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Articles

1-methyl-2,4,5-trinitroimidazole (MTNI), a melt-cast explosive: synthesis and studies on thermal behavior in presence of explosive ingredients

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References

  • Agrawal, J. P. 2010. High energy materials: Propellants, explosives and pyrotechnics. Verlag GmbH & Co. KGaA, Weinheim: Wiley-VCH. ISBN: 978-3-527-32610-5.
  • Agrawal, J. P., and R. D. Hodgson. 2007. Organic chemistry of explosives. USA: John Wiley & Sons. ISBN: 9780470059364.
  • Anniyappan, M., S. H. Sonawane, S. J. Pawar, and A. K. Sikder. 2015. Thermal decomposition and kinetics of 2,4-dinitroimidazole: An insensitive high explosive. Thermochemica Acta 93–99. doi:10.1016/j.tca.2015.05.027.
  • Bayat, Y., J. Mokhtari, N. Farhadian, and M. Bayat. 2012. Heteropolyacids: An efficient catalyst for synthesis of CL-20. Journal of Energetic Materials 30:124–34. doi:10.1080/07370652.2010.549539.
  • Cho, J. R., K. J. Kim, S. G. Cho, and J. K. Kim. 2002. Synthesis and characterization of 1-methyl-2,4,5-trinitroimidazole (MTNI). Journal of Heterocyclic Chemistry 39:141–47. doi:10.1002/jhet.v39:1.
  • Fordham, S. 1980. High explosives and propellants. 2nd ed. New York: Pergamon Press.
  • Hodges, R., and M. R. Grimmett. 1968. The mass spectra of imidazole and 1-methylimidazole. Australian Journal of Chemistry 21:1085–87. doi:10.1071/CH9681085.
  • Jadhav, H. S., M. B. Talawar, R. Sivabalan, D. D. Dhavale, S. N. Asthana, and V. N. Krishnamurthy. 2007. Synthesis, characterization and thermolysis studies on new derivatives of 2,4,5-trinitroimidazoles: Potential insensitive high energy materials. Journal of Hazardous Materials 161:192–97. doi:10.1016/j.jhazmat.2006.09.014.
  • Minier, L., and R. Behrens. 1996. Mass spectra of 2,4-dinitroimidazole and its isotopomers using simultaneous thermogravimetric modulated beam mass spectrometry. Journal of Mass Spectrometry 31:25. doi:10.1002/(SICI)1096-9888(199601)31:1<25::AID-JMS252>3.0.CO;2-C.
  • Raja, D., R. D. Paritosh, S. Rao, and P. Damon. 2009. Nucleophilic substitution reactions of 1-methyl-2,4,5-trinitroimidazole (MTNI). Synthetic Communications 39:4282–88. doi:10.1080/00397910902898635.
  • Reddy, D., G. Nathaniel, S. Rao, M.-A.-X. Zhang, D. Raja, and D. Paritosh, 2009. Novel melt-cast explosive material: 1-methyl-2,4,5-trinitroimidazole (MTNI). Proceedings of the 12th Seminar on New Trends in Research of Energetic Materials (NTREM), Pardubice, April 1-3, 107
  • Reddy, D., S. Rao, G. Nathaniel, D. Raja, Z. MaoXi, and D. Paritosh, 2007. Melt-cast explosive material, U.S. Patent. US 7304164 B1.
  • Sabatini, J. J., and K. D. Oyler. 2016. Recent advances in the synthesis of high explosive materials. Crystals 6:5. doi:10.3390/cryst6010005.
  • Samuels, P., 2012. Process improvement and optimization of insensitive explosive IMX-101. Presented at the Insensitive Munitions and Energetic Materials (IMEM) Symposium, May 14−17.
  • Sikder, N., A. K. Sikder, N. R. Bulakh, and B. R. Gandhe. 2004. 1,3,3-Trinitroazetidine (TNAZ): A melt-cast explosive: Synthesis, characterization and thermal behavior. Journal of Hazardous Materials 113:35–43. doi:10.1016/j.jhazmat.2004.06.002.
  • Simpson, R. L., C. L. Coon, M. F. Folts, and P. F. Pagoria. 1995. A new insensitive explosive that has moderate performance and is low cost: 2,4 dinitroimidazole. Report LA 1–7. Los Alamos, NM, USA: Los Alamos National Laboratory.
  • Talawar, M. B., R. Sivabalan, M. Anniyappan, G. M. Gore, S. N. Asthana, and B. R. Gandhe. 2007. Emerging trends in advance high energy materials. Combustion, Explosion, Shock Wave 43:62–72.

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