. and Wilden , A. Nov. 1–4 2010 . Selective Aqueous Complexation of Actinides with Hydrophilic BTP and BTBP: Towards Improved i-SANEX Processes , Nov. 1–4 , San Francisco , CA : In: Actinide and Fission Product Partitioning and Transmutation, 11th Information Exchange Meeting . NEA No. 6996 OECD-NEA (2012)
   Google Scholar
• Geist , A. , Müllich , U. , Modolo , G. and Wilden , A. Oct. 3–7 2011 . Actinide(III)/Lanthanide(III) Separation via Selective Aqueous Complexation of Actinides(III) in Nitric Acid , Oct. 3–7 , Santiago , , Chile : Proceedings of the International Solvent Extr. Conf. (ISEC 2011) .
   Google Scholar
• Geist , A. and Modolo , G. Sept. 6–11 2009 . TODGA Process Development: An Improved Solvent Formulation , Sept. 6–11 , 1022 – 1026 . Paris : Proceedings of the International Conference GLOBAL 2009 (The Nuclear Fuel Cycle: Sustainable Options & Industrial Perspectives) . Paper No. 9193
   Google Scholar
• Case , F.H. 1971 . The preparation of 2,4- and 2,6-bis-triazinyl and triazolinyl derivates of pyridine . J. Heterocycl. Chem. , 8 ( 6 ) : 1043 – 1046 .
   Web of Science ®Google Scholar
• Weigl , M. , Geist , A. , Müllich , U. and Gompper , K. 2006 . Kinetics of americium(III) extraction and back extraction with BTP . Solvent Extr. Ion Exch. , 24 ( 6 ) : 845 – 860 .
   Web of Science ®Google Scholar
• Ruff , C.M. , Müllich , Geist , A. and Panak , P.J. 2011 . A novel path in partitioning: Water-soluble BTP ligands for the innovative SANEX process . ATW—Int. J. Nuc. Power , 56 : 489 – 491 .
   Web of Science ®Google Scholar
• Steppert , M. , Walther , C. , Geist , A. and Th , Fanghänel . 2009 . Direct nano ESI time-of-flight mass spectrometric investigations on lanthanide BTP complexes in the extraction-relevant diluent 1-octanol . New J. Chem. , 33 : 2437 – 2442 .
   Web of Science ®Google Scholar
• Geist , A. 2010 . Extraction of nitric acid into alcohol:kerosene mixtures . Solvent Extr. Ion Exch. , 28 ( 5 ) : 596 – 607 .
   Web of Science ®Google Scholar
• Madic , C. , Hudson , M.J. , Liljenzin , J.-O. , Glatz , J.-P. , Nannicini , R. , Facchini , A. , Kolarik , Z. and Odoj , R. 2000 . New Partitioning Techniques for Minor Actinides , Luxembourg : EUR 19149, European Commission .
   Google Scholar
• Colette , S. , Amekraz , B. , Madic , C. , Berthon , L. , Cote , G. and Moulin , C. 2003 . Trivalent lanthanide interactions with a terdentate bis(dialkyltriazinly)pyridine ligand studied by electrospray ionisation mass spectrometry . Inorg. Chem. , 42 : 2215 – 2226 .
   PubMed Web of Science ®Google Scholar
• Magnusson , D. and Malmbeck , R. 2012 . Development of a solvent extraction model for process tests in short residence time centrifugal contactors . Solvent Extr. Ion Exch. , 30(2) : 115 – 126 .
   Web of Science ®Google Scholar