188
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO3-Ph-BTP and SO3-Ph-BTBP Ligands

, ORCID Icon, ORCID Icon & ORCID Icon

References

  • Miguirditchian, M.; Chareyre, L.; Sorel, C.; Bisel, I.; Baron, P.; Masson, M. Development of the GANEX Process for the Reprocessing of Gen IV Spent Nuclear Fuels. Proc. ATALANTE 2008, Montpellier, France, O1_14, May 19–22, 2008; pp. 1–4.
  • Aneheim, E.; Ekberg, C.; Fermvik, A.; Foreman, M. R. S. J.; Retegan, T.; Skarnemark, G. A TBP/BTBP-based GANEX Separation Process. Part 1: Feasibility. Solvent Extr. Ion Exch. 2010, 28, 437–458. DOI: 10.1080/07366299.2010.480930.
  • Carrott, M.; Geist, A.; Hères, X.; Lange, S.; Malmbeck, R.; Miguirditchian, M.; Modolo, G.; Wilden, A.; Taylor, R. Distribution of Plutonium, Americium and Interfering Fission Products between Nitric Acid and a Mixed Organic Phase of TODGA and DMDOHEMA in Kerosene, and Implications for the Design of the “EURO-GANEX” Process. Hydrometallurgy. 2015, 152, 139–148. DOI: 10.1016/j.hydromet.2014.12.019.
  • Modolo, G.; Geist, A.; Miguirditchian, M. Minor Actinide Separations in the Reprocessing of Spent Nuclear Fuels: Recent Advances in Europe. In Reprocessing and Recycling of Spent Nuclear Fuel; Taylor, R., Ed.; Woodhead Publishing: Cambridge, 2015; pp 245–287.
  • Lewis, F. W.; Harwood, L. M.; Hudson, M. J.; Afsar, A.; Laventine, D. M.; Šťastnác, K.; John, J.; Distler, P. Separation of the Minor Actinides americium(III) and curium(III) by Hydrophobic and Hydrophilic BTPhen Ligands: Exploiting Differences in Their Rates of Extraction and Effective Separations at Equilibrium. Solvent Extr. Ion Exch. 2018, 36, 115–135. DOI: 10.1080/07366299.2018.1429358.
  • Geist, A.; Müllich, U.; Magnusson, D.; Kaden, P.; Modolo, G.; Wilden, A.; Zevaco, T. Actinide(III)/lanthanide(III) Separation via Selective Aqueous Complexation of actinides(III) Using a Hydrophilic 2,6-bis(1,2,4-triazin-3-yl)pyridine in Nitric Acid. Solvent Extr. Ion Exch. 2010, 30, 433–444. DOI: 10.1080/07366299.2012.671111.
  • Muellich, U.; Geist, A.; Zevaco, T. Water-soluble Bis-triazinyl-pyridines, Bipyridines and Terpyridines, Synthesis and Use of Same. EP. 2011, 2377861, A1.
  • Shannon, R. D. Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides. Acta Cryst. 1976, A32, 751–767. DOI: 10.1107/S0567739476001551.
  • Steczek, L.; Narbutt, J.; Charbonnel, M.-C.; Moisy, P. Determination of Formation Constants of uranyl(VI) Complexes with a Hydrophilic SO3-Ph-BTP Ligand, Using Liquid-liquid Extraction. Nukleonika. 2015, 60, 821–827. DOI: 10.1515/nuka-2015-0150.
  • Steczek, Ł.; Rejnis, M.; Narbutt, J.; Charbonnel, M.-C.; Moisy, P. On the Stoichiometry and Stability of americium(III) Complexes with a Hydrophilic SO3-Ph-BTP Ligand, Studied by Liquid-liquid Extraction. J. Radioanal. Nucl. Chem. 2016, 309, 891–897. DOI: 10.1007/s10967-015-4663-7.
  • Reilly, S. D.; Gaunt, A. J.; Scott, B. L.; Modolo, G.; Iqbal, M.; Verboom, W.; Sarsfield, M. J. Plutonium(IV) Complexation by Diglycolamide Ligands - Coordination Chemistry Insight into TODGA-based Actinide Separations. Chem. Commun. 2012, 48, 9732–9734. DOI: 10.1039/c2cc34967a.
  • Rode, J. E.; Narbutt, J.; Dudek, M. K.; Kaźmierski, S.; Dobrowolski, J. C. On the Conformation of the Actinide-selective Hydrophilic SO3-Ph-BTP Ligand in Aqueous Solution. A Computational Study. J. Mol. Liq. 2016, 219, 224–231. DOI: 10.1016/j.molliq.2016.02.085.
  • Ruff, C.; Spektroskopische und thermodynamische Untersuchung der Komplexierung von Cm(III) und Eu(III) mit hydrophilen Bis-Triazinylpyridinen. Doctoral dissertation, Ruprecht-Karls-Universität Heidelberg, 2013; pp. 49–52. www.ub.uni-heidelberg.de/archiv/16784.
  • Wagner, C.; Müllich, U.; Geist, A.; Panak, P. J. TRLFS Study on the Complexation of Cm(III) and Eu(III) with SO3-Ph-BTBP. Dalton Trans. 2015, 44, 17143–17151. DOI: 10.1039/c5dt02923f.
  • Lemire, R. J.; Fuger, J.; Nitsche, H.; Potter, P.; Rand, M. H.; Rydberg, J.; Spahiu, K.; Sullivan, J. C.; Ullman, W. J.; Vitorge, P.; Wanner, H. Chemical Thermodynamics of Neptunium and Plutonium; OECD Nuclear Energy Agency, Data Bank, Issy-les-Moulineaux (France), Elsevier: Amsterdam, 2001; pp 62.
  • Rand, M. H.; Fuger, J.; Grenthe, I.; Neck, V.; Rai, D. Chemical Thermodynamics of Thorium; OECD Nuclear Energy Agency, Data Bank, Issy-les-Moulineaux (France), Elsevier: Amsterdam, 2008; pp 317.
  • Stary, J. The Use of Solvent Extraction of Metal Chelates for the Investigation of Complexation in Aqueous Solutions. In Solvent Extraction Chemistry. Proceedings of the International Conference Held at Gothenburg Sweden; Dyrssen, D., Liljenzin, J. O., Rydberg, J., Eds.; North-Holland Publ: Amsterdam, 1967; pp 1–10.
  • Ruff, C. M.; Müllich, U.; Geist, A.; Panak, P. J. Complexation of Cm(III) and Eu(III) with Hydrophilic 2,6-bis(1,2,4-triazin-3-yl)-pyridine Studied by Time-resolved Laser Fluorescence Spectroscopy. Dalton Trans. 2012, 41, 14594–14602. DOI: 10.1039/c2dt31748f.
  • Steczek, L.; Complexation of Actinides Am(III), Th(IV), Pu(IV) and U(VI) with poly-N-dentate Ligands SO3-Ph-BTP and SO3-Ph-BTBP. Doctoral dissertation, University of Montpellier (France) and Institute of Nuclear Chemistry and Technology (Poland), 2016; pp. 86–96. http://www.biu-montpellier.fr/florabium/jsp/nnt.jsp?nnt=2016MONTT238.
  • Pacary, V.; Burdet, F.; Duchesne, M.-T. Experimental and Modeling of Extraction of Lanthanides in System HNO3-TEDGA-{DMDOHEMA-HDEHP}. Procedia Chem. 2012, 7, 328–333. DOI: 10.1016/j.proche.2012.10.052.
  • Chapron., S.; Marie, C.; Arrachart, G.; Miguirditchian, M.; Pellet-Rostaing, S. New Insight into the Americium/curium Separation by Solvent Extraction Using Diglycolamides. Solvent Extr. Ion Exch. 2015, 33, 236–248. DOI: 10.1080/07366299.2014.1000792.
  • Herdzik-Koniecko, I.; Wagner, C.; Trumm, M.; Müllich, U.; Schimmelpfennig, B.; Narbutt, J.; Geist, A.; Panak, P. J. Do An(III) and Ln(III) ions form heteroleptic complexes with diglycolamide and hydrophilic BT(B)P ligands in solvent extraction systems? A spectroscopic and DFT study. New J. Chem. 2019, 43, 6314-6322. DOI: 10.1039/c9nj00651f.
  • Steczek, L.; Narbutt, J.; Moisy, P.; Charbonnel, M.-C. Solvent Extraction Investigations on Th and Pu(IV) Complexes with Hydrophilic SO3-Ph-BTP and SO3-Ph-BTBP Ligands. ATALANTE 2016 – Nuclear Chemistry for Sustainable Fuel Cycles, Montpellier, France, oral presentation: ATAL2016-065, Book of Abstracts, June 5–10, 2016; pp. 77.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.