Beyond 16 Priority Pollutant PAHs: A Review of PACs used in Environmental Forensic Chemistry

REFERENCES

• U.S. Environmental Protection Agency. “Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)”. US EPA, Office of Solid Waste and Emergency Response, Publication SW-846, Manual for Evaluating Waste, Physical/Chemical Methods, Update III. (Washington, D.C., 1997).
   Google Scholar
• Sauer, T.C. and A.D. Uhler. “Pollutant Source Identification and Allocation: Advances in Hydrocarbon Fingerprinting.” Remediation, Winter Issue (1994): 25–50.
   Google Scholar
• Kaplan, I.R., Y. Galperin, S.T. Lu, and R.P. Lee. “Forensic Environmental Geochemistry: Differentiation of Fuel-Types, Their Sources and Release Time.” Organic Geochemistry 27 (1997): 289–317.
   Web of Science ®Google Scholar
• Stout, S.A., A.D. Uhler, T.J. Naymik, and K.J. McCarthy. “Environmental Forensics – Unraveling Site Liability.” Environmental Science and Technology 32, no. 11 (1998): 260A–264A.
   PubMed Web of Science ®Google Scholar
• Stout, S.A., A.D. Uhler, K.J. McCarthy, and S.D. Emsbo-Mattingly. “Chemical Fingerprinting of Hydrocarbons,” in Introduction to Environmental Forensics, eds. B. Murphy and R. Morrison (New York: Academic Press, 2002), 135–260.
   Google Scholar
• Blumer, M. “Polycyclic Aromatic Compounds in Nature.” Scientific American 234 (1975): 35–45.
   Web of Science ®Google Scholar
• Giger, W. and M. Blumer. “Polycyclic Aromatic Hydrocarbons in the Environment: Isolation and Characterization by Chromatography, Visible, Ultraviolet, and Mass Spectrometry.” Analytical Chemistry 46 (1974): 1663–1671.
   PubMed Web of Science ®Google Scholar
• Youngblood, W.W. and M. Blumer. “Polycyclic Aromatic Hydrocarbons in the Environment: Homologous Series in Soils and Recent Marine Sediments. Geochimica Cosmochimica Acta 39 (1975): 1303–1314.
   Web of Science ®Google Scholar
• Shaw, D.G., D.J. McIntosh, and E.R. Smith. “Arene and Alkane Hydrocarbons in Nearshore Beaufort Sea sediments.” Estuarine Coastal Marine Science 9 (1979): 435–449.
   Web of Science ®Google Scholar
• Laflamme, R.E. and R.A. Hites. “The Global Distribution of Polycyclic aromatic Hydrocarbons in Recent Sediments.” Geochimica Cosmochimica Acta 42 (1978): 289–303.
   Web of Science ®Google Scholar
• Mueller, G., G. Grimmer, and H. Bohnke. “Sedimentary Record of Heavy Metals and Polycyclic Aromatic Hydrocarbons in Lake Constance.” Naturwissenschaften 64 (1977): 427–431.
   PubMed Web of Science ®Google Scholar
• Lake, J.L., C. Norwood, C. Dimock, and R. Bowen. “Origins of Polycyclic Aromatic Hydrocarbons in Estuarine Sediments.” Geochimica Cosmochimica Acta 43 (1979): 1847–54.
   Web of Science ®Google Scholar
• Hites, R.A., R.E. Laflamme, and J.G. Windsor. “Polycyclic Aromatic Hydrocarbons in Marine Aquatic Sediments: Their Ubiquity,” in Petroleum in the Marine Environment, Advances in Chemistry Series, eds. L. Petrakis and F.T. Weiss (Washington, D.C.: American Chemical Society, 1980), 289–311.
   Google Scholar
• Overton, E.B. and J.L. Laseter. “Distribution of Aromatic Hydrocarbons in Sediments from Selected Atlantic, Gulf of Mexico, and Pacific Outer Continental Shelf Areas,” in Petroleum in the Marine Environment, Advances in Chemistry Series 185, eds. L. Petrakis and F.T. Weiss (Washington, D.C.: American Chemical Society, 1980), 327–341.
   Google Scholar
• Prahl, F.G. and R.G. Carpenter. “Polycyclic Aromatic Hydrocarbon (PAH) Phase Associations in Washington Coastal Sediment.” Geochimica Cosmochimica Acta 47 (1983): 1013–1023.
   Web of Science ®Google Scholar
• Sporstol, S., N. Gjos, R.G. Lichtenthaler, K.O. Gustavsen, K. Urdel, F. Oreld, and J. Skel. “Source Identification of Aromatic Hydrocarbons in Sediments using GC/MS.” Environmental Science and Technology 17 (1983): 282–286.
   Web of Science ®Google Scholar
• Stout, S.A. and A.D. Uhler. “Distinguishing “Background” Hydrocarbons from Contamination using Chemical Fingerprinting.” Environmental Claims Journal 15, no. 2 (2003): 241–259.
   Google Scholar
• Stout, S.A., A.D. Uhler, and S.D. Emsbo-Mattingly. “Comparative Evaluation of Background Anthropogenic Hydrocarbons in Surficial Sediments from Nine Urban Waterways.” Environmental Science and Technology 38, no. 11 (2004): 2987–2994.
   PubMed Web of Science ®Google Scholar
• U.S. Environmental Protection Agency. “The Relationship between SW-846, PBMs, and Innovative Analytical Technologies.” US EPA, Office of Solid Water and Emergency Response, Publication QA/G-1. EPA/240/R-02/008. Office of Information, (Washington, D.C., 2001).
   Google Scholar
• National Oceanographic & Atmospheric Administration. “Trace Organic Analytical Procedures,” in Sampling and Analytical Methods of the National Status and Trends Program Mussel Watch Project: 1984-1992, NOAA Tech. Memo. NOS/ORCA 71 (Silver Spring, MD: NOAA, 1993).
   Google Scholar
• National Oceanographic & Atmospheric Administration. “Trace Organic Analytical Procedures,” in Sampling and Analytical Methods of the National Status and Trends Program Mussel Watch Project: 1993-1996 Update, NOAA Tech. Memo. NOS/ORCA 130 (Silver Spring, MD: NOAA, 1998).
   Google Scholar
• U.S. Environmental Protection Agency. “Environmental Monitoring and Assessment Program, EMAP,” in Estuaries Virginia Province 1993 Quality Assurance Project Plan. US EPA, Office of Research and Development (Washington, D.C., 1993).
   Google Scholar
• National Oil and Hazardous Substances Pollution Contingency Plan – Final Rule 40, CFR Parts 9 and 300. Federal Register (1994).
   Google Scholar
• Douglas, G.S., S.D. Emsbo-Mattingly, S.A. Stout, A.D. Uhler, and K.J. McCarthy. “Chemical Fingerprinting of Hydrocarbons and Polychlorinated Biphenyls,” in Introduction to Environmental Forensics, 2nd ed., eds. B. Murphy and R. Morrison (New York, Academic Press, 2007), 317–459.
   Google Scholar
• Douglas, G.S., W.A. Burns, A.E. Bence, D.S. Page, and P. Boehm. “Optimizing Detection Limits for the Analysis of Petroleum Hydrocarbons in Complex Environmental Samples.” Environmental Science and Technology 38 (2004): 3958–3964.
   PubMed Web of Science ®Google Scholar
• Douglas, G.S., K.J. McCarthy, D.T. Dahlen, J.A. Seavey, W.G. Steinhauer, R.C. Prince, and D.L. Elmendorf.” The Use of Hydrocarbon Analyses for Environmental Assessment and Remediation.” Journal of Soil Contamination 1, no. 3 (1992): 197–216.
   Google Scholar
• Sauer, T.C. and P. Boehm. “Hydrocarbon Chemistry Analytical Methods for Oil Spill Assessment.” Marine Spill Response Corp., Technical Report 95-032 (1995).
   Google Scholar
• Zeigler, C.D. and A. Robbat. “Comprehensive Profiling of Coal Tar and Crude Oil to Obtain Mass Spectra and Retention Indices for Alkylated PAH Shows why Current Methods Err.” Environmental Science and Technology 46, no. 7 (2012): 3935–3942.
   PubMed Web of Science ®Google Scholar
• Hawthorne, S.B., C.B. Grabanski, D.J. Miller, and J.P. Kreitinger. “Solid Phase Microextraction Measurement of Parent and Alkyl Polycyclic Aromatic Hydrocarbons in Milliliter Sediment Pore Water Samples and Determination of KDOC Values.” Environmental Science and Technology 39 (2005): 2795–2803.
   PubMed Web of Science ®Google Scholar
• Hawthorne, S.B., C.B. Grabanski, and D.J. Miller. “Measured Partitioning Coefficients for Parent and Alkyl Polycyclic Aromatic Hydrocarbons in 114 Historically Contaminated Sediments: Part 1. Koc Values.” Environmental Toxicology and Chemistry 25, no. 11 (2006): 2901–2911.
   PubMed Web of Science ®Google Scholar
• Johnson, G.W., R. Ehrlich, W. Full, and S. Ramos. “Principle Component Analysis and Receptor Models in Environmental Forensics,” in Introduction to Environmental Forensics, 2nd ed., eds. B. Murphy and R. Morrison (New York: Academic Press, 2007), 205–260.
   Google Scholar
• Wang, Z., M. Fingas, and D. Page. “Oil Spill Identification.” Journal of Chromatography A 843 (1999): 369–411.
   Web of Science ®Google Scholar
• Wang, Z., M. Fingas, and K. Li. “Fractionation of a Light Crude Oil and Identification and Quantitation of Aliphatic, Aromatic and Biomarker Compounds by GC/FID and GC/MSD.” Journal of Chromatographic Science 32 (1994): 361–382.
   Web of Science ®Google Scholar
• Boehm, P.D. and J.W. Farrington. “Aspects of Polycyclic Aromatic Hydrocarbon Geochemistry of Recent Sediments in the Georges Bank Region.” Environmental Science and Technology 18, no. 11 (1984): 840–845.
   PubMed Web of Science ®Google Scholar
• Requejo, A.G., R. Sassen, T. McDonald, G. Denoux, M.C. Kennicutt II, and J.M. Brooks. “Polynuclear Aromatic Hydrocarbons (PAH) as Indicators of the Source and Maturity of Marine Crude Oils.” Organic Geochemistry 24, no. 11 (1996): 1017–1033.
   Web of Science ®Google Scholar
• Elmendorf, D.L., C.E. Haith, G.S. Douglas, and R.C. Prince. “Relative Rates of Biodegradation of Substituted Polycyclic Aromatic Hydrocarbons,” in Bioremediation of Chlorinated and Polycyclic Aromatic Hydrocarbon Compounds, eds. R.E. Hinchee, A. Leeson, L. Semprini, and S.K. Ong (Boca Raton, FL: Lewis Publishers, 1994), 188–202.
   Google Scholar
• Prince, R.C., E.H. Owens, and G.A. Sergy. “Weathering of an Arctic Oil Spill after 20 Years: The BIOS Experiment Revisited.” Marine Pollution Bulletin 44, no. 11 (2002): 1236–1242.
   PubMed Web of Science ®Google Scholar
• Prince, R.C., R.M. Garrett, R.E. Bare, M.J. Grossman, T. Townsend, J.M. Suflita, K. Lee, E.H. Owens, G.A. Sergy, J.F. Braddock, J.E. Linstrom, and R.R. Lessard. “The Roles of Photooxidation and Biodegradation in Long-Term Weathering of Crude and Heavy Fuel Oils.” Spill Science and Technology Bulletin 8, no. 2 (2003): 145–156.
   Google Scholar
• Uhler, A.D. and S.D. Emsbo-Mattingly. “Environmental Stability of PAH source indices in Pyrogenic Tars.” Bulletin of Environmental Contamination and Toxicology 76 (2006): 689–696.
   PubMed Web of Science ®Google Scholar
• Hergazi, A.H. and J.T. Andersson. “Characterization of Polycyclic Aromatic Sulfur Heterocyclics for Source Identification,” in Oil Spill Environmental Forensics: Fingerprinting and Source Identification, eds. Z. Wang and S.A. Stout (Boston: Academic Press, 2007), 147–168.
   Google Scholar
• Daling, P.S., L.G. , Faksness, A.B. Hansen, and S.A. Stout “Improved and Standardized Methodology for Oil Spill Fingerprinting.” Environmental Forensics 3, no. 3/4 (2002): 263–278.
   Web of Science ®Google Scholar
• Burns, W.A., P.J. Mankiewicz, A.E. Bence, D.S. Page, and K.R. Parker. “A Principal Component and Least Squares Method for Allocating Polycyclic Aromatic Hydrocarbons in Sediment to Multiple Sources.” Environmental Toxicology and Chemistry 16, no. 6 (1997): 1119–1131.
   Web of Science ®Google Scholar
• Boehm, P.D., G.S. Douglas, W.A. Burns, P.J. Mankiewicz, D.S. Page, and A.E. Bence. “Application of Petroleum Hydrocarbon Chemical Fingerprinting and Allocation Techniques after the Exxon Valdez Oil Spill.” Marine Polluton Bulletin 34, no. 8 (1997): 599–613.
   Web of Science ®Google Scholar
• Douglas, G.S., A.E. Bence, R.C. Prince, S.J. McMillen, and E.L. Butler. “Environmental Stability of Selected Petroleum Hydrocarbons Source and Weathering Ratios.” Environmental Science and Technology 30 (1996): 2332–2339.
   Web of Science ®Google Scholar
• Stout, S.A., A.D. Uhler, and K.J. McCarthy. “Chemical Characterization and Sources of Distillate Fuels in the Subsurface, Mandan, North Dakota.” Environmental Forensics 7, no. 3 (2006): 267–282.
   Web of Science ®Google Scholar
• Galperin, Y. and I.R. Kaplan. “Forensic Environmental Geochemistry in Dispute Resolution – Case History 2: Differentiating Source of Diesel Fuel in a Plume at a Fueling Station.” Environmental Forensics 9 (2008): 55–62.
   Web of Science ®Google Scholar
• Uhler, A.D., S.A. Stout, and G.S. Douglas. “Chemical Heterogeneity in Modern Marine Residual Fuel Oils,” in Oil Spill Environmental Forensics: Fingerprinting and Source Identification, eds. Z. Wang and S.A. Stout (Boston: Academic Press, 2007), 327–348.
   Google Scholar
• Emsbo-Mattingly, S. “Tar Formation and Alteration.” EPRI MGP 2007 Symposium: Advancements in Manufactured Gas Plant Site Remediation, January 8–11. 2007, Atlanta, Georgia, USA.
   Google Scholar
• Emsbo-Mattingly, S.D., A.D. Uhler, S.A. Stout, K.J. McCarthy, G.S. Douglas, J.S. Brown, and P.D. Boehm. “Polycyclic Aromatic Hydrocarbon (PAH) Chemistry of MGP Tar and Source Identification in Sediment,” in Sediments Guidance Compendium, Report No. 1005216 (Palo Alto, CA: Electric Power Research Institute, 2002), . 1-1 to 1-41.
   Google Scholar
• Emsbo-Mattingly, S.D., S.A. Stout, A.D. Uhler, and K.J. McCarthy. “Identifying Creosote Releases in the Environment,” American Wood Preservers Association, Proceedings of the 99th Annual Mtg., April 2003, Boston, MA.
   Google Scholar
• Emsbo-Mattingly, S.D. and S.A. Stout. “Semivolatile Residues of Coal and Coal Tar,” in Coal and Peat Fires: A Global Perspective, eds. G.B. Stracher, A. Prakash, and E.V. Sokol (Elsevier, 2011) 173–208.
   Google Scholar
• Radke, M., H. Willsch, D. Leythaeuser, and M. Teichmuller. “Aromatic Components of Coal: Relation of Distribution Pattern to Rank.” Geochimica Cosmochimica Acta 46 (1982): 1831–1848.
   Web of Science ®Google Scholar
• Wang, Z. and M. Fingas. “Use of Methyldibenzothiophenes as Markers for Differentiation and Source Identification of Crude and Weathered Oils.” Environmental Science and Technology 29, no. 11 (1995): 2842–2849.
   PubMed Web of Science ®Google Scholar
• Schade, T., B. Roberz, and J.T. Andersson. “Polycyclic Aromatic Sulfur Heterocycles in Desulfurized Diesel Fuels and Their Separation on a Novel Palladium(II) Complex Stationary Phase.” Polycyclic Aromatic Compounds 22 (2002): 311–320.
   Web of Science ®Google Scholar
• Wang, Z., M. Fingas, S. Blenkinsopp, G. Sergy, M. Landriault, L. Sigouin, J. Foght, K. Semple, and D.W. S. Westlake. “Comparison of Oil Composition Changes due to Biodegradation and Physical Weathering in Different Oils.” Journal of Chromatography A 809 (1998): 89–107.
   PubMed Web of Science ®Google Scholar
• Garrett, R.M., I.J. Pickering, C.E. Haith, and R.C. Prince. “Photooxidation of Crude Oils.” Environmental Science and Technology 32 (1998): 3719–3723.
   Web of Science ®Google Scholar
• Matsuzawa, S., L. Nasser-Ali, and P. Garrigues. “Photolytic Behavior of Polycyclic Aromatic Hydrocarbons in Diesel Particulate Matter Deposited on the Ground.” Environmental Science and Technology 35 (2001): 3139–3143.
   PubMed Web of Science ®Google Scholar
• Plata, D.L., C.M. Sharpless, and C.M. Reddy. “Photochemical Degradation of Polycyclic Aromatic Hydrocarbons in Oil Films.” Environmental Science and Technology 42 (2008): 2432–2438.
   PubMed Web of Science ®Google Scholar
• Peters, K.E. and J.M. Moldowan. The Biomarker Guide (Englewood Cliffs, NJ: Prentice Hall, 1993).
   Google Scholar
• Barakat, A.O., Y. Qian, M. Kim, and M.C. Kennicutt II. “Compositional Changes of Aromatic Steroid Hydrocarbons in Naturally Weathered Oil Residues in the Egyptian Western Desert.” Environmental Forensics 3 (2002): 219–225.
   Web of Science ®Google Scholar
• Douglas, G.S., J.H. Hardenstine, B. Liu, and A.D. Uhler. “Laboratory and Field Verification of a Method to Estimate the Extent of Petroleum Biodegradation in Soil.” Environmental Science and Technology 46 (2012): 8279–8287.
   PubMed Web of Science ®Google Scholar
• Peters, K.E., G.L. Scheuerman, C.Y. Lee, J.M. Moldowan, R.N. Reynolds, and M.M. Pena. “Effects of Refinery Processes on Biological Markers.” Energy & Fuels 6 (1992): 567–577.
   Web of Science ®Google Scholar
• Centre for European Norms. “Oil Spill Identification: Waterborne Petroleum and Petroleum Product Analytical Methodology and Interpretation of Results based upon GC-FID and GC-MS Low Resolution Analysis.” (CEN, Technical Report 15522-2, 2012), 142.
   Google Scholar
• Stout, S.A. and T.P. Graan. “Source Apportionment of PAHs in Sediments of Little Menomonee River, Wisconsin: Weathered Creosote versus Urban Background.” Environmental Science and Technology 44, no. 8 (2010): 2932–2939.
   PubMed Web of Science ®Google Scholar
• U.S. Environmental Protection Agency. “Development of a Relative Potency Factor (RPF) Approach for Polycyclic Aromatic Hydrocarbon (PAH) Mixtures” Draft EPA/635/R-08/012A www.epa.gov/iris (2010), 5–19.
   Google Scholar