Development of a Selective Americium Separation Process Using H₄TPAEN as Water-Soluble Stripping Agent

References

• Poinssot, C.; Rostaing, C.; Baron, P.; Warin, D.; Boullis, B. Main Results of the French Program on Partitioning of Minor Actinides, a Significant Improvement Towards Nuclear Waste Reduction. Procedia Chem. 2012, 7, 358–366. DOI: 10.1016/j.proche.2012.10.056.
   Google Scholar
• Poinssot, C.; Rostaing, C.; Greandjean, S.; Boullis, B. Recycling the Actinides, the Cornerstone of Any Sustainable Nuclear Fuel Cycles. Procedia Chem. 2012, 7, 349–357. DOI: 10.1016/j.proche.2012.10.055.
   Google Scholar
• Serp, J.; Poinssot, C.; Bourg, S. Assessment of the Anticipated Environmental Footprint of Future Nuclear Energy Systems. Evidence of the Beneficial Effect of Extensive Recycling. Energies. 2017, 10(9), 1445.
   Web of Science ®Google Scholar
• Pearson, R. G.;. Hard and Soft Acids and Bases. J. Am. Chem. Soc. 1963, 85(22), 3533–3539. DOI: 10.1021/ja00905a001.
   Web of Science ®Google Scholar
• Adnet, J.-M.; Donnet, L.; Brossard, P.; Bourges, J.; Process for the Oxidation of Am(III) to Am(VI) Usable for Separating Americium from Spent Nuclear Fuel Reprocessing Solutions. Patent US5609745, 1997.
   Google Scholar
• Chartier, D.; Donnet, L.; Adnet, J. M. Electrochemical Oxidation of Am(III) with Lacunary Heteropolyanions and Silver Nitrate. Radiochim. Acta. 1998, 83, 129. DOI: 10.1524/ract.1998.83.3.129.
   Web of Science ®Google Scholar
• McCann, K.; Mincher, B. J.; Schmitt, N. C.; Braley, J. C. Hexavalent Actinide Extraction Using N,N-Dialkyl Amides. Ind. Eng. Chem. Res. 2017, 56(22), 6515–6519. DOI: 10.1021/acs.iecr.7b01181.
   Web of Science ®Google Scholar
• Martin, L. R.; Mincher, B. J.; Schmitt, N. C. Extraction of americium(VI) by a Neutral Phosphonate Ligand. J. Radioanal. Nucl. Chem. 2009, 282(2), 523–526. DOI: 10.1007/s10967-009-0153-0.
   Web of Science ®Google Scholar
• Mincher, B. J.; Martin, L. R.; Schmitt, N. C. Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium. Inorg. Chem. 2008, 47(15), 6984–6989. DOI: 10.1021/ic800667h.
   PubMed Web of Science ®Google Scholar
• Runde, W. H.; Mincher, B. J. Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations. Chem. Rev. 2011, 111(9), 5723–5741. DOI: 10.1021/cr100181f.
   PubMed Web of Science ®Google Scholar
• Burns, J. D.; Shehee, T. C.; Clearfield, A.; Hobbs, D. T. Separation of Americium from Curium by Oxidation and Ion Exchange. Anal. Chem. 2012, 84(16), 6930–6932. DOI: 10.1021/ac3018394.
   PubMed Web of Science ®Google Scholar
• Mincher, B. J.; Schmitt, N. C.; Schuetz, B. K.; Shehee, T. C.; Hobbs, D. T. Recent Advances in F-element Separations Based on a New Method for the Production of Pentavalent Americium in Acidic Solution. RSC Adv. 2015, 5(34), 27205–27210. DOI: 10.1039/C5RA03196F.
   Web of Science ®Google Scholar
• Shehee, T.; Martin, L. R.; Zalupski, P. R.; Nash, K. L. Redox-Based Separation of Americium from Lanthanides in Sulfate Media. Sep. Sci. Technol. 2010, 45(12–13), 1743–1752
   Web of Science ®Google Scholar
• Modolo, G.; Nabet, S. Thermodynamic Study on the Synergistic Mixture of Bis(chlorophenyl)dithiophosphinic Acid and Tris(2-ethylhexyl)phosphate for Separation of Actinides(III) from Lanthanides(III). Solvent Extr. Ion Exch. 2005, 23(3), 359–373. DOI: 10.1081/SEI-200056515.
   Web of Science ®Google Scholar
• Modolo, G.; Odoj, R.; Method for Separating Trivalent Americium from Trivalent Curium. Patent WO2005021810, 2005.
   Google Scholar
• Modolo, G.; Kluxen, P.; Geist, A. Demonstration of the LUCA Process for the Separation of americium(III) from curium(III), californium(III), and lanthanides(III) in Acidic Solution Using a Synergistic Mixture of Bis(chlorophenyl)dithiophosphinic Acid and Tris(2-ethylhexyl)phosphate. Radiochim. Acta. 2010, 98(4), 193–201. DOI: 10.1524/ract.2010.1708.
   Web of Science ®Google Scholar
• Suzuki, H.; Tsubata, Y.; Matsumura, T. High-Performance Alkyl Diamide Amine and Water-soluble Diamide Ligand for Separating of Am(III) from Cm(III). Anal. Sci. 2017, 33(2), 239–242. DOI: 10.2116/analsci.33.239.
   PubMed Web of Science ®Google Scholar
• Lange, S.; Wilden, A.; Modolo, G.; Sadowski, F.; Gerdes, M.; Bosbach, D. Direct Selective Extraction of Trivalent Americium from PUREX Raffinate Using a Combination of CyMe4BTPhen and TEDGA—A Feasibility Study. Solvent Extr. Ion Exch. 2017, 35(3), 161–173. DOI: 10.1080/07366299.2017.1326761.
   Web of Science ®Google Scholar
• Marie, C.; Duchesne, M.-T.; Pacary, V.; Vanel, V.; Montuir, M.; Rudloff, D.; Bertrand, M.; Miguirditchian, M. Separation of Americium from a Concentrated Raffinate by Liquid-Liquid Extraction. Proceedings ISEC Conference, Würzburg, Germany, 2014, 105–110.
   Google Scholar
• Chapron, S.; Marie, C.; Arrachart, G.; Miguirditchian, M.; Pellet-Rostaing, S. New Insight into the Americium/Curium Separation by Solvent Extraction Using Diglycolamides. Solvent Extr. Ion Exch. 2015, 33(3), 236–248. DOI: 10.1080/07366299.2014.1000792.
   Web of Science ®Google Scholar
• Chapron, S.; Marie, C.; Pacary, V.; Duchesne, M. T.; Arrachart, G.; Pellet-Rostaing, S.; Miguirditchian, M. Separation of Americium by Liquid-Liquid Extraction Using Diglycolamides Water-Soluble Complexing Agents. Procedia Chem. 2016, 21, 133–139. DOI: 10.1016/j.proche.2016.10.019.
   Google Scholar
• Vanel, V.; Bollesteros, M. J.; Marie, C.; Montuir, M.; Pacary, V.; Antégnard, F.; Costenoble, S.; Boyer-Deslys, V. Consolidation of the EXAm Process: Towards the Reprocessing of a Concentrated PUREX Raffinate. Procedia Chem. 2016, 21, 190–197. DOI: 10.1016/j.proche.2016.10.027.
   Google Scholar
• Rostaing, C.; Poinssot, C.; Warin, D.; Baron, P.; Lorrain, B. Development and Validation of the EXAm Separation Process for Single Am Recycling. Procedia Chem. 2012, 7, 367–373. DOI: 10.1016/j.proche.2012.10.057.
   Google Scholar
• Modolo, G.; Geist, A.; Miguirditchian, M. Minor Actinide Separations in the Reprocessing of Spent Nuclear Fuels: Recent Advances in Europe. In Reprocessing and Recycling of Spent Nuclear Fuel; Taylor, R., Ed.; Woodhead Publishing: Oxford, 2015; pp 245–287.
   Google Scholar
• Marie, C.; Vanel, V.; Watanabe, S.; Duchesne, M.-T.; Zorz, N.; Berthon, L. Behavior of Molybdenum (VI) in {dmdohema–Hdehp/nitric Acid} Liquid–Liquid Extraction Systems. Solvent Extr. Ion Exch. 2016, 34(5), 407–421. DOI: 10.1080/07366299.2016.1208029.
   Web of Science ®Google Scholar
• Borrini, J.; Favre-Reguillon, A.; Lemaire, M.; Gracia, S.; Arrachart, G.; Bernier, G.; Hérès, X.; Hill, C.; Pellet-Rostaing, S. Water Soluble PDCA Derivatives for Selective Ln(III)/An(III) and Am(III)/Cm(III) Separation. Solvent Extr. Ion Exch. 2015, 33(3), 224–235. DOI: 10.1080/07366299.2014.974449.
   Web of Science ®Google Scholar
• Gracia, S.; Arrachart, G.; Marie, C.; Chapron, S.; Miguirditchian, M.; Pellet-Rostaing, S. Separation of Am (III) by Solvent Extraction Using Water-soluble H4tpaen Derivatives. Tetrahedron. 2015, 71(33), 5321–5336. DOI: 10.1016/j.tet.2015.06.015.
   Web of Science ®Google Scholar
• Geist, A.; Taylor, R.; Ekberg, C.; Guilbaud, P.; Modolo, G.; Bourg, S. The SACSESS Hydrometallurgy Domain — An Overview. Procedia Chem. 2016, 21, 218–222. DOI: 10.1016/j.proche.2016.10.031.
   Google Scholar
• Heres, X.; Burdet, F.; Borrini, J.; Duchesne, M.-T.; Mazzanti, M.; Bernier, G.; Pellet-Rostaing, S.; Favre-Reguillon, A.; Lemaire, M.; Process for Separating Americium from Other Metallic Elements Present in an Acidic Aqueous or Organic Phase and Applications Thereof. Patent WO2012069573, 2011.
   Google Scholar
• Modolo, G.; Kaufholz, P.; Sadowski, F.; Lange, S.; Sypula, M.; Magnusson, D.; Müllich, U.; Geist, A.; Bosbach, D. Laboratory-Scale Counter-Current Centrifugal Contactor Demonstration of an Innovative-SANEX Process Using a Water Soluble BTP. Solvent Extr. Ion Exch. 2015, 33(2), 91–108. DOI: 10.1080/07366299.2014.952532.
   Web of Science ®Google Scholar
• Boubals, N.; Wagner, C.; Dumas, T.; Chanèac, L.; Manie, G.; Kaufholz, P.; Marie, C.; Panak, P. J.; Modolo, G.; Geist, A.; et al. Complexation of Actinide(III) and Lanthanide(III) with H4TPAEN for a Separation of Americium from Curium and Lanthanides. Inorg. Chem. 2017, 56(14), 7861–7869. DOI: 10.1021/acs.inorgchem.7b00603.
   PubMed Web of Science ®Google Scholar
• Huang, P.-W.; Wang, C.-Z.; Wu, Q.-Y.; Lan, J.-H.; Song, G.; Chai, Z.-F.; Shi, W.-Q. Understanding Am3+/Cm3+ Separation with H4TPAEN and Its Hydrophilic Derivatives: A Quantum Chemical Study. Phys. Chem. Chem. Phys. 2018, 20(20), 14031–14039. DOI: 10.1039/c7cp08441b.
   PubMed Web of Science ®Google Scholar
• Geist, A.; Modolo, G. TODGA Process Development: An Improved Solvent Formulation. Proceedings of GLOBAL (The Nuclear Fuel Cycle: Sustainable Options & Industrial Perspectives), Paris, 6–11 September 2009. ( paper 9193), 1022–1026.
   Google Scholar
• Chatterton, N.; Bretonnière, Y.; Pécaut, J.; Mazzanti, M. An Efficient Design for the Rigid Assembly of Four Bidentate Chromophores in Water-Stable Highly Luminescent Lanthanide Complexes. Angew. Chem. Int. Ed. 2005, 44(46), 7595–7598. DOI: 10.1002/anie.200502231.
   PubMed Web of Science ®Google Scholar
• Sasaki, Y.; Kitatsuji, Y.; Tsubata, Y.; Sugo, Y.; Morita, Y. Separation of Am, Cm and Lanthanides by Solvent Extraction with Hydrohilic and Lipophilic Organic Ligands. Solvent Extr. Res. Dev., Jpn. 2011, 18, 93–101. DOI: 10.15261/serdj.18.93.
   Web of Science ®Google Scholar
• Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S.; Extractants, T. N.; Diglycolamides, F. The Extraction of Lanthanides and Actinides in HNO3–N-Dodecane System. Solvent Extr. Ion Exch. 2001, 19(1), 91–103. DOI: 10.1081/SEI-100001376.
   Web of Science ®Google Scholar
• Wilden, A.; Modolo, G.; Kaufholz, P.; Sadowski, F.; Lange, S.; Sypula, M.; Magnusson, D.; Müllich, U.; Geist, A.; Bosbach, D. Laboratory-Scale Counter-Current Centrifugal Contactor Demonstration of an Innovative-SANEX Process Using a Water Soluble BTP. Solvent Extr. Ion Exch. 2015, 33(2), 91–108. DOI: 10.1080/07366299.2014.952532.
   Web of Science ®Google Scholar
• Hubscher-Bruder, V.; Mogilireddy, V.; Michel, S.; Leoncini, A.; Huskens, J.; Verboom, W.; Galán, H.; Núñez, A.; Cobos, J.; Modolo, G.; et al. Behaviour of the Extractant Me-TODGA upon Gamma Irradiation: Quantification of Degradation Compounds and Individual Influences on Complexation and Extraction. New J. Chem. 2017, 41(22), 13700–13711. DOI: 10.1039/C7NJ02136D.
   Web of Science ®Google Scholar
• Ansari, S. A.; Pathak, P. N.; Husain, M.; Prasad, A. K.; Parmar, V. S.; Manchanda, V. K. Extraction of Actinides Using N, N, N′, N′-tetraoctyl Diglycolamide (TODGA): A Thermodynamic Study. Radiochim. Acta. 2006, 94(6–7), 307. DOI: 10.1524/ract.2006.94.6.307.
   Web of Science ®Google Scholar
• Arisaka, M.; Kimura, T. Thermodynamic and Spectroscopic Studies on Am(III) and Eu(III) in the Extraction System of N,N,N’,N’-Tetraoctyl-3-Oxapentane-1,5-Diamide in n-Dodecane/Nitric Acid. Solvent Extr. Ion Exch. 2011, 29(1), 72–85. DOI: 10.1080/07366299.2011.539127.
   Web of Science ®Google Scholar
• Bell, K.; Geist, A.; McLachlan, F.; Modolo, G.; Taylor, R.; Wilden, A. Nitric Acid Extraction into TODGA. Procedia Chem. 2012, 7, 152–159. DOI: 10.1016/j.proche.2012.10.026.
   Google Scholar