The Formation of Me(AOT)_n Micelles as Nanoreactors, Crystallizers, and Charging Agents: Cation-Exchange Solvent Extraction versus Direct Injection Solubilization

References

• Martinez, A. V.; Dominguez, L.; Malolepsza, E.; Moser, A.; Ziegler, Z.; Straub, J. E. Probing the Structure and Dynamics of Confined Water in AOT Reverse Micelles. J. Phys. Chem. B. 2013, 117, 7345−7351. DOI: 10.1021/jp402270e.
   PubMedGoogle Scholar
• Eastoe, J.; Hollamby, M. J.; Hudson, L. Recent Advances in Nanoparticle Synthesis with Reversed Micelles. Adv. Colloid Interface Sci. 2006, 128(130), 5−15. DOI: 10.1016/j.cis.2006.11.009.
   PubMedGoogle Scholar
• Bulavchenko, A. I.; Demidova, M. G.; Beketova, D. I. Preparation of Ultradispersed KNO3 Powders in Mixed Reverse Micelles of Tergitol NP4 + AOT by Isothermal Evaporation Crystallization. Cryst. Growth Des. 2013, 13(2), 485−490. DOI: 10.1021/cg300721q.
   Web of Science ®Google Scholar
• Talukder, M. R.; Susanto, D.; Feng, G.; Wu, J.; Choi, W. J.; Chow, Y. Improvement in Extraction and Catalytic Activity of Mucor Javanicus Lipase by Modification of AOT Reverse Micelle. Biotechnol. J. 2007, 2, 1369−1374. DOI: 10.1002/biot.200700099.
   PubMedGoogle Scholar
• Tang, L. L.; Ryabov, A. D.; Collins, T. J. Kinetic Evidence for Reactive Dimeric TAML Iron Species in the Catalytic Oxidation of NADH and a Dye by O2 in AOT Reverse Micelles. ACS Catal. 2016, 6, 3713–3718. DOI: 10.1021/acscatal.6b00787.
   Web of Science ®Google Scholar
• Neuman, R. D.; Zhou, N.-F.; Wu, J.; Jones, M. A.; Gaonkar, A. G.; Parks, S. J.; Agrawal, M. L. General Model for Aggregation of Metal-extractant Complexes in Acidic Organophosphorus Solvent Extraction Systems. Sep. Sci. Technol. 1990, 25(13–15), 1655–1674. DOI: 10.1080/01496399008050415.
   Web of Science ®Google Scholar
• Jackson, A.; Nilsson, M. Synergism and Aggregation in Multi-Extractant Solvent Extraction Systems. Solvent Extr. Ion Exch. 2019, 37(3–4), 269–283. DOI: 10.1080/07366299.2019.1639367.
   Web of Science ®Google Scholar
• Krishna, S. H.; Srinivas, N. D.; Raghavarao, K. S. M. S.; Karanth, N. G. Reverse Micellar Extraction for Downstream Processing of Proteins/enzymes. Adv. Biochem. Engin. Biotechnol. 2002, 75, 119–183. DOI: 10.1007/3-540-44604-4_5.
   PubMedGoogle Scholar
• Urbanski, R.; Draye, M.; Cote, G.; Szymanowski, J. Removal of Bisphenol a from Aqueous Streams by Micellar Extraction and Ultrafiltration. Solvent Extr. Ion Exch. 2000, 18(3), 533–550. DOI: 10.1080/07366290008934696.
   Web of Science ®Google Scholar
• Rey, J.; Atak, S.; Dourdain, S.; Arrachart, G.; Berthon, L.; Pellet-Rostaing, S. Synergistic Extraction of Rare Earth Elements from Phosphoric Acid Medium Using a Mixture of Surfactant AOT and DEHCNPB. Solvent Extr. Ion Exch. 2017, 35(5), 321–331. DOI: 10.1080/07366299.2017.1362852.
   Web of Science ®Google Scholar
• Vijayalakshmi, C. S.; Gulari, E. Extraction of Trivalent Metals and Separation of Binary Mixtures of Metals Using Winsor II Microemulsion Systems. Sep. Sci. Technol. 1992, 27(2), 173–198. DOI: 10.1080/01496399208018872.
   Web of Science ®Google Scholar
• Caselli, M.; Mangone, A.; Pellegrino, T.; Traini, A. Selective Transition Metal Extraction by Reverse Micelles. Annali di Chimica. 2004, 94(1–2), 33–44. DOI: 10.1002/adic.200490003.
   PubMedGoogle Scholar
• Pal, S.; Visha, G.; Gandhi, K. S.; Ayappa, K. G. Ion Exchange in Reverse Micelles. Langmuir. 2005, 21(2), 767–778. DOI: 10.1021/la048771u.
   PubMed Web of Science ®Google Scholar
• Vijayalakshmi, C. S.; Gulari, E. An Improved Model for the Extraction of Multivalent Metals in Winsor II Microemulsion Systems. Sep. Sci. Technol. 1991, 26(2), 291–299. DOI: 10.1080/01496399108050473.
   Web of Science ®Google Scholar
• Paatero, E.; Sjoblom, J.; Datta, S. K. Microemulsion Formation and Metal Extraction in the System Water/aerosol OT/extractant/isooctane. J. Colloid Interface Sci. 1990, 138(2), 388–396. DOI: 10.1016/0021-9797(90)90222-A.
   Web of Science ®Google Scholar
• Naganawa, H.; Suzuki, H.; Yanase, N.; Nagano, T.; Noro, J. Reversed-micellar Extraction of Strontium(II) from Model Solutions of Seawater. Anal. Sci. 2011, 27(3), 321–324. DOI: 10.2116/analsci.27.321.
   PubMed Web of Science ®Google Scholar
• Gao, S.; Shen, X.; Chen, Q.; Gao, H. Solvent Extraction of Thorium(IV) Using W/O Microemulsion. Sci. China Chem. 2012, 55(9), 1712–1718. DOI: 10.1007/s11426-012-4686-7.
   Web of Science ®Google Scholar
• Liu, F.; Yang, Y.; Lu, Y.; Shang, K.; Lu, W.; Zhao, X. Extraction of Germanium by the AOT Microemulsion with N235 System. Ind. Eng. Chem. Res. 2010, 49(20), 10005–10008. DOI: 10.1021/ie100963t.
   Web of Science ®Google Scholar
• Naganawa, H.; Suzuki, H.; Tachimori, S. Cooperative Effect of Carbamoylmethylene Phosphine Oxide on the Extraction of Lanthanides (III) to Water-in-oil Microemulsion from Concentrated Nitric Acid Medium. Phys. Chem. Chem. Phys. 2000, 2, 3247–3253. DOI: 10.1039/b001710h.
   Web of Science ®Google Scholar
• Kubota, F.; Shinohara, K.; Shimojo, K.; Oshima, T.; Goto, M.; Furusaki, S.; Hano, T. Extraction of Rare Earth Metals by Calix[4]arene Solubilized in AOT Reversed Micellar Solution. Sep. Purif. Technol. 2001, 24(1–2), 93–100. DOI: 10.1016/S1383-5866(00)00215-X.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Arymbaeva, A. T.; Bulavchenko, O. A.; Tatarchuk, V. V.; Petrova, N. I. The Preparation of Gold Nanoparticles in Triton N-42 Reverse Micelles after Preliminary Concentration from Acid Sulfate-chloride Solutions. Russ. J. Phys. Chem. 2006, 80(12), 1980–1985. DOI: 10.1134/S0036024406120181.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Arymbaeva, A. T.; Tatarchuk, V. V. The Kinetics of Synthesis and Mechanism of Coagulation of Gold Nanoparticles in Triton N-42 Reverse Micelles. Russ. J. Phys. Chem. 2008, 82(5), 801–806. DOI: 10.1134/S003602440805018X.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Podlipskaya, T. Y.; Arymbaeva, A. T. Extraction-Electrophoretic Concentration of Gold by Reverse Mixed Micelles of Triton N-42 and AOT. Sep. Sci. Technol. 2011, 46(1), 54–63. DOI: 10.1080/01496395.2010.493547.
   Web of Science ®Google Scholar
• López-Quintela, M. А.;. Synthesis of Nanomaterials in Microemulsions: Formation Mechanisms and Growth Control. Cur. Opinion Colloid Interface Sci. 2003, 8(2), 137–144. DOI: 10.1016/S1359-0294Ž03.00019-0.
   Web of Science ®Google Scholar
• Guo, F.; Li, H.; Zhang, Z.; Meng, S.; Li, D. Synthesis of REF3 (RE=Nd, Tb) Nanoparticles via a Solvent Extraction Route. Mater. Res. Bull. 2009, 44, 1565–1568. DOI: 10.1016/j.materresbull.2009.02.001.
   Web of Science ®Google Scholar
• Seo, D.; Yoon, W.; Park, S.; Kim, J.; Kim, J. The Preparation of Hydrophobic Silver Nanoparticles via Solvent Exchange Method. Colloids Surf. A: Physicochem. Eng. Aspects. 2008, 313–314, 158–161. DOI: 10.1016/j.colsurfa.2007.04.086.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Arymbaeva, A. T.; Demidova, M. G.; Popovetskiy, P. S.; Plusnin, P. E.; Bulavchenko, O. A. Synthesis and Concentration of Organosols of Silver Nanopartcles Stabilized by AOT: Emulsion versus Microemulsion. Langmuir. 2018, 34(8), 2815−2822. DOI: 10.1021/acs.langmuir.7b04071.
   PubMed Web of Science ®Google Scholar
• Bulavchenko, A. I.; Shaparenko, N. O.; Demidova, M. G. Synthesis, Characterization, and Electrophoretic Concentration of Titanium Dioxide Nanoparticles in AOT Microemulsions. Electrophoresis. 2017, 38(13–14), 1678–1684. DOI: 10.1002/elps.201600542.
   PubMed Web of Science ®Google Scholar
• Bulavchenko, A. I.; Pletnev, D. N. Electrophoretic Concentration of Nanoparticles of Gold in Reversed Micellar Solutions of AOT. J. Phys. Chem. C. 2008, 112(42), 16365–16369. DOI: 10.1021/jp805268w.
   Web of Science ®Google Scholar
• Bergenholtz, J.; Romagnoli, A. A.; Wagner, N. J. Viscosity, Microstructure, and Interparticle Potential of AOT/H2O/n-Decane Inverse Microemulsions. Langmuir. 1995, 11(5), 1559–1570. DOI: 10.1021/la00005a025.
   Web of Science ®Google Scholar
• Bardakhanov, S. P.; Korchagin, A. I.; Kuksanov, N. K.; Larukhin, A. V.; Salimov, R. A.; Fadeev, S. N.; Cherepkov, V. V. Nanopowder Production Based on Technology of Solid Raw Substances Evaporation by Electron Beam Accelerator. Mater. Sci. Eng. B. 2006, 132, 204–208. DOI: 10.1016/j.mseb.2006.02.038.
   Google Scholar
• Kuo, S.; Osterle, F. High Field Electrophoresis in Low Conductivity Liquids. J. Colloid Interface Sci. 1967, 25, 421–428. DOI: 10.1016/0021-9797(67)90050-1.
   Web of Science ®Google Scholar
• Schwarzenbach, G.; Flaschka, H. Die komplexometrische Titration; Ferdinand enke Verlang: Stuttgart, 1965.
   Google Scholar
• Valero, M.; Sanchez, F.; Gomez-Herrera, C.; Lopez-Cornejo, P. Study of Water Solubilized in AOT/n-decane/water Microemulsions. Chem. Phys. 2008, 345(1), 65–72. DOI: 10.1016/j.chemphys.2008.01.048.
   Web of Science ®Google Scholar
• Zhou, G.-W.; Li, G.-Z.; Chen, W.-J. Fourier Transform Infrared Investigation on Water States and the Conformations of Aerosol-OT in Reverse Microemulsions. Langmuir. 2002, 18(12), 4566–4571. DOI: 10.1021/la0116241.
   Web of Science ®Google Scholar
• Smith, D. W.;. Ionic Hydration Enthalpies. J. Chem. Educ. 1977, 54, 540−542. DOI: 10.1021/ed054p540.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Beketova, D. I.; Podlipskaya, T. Y.; Demidova, M. G. Composition and Size of Reverse Micelles Tergitol NP-4 and Tergitol NP-4 + AOT in N-decane during Isothermal Mass Crystallization of KNO3. Cryst. Growth Des. 2014, 14(3), 1142−1148. DOI: 10.1021/cg401610m.
   Web of Science ®Google Scholar
• Kolodin, A. N.; Bulavchenko, A. I. Contact Angle and Free Surface Energy of CdS Films on Polystyrene Substrate. Appl. Surf. Sci. 2019, 463, 820–828. DOI: 10.1016/j.apsusc.2018.08.176.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Beketova, D. I.; Demidova, M. G.; Podlipskaya, T. Y. Ion-exchange Processes between Surface Layer and Core of Reverse Micelles of NaAOT+Tergitol NP-4 during Evaporation Crystallization of KNO3. Cryst. Growth Des. 2017, 17, 5216–5222. DOI: 10.1021/acs.cgd.7b00718.
   Web of Science ®Google Scholar
• Michor, E. L.; Berg, J. C. The Particle Charging Behavior of Ion-Exchanged Surfactants in Apolar Media. Colloids Surf. A: Physicochem. Eng. Aspects. 2017, 512, 1–6. DOI: 10.1016/j.colsurfa.2016.10.032.
   Web of Science ®Google Scholar
• Bulavchenko, A. I.; Popovetskiy, P. S. Structure of Adsorption Layer of Silver Nanoparticles in Sodium Bis(2-ethylhexyl) Sulfosuccinate Solutions in n-Decane as Observed by Photon-Correlation Spectroscopy and Nonaqueous Electrophoresis. Langmuir. 2014, 30(43), 12729−12735. DOI: 10.1021/la5004935.
   PubMed Web of Science ®Google Scholar