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Research Article

Characterization of Fe and Cr Dissolution and Reaction Product Formation in Molten Chloride Salts With and Without Impurities

ORCID Icon, , ORCID Icon & ORCID Icon
Pages 360-370 | Received 27 Mar 2023, Accepted 17 Apr 2023, Published online: 01 May 2023

References

  • Myers PD Jr, Goswami DY. Goswami DY thermal energy storage using chloride salts and their eutectics. App Thermal Eng. 2016;109:889–900.
  • Liu M, Tay NHS, Bell S, et al. Review on concentrating solar power plants and new developments in high temperature thermal energy storage technologies. Renewable and Sustainable Energy Rev. 2016;53:1411–1432.
  • LeBlanc D. Molten salt reactors: a new beginning for an old idea. Nucl Eng Des. 2010;240(6):1644–1656.
  • Serp J, Allibert M, Benes O, et al. The molten salt reactor (MSR) in generation IV: overview and perspectives‎. Prog Nucl Energy. 2014;77:308–319.
  • Sorbom BN, Ball J, Palmer TR, et al. ARC: a compact, high-field, fusion nuclear science facility and demonstration power plant with demountable magnets. Fus Eng Design. 2015;100:378–405.
  • McConohy G, Kruizenga A. Molten nitrate salts at 600 and 680 °C: thermophysical property changes and corrosion of high-temperature nickel alloys. Solar Energy. 2014;103:242–252.
  • Vignarooban K, Pugazhendhi P, Tucker C, et al. Corrosion resistance of Hastelloys in molten metal-chloride heat-transfer fluids for concentrating solar power applications. Sol Energy. 2014;103:62–69.
  • Hofmeister M, Klein L, Miran H, et al. Corrosion behaviour of stainless steels and a single crystal superalloy in a ternary LiCl–KCl–CsCl molten salt. Corros Sci. 2015;90:46–53.
  • Gomez-Vidal JC, Fernandez AG, Tirawat R, et al. Corrosion resistance of alumina-forming alloys against molten chlorides for energy production. I: pre-oxidation treatment and isothermal corrosion tests. Solar Energy Mater Solar Cells. 2017;166:222–233.
  • Ding W, Bonk A, Bauer T et al. Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated solar power plants: a review. Chem Sci Eng. 2018;12(3):564–576.
  • Sun H, Wang J, Lia Z, et al. Corrosion behavior of 316SS and Ni-based alloys in a ternary NaCl-KCl-MgCl2 molten salt. Solar Energy. 2018;171:320–329.
  • Raiman SS, Lee S. Aggregation and data analysis of corrosion studies in molten chloride and fluoride salts. J Nucl Mater. 2018;511:523–535.
  • Vreeland DC, Hoffman EE, Manly WD. Corrosion tests for liquid metals, fused salts at high temperatures. Nucleonics. 1953;11:36–39.
  • Koger JW. Fluoride salt corrosion and mass-transfer in high-temperature dynamic-systems. Corros. 1973;29(3):115–122.
  • Koger JW. Corrosion product deposition in molten fluoride salt systems. Corros. 1974;30(4):125–130.
  • Keiser JR, De Van JH, Lawrence EJ. Compatibility of Molten Salts with Type 316 Stainless Steel and Lithium. J Nucl Mater. 1979;85-86:295–298.
  • Raiman SS, Kurley JM, Sulejmanovic D, et al. Corrosion of 316H Stainless Steel in Flowing FLiNaK Salt. J Nucl Mater. 2022;561:153551.
  • Haubenreich PN, Engel JR. Experience with the molten-salt reactor experiment. Nucl App Technol. 1970;8(2):118–136.
  • McCoy HE, Beatty RL, Cook WH, et al. New developments in materials for molten-salt reactors nucl. App Technol. 1970;8(2):156–169.
  • Raiman SS, Mayes RT, Kurley JM, et al. Amorphous and partially-amorphous metal coatings for corrosion resistance in molten chloride salt. Solar Energy Mater Solar Cells. 2019;201:110028.
  • Pint BA, McMurray JW, Willoughby AW, et al. Re-establishing the paradigm for evaluating halide salt compatibility to study commercial chloride salts at 600°C–800°C. Mater Corros. 2019;70(8):1439–1449.
  • Raiman SS, Sulejmanovic D, Utlak SA, et al., Corrosion of 316H Stainless Steel in Molten NaCl-MgCl2 with and without Mg as a Redox Control Additive. ORNL report ORNL/TM-2019/1297, Oak Ridge, TN, 2019.
  • Pint BA, Progression to Compatibility Evaluations in Flowing Molten Salts. ORNL Report ORNL/SPR-2020/1940, Oak Ridge, TN (2020). 10.2172/1649281.
  • Pint BA, Kurley JM, Sulejmanovic D. Performance of alloy 600 in flowing commercial Cl salt at 600°-750°C. AIP Conf Proc. 2022;2445:020011.
  • Susskind H, Hill FB, Green L, et al. Corrosion Studies for a Fused Salt-Liquid Metal Extraction Process for the Liquid Metal Fuel Reactor. Chem Eng Prog. 1960;56:57–63.
  • Raseman CJ, Susskind H, Farber G, et al., Engineering experience at brookhaven national laboratory in handling fused chloride salts. Technical Report BNL 627 (T-192), Brookhaven National Laboratory, Brookhaven, NY, 1960.
  • Young JP, Mamantov G, Coffield JE, et al. In-line sensors for electrolytic magnesium cells. Technical Report ORNL/M-3003, Oak Ridge National Laboratory, Oak Ridge, TN, 1993.
  • Chen GS, Sun IW, Sienerth KD, et al. Mamantov G removal of oxide impurities from Alkali Haloaluminate melts using carbon tetrachloride. J Electrochem Soc. 1993;140(6):1523–1526.
  • Zhao Y, Klammer N, Vidal J. Purification strategy and effect of impurities on corrosivity of dehydrated carnallite for thermal solar applications RSC. Adv. 2019;9:41664.
  • Zhao SQ, Xie XS, Smith GD, et al. Microstructural stability and mechanical properties of a new nickel based superalloy. Mater Sci Eng A. 2003;355(1–2):96–105.
  • Shingledecker JP, Pharr GM. Testing and Analysis of Full-Scale Creep-Rupture Experiments on Inconel Alloy 740 Cold-Formed Tubing J. Mater Eng Perform. 2013;22(2):454–462.
  • Kurley JM, Halstenberg PW, McAlister A, et al. Enabling chloride salts for thermal energy storage: implications of salt purity. RSC Adv. 2019;9(44):25602–25608.
  • Ding W, Shi H, Xiu Y, et al. Hot corrosion behavior of commercial alloys in thermal energy storage material of molten MgCl2/KCl/NaCl under inert atmosphere. Solar Energy Mater Solar Cells. 2018;184:22–30. DOI:10.1016/j.solmat.2018.04.025.
  • Sulejmanovic D, Kurley JM, Robb K, et al. Validating Modern Methods for Impurity Analysis in Fluoride Salts. J Nucl Mater. 2021;553:152972.
  • Epstein LF. Static and dynamic Corrosion and mass transfer in liquid metal systems. Liquid Metals Technology, Chem Eng Prog Symp Ser. 1957;20(53):67–81.
  • Pint BA, Parker CG, Su YF, et al., Assessing stainless steel compatibility in flowing fluoride salts. Proceedings of the 20th International Conference on Environmental Degradation of Materials in Nuclear Systems, paper ED2021-18337; Snowmass Village, CO. 2022.
  • Pillai R, Raiman SS, Pint BA. First steps toward predicting corrosion behavior of structural materials in molten salts. J Nucl Mater. 2021;543:152755.
  • Pillai R, Sulejmanovic D, Lowe T, et al. Establishing a design strategy for corrosion resistant structural materials in molten salt technologies. JOM. 2023;75(4):994–1005. in press. DOI:https://doi.org/10.1007/s11837-022-05647-9.

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