Extraction of Uranium(VI) and Plutonium(IV) with Tetra-Alkylcarbamides

References

• Suresh, A.; Srinivasan, T. G.; Rao, P. R. V. Extraction of U(VI), Pu(IV)and Th(IV) by Some Trialkyl Phosphates. Solvent Extr. Ion Exch. 1994, 12(4), 727–744.
   Web of Science ®Google Scholar
• Chumakova, G.; Yakshin, V.; Filippov, E.; Belov, V.; Volodin, I.; Arkhipova, G.; Laskorin, B. Extraction of Uranium and Transuranium Elements from Nitric Acid Solutions by Carbonyl-Containing Compounds. Radiochemistry. 1980, 22(2), 213–217.
   Web of Science ®Google Scholar
• Milanole, G.; Russello, E.; Marie, C.; Miguirditchian, M.; Sorel, C. Dissymmetric N, N-Dialkylamides Used Particularly for Separating uranium(VI) from plutonium(IV), Synthesis Thereof and Uses of Same. WO2018138441 (A1), 2018.
   Google Scholar
• Miguirditchian, M.; Sorel, C.; Costenoble, S.; Vanel, V.; Heres, X.; Baron, P.; Masson, M.; Chareyre, L. Method for the Treatment of an Aqueous Nitric Solution Used Resulting from Dissolving Spent Nuclear Fuel, Said Method Being Performed in a Single Cycle and without Requiring Any Operation Involving the Reductive Back-Extraction of Plutonium WO2017017207 (A1), 2017.
   Google Scholar
• Miguirditchian, M.; Baron, P.; Lopes Moreira, S.; Milanole, G.; Marie, C. Novel Dissymmetric N, N-Dialkylamides, the Synthesis Thereof and Uses of Same. WO2017017193A1, 2017.
   Google Scholar
• Musikas, C.; Zorz, P. Method of Extracting uranium(VI) And/Or plutonium(IV) Present in an Aqueous Acid Solution by Means of a Mixture of N, N-Dialkyl Amides, for Use in the Reprocessing of Irradiated Nuclear Fuels. FR2642562 (A1), 1990. .
   Google Scholar
• Sorel, C.; Miguirditchian, M., New Developments with Monoamide Type Extractants. Proceeding of International Solvent Extraction Community (ISEC), Würzburg, Germany, 2014, 436.
   Google Scholar
• Condamines, N.; Musikas, C. The Extraction by N,N-dialkylamides. II Extraction of Actinide Cations. Solvent Extr. Ion Exch. 1992, 10(1), 69–100. DOI: 10.1080/07366299208918093.
   Web of Science ®Google Scholar
• Lopes Moreira, S.;. New Monoamides Synthesis for the uranium(VI) and plutonium(IV) Extraction; University of Nantes, 2013.
   Google Scholar
• McCann, K.; Drader, J. A.; Braley, J. C. Comparing Branched versus Straight-Chained Monoamide Extractants for Actinide Recovery. Sep. Purif. Rev. 2018, 47(1), 49–65. DOI: 10.1080/15422119.2017.1321018.
   Web of Science ®Google Scholar
• Sorel, C.; Costenoble, S.; Bollesteros, M.-J.; Antégnard, F.; Montuir, M.; Vincent, V.; Miguirditchian, M.; Boyer-Deslys, V.; Hérès, X.; Grandjean, S., Demonstration of Uranium - Plutonium Separation and Purification from Spent Nuclear Fuel with Monoamide Solvent. Proceeding of International Nuclear Fuel Cycle Conference (GLOBAL), Seoul, Republic of Korea, 2017, a221.
   Google Scholar
• Rodrigues, F.; Ferru, G.; Berthon, L.; Boubals, N.; Guilbaud, P.; Sorel, C.; Diat, O.; Bauduin, P.; Simonin, J.-P.; Morel, J.-P.;; et al. New Insights into the Extraction of uranium(VI) by an N, N-Dialkylamide. Mol. Phys. 2014, 112(9–10), 1362–1374.
   Web of Science ®Google Scholar
• Gupta, K.; Manchanda, V.; Subramanian, M.; Singh, R. Solvent Extraction Studies on U(VI), Pu(IV), and Fission Products Using N, N-Dihexyloctanamide. Solvent Extr. Ion Exch. 2000, 18(2), 273–292. DOI: 10.1080/07366290008934681.
   Web of Science ®Google Scholar
• Nair, G.; Mahajan, G.; Prabhu, D. Extraction of uranium(VI) and plutonium(IV) with Some High Molecular Weight Aliphatic Monoamides from Nitric Acid Medium. J. Radioanal. Nucl. Chem. 1995, 191(2), 323–330. DOI: 10.1007/BF02038228.
   Web of Science ®Google Scholar
• Prabhu, D.; Mahajan, G.; Nair, G. Di(2-Ethyl Hexyl) Butyramide and Di(2-Ethyl Hexyl)Isobutyramide as Extractants for uranium(VI) and plutonium(IV). J. Radioanal. Nucl. Chem. 1997, 224(1), 113–117. DOI: 10.1007/BF02034622.
   Web of Science ®Google Scholar
• Dukes, E.; Siddall, T. Tetrabutylurea as an Extractant for Nitric Acid and Some Actinide Nitrates. J. Inorg. Nucl. Chem. 1966, 28(10), 2307–2312. DOI: 10.1016/0022-1902(66)80121-5.
   Web of Science ®Google Scholar
• Zhu, L.; Li, B.; Zhu, X.; Chen, L.; Cao, Z. Extracting of uranium(VI) from Nitric Acid by Tetrabutylurea. Chem. Res. Appl. 2004, 16(2), 276–277.
   Google Scholar
• Zhu, L.; Cao, Z.; Li, B.; Luo, A.; Yu, K. Extraction Properties of N,N’-diethyl-N,N’-dibenzyl-urea and Synthesis, Crystal Structure of bis(nitrate)bis(N,N’-diethyl-N,N’-dibenzyl-urea)uranyl(II). Chin. J. Inorg. Chem. 2002, 18(9), 924–928.
   Web of Science ®Google Scholar
• Vats, B.; Das, D.; Sadhu, B.; Kannan, S.; Pius, I.; Noronha, D.; Sundararajan, M.; Kumar, M. Selective Recognition of Uranyl Ions from Bulk of thorium(IV) and lanthanide(III) Ions by Tetraalkylurea: A Combined Experimental and Quantum Chemical Study. Dalton Trans. 2016, 45(25), 10319–10325. DOI: 10.1039/c6dt01191h.
   PubMed Web of Science ®Google Scholar
• Suzuki, T.; Kawasaki, T.; Takao, K.; Harada, M.; Nogami, M.; Ikeda, Y. A Study on Selective Precipitation Ability of Cyclic Urea to U(VI) for Developing Reprocessing System Based on Precipitation Method. J. Nucl. Sci. Technol. 2012, 49(10), 1010–1017. DOI: 10.1080/00223131.2012.723175.
   Web of Science ®Google Scholar
• Suzuki, T.; Takao, K.; Kawasaki, T.; Harada, M.; Nogami, M.; Ikeda, Y. A Study on Selective Precipitation of U(VI) by Hydrophilic Cyclic Urea Derivatives for Development of A Reprocessing System Based on Precipitation Method. J. Nucl. Sci. Technol. 2014, 51(4), 514–520. DOI: 10.1080/00223131.2013.877406.
   Web of Science ®Google Scholar
• McCann, K.; Mincher, B.; Schmitt, N.; Braley, J. Hexavalent Actinide Extraction Using N,N-dialkyl Amides. Ind. Eng. Chem. Res. 2017, 56(22), 6515–6519. DOI: 10.1021/acs.iecr.7b01181.
   Web of Science ®Google Scholar
• McCann, K.; Sinkov, S.; Lumetta, G.; Shafer, J. Inner versus Outer Sphere Metal-Monoamide Complexation: Ramifications for Tetravalent & Hexavalent Actinide Selectivity. New J. Chem. 2018, 42(7), 5415–5424. DOI: 10.1039/C7NJ04851C.
   Web of Science ®Google Scholar
• Marie, C.; Berger, C.; Mossand, G.; Russello, E.; Andreiadis, E.; Guillaumont, D.; Miguirditchian, M.; Sorel, C. Ureas for Separating uranium(VI) and plutonium(IV) without Reducing the plutonium(IV). WO2019002788, 2019.
   Google Scholar
• Wimer, D.;. Potentiometric Determination of Amides in Acetic Anhydride. Anal. Chem. 1958, 30(1), 77–80. DOI: 10.1021/ac60133a022.
   Web of Science ®Google Scholar
• Streuli, C.;. Basic Behavior of Molecules and Ions in Acetic Anhydride. Anal. Chem. 1958, 30(5), 997–1000. DOI: 10.1021/ac60137a036.
   Web of Science ®Google Scholar
• Dinh, B.; Baron, P.; Duhamet, J. The PUREX Process Separation and Purification Operations. In Treatment and Recycling of Spent Nuclear Fuel; Parisot, J.-F., Ed.; Le Moniteur: France, 2008; pp 55–70.
   Google Scholar
• Prabhu, D.; Mahajan, G.; Nair, G.; Subramanian, M. Extraction of uranium(VI) and plutonium(IV) with Unsymmetrical Monoamides. Radiochim. Acta. 1993, 60, 109–113. DOI: 10.1524/ract.1993.60.23.109.
   Web of Science ®Google Scholar
• Ruikar, P.; Nagar, M.; Pai, S.; Subramanian, M. Extraction of uranium(VI) and plutonium(IV) with Some Aliphatic Amides. J. Radioanal. Nucl. Chem. 1991, 150(2), 473–481. DOI: 10.1007/BF02035334.
   Web of Science ®Google Scholar
• Gupta, K.; Manchanda, V.; Subramanian, M.; Singh, R. Thermodynamics of Extraction of Uranium(VI) and Plutonium(IV) with Some Long-Chain Aliphatic Amides. Radiochim. Acta. 1999, 85(3–4), 103. DOI: 10.1524/ract.1999.85.34.103.
   Web of Science ®Google Scholar
• Vasudevan, T.; Murali, M.; Nagar, M.; Mathur, J. Extraction of U(VI) from Nitrate and Thiocyanate Media with Monoamides. Solvent Extr. Ion Exch. 2002, 20(6), 665–686. DOI: 10.1081/SEI-120016072.
   Web of Science ®Google Scholar
• Acher, E.; Cherkaski, Y.; Dumas, T.; Tamain, C.; Guillaumont, D.; Boubals, N.; Javierre, G.; Hennig, C.; Solari, P. L.; Charbonnel, M.-C. Structures of plutonium(IV) and uranium(VI) with N,N-dialkyl Amides from Crystallography, X-Ray Absorption Spectra, and Theoretical Calculations. Inorg. Chem. 2016, 55(11), 5558–5569. DOI: 10.1021/acs.inorgchem.6b00592.
   PubMed Web of Science ®Google Scholar
• Acher, E.; Dumas, T.; Tamain, C.; Boubals, N.; Solari, P.; Guillaumont, D. Inner to Outer-Sphere Coordination of Plutonium(Iv) with N,N-dialkyl Amide: Influence of Nitric Acid. Dalton Trans. 2017, 46(12), 3812–3815. DOI: 10.1039/c7dt00031f.
   PubMed Web of Science ®Google Scholar
• Vaughn, J.;. 5. Amide. In The Chemistry of Non-Aqueous Solvents: Acidic and Basic Solvents; Lagowski, J., Ed.; New York; London: Academic Press, 1967; Vol. 2, pp. 192–258.
   Google Scholar
• Condamines, N.;. A Contribution to the Study of the Extraction of Ineral Acids and of actinides(IV) and (VI) Cations by N, N-Dialkylamides; University Pierre et Marie Curie (Paris VI), 1989.
   Google Scholar