Extraction Behavior of Ln(III) Ions by T2EHDGA/n-Dodecane from Nitric Acid and Sodium Nitrate Solutions

References

• Wigeland, R. A.; Bauer, T. H.; Fanning, T. H.; Morris, E. E. Spent Nuclear Fuel Separations and Transmutation Criteria for Benefit to a Geologic Repository. Proceedings of Waste Management, Tuscon, Arizon, 2004.
   Google Scholar
• Nash, K. L.;. The Chemistry of TALSPEAK: A Review of the Science. Solvent Extr. Ion Exch. 2015, 33(1), 1–55. DOI: 10.1080/07366299.2014.985912.
   Web of Science ®Google Scholar
• Tachimori, S.; Morita, Y. Overview of Solvent Extraction Chemistry for Reprocessing. In Ion Exchange and Solvent Extraction, Vol. 19; Moyer B. A., Ed.; CRC Press: Boca Raton, 2010; pp 1–63.
   Google Scholar
• IAEA. Implication of Partioning and Transmutation in Radioactive Waste Management. Tech. Reports Ser. 2004, 435, 4–7, STI/DOC/010/435.
   Google Scholar
• Weaver, B.; Kappelmann, F. A. TALSPEAK: A New Method of Separating Americium and Curium from the Lanthanides by Extraction from an Aqueous Solution of an Aminopolyacetic Acid Complex with a Monoacidic Organophosphate or Phosphonate; Oak Ridge, 1964.
   Google Scholar
• Pearson, G.;. Hard and Soft Acids and Bases. J. Am. Chem. Soc. 1963, 85(22), 3533–3539. DOI: 10.1021/ja00905a001.
   Web of Science ®Google Scholar
• Clark, D. L.;. The Chemical Complexities of Plutonium. Los Alamos Sci. 2000, 26, 364–381.
   Google Scholar
• Seaborg, G. T.; Loveland, W. D. The Elements beyond Uranium; Wiley & Sons: New York, 1990.
   Google Scholar
• Jensen, M. P.; Chiarizia, R.; Ulicki, J. S.; Spindler, B. D.; Murphy, D. J.; Hossain, M. M.; Roca-Sabio, A.; De Blas, A.; Rodríguez-Blas, T. Solvent Extraction Separation of Trivalent Americium from Curium and the Lanthanides. Solvent Extr. Ion Exch. 2015, 33(4), 329–345. DOI: 10.1080/07366299.2015.1046292.
   Web of Science ®Google Scholar
• Rydberg, J.; Cox, M.; Musikas, C.; Choppin, G. R. Solvent Extraction Principles and Practice, 2nd ed.; Marcel Dekker: New York, 2004.
   Google Scholar
• Yaita, T.; Herlinger, A. W.; Thiyagarajan, P.; Jensen, M. P. Influence of Extractant Aggregation on the Extraction of Trivalent f‐Element Cations by a Tetraalkyldiglycolamide. Solvent Extr. Ion Exch. 2004, 22(4), 553–571. DOI: 10.1081/SEI-120039640.
   Web of Science ®Google Scholar
• Gujar, R. B.; Ansari, S. A.; Mohapatra, P. K.; Manchanda, V. K. Development of T2EHDGA Based Process for Actinide Partitioning. Part I: Batch Studies for Process Optimization. Solvent Extr. Ion Exch. 2010, 28(3), 350–366. DOI: 10.1080/07366291003685383.
   Web of Science ®Google Scholar
• Ansari, S. A.; Pathak, P.; Mohapatra, P. K.; Manchanda, V. K. Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning. Chem. Rev. 2012, 112(3), 1751–1772. DOI: 10.1021/cr200002f.
   PubMed Web of Science ®Google Scholar
• Gelis, A. V.; Lumetta, G. J. Actinide Lanthanide Separation Process - ALSEP. Ind. Eng. Chem. Res. 2014, 53(4), 1624–1631. DOI: 10.1021/ie403569e.
   Web of Science ®Google Scholar
• Kawasaki, T.; Okumura, S.; Sasaki, Y.; Ikeda, Y. Crystal Structures of Ln(III) (Ln = La, Pr, Nd, Sm, Eu, and Gd) Complexes with N,N,N’,N’-Tetraehtyldiglycolamide Associated with Homoleptic [Ln(No3)6)]3-. Bull. Chem. Soc. Jpn. 2014, 87(2), 294–300. DOI: 10.1246/bcsj.20130259.
   Web of Science ®Google Scholar
• Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. An Additional Insight into the Correlation between the Distribution Ratios and the Aqueous Acidity of the TODGA System. Solvent Extr. Ion Exch. 2007, 25(2), 187–204. DOI: 10.1080/07366290601169345.
   Web of Science ®Google Scholar
• Pathak, P. N.; Ansari, S. A.; Mohapatra, P. K.; Manchanda, V. K.; Patra, A. K.; Aswal, V. K. Role of Alkyl Chain Branching on Aggregation Behavior of Two Symmetrical Diglycolamides: Small Angle Neutron Scattering Studies. J. Colloid Interface Sci. 2013, 393(1), 347–351. DOI: 10.1016/j.jcis.2012.10.023.
   PubMedGoogle Scholar
• Jensen, M. P.; Yaita, T.; Chiarizia, R. Reverse-Micelle Formation in the Partitioning of Trivalent F-Element Cations by Biphasic Systems Containing a Tetraalkyldiglycolamide. Langmuir. 2007, 23(9), 4765–4774. DOI: 10.1021/la0631926.
   PubMed Web of Science ®Google Scholar
• Antonio, M. R.; McAlister, D. R.; Horwitz, E. P. An Europium(Iii) Diglycolamide Complex: Insights into the Coordination Chemistry of Lanthanides in Solvent Extraction. Dalton Trans. 2015, 44(2), 515–521. DOI: 10.1039/C4DT01775G.
   PubMed Web of Science ®Google Scholar
• Nave, S.; Modolo, G.; Madic, C.; Testard, F. Aggregation Properties of N, N, N′, N′‐Tetraoctyl‐3‐oxapentanediamide (TODGA) in n‐Dodecane. Solvent Extr. Ion Exch. 2004, 22(4), 527–551. DOI: 10.1081/SEI-120039721.
   Web of Science ®Google Scholar
• Ansari, S. A.; Mohapatra, P. K.; Prabhu, D. R.; Manchanda, V. K. Transport of Americium(III) through a Supported Liquid Membrane Containing N,N,N’,N’-tetraoctyl-3-Oxapentane Diamide (TODGA) in N-Dodecane as the Carrier. J. Memb. Sci. 2006, 282(1–2), 133–141. DOI: 10.1016/j.memsci.2006.05.013.
   Web of Science ®Google Scholar
• Campbell, E. L.; Holfeltz, V. E.; Hall, G.; Nash, K. L.; Lumetta, G. J.; Levitskaia, T. G. Nitric Acid and Water Extraction by T2EHDGA in n-Dodecane. Solvent Extr. Ion Exch. 2017, 35(7), 586–603. DOI: 10.1080/07366299.2017.1400161.
   Web of Science ®Google Scholar
• Baes, C. F.;. SXLSQI, A Program for Modeling Solvent Extraction Systems; ORNL/TM-13604, Oak Ridge National Laboratory: Oak Ridge, TN, 1998.
   Google Scholar
• Herbst, R. S.; Peterman, D. R.; Zalupski, P. R.; Nash, K. L.; Tillotson, R. D.; Delmau, L. H. Thermodynamics of Cesium Extraction from Acidic Media by HCCD and PEG. Solvent Extr. Ion Exch. 2010, 28(5), 563–578. DOI: 10.1080/07366299.2010.502865.
   Web of Science ®Google Scholar
• Pitzer, K.;. Activity Coefficients in Electrolyte Solutions, 2nd ed.; Pitzer K. S., Ed.; CRC Press: Boca Raton, 1991.
   Google Scholar
• Millero, F. J.;. Water and Aqueous Solutions; Horne, R. A., Ed.; Wiley-Interscience: New York, 1971.
   Google Scholar
• Barton, A. F. M.;. CRC Handbook of Solubility Parameters and Other Cohesion Parameters; CRC Press: Boca Raton, 1991.
   Google Scholar
• Deepika, P.; Sabharwal, K. N.; Srinivasan, T. G.; Vasudeva Rao, P. R. Studies on the Use of N, N, N′, N′-Tetra(2-Ethylhexyl) Diglycolamide (TEHDGA) for Actinide Partitioning II: Investigation on Radiolytic Stability. Solvent Extr. Ion Exch. 2011, 29(2), 230–246. DOI: 10.1080/07366299.2011.539145.
   Web of Science ®Google Scholar
• Sasaki, Y.; Sugo, Y.; Suzuki, S.; Kimura, T. A Method for the Determination of Extraction Capacity and Its Application to N,N,N′,N′-Tetraalkylderivatives of Diglycolamide-Monoamide/n- Dodecane Media. Anal. Chim. Acta. 2005, 543(1–2), 31–37. DOI: 10.1016/j.aca.2005.04.061.
   Web of Science ®Google Scholar
• Gujar, R. B.; Ansari, S. A.; Murali, M. S.; Mohapatra, P. K.; Manchanda, V. K. Comparative Evaluation of Two Substituted Diglycolamide Extractants for “Actinide Partitioning.”. J. Radioanal. Nucl. Chem. 2010, 284(2), 377–385. DOI: 10.1007/s10967-010-0467-y.
   Web of Science ®Google Scholar
• Berthon, L.; Martinet, L.; Testard, F.; Madic, C.; Zemb, T. Solvent Penetration and Sterical Stabilization of Reverse Aggregates Based on the DIAMEX Process Extracting Molecules: Consequences for the Third Phase Formation. Solvent Extr. Ion Exch. 2007, 25, 545–576. DOI: 10.1080/07366290701512576.
   Web of Science ®Google Scholar
• Ravi, J.; Venkatesan, K. A.; Antony, M. P.; Srinivasan, T. G.; Vasudeva Rao, P. R. Tuning the Diglycolamides for Modifier-Free Minor Actinide Partitioning. J. Radioanal. Nucl. Chem. 2013, 295(2), 1283–1292. DOI: 10.1007/s10967-012-1905-9.
   Web of Science ®Google Scholar
• Reilly, S. D.; Gaunt, A. J.; Scott, B. L.; Modolo, G.; Iqbal, M.; Verboom, W.; Sarsfield, M. J. Plutonium(Iv) Complexation by Diglycolamide Ligands—Coordination Chemistry Insight into TODGA-Based Actinide Separations. Chem. Commun. 2012, 48(78), 9732. DOI: 10.1039/c2cc34967a.
   PubMed Web of Science ®Google Scholar
• Mowafy, E. A.; Mohamed, D. Extraction of Rare Earth Elements from Nitrate Solution Using Novel Unsymmetrical Diglycolamide. Sep. Sci. Technol. 2017, 52(6), 1006–1014. DOI: 10.1080/01496395.2016.1274760.
   Web of Science ®Google Scholar
• Mowafy, E. A.; Aly, H. F. Extraction Behaviours of Nd(III), Eu(III), La(III), Am(III), and U(VI) with Some Substituted Malonamides from Nitrate Medium. Solvent Extr. Ion Exch. 2002, 20(2), 177–194. DOI: 10.1081/SEI-120003020.
   Web of Science ®Google Scholar
• Mowafy, E. A.; Mohamed, D. Extraction and Separation of Nd(III), Sm(III), Dy(III), Fe(III), Ni(II), and Cs(I) from Concentrated Chloride Solutions with N,N,N’,N’-tetra(2-Ethylhexyl) Diglycolamide as New Extractant. J. Rare Earths. 2015, 33(4), 432–438. DOI: 10.1016/S1002-0721(14)60437-3.
   Web of Science ®Google Scholar
• Mowafy, E. A.; Mohamed, D. Extraction Behavior of Trivalent Lanthanides from Nitric Acid Medium by Selected Structurally Related Diglycolamides as Novel Extractants. Sep. Purif. Technol. 2014, 128, 18–24. DOI: 10.1016/j.seppur.2014.03.005.
   Web of Science ®Google Scholar
• Curtis, N. F.; Curtis, Y. M. Some Nitrato-Amine Nickel(II) Compounds with Monodentate and Bidentate Nitrate Ions. Inorg. Chem. 1965, 4(6), 804–809. DOI: 10.1021/ic50028a007.
   Web of Science ®Google Scholar
• Gatehouse, B. B. M.; Nyholm, R. S. Gatehouse, Livingstone, and Nyholm : Infrared Bpectra of Xome Nitrato-Co-Ordination Complexes. J. Chem. Soc. 1956, 4222, 4222–4225.
   Google Scholar
• Chiarizia, R.; Jensen, M. P.; Borkowski, M.; Ferraro, J. R.; Thiyagarajan, P.; Littrell, K. C. Third Phase Formation Revisited: The U(VI), HNO 3 –TBP, n‐Dodecane System. Solvent Extr. Ion Exch. 2003, 21(1), 1–27. DOI: 10.1081/SEI-120017545.
   Web of Science ®Google Scholar
• Narita, H.; Yaita, T.; Tamura, K.; Tachimori, S. Study on the Extraction of Trivalent Lanthanide Ions with N, N’-dimethyl-N, N’-diphenyl-Malonamide and -Diglycolamide. J. Radioanal. Nucl. Chem. 1999, 239(2), 38–41. DOI: 10.1007/BF02349516.
   Web of Science ®Google Scholar
• Borkowski, M.; Ferraro, J. R.; Chiarizia, R.; McAlister, D. R. FT-IR Study of Third Phase Formation in the U(VI) or Th(IV)/HNO3, TBP/Alkane Systems. Solvent Extr. Ion Exch. 2002, 20(3), 313–330. DOI: 10.1081/SEI-120004807.
   Web of Science ®Google Scholar
• Song, X.-Q.; Liu, W.-S.; Dou, W.; Zheng, J.-R.; Tang, X.-L.; Zhang, H.-R.; Wang, D.-Q. Tuning the Self-Assembly and Luminescence Properties of Lanthanide Coordination Polymers by Ligand Design. Dalton Trans. 2008, 27, 3582–3591. DOI: 10.1039/b800217g.
   Google Scholar
• Henrie, D. E.; Fellows, R. L.; Choppin, G. R. Hypersensitivity in the Electronic Transitions of Lanthanide and Actinide Complexes. Coord. Chem. Rev. 1976, 18(2), 199–224. DOI: 10.1016/S0010-8545(00)82044-5.
   Web of Science ®Google Scholar
• Chatterjee, S.; Campbell, E. L.; Neiner, D.; Pence, N. K.; Robinson, T. A.; Levitskaia, T. G. Aqueous Binary Lanthanide(III) Nitrate Ln(NO3)3 Electrolytes Revisited: Extended Pitzer and Bromley Treatments. J. Chem. Eng. Data. 2015, 60(10), 2974–2988. DOI: 10.1021/acs.jced.5b00392.
   Web of Science ®Google Scholar
• Andersson, S.; Eberhardt, K.; Ekberg, C.; Liljenzin, J. O.; Nilsson, M.; Skarnemark, G. Determination of Stability Constants of Lanthanide Nitrate Complex Formation Using a Solvent Extraction Technique. Radiochim. Acta. 2006, 94, 469–474.
   Web of Science ®Google Scholar