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Original Articles

Synergistic Extraction of Lanthanides (III) with Mixtures of TODGA and Hydrophobic Ionic Liquid into Molecular Diluent

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References

  • Huddleston, J. G.; Willauer, H. D.; Swatloski, R. P.; Visser, A. E.; Rogers, R. D.; Room temperature ionic liquids as novel media for “clean” Liquid-liquid extraction. Chem. Commun. 1998, 16, 1765–1766.
  • Dai, S.; Yu, Y. H.; Barnes, C. E.; Solvent extraction of strontium nitrate by a crown ether using room temperature ionic liquids. J. Chem. Soc. Dalton Trans. 1999, 8, 1201–1202.
  • Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Griffin, S. T.; Rogers, R. D.; Traditional extractants in nontraditional solvents: group 1 and 2 extraction by a crown ethers in room temperature ionic liquids. Ind. Eng. Chem. Res. 2000, 39, 3596–3604.
  • Dietz, M. L.; Dzielawa, J. A.; Ion-exchange as a mode of cation transfer into room temperature ionic liquids containing crown ethers: implications for the ‘greennes’ of ionic liquids as diluents in liquid-liquid extraction. Chem. Commun. 2001, 20, 2124–2125.
  • Chun, S.; Dzyuba, S. V.; Bartch, R. A.; Influence of structural variation in room temperature ionic liquids on the selectivity and efficiency of competitive alkaline metal salt extraction by a crown ether. Anal. Chem. 2001, 73, 3737–3741.
  • Jensen, M. P.; Neuefeind, J.; Beitz, J. V.; Skanthakumar, S.; Soderholm, L.; Mechanisms of metal ion transfer into room-temperature ionic liquids: the role of anion exchange. J. Amer. Chem. Soc. 2003, 125, 15466–15473.
  • Dietz, M. L.; Dzielawa, J. A.; Laszak, I.; Young, B. A.; Jensen, M. P.; Influence of solvent structural variation on the mechanism of facilitated ion transfer into room-temperature ionic liquids. Green Chem. 2003, 5, 682–685.
  • Visser, A. E.; Rogers, R. D.; Room-temperature ionic liquids: new solvents for F-element separations and associated solution chemistry. J. Solid State Chem. 2003, 171, 109–113.
  • Nakashima, K.; Kubota, F.; Maruyama, T.; Goto, M.; Ionic liquids as a novel solvent for lanthanide extraction. Anal. Sci. 2003, 19, 1097–1098.
  • Luo, H.; Dai, S.; Bonnesen, P. V.; Haverlock, T. J.; Moyer, B. A.; Buchanan, A. C., III.; A striking effect of ionic-liquid anions in the extraction of Sr2+ and Cs+ by dicyclohexano-18-crown-6. Solvent Extr. Ion Exch. 2006, 24, 19–31.
  • Dietz, M. L.; Ionic liquids as extraction solvents: Where do we stand? Sep. Sci. Technol. 2006, 41, 2047–2063.
  • Zhao, H.; Xia, S.; Ma, P.; Use of ionic liquids as green solvents for extractions. J. Chem. Technol. Biotechnol. 2005, 80, 1089–1096.
  • Kubota, F.; Goto, M.; Application of ionic liquids to solvent extraction. Solvent Extr. Res. Develop. Japan. 2006, 13, 23–36.
  • Tian, G.-C.; Li, J.; Hua, Y.-X.; Application of ionic liquids in hydrometallurgy of nonferrous metals. Trans. Nonferrous Met. Soc. China. 2010, 20, 513–520.
  • Billard, I.; Ouadi, A.; Gaillard, C.; Liquid-liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding. Anal. Bioanal. Chem. 2011, 400, 1555–1566.
  • Sun, X.; Luo, H.; Dai, S.; Ionic liquids-based extraction: A promising strategy for the advanced nuclear fuel cycle. Chem. Rev. 2012, 112, 2100–2128.
  • Billard, I.; Ionic liquids: New hopes for efficient lanthanide/Actinide extraction and separation? Handbook on the physics and chemistry of rare earth; Bunzli J. C. G., Pecharsky V. K., Eds.; Elsevier: Amsterdam; 2013, 213–273.
  • Kolaric, Z.; Ionic liquids: How far do they extend the potential of solvent extraction of f-elements? Solvent Extr. Ion Exch. 2013, 31, 24–60.
  • Li, S.-G.; Functionalized imidazolium salts for task-specific ionic liquids and their applications. Chem. Commun. 2006, 10, 1049–1063.
  • Fei, Z.; Geldbach, T. J.; Zhao, D.; Dyson, P. J.; From dysfunction to bis-function: on the design and applications of functionalized ionic liquids. Chem. Eur. J. 2006, 12, 2122–2130.
  • Shkrob, I. A.; Marin, T. W.; Jensen, M. P.; Ionic liquid based separation of trivalent lanthanide and actinide ions. Ind. Eng. Chem. Res. 2014, 53, 3641–3653.
  • Hoogestraete, T. V.; Wellens, S.; Verachtert, K.; Binnemans, K.; Removal of transitional metals from rare earth by solvent extraction with an undiluted ionic liquid: separations relevant to rare-earth magnet recycling. Green Chem. 2013, 15, 919–927.
  • Parmentier, D.; Hoogestraete, T. V.; Metz, S. J.; Binnemans, K.; Kroon, M. C.; Selective extraction of metals from chloride solutions with the tetraoctylphosphonium oleate ionic liquid. Ind. Eng. Chem. Res. 2015, 54, 5149–5158.
  • Mazan, V.; Billard, I.; Papaiconomou, N.; Experimental connections between aqueous-aqueous and aqueous-ionic liquid biphasic systems. RSC Adv. 2014, 4, 13371–13384T.
  • Janssen, C. H. C.; Sanchez, A.; Witkamp, G.-J.; Kobrak, M. N.; A novel mechanism for the extraction of metals from water to ionic liquids. ChemPhysChem. 2013, 14, 3806–3813.
  • Janssen, C. H. C.; Macias-Ruvalcaba, N. A.; Aguilar-Martinez, M.; Kobrak, M. N.; Metal extraction to ionic liquids: the relationship between structure, mechanism and application. Int. Rev. Phys. Chem. 2015, 34, 591–622.
  • Narita, H.; Yaita, T.; Tamura, K.; Tachimiti, S.; Solvent extraction of trivalent lantanoid ions with N,N’-dimethyl-N,N’-diphenyl-3-oxapentanediamide. Radiochim. Acta. 1998, 81, 223–226.
  • Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S.; The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3 - n-dodecane system. Solvent Extr. Ion Exch. 2001, 19, 91–103.
  • Tachimori, S.; Sasaki, Y.; Suzuki, S.; Modification of TODGA – n-dodecane solvent with monoamide for high loading of lanthanides(III) and actinides(III). Solvent Extr. Ion Exch. 2002, 20, 687–699.
  • Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T.; Cumulative study on solvent extraction of elements by N,N,N’,N’-tetraoctyl-3-oxapentanediamide (TODGA) from Nitric acid into n-dodecane. Anal. Chim. Acta. 2004, 527, 163–168.
  • Ansari, S. A.; Pathak, P. N.; Manchanda, V. K.; Husain, M.; Prasad, A. K.; Parmar, V. S.; N,N,N’,N’-tetraoctyldiglycolamide (TODGA): A promising extractant for actinide-partitioning from high-level waste (HLW). Solvent Extr. Ion Exch. 2005, 23, 463–479.
  • Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA system. Solvent Extr. Ion Exch. 2007, 25, 187–204.
  • Sasaki, Y.; Tsubata, Y.; Kitatsuji, Y.; Sugo, N.; Shirrasu, N.; Morita, Y.; Kimura, T.; Extraction behavior of metal ions by TODGA, DOODA, MIDOA, and NTAmide extractants from HNO3 to n-dodecane. Solvent Extr. Ion Exch. 2013, 31, 401–415.
  • Sasaki, Y.; Sugo, N.; Morita, Y.; Nash, K. L.; The effect of alkyl substituents on actinide and lanthanide extraction by diglycolamide compounds. Solvent Extr. Ion Exch. 2015, 33, 625–641.
  • Mowafy, E. A.; Mohamed, D.; Extraction behavior of trivalent lanthanides from nitric acid medium by selected structurally related diglycolamides as novel extractants. Sep. Purif. Technol. 2014, 128, 18–24.
  • Ansari, S. A.; Pathak, P. N.; Mohapatra, P. K.; Manchanda, V. K.; Chemistry of diglycolamides: Promising extractants for actinide partitioning. Chem. Rev. 2012, 112, 1751–1772.
  • Shimojo, K.; Kurahashi, K.; Naganawa, H.; Extraction behavior of lanthanides using a diglycolamide derivative TODGA in ionic liquids. Dalton Trans. 2008, 37, 5083–5088.
  • Mincher, M. E.; Quach, D. L.; Liao, Y. J.; Mincher, B. J.; Wai, C. M.; The partitioning of americium and lanthanides using Tetrabutyldiglycolamide (TBDGA) in octanol and ionic liquid solution. Solvent Extr. Ion Exch. 2012, 30, 735–747.
  • Panja, S.; Mohapatra, P. K.; Tripathi, S. C.; Gandhi, P. M.; Janardan, P.; A highly efficient solvent system containing TODGA in room temperature ionic liquids for actinide extraction. Sep. Purif. Technol. 2012, 96, 289–295.
  • Mohapatra, P. K.; Diglycolamide-based solvent systems in room temperature ionic liquids for actinide ion extraction: A review. Chem. Prod. Process. Model. 2015, 10, 135–145.
  • Sasaki, Y.; Choppin, G. R.; Solvent extraction of Eu, Th, U, Np and Am with N,N’-dimethyl-N,N’-dihexyl-3-oxapentanediamide and its analogous compounds. Anal. Sci. 1996, 12, 225–230.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Effect of anions on the extraction of lanthanides(III) by N,N’-dimethyl-N,N’-diphenyl-3-oxapentanediamide. Solvent Extr. Ion Exch. 2008, 26, 77–99.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Effect of ionic liquids on the extraction of rare-earth elements by bidentate neutral organophosphorus compounds from chloride solutions. Russ. J. Inorg. Chem. 2008, 53, 968–973.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Extraction of rare-earth elements from nitric acid solutions with bidentate neutral organophosphorus compounds in the presence of 1-butyl-3-methylimidazolium hexafluorophosphate. Radiochemistry. 2008, 50, 266–273.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Extraction of alkaline earth metal ions with TODGA in the presence of ionic liquids. Solvent Extr. Ion Exch. 2010, 28, 367–387.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Extraction of lanthanides(III) with N,N’-bis(diphenylphosphinylmethylcarbonyl)diaza-18-crown-6 in the presence of ionic liquids. Solvent Extr. Ion Exch. 2012, 30, 244–261.
  • Turanov, A. N.; Karandashev, V. K.; Yarkevich, A. N.; Extraction of REEs(III), U(VI), and Th(IV) from nitric acid solutions with carbamoylmethylphosphine oxides in the presence of an ionic liquid. Radiochemistry. 2013, 55, 382–387.
  • Turanov, A. N.; Karandashev, V. K.; Yarkevich, A. N.; Preconcentration of rare earth elements(III) from nitric acid solutions using carbamoylmethylphosphine oxide and an ionic liquid. Radiochemistry. 2014, 56, 515–519.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Kalashnikova, I. P.; Kirillov, E. V.; Kirillov, S. V.; Rychkov, V. N.; Tsivadze, A. Y.; Extraction of rare-earths and scandium by 2-phosphorylphenoxyacetic acid amides in the presence of ionic liquids. Russ. J. Inorg. Chem. 2016, 61, 377–383.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Kirillov, E. V.; Kirillov, S. V.; Rychkov, V. N.; Tsivadze, A. Y.; Extraction of rare earth elements with 2-2’-(methoxydiphenylphosphoryl)phenyldiazenyl]-4-tert-butylphenol in the presence of 1-butyl-3-methylimidazolium and trioctylmethylammonium picrates. Russ. J. Inorg. Chem. 2016, 61, 1479–1482.
  • Turanov, A. N.; Karandashev, V. K.; Boltoeva, M.; Gailard, C.; Mazan, V.; Sinergistic extraction of uranium(VI) with TODGA and hydrophobic ionic liquid mixtures into molecular diluent. Sep. Purif. Technol. 2016, 164, 97–106.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Extraction of metal chloride complexes by phosphoryl-containing podands. Solvent Extr. Ion Exch. 1996, 14(2), 227–245.
  • Yaita, T.; Narita, H.; Suzuki, S.; Tachimori, S.; Motohashi, H.; Shiwaku, H.; Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS. J. Radioanal. Nucl. Chem. 1999, 239, 371–375.
  • Antonio, M. R.; McAlister, D. R.; Horwitz, E. P.; An europium(III) diglycolamide complex: Insights into the coordination chemistry of lanthanides in solvent extraction. Dalton Trans. 2015, 44, 515–521.
  • Ellis, R. J.; Brigham, D. M.; Delmau, L.; Ivanov, A. S.; Williams, N. J.; Vo, M. N.; Reinhart, B.; Moyer, B. A.; Bryantsev, V. S.; “Straining” to separate the rare earth: How the lanthanide contraction impacts chelation by diglycolamide ligands. Inorg. Chem. 2017, 56, 1152–1160.
  • Binnemans, K.; Lanthanides and actinides in ionic liquids. Chem. Rev. 2007, 107, 2593–2614.
  • Turanov, A. N.; Karandashev, V. K.; Baulin, V. E.; Extraction of U(VI), Th(IV), and rare-earth elements from nitric acid solutions with phosphoryl- and carbonyl-containing podands. Radiochemistry. 2007, 49, 256–263.
  • Saipriya, G.; Kumaresan, R.; Nayak, P. K.; Venkatesan, K. A.; Kumar, T.; Antony, M.; Extraction behaviour of Am(III) and Eu(III) from nitric acid medium in TEHDGA-HDEHP impregnated resins. Radiochim. Acta. 2016, 104, 781–790.

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