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Original Articles

Micro-phase separation and configuration of ABC triblock copolymer in ultra-thin film by Monte Carlo simulation

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Pages 1083-1091 | Received 01 Mar 2007, Accepted 01 Jul 2007, Published online: 20 Nov 2007

References

  • Goodman , I. 1982 . Development in Block Copolymers , New York : Applied Sciences .
  • Folks , M.J. 1985 . Processing, Structure and Properties of Block Copolymers , New York : Elsevier .
  • Malenfant , P.R.L. , Groenendaal , L. and Frechet , J.M.J. 1998 . Well-defined triblock hybrid dendrimers based on lengthy oligothiophene cores and poly(benzyl ether) dendrons . J. Am. Chem. Soc. , 120 : 10990
  • Minoura , N. and Higuchi , M. 1997 . Microphase-separated structure in triblock copolypeptide membranes composed of l-glutamic acid and l-leucine . Macromolecules , 30 : 1023
  • Urbas , A. , Fink , Y. and Thomas , E.L. 1999 . One-dimensionally periodic dielectric reflectors from self-assembled block copolymer-homopolymer blends . Macromolecules , 32 : 4748
  • Trinh , A.H. , Le , H.H. , Rameshwar , A. , Roland , W. , Michler , G.H. and Knoll , K. 2003 . Influence of interfacial structure on morphology and deformation behavior of SBS block copolymers . Polymer , 44 : 1237
  • Krishnamoorti , R. , Modi , M.A. , Tse , M.F. and Wang , H.C. 2000 . Pathway and kinetics of cylinder-to-sphere order–order transition in block copolymers . Macromolecules , 33 : 3810
  • Miyamoto , T. , Kodama , K. and Shibayama , K. 1970 . Structure and properties of a styrene–butadiene–styrene block copolymer . J. Polym. Sci. A , 8 : 2059
  • Peters , R.D. , Yang , X.M. and Nealey , P.F. 2002 . Morphology of thin films of diblock copolymers on surfaces micropatterned with regions of different interfacial energy . Macromolecules , 35 : 1822
  • Budkowski , A. , Bernasik , A. , Cyganik , P. , Raczkowska , J. , Penc , B. , Bergues , B. , Kowalski , K. , Rysz , J. and Janik , J. 2003 . Substrate-determined shape of free surface profiles in spin–cast polymer blend films . Macromolecules , 36 : 4060
  • Avgeropoulos , A. , Dair , B.J. , Hadjichristidis , N. and Thomas , E.L. 1997 . Tricontinuous double gyroid cubic phase in triblock copolymers of the ABA type . Macromolecules , 30 : 5634
  • Xu , T. , Zhu , Y. , Gido , S.P. and Russell , T.P. 2004 . Electric field alignment of symmetric diblock copolymer thin films . Macromolecules , 37 : 2625
  • Nakazawa , H. and Ohta , T. 1993 . Microphase separation of ABC-type triblock copolymers . Macromolecules , 26 : 5503
  • Matsen , M.W. 1998 . Gyroid versus double-diamond in ABC triblock copolymer melts . J. Chem. Phys. , 108 : 785
  • Ren , X.F. and Wei , J.C. 2003 . Triblock copolymer theory: free energy, disordered phase and weak segregation . Physica D. , 178 : 103
  • Feng , J. and Ruckenstein , E. 2002 . Monte Carlo simulation of triblock copolymer thin films . Polymer , 43 : 5775
  • Huang , Y.M. , Liu , H.L. and Hu , Y. 2006 . Monte Carlo simulations of the morphologies and conformations of triblock copolymer thin films . Macromol. Theory Simul. , 15 : 117
  • Matsen , M.W. 1997 . Thin films of block copolymer . J. Chem. Phys. , 106 : 7781
  • Matsen , M.W. and Thompson , R.B. 1999 . Equilibrium behavior of symmetric ABA triblock copolymer melts . J. Chem. Phys. , 111 : 7139
  • Wang , Q. , Yan , Q.L. , Neeley , P.F. and de Pablo , J.J. 2000 . Monte Carlo simulations of diblock copolymer thin films confined between two homogeneous surfaces . J. Chem. Phys. , 112 : 450
  • Xuan , Y. , Peng , J. , Cui , L. , Wang , H. , Li , B. and Han , Y. 2004 . Morphology development of ultrathin symmetric diblock copolymer film via solvent vapor treatment . Macromolecules , 37 : 7301
  • Carmesin , I. and Kremer , K. 1988 . The bond fluctuation method: a new effective algorithm for the dynamics of polymers in all spatial dimensions . Macromolecules , 21 : 2819
  • Larson , R.G. , Scriven , L.E. and Davis , H.T. 1985 . Monte Carlo simulation of model amphiphile-oil-water systems . J. Chem. Phys. , 83 : 2411
  • Larson , R.G. 1989 . Self-assembly of surfactant liquid crystalline phases by Monte Carlo simulation . J. Chem. Phys. , 91 : 2479
  • Reiter , J. , Edling , T. and Pakula , T. 1990 . Monte Carlo simulation of lattice models for macromolecules at high densities . J. Chem. Phys. , 93 : 837
  • Mischler , C. , Baschnagel , J. and Binder , K. 2001 . Polymer films in the normal-liquid and supercooled state: a review of recent Monte Carlo simulation results . Adv. Colloid Interface Sci. , 94 : 197
  • Yethiraj , A. and Hall , C.K. 1990 . Monte Carlo simulation of polymers confined between flat plates . Macromolecules , 23 : 1865
  • Yethiraj , A. 1994 . Monte Carlo simulation of confined semiflexible polymer melts . J. Chem. Phys. , 101 : 2489
  • Wilson , M.R. and Allen , M.P. 1993 . Computer simulation study of liquid crystal formation in a semi-flexible system of linked hard spheres . Mol. Phys. , 80 : 277
  • Fraser , B. , Denniston , C. and Müser , M.H. 2006 . On the orientation of lamellar block copolymer phases under shear . J. Chem. Phys. , 124 : 104902
  • Yang , J. , Winnik , M.A. and Pakula , T. 2005 . Interface orientation and chain conformation in simulated symmetric diblock copolymer lamellar systems . Macromol. Theory Simul. , 14 : 9
  • Böker , A. , Knoll , A. , Elbs , H. , Abetz , V. , Muller , A.H.E. and Krausch , G. 2002 . Large scale domain alignment of a block copolymer from solution using electric fields . Macromolecules , 35 : 1319
  • Huh , J. , Jo , W.H. and ten Brinke , G. 2002 . Conformational analysis in ABA triblock melts by Monte Carlo simulation . Macromolecules , 35 : 2413
  • Wang , Q. , Yan , Q.L. , Nealey , P.F. and de Pablo , J.J. 2000 . Monte Carlo simulations of diblock copolymer thin films confined between two homogeneous surfaces . J. Chem. Phys. , 112 : 450
  • Bates , F.S. and Fredrickson , G.H. 1999 . Block copolymers-designer soft materials. Advances in synthetic chemistry and statistical theory provide unparalleled control over molecular scale morphology in this class of macromolecules . Phys. Today , 52 : 32
  • Lee , D.H. , Kim , H.Y. and Kim , J.K. 2006 . Swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride . Macromolecules , 39 : 2027

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