Radiolytic Degradation of Uranyl-Loaded Tributyl Phosphate by High and Low LET Radiation

References

• Glatz, J.;. Spent Fuel Dissolution and Reprocessing Processes. In Comprehensive Nuclear Materials, Vol 5: Material Performance and Corrosion/Waste Materials; Koningsm, R. J. M., Allen, T. R., Stoller, R. E., Yamanaka, S., Eds.; Elsevier: Amsterdam, Holland, 2012; pp 342–366.
   Google Scholar
• Lanham, W. G.; Runion, T. C. Purex Process for Uranium and Plutonium Recovery, AEC Technical Report ORNL-479; Oak Ridge National Laboratory, TN, 1949.
   Google Scholar
• Schulz, W.; Navratil, J.; Kertes, A. Science and Technology of Tributyl Phosphate; CRC Press Inc.: Boca Raton, FL, USA, 1984.
   Google Scholar
• Dukes, E. K.; The formation and Effects of Dibutyl Phosphate in Solvent Extraction. E.I. du Pont de Nemours & Co., Explosives Dept., Atomic Energy Division, Technical Division: Savannah River Laboratory, AEC Research and Development Report no. DP-250, 1957.
   Google Scholar
• Shook, H. E., Jr; . Solvent Degradation Products in Nuclear Fuel Processing Solvent; E.I. Du Pont De Nemours & Co. Savannah River Laboratory, DOE report no. DP-1759, 1988.
   Google Scholar
• Mincher, J.; Modolo, G.; Mezyk, S. P. Review Article: The Effects of Radiation Chemistry on Solvent Extraction: 1. Conditions in Acidic Solution and a Review of TBP Radiolysis. Solvent Extr. Ion Exch. 2009, 27(1), 1–25. DOI: 10.1080/07366290802544767.
   Web of Science ®Google Scholar
• Pearson, J.; Nilsson, M. Radiolysis of Tributyl Phosphate by Particles of High Linear Energy Transfer; Solvent Extr. Ion Exch. 2014, 32(6), 584–600. DOI: 10.1080/07366299.2014.924305.
   Web of Science ®Google Scholar
• Pearson, J.; Jan, O.; Wariner, A.; Miller, G. E.; Nilsson, M. Development of a Method for High LET Irradiation of Liquid System. J. Radioanal. Nucl. Chem. 2013, 298(2), 1401–1409. DOI: 10.1007/s10967-013-2549-0.
   Web of Science ®Google Scholar
• Jayson, G.; Parsons, B.; Swallow, A. Mechanism of Fricke Dosimeter. Int. J. Radiat. Phys. Chem. 1975, 7(2–3), 363–370. DOI: 10.1016/0020-7055(75)90075-3.
   Google Scholar
• Fricke, H.; Morse, S. The Chemical Action of Roentgen Rays on Dilute Ferrosulphate Solutions as a Measure of Dose. Am. J. Roent. Radium. Ther. Nucl. Med.. 1927, 18, 430–432.
   Google Scholar
• Zaitsev, V. D.; Khaikin, G. I. Formation of Solvated Electrons during Radiolysis of Liquid Tri-n-Butylphosphate. High Energ. Chem. 1989, 23(2), 79–82.
   Web of Science ®Google Scholar
• Mincher, B. J.; Mezyk, S. P.; Martin, L. R. A Pulse Radiolysis Investigation of the Reactions of Tributyl Phosphate with the Radical Products of Aqueous Nitric Acid Irradiation. J. Phys. Chem. A. 2008, 112(28), 6275–6280. DOI: 10.1021/jp802169v.
   PubMed Web of Science ®Google Scholar
• Vladimirova, M.; Kulikov, I. Kinetics of Tributyl Phosphate Radiolytic Decomposition. Atomnaya Energiya. 1986, 60(3), 195–197.
   Google Scholar
• Sasaki, T.; Meguro, Y.; Yoshida, Z. Spectrophotometric Measurement of Uranium(VI)-Tributylphosphate Complex in Supercritical Carbon Dioxide. Talanta. 1998, 46(4), 689–695. DOI: 10.1016/S0039-9140(97)00331-7.
   PubMed Web of Science ®Google Scholar
• Becker, R.; Bautz, H.; Stieglitz, L. Untersuchung der Strahlenchemischen TBP-Zersetzung Unter den Bedingungen des PUREX-Prozesses. Report no. KfK-3639, Kernforschungszentrum Karlsruhe, Germany, 1983.
   Google Scholar
• Kuno, Y.; Hina, T. Degradation of Tributylphosphate in Plutonium Nitrate Solution. J. Nucl. Sci. Technol. 1992, 29(8), 762–767. DOI: 10.1080/18811248.1992.9731592.
   Web of Science ®Google Scholar
• Stas, J.; Dahdouh, A.; Shlewit, H. Extraction of Uranium (VI) from Nitric Acid and Nitrate Solutions by Tributylphosphate/Kerosene. Period. Polytech. Chem. Eng. 2005, 49(1), 3–18.
   Google Scholar
• Orabi, A. H.;. Determination of Uranium after Separation Using Solvent Extraction from Slightly Nitric Acid Solution and Spectrophotometric Detection. J. Radiat. Res. Appl. Sci. 2013, 6(2), 1–10. DOI: 10.1016/j.jrras.2013.09.001.
   Google Scholar
• Mitsuhiro, H.; Chie, M.; Masayasu, I. The Third Phase of Extraction Processes in Fuel Reprocessing, (III)J. Nucl. Sci. Technol. 1993, 30(3), 232–238. DOI: 10.1080/18811248.1993.9734474.
   Google Scholar
• Adamov, V. M.;. Identification and Formation Mechanism of Decomposition Products of Tri-Normal-Butylphosphate Extraction Systems in Aliphatic-Hydrocarbons. Sov. Radiochem. 1992, 34(1), 150–157.
   Google Scholar
• Kulikov, I. A.; Kermanova, N. V.; Vladimirova, M. V. Radiolysis of TBP in the Presence of Plutonium and Uranium. Sov. Radiochem. 1983, 25, 310–316.
   Google Scholar
• Gao, Y.; Zhen, W.-F.; Cao, X.-M.; Chen, S.-L. Gamma and Alpha Radiolysis of TBP solvent. Nucl. Sci. Technol. 2015, 26, S10303.
   Web of Science ®Google Scholar