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Original Articles

Physiochemical Modification of Extractants

Pages 143-194 | Published online: 23 Oct 2006

References

  • Szymanowski , J. 1993 . Hydroxyoximes and Copper Hydrometallurgy , Boca Raton, FL : CRC Press .
  • Dalton , R. F. 1979 . The effect of alkyl phenols on the copper transfer properties of extractant Acorga P-1 . CIM Spec. Vol. , 22 ( 1 ) : 40
  • Blumberg , R. and Gai , J. E. 1979 . Strong diluent effects . CIM Spec. , 22 ( 1 ) : 9
  • Komasawa , I. and Otake , T. 1983 . The effect of diluent in the liquid-liquid extraction of copper and nickel using 2-hydroxy-5-alkyl-benzophenone oxime . J. Chem. Eng. Jpn. , 16 : 377
  • Dalton , R. F. , Severs , K. J. and Stephens , G. Advances in solvent extraction for copper by optimized use of modifiers . Pap. Min. Lat. Am. Conf. pp. 67 London : IMM .
  • Dalton , R. F. and Steward , C. W. The role of aryl aldoxime reagents in the technical and economical advancement of copper production by solvent extraction . Proc. ISEC'86 . Vol. 2 , pp. 199 Munich 11; Modified aldoxime reagents for the solvent extraction of copper, in Reagents in Mineral Industry, IMM, London, 1984, 107
  • Majdan , M. , Sperline , R. P. , Gu , W.-G. , Yu , W.-H. and Freiser , H. 1987 . Interaction of long-chain alcohol “modifiers” with LIX solvent extraction reagents . Solvent Extraction Ion Exchange , 7 : 987
  • Hanson , C. , Hughes , M. A. and Preston , J. S. 1976 . The kinetics of the solvent extraction of copper(II) with LIX reagents. IV. The effect of nonylphenol . J. Inorg. Nucl. Chem. , 38 : 2306
  • Szymanowski , J. and Wolniewicz-Pujanek , I. The influence of alkylphenols upon the equilibrium of copper extraction by hydroxy-oximes . Proc. 25th Symp. Hornicka Pribram ve Vede a Technice, Sekce Chemicke Dobyvani a Zpracovani Surovin . pp. 299 Czechoslovakia : Pribram .
  • Szymanowski , J. , Wolniewicz-Pujanek , I. and Tarasov , V. V. 1984 . Kinetics of copper extraction with 2-hydroxy-5-nonylbenzaldehyde oxime and 2-hydroxy-5-nonylbenzophenone oxime in the presence of p-nonylphenol . Chem. Stos. , 28 : 383 in Polish
  • Flett , D. S. and Melling , J. 1979 . Extraction of ammonia by commercial copper chelating extractants . Hydrometallurgy , 4 : 135
  • Rickelton , W. A. Phosphine oxide phase modifiers in the recovery of indium . Solvent Extraction in the Process Industries, Proc. ISEC'93 . Edited by: Logsdail , D. H. and Slater , M. Vol. 1 , pp. 532 London : Elsevier .
  • Rickelton , W. A. U.S. Patent . 4,619,816 . 1985 . Recovery of Cobalt from Ammoniacal Solutions Containing Cobalt and Nickel
  • Itzkovitch , I. J. and Rickelton , W. A. Canadian Patent . 1,157,278 . 1983 . Solvent Extraction of Uranium Recovery
  • Hurst , F. J. , Crouse , D. J. and Brown , K. B. 1972 . Recovery of uranium from wet-process phosphoric acid . IEC Proc. Des. Dev. , 11 : 122
  • Medkov , M. A. , Steblevskaya , N. I. , Smolkov , A. A. and Zeleznov , V. V. 1990 . Extraction of metals with aliphatic amines in octanol presence . Z. Neorgan. Khim. , 35 : 2416 in Russian
  • Medkov , M. A. , Steblevskaya , N. I. , Smolkov , A. A. and Zeleznov , V. V. The influence of modifiers on extraction of metals with tertiary amines, trialkylbenzylamine and tributylphosphate . Solvent Extraction in the Process Industries, Proc. ISEC'93 . Edited by: Logsdail , D. L. and Slater , M. Vol. 1 , pp. 622 London : Elsevier .
  • Ochkin , A. V. , Kudrov , A. N. and Ospoprivivatelev , A. A. 1985 . Effect of n-tetradecanol on iron(III), cobalt(II) and zinc(II) chlorides with tri-n-dodecylamine . Radiokhimia , 27 : 598
  • Tait , B. K. and Shillington , D. P. 1993 . Effect of isodecanol on amine extraction systems . Solvent Extraction Ion Exchange , 11 : 87
  • Joesten , M. D. and Schaad , L. J. 1974 . Hydrogen Bonding , New York : Marcel Dekker .
  • Pimentel , G. C. and McClellan , A. L. 1960 . The Hydrogen Bond , San Francisco : W. H. Freeman and Co. .
  • Pimental , G. C. , McClellan , A. L. , bonding , Hydrogen , Eyring , H. , Christensen , C. J. and Johnston , H. S. 1971 . Annu. Rev. Phys. Chem. , 22 : 347
  • Musa , R. S. and Eisner , M. 1959 . Kinetics: self-association of t-butanol, ultrasonic adsorption measurements . J. Chem. Phys. , 30 : 227
  • Malecki , J. 1965 . Investigations of hexanol-1 multimers and complexes by the method of dielectric polarization in weak and strong electric fields . J. Chem. Phys. , 43 : 1351
  • Fletcher , A. N. and Heller , C. A. 1967 . Self-association of alcohols in nonpolar solvents . J. Phys. Chem. , 71 : 3742
  • Steurer , E. and Wolf , K. C. 1938 . The effect of intermolecular forces in gases and liquids . Z. Physik. Chem. (Leipzig) , B39 : 1
  • Berman , N. S. and McKetta , J. J. 1962 . The thermodynamic properties of butanol . J. Phys. Chem. , 66 : 1444
  • Berezin , I. V. , Vatsek , K. and Kazanskaya , N. F. 1962 . Interactions of free methyl radicals with hydrogen atom of hydroxyl of t-butanol . Dokl. Akad. Nauk SSSR , 144 : 139 in Russian
  • Griffiths , V. S. and Socrates , G. 1966 . NMR: Kn for self-association of substituted phenols . J. Mol. Spectrosc. , 21 : 302
  • Cáceres-Alonso , M. , Costas , M. , Andreoli-Ball , L. and Patterson , D. 1988 . Steric effects on the self-association of branched and cyclic alcohols in inert solvents. Apparent heat capacities of secondary and tertiary alcohols in hydrocarbons . Can. J. Chem. , 66 : 989
  • Costas , M. and Patterson , D. 1985 . Self-association of alcohols in inert solvents. Apparent heat capacity and volumes of linear alcohols in hydrocarbons . J. Chem. Soc. Faraday Trans. I , 81 : 635
  • Costas , M. and Patterson , D. 1987 . Order destruction and order creation in binary mixture of non-electrolyte . Thermochim. Acta , 120 : 161
  • Bellamy , L. J. and Pace , R. J. 1966 . IR: structure of alcohol and phenol dimers . Spectrochim. Acta , 22 : 525
  • Littlewood , A. B. and Wilmott , F. W. 1966 . NMR: self-association of 1-dodecanol in squalene . Trans. Faraday Soc. , 42 : 3287
  • Ibbitson , D. A. and More , L. F. 1967 . Near-IR: self-association, alcohols, dielectric constants studies . J. Chem. Soc. , 76 : 80
  • Singh , S. and Rao , C. N. R. 1967 . IR, NMR: Self-association, hindered alcohols . J. Phys. Chem. , 71 : 1074
  • Fletcher , A. N. and Heller , C. A. 1968 . IR, near-IR: self-association, alcohols . J. Phys. Chem. , 72 : 1839
  • Hammaker , R. M. , Cleg , R. M. , Patterson , L. K. , Rider , P. E. and Rock , S. L. 1968 . IR, near-IR: self-association, alcohols . J. Phys. Chem. , 72 : 1837
  • Dixan , W. B. 1970 . NMR: self-association, methanol . J. Phys. Chem. , 74 : 1396
  • Tucker , E. E. and Becker , E. D. 1973 . NMR, IR: self-association, t-butyl alcohol in hexadecane . J. Phys. Chem. , 77 : 1783
  • Stępniak-Biniakiewicz , D. 1987 . Association of model 2-hydroxy-5-alkylbenzal-dehyde oximes . Polish J. Chem. , 61 : 433
  • Puttman , N. A. 1960 . IR: effect of alkyl groups on the self-association of o-phenols . J. Chem. Soc. , : 486
  • Brusset , H. and Bono , D. 1956 . Pressions de vapeur des solutions associées. Systémes formes par quelque phénols avec le tétrachlorure de carbone . C.R. Acad. Sci. Ser. C , 242 : 130
  • Vanderborgh , N. E. , Armstrong , N. R. and Spall , W. D. 1970 . A cryoscopic study of the association of phenolic compounds in benzene . J. Phys. Chem. , 74 : 1734
  • Baron , D. and Lumbroso-Bader , N. 1972 . Détermination de l'enthalpie de dimerisation de phenols par RMN. II. Cas des alkyl-phénols dans CCl4 et de phénols dans le cyclohexane . J. Chim. Phys. , 69 : 1076
  • Tack , J. and Huyskens , P. 1974 . Etude de l'autoassociation des phénols par calorimétrie et par partage entre le cyclohexane et l'eau . J. Chim. Phys. , 71 : 1231
  • Barela , R. and Buchowski , H. 1990 . Vapour-liquid equilibria of dilute solutions of phenols in cyclohexane. Self-association of meta and para-substituted phenols . Fluid Phase Equilibria , 59 : 99
  • Barela , R. and Buchowski , H. 1988 . Vapour-liquid equilibria of dilute solutions of phenols in cyclohexane. Self-association of ortho-substituted phenols . Fluid Phase Equilibria , 39 : 293
  • Preston , J. S. and Luklinska , Z. B. 1980 . Solvent extraction of copper(II) with ortho-hydroxy-oximes. I. Kinetics and mechanism of extraction . J. Inorg. Nucl. Chem. , 42 : 431
  • Cox , M. , Hirons , C. G. and Flett , D. S. Kinetics and mechanism of extraction of copper by hydroxyoximes under quiscent and turbulent mixing . Int. Solvent Extr. Conf., ISEC'80 . Vol. 1 , pp. 80 – 118 . Liege
  • Hummelstedt , L. 1979 . Some reagents suitable for metal extraction from sulfate media with particular emphasis on the kinetics of copper extraction with chelating agents . CIM Spec. Vol. , 21 : 17
  • Hummelstedt , L. , Patero , E. , Nyberg , T. and Rosenback , L. Investigation of the catalytic mechanism in the extraction of copper with mixtures of the pure active hydroxyoxime isomers of LIX 64N . Int. Solvent Extr. Conf., ISEC'80 . Vol. 2 , pp. 80 – 73 . Liege
  • Kojima , T. and Miyauchi , T. 1982 . Catalytic effect of LIX 63 on copper extraction in the LIX 63/LIX 65N system . Ind. Eng. Chem. Fund. , 21 : 220
  • Stępniak-Biniakiewicz , D. and Szymanowski , J. 1981 . Influence of the structure of oxime derivatives of 2-hydroxy-5-alkylbenzaldehyde on copper extraction from dilute acidic sulfate solutions . Hydrometallurgy , 7 : 1298
  • Fleming , C. A. 1976 . Kinetics and mechanism of solvent extraction of copper by LIX 64N and Kelex 100 1 NIM Rep. 1973, Republic of South Africa
  • Whewell , R. J. , Hughes , M. A. and Hanson , C. 1979 . Aspects of kinetics and mechanism of the extraction of copper with hydroxyoximes . CIM Spec. Vol. , 21 : 185
  • Hanson , C. , Hughes , M. A. and Whewell , R. J. 1978 . The rate of mass transfer to single drop. The copper hydroxyoxime system . J. Appl. Chem. Biotechnol. , 28 : 426
  • Preston , J. S. and Whewell , R. J. 1977 . Purification and acid-base properties of hydroxyoxime extractants for copper . J. Inorg. Nucl. Chem. , 39 : 1675
  • Komasawa , I. , Otake , T. and Muraoka , T. 1980 . Kinetics of copper with hydroxyoxime extractants . J. Chem. Eng. Jpn. , 13 : 204
  • Stępniak-Biniakiewicz , D. 1987 . Association of model 2-hydroxy-5-alkylbenzal-dehyde oximes . Polish J. Chem. , 61 : 433
  • Rusińska-Roszak , D. and Łozynski , M. 1986 . Hydrogen bonding in ortho hydroxyoximes and their derivatives . Zesz. Nauk. Politech. Pozn., Chem. Inz. Chem. , 16 : 193
  • Szymanowski , J. 1989 . “ Adsorption of hydroxy-oximes at the organic/aqueous interface and the interfacial mechanism of copper extraction ” . In Surfactants in Solutions , Edited by: Mittal , B. K. L. and Lindman , B. New York : Plenum Press .
  • Whewell , R. J. and Hughes , M. A. 1979 . The modelling of equilibrium data for the liquid-liquid extraction of metals. III. An improved chemical model for the copper/LIX 64N system . Hydrometallurgy , 4 : 109
  • Szymanowski , J. , Alejski , K. and Prochaska , K. 1990 . Interfacial behaviour of LIX 65N and kinetics and mechanism of copper extraction . Hydrometallurgy , 25 : 329
  • Geiseler , G. and Fruwert , J. 1960 . Association behavior of position isomeric n-alkanone oximes . Z. Phys. Chem. , 26 : 111
  • Komasawa , I. , Otake , T. and Yamada , A. 1980 . Equilibrium studies of copper extraction from sulfate media with hydroxyoxime extractants . J. Chem. Eng. Jpn. , 13 : 130
  • Komasawa , I. and Otake , T. 1983 . Extraction of copper with 2-hydroxy-5-nonylbenzophenone oxime and the catalytic role of bis(2-ethylhexyl)phosphoric acid . Ind. Eng. Chem. Fundam. , 22 : 122
  • Dobson , S. and van der Zeeuw , A. J. 1976 . Hydrocarbon solvent diluents in hydroxyoxime solvent extraction process . Chem. Ind. , : 175
  • Aguilar , M. , Elizalde , M. P. and Castresana , J. M. Extraction of Ni(II) by 5,8-diethyl-7-hydroxydodecan-6-oxime in mixtures with other extractants and toluene . Proc. Int. Solvent Extr. Conf., ISEC'93 . Vol. 1 , pp. 493 Denver
  • Kolarik , Z. 1971 . Interactions of acidic organophosphorus extractants in the organic phase . Solvent Extraction Rev. , 1 : 1
  • Kolarik , Z. 1982 . Critical evaluation of equilibrium constants in solution. B. Equilibrium constants of liquid-liquid distribution systems. Critical evaluation of some equilibrium constants involving acidic organophosphorus extractants . Pure Appl. Chem. , 54 : 2593
  • Marcus , Y. , Kertes , A. S. and Yanir , E. 1974 . Equilibrium Constants of Liquid-Liquid Distribution Reactions. Introduction and Part I; Organophosphorus Extractants , London : Butterworths .
  • Marcus , Y. and Kertes , A. S. 1969 . Ion Exchange and Solvent Extraction of Metal Complexes , London : Wiley .
  • Soldatov , V. S. , Yurevich , L. V. and Hogfeldt , E. 1977 . On the properties of solid and liquid ion exchangers. IV. Thermodynamic and IR-investigation of the hydration of dinonyl-naphthalene sulfonic acid in heptane . J. Inorg. Nucl. Chem. , 39 : 2069
  • Hogfeldt , E. , Kuvaeva , Z. I. and Soldatov , V. S. 1978 . On the properties of solid and liquid ion exchangers. V. The potassium-hydrogen exchange on dinonylnaphthalene sulfonic acid in heptane in the temperature range 1–80°C . J. Inorg. Nucl. Chem. , 40 : 1405
  • Kuvaeva , Z. I. , Soldatov , V. S. , Fredlund , F. and Hogfeldt , E. 1978 . On the properties of solid and liquid ion exchangers. VI. Application of a simple model to some ion exchange reactions on dinonylnaphthalene sulfonic acid in different solvents and for different cations with heptane as solvents . J. Inorg. Nucl. Chem. , 40 : 103
  • Hogfeldt , E. and Soldatov , V. S. 1979 . On the properties of solid and liquid ion exchangers. VII. A simple model for the formation of mixed micelles applied to salts of dinonylnaphthalene sulfonic acid . J. Inorg. Nucl. Chem. , 41 : 575
  • Kuvaeva , Z. I. , Soldatov , V. S. and Hogfeldt , E. 1979 . On the properties of solid and liquid ion exchangers. VIII. Potassium-hydrogen and calcium-hydrogen exchange in dinonylnaphthalene sulfonic acid dissolved in heptane-isodecanol mixtures . J. Inorg. Nucl. Chem. , 43 : 579
  • McDowell , W. J. 1971 . Equilibria in the system: di(2-ethylhexyl)phosphoric acid-benzene-water-alkali (hydroxide, nitrate) . J. Inorg. Nucl. Chem. , 33 : 1067
  • McDowell , W. J. and Coleman , C. F. 1965 . Sodium and strontium extraction by di(2-ethylhexyl)phosphate: mechanism and equilibria . J. Inorg. Nucl. Chem. , 27 : 1117
  • Myers , A. L. , McDowell , W. J. and Coleman , C. F. 1964 . Degree of polimerization of di(2-ethylhexyl)-phosphoric acid and sodium di(2-ethylhexyl)phosphate in wet benzene by different vapour-pressure measurements . J. Inorg. Nucl. Chem. , 26 : 2005
  • Ekwall , P. , Danielsson , I. and Stenius , P. 1972 . “ Aggregation in surfactant systems ” . In Surface Chemistry of Colloids , Edited by: Kerker , K. Vol. 7 , 97 London : Butterworth .
  • Eicke , H. E. 1980 . Surfactants in nonpolar solvents. Aggregation and micellization . Top. Curr. Chem. , 87 : 85
  • Sjoblom , E. and Friberg , S. 1978 . Light-scattering and electron microscopy determinations of associated structure in W/O microemulsions . J. Colloid Interface Sci. , 67 : 16
  • Ekwall , P. 1969 . Two types of micelle formation in organic solvents . J. Colloid Interface Sci. , 29 : 16
  • Faure , A. , Tistchenko , A. M. , Zemb , T. and Chachaty , C. 1985 . Aggregation and dynamic behavior in sodium diethylhexyl phosphate/water/benzene/inverted micelles . J. Phys. Chem. , 89 : 3373
  • Danesi , P. R. , Alexandro , G. D. and Scuppa , B. 1976 . Interfacial behaviour of dinonylnaphthalene sulfonic acid in the toluene-HCl4 interface . J. Inorg. Nucl. Chem. , 38 : 1367
  • Neuman , R. D. , Jones , M. A. and Zhou , N. F. 1990 . Photon correlation applied to hydrometallurgical solvent extraction systems . Colloids Surf. , 46 : 45
  • Gaonkar , A. G. , Garver , T. M. and Neuman , R. D. 1987 . 1H-NMR spectroscopic investigation of reversed micellization in metal/organophosphorous surfactant system . Colloids Surf. , 20 : 265
  • Gaonkar , A. G. and Neuman , R. D. 1984 . Purity considerations and interfacial behavior of solvent extraction systems . Sep. Purif. Methods , 13 ( 2 ) : 141
  • Gaonkar , A. G. and Neuman , R. D. The role of aggregate formation in solvent extraction of calcium . Proc. ISEC'86 . Vol. 2 , pp. 361 Frankfurt : Munchen, DECHEMA . 1986
  • Neuman , R. D. , Zhou , N. F. , Wu , J. , Jones , M. A. , Gaonkar , A. G. , Park , S. J. and Agrawal , M. L. 1990 . General model for aggregation of metal-extractant complexes in acidic organophosphorus solvent extraction systems . Sep. Sci. Technol. , 25 : 1655
  • Park , S. J. and Neuman , R. D. 1992 . “ Extraction of nickel from nitrate media with di(2-ethylhexyl)phosphoric acid under high loading conditions ” . In Process Metallurgy 7B, Solvent Extraction, 1990 , 201 New York : Elsevier . Part A
  • Zhou , N. F. , Wu , J. , Liu , P. K. and Neuman , R. D. 1990 . “ Comparison of aggregates formed by acidic organophosphorus extractants and metals (Ni and Co) in solvent extraction ” . In Process Metallurgy 7B, Solvent Extraction 1990 , 165 New York : Elsevier . Part A
  • Neuman , R. D. and Park , S. J. 1992 . Characterization of association microstructures in hydrometallurgical nickel extraction by di(2-ethylhexyl)phosphoric acid in heptane in the presence of water . J. Colloid Interface Sci. , 152 : 41
  • Neuman , R. D. , Park , S. J. , Zhou , N. F. and Shah , P. Interfacial phenomena in hydromet-allurgical solvent extraction systems . Proc ISEC'93, Solvent Extraction in the Process Industries . Edited by: Logsdail , D. H. and Slater , M. J. Vol. 3 , pp. 1689 London : Elsevier .
  • Stoyanov , E. S. and Mikhailov , V. A. 1990 . Structure of nickel(II) di-2-ethylhexyl phosphate in organic solutions in presence of water . Koord. Khim. , 16 : 1537
  • Stoyanov , E. S. Composition and structure of mixed micelles formed in nickel(II) and cobalt(II) extracts by di(2-ethylhexyl)phosphoric acid and their influence on the Co/Ni separation factor . Proc ISEC'93, Solvent Extraction in the Process Industries . Edited by: Logsdail , D. H. and Slater , M. J. Vol. 3 , pp. 1720 Elsevier .
  • Wu , J. , Shi , N. , Gao , H. , Chen , D. , Guo , H. , Weng , S. and Xu , G. 1984 . Fourier transform infrared study on the hydration of extractant anions-sodium salt of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester-sec-octyl alcohol-water system . Sci. Sin. B , 27 ( 8 ) : 249
  • Wu , J. , Shi , N. , Zhou , W. , Liao , H. , Zhou , N. , Neuman , R. D. , Gao , H. and Xu , G. The structure of the extracted organic phase and interface chemistry . Proc ISEC'93, Solvent Extraction in the Process Industries . Edited by: Logsdail , D. L. and Slater , M. J. pp. 1762 London : Elsevier .
  • Paatero , E. , Ernola , P. , Sjoblom , J. and Hummelstedt , L. Proc. Summer School in Solvent Extraction . pp. E-1 Toulose : Institut de Genie Chimie .
  • Mitchel , D. J. and Ninham , B. W. 1981 . Micelles, vesicles and microemulsions . J. Chem. Soc. Faraday Trans. II , 77 : 601
  • Osseo-Asare , K. 1991 . Aggregation, reversed micelles, and microemulsions in liquid-liquid extraction: the tri-n-butyl phosphate-diluent-water-electrolyte system . Adv. Colloid Interface Sci. , 37 : 123
  • Szymanowski , J. and Tondre , C. 1994 . Kinetics and interfacial phenomena in classical and micellar extraction systems . Solvent Extraction Ion Exchange , 12 : 873
  • Bogacki , M. B. , Łozyński , M. and Szymanowski , J. 1994 . Modelling of metal extraction equilibrium in the modifier presence . Solvent Extraction Res. Dev. Jpn. , 1 : 108
  • Bogacki , M. B. and Szymanowski , J. 1990 . Modeling of extraction equilibrium and computer simulation of extraction-stripping systems for copper extraction by 2-hydroxy-5-nonyl-banzaldehyde oxime . Ind. Eng. Chem. Res. , 29 : 601
  • Bogacki , M. B. and Szymanowski , J. 1992 . Computer simulation of copper extraction- stripping systems containing different hydroxy oxime extractants in various extraction-stripping loops . Ind. Eng. Chem. Res. , 31 : 328
  • Prochaska , K. , Łozyński , M. , Szymanowski , J. , Uhlemann , E. and Mickler , W. in press . Interfacial activity and semiempirical PM3 calculations of 2-ethylhexanoylbenzoyl methane . Sep. Sci. Technol. ,
  • Kopczynski , T. , Łozyński , M. , Prochaska , K. , Burdzy , A. , Cierpiszewski , R. and Szymanowski , J. 1994 . Structure and properties of alkanal oximes as copper extractants . Solvent Extraction Ion Exchange , 12 : 701
  • Bogacki , M. B. and Szymanowski , J. in press . Association of model sulfonic acids with modifiers . Solvent Extraction Res. Dev. Jpn. ,
  • Dalton , R. F. and Leng , K. I. European Patent . 202,833 . 1986 . Composition for the Extraction of Metals from Aqueous Solutions
  • Szymanowski , J. , Blondet , I. , Cote , G. , Bauer , D. and Sabot , J.-L. 1992 . Interfacial activity of dinonylnaphthalene sulphonic acid in the presence of modifiers possessing an hydroxyl group . Hydrometallurgy , 28 : 277
  • Szymanowski , J. , Miesiac , I. , Schügerl , K. and Sobczyńska , A. 1992 . Interfacial activity of Hostarex A327 in systems containing modifiers . Solvent Extraction Ion Exchange , 10 : 509
  • Szymanowski , J. , Blondet , I. , Cote , G. , Bauer , D. and Sabot , J.-L. Interfacial activity of bis(2-ethylhexyl)phosphoric acid and association and solvation phenomena in model liquid-liquid extraction systems . Hydrometallurgy , submitted
  • Kordosky , G. A. , Sierakoski , J. M. and House , J. E. The LIX 860 series: unmodified extraction reagents . Proc. Int. Solvent Extr. Conf., ISEC'83 . pp. 191 Denver
  • Keeney , M. E. and Osseo-Asare , K. 1982 . Molecular interactions in a mixed α-hydroxyoxime-sulfonic acid solvent extraction system . Polyhedron , 1 : 453
  • Osseo-Asare , K. and Keeney , M. E. 1980 . Aspects of interfacial chemistry of nickel extraction with LIX 63-HDNNS . Metall. Trans. B. , 11B : 63
  • Taylor , R. and Kennard , O. 1982 . Crystallographic evidence for the existance of C-H…O, C-H…N and C-H°Cl hydrogen bonds . J. Am. Chem. Soc. , 104 : 5063
  • Steiner , T. and Saenger , W. 1993 . Role of C-H…O hydrogen bonds in the coordination of water molecules. Analysis of neutron diffraction data . J. Am. Chem. Soc. , 115 : 4540
  • Jasper , J. J. and Houseman , B. L. 1963 . The interfacial surface pressure of soluble alcohol monolayers at the water-octane interface . J. Phys. Chem. , 67 : 1548
  • Jasper , J. J. and Houseman , B. L. 1965 . The thermodynamic properties of soluble monolayers produced by normal alcohols (C8 to C12) at the water-octane interface . J. Phys. Chem. , 69 : 310
  • Jasper , J. J. and Van Dell , R. D. 1969 . The shapes and close-pack areas of oriented long-chain dipoles at the water-octane interface . J. Phys. Chem. , 69 : 481
  • Chatterjee , A. K. and Chattoraj , D. K. 1968 . Adsorption of short-chain acids and their ions at the oil/water interface . J. Colloid Interface Sci. , 26 : 1
  • Clint , J. H. , Corkill , J. M. , Goodman , J. F. and Tate , J. A. 1968 . Adsorption of n-alcanols at the air/aqueous solution interface . J. Colloid Interface Sci. , 28 : 522
  • Lutton , E. S. , Stauffer , C. E. , Martin , J. B. and Fehl , A. J. 1969 . Solid and liquid monomolecular film at oil/H2O interfaces . J. Colloid Interface Sci. , 30 : 283
  • Aveyard , R. , Briscoe , B. J. and Chapman , J. 1973 . Analysis of adsorption data for polar organic molecules at the liquid-liquid interface . J. Colloid Interface Sci. , 44 : 282
  • Aveyard , R. and Briscoe , B. J. 1970 . Adsorption of n-octanol at n-dodecane/water interface . Trans. Faraday Soc. , 66 : 2911
  • Aveyard , R. and Briscoe , B. J. 1972 . Adsorption of n-alkanols at alkane/water interfaces . J. Chem. Soc. Faraday Trans. 1 , 68 : 478
  • Aveyard , R. and Chapman , J. 1975 . Adsorption of polar organic molecules at oil/water and air/water interfaces . Can. J. Chem. , 53 : 916
  • Aveyard , R. and Mitchell , R. W. 1969 . Distribution of n-alkanols between water and n-alkanes . Trans. Faraday Soc. , 65 : 2645
  • Ross , S. and Chen , E. S. 1965 . Adsorption and thermodynamics at the liquid-liquid interface . Ind. Eng. Chem. , 57 : 40
  • Motomura , K. 1978 . Thermodynamic studies on adsorption at interfaces. I. General formulation . J. Colloid Interface Sci. , 64 : 348
  • Motomura , K. , Matubayasi , N. , Aratono , M. and Matuura , R. 1978 . Thermodynamic studies on adsorption at interfaces. II. One surface-active component system: tetradecanol at hexane/water interface . J. Colloid Interface Sci. , 64 : 356
  • Matubayasi , N. , Motomura , K. , Aratono , M. and Matuura , R. 1978 . Thermodynamic study on the adsorption of 1-octadecanol at hexane/water interface . Bull. Chem. Soc. Jpn. , 51 : 2800
  • Ikenaga , T. , Matubayasi , N. , Aratono , M. , Motomura , K. and Matuura , R. 1980 . Solvent effect on the adsorption of 1-octandecanol at oil/water interface . Bull. Chem. Soc. Jpn. , 53 : 653
  • Matsuguchi , M. , Aratono , M. and Motomura , K. 1990 . Adsorption of cholesterol at hexane/water interface . Bull. Chem. Soc. Jpn. , 63 : 17
  • Al-Diwan , T. A. , Hughes , M. A. and Whewell , R. J. 1977 . Behavior of interfacial tension in systems involving hydroxyoxime extractants for copper . J. Inorg. Nucl. Chem. , 39 : 1419
  • Szymanowski , J. and Prochaska , K. 1988 . Interfacial activity of model 2-hydroxy-5-alkyl-benzophenone oximes and their intermediates . J. Colloid Interface Sci. , 123 : 456
  • Lunkenheimer , K. , Pergande , H. J. and Kmeger , H. 1987 . Apparatus for programmed high performance purification of surfactant solutions . Rev. Sci. Instrum. , 58 : 2313
  • Stepniak-Biniakiewicz , D. , Szymanowski , J. , Alejski , K. and Prochaska , K. 1990 . Interfacial activity of 2-hydroxy-5-alkylbenz-aldehyde oximes and mechanism and kinetics of copper extraction . Solvent Extraction Ion Exchange , 8 : 425
  • Szymanowski , J. and Prochaska , K. 1987 . The surface excess and the rate of copper extraction by hydroxyoximes . J. Chem. Technol. Biotechnol. , 40 : 177
  • Szymanowski , J. and Alejski , K. 1990 . Activities of metal extractants as determined from interfacial tension isotherm . Solvent Extraction Ion Exchange , 8 : 445
  • Szymanowski , J. and Prochaska , K. 1988 . Interfacial activity of 1-(2′-hydroxy-5′-methylphenyldodecane-1-one oxime and the interfacial mechanism of copper extraction . Prog. Colloid Polym. Sci. , 76 : 260
  • Szymanowski , J. and Prochaska , K. The interfacial activity of hydroxyoximes and the reaction order of copper extraction in the octane/water system . Proc. Int. Solvent Extr. Conf., ISEC'88 . Vol. 3 , pp. 24 Moscow
  • Szymanowski , J. , Prochaska , K. and Alejski , K. 1990 . Interfacial behaviour of LIX 65N and surface kinetics of copper extraction . Hydrometallurgy , 25 : 329
  • Hutchinson , E. 1948 . Films at oil–water interfaces. III . J. Colloid. Sci. , 3 : 513
  • Rosen , M. J. 1986 . “ Molecular interaction and synergism in binary mixtures of surfactants ” . In ACS Symposium Series 311 Phenomena in Mixed Surfactant Systems , Edited by: Scamehorn , J. F. 145 Washington, D.C. : American Chemical Society .
  • Rosen , M. J. and Hua , X. Y. 1982 . Surface concentrations and molecular interactions in binary mixtures of surfactants . J. Colloid Interface Sci. , 86 : 164
  • Hua , X. Y. and Rosen , M. 1982 . Synergism in binary mixtures of surfactants. I. Theoretical analysis . J. Colloid Interface Sci. , 90 : 212
  • Rosen , M. J. and Murphy , D. S. 1986 . Synergism in binary mixtures of surfactants. V. Two-phase liquid-liquid systems at low surfactant concentrations . J. Colloid Interface Sci. , 110 : 224
  • Hua , X. Y. and Rosen , M. J. 1988 . Conditions for synergism in surface tension reduction effectiveness in binary mixtures of surfactants . J. Colloid Interface Sci. , 125 : 730
  • Rosen , M. J. and Murphy , D. S. 1989 . Synergism in binary mixtures of surfactants. VIII. Effect of hydrocarbon in hydrocarbon/water systems . J. Colloid Interface Sci. , 129 : 208
  • Szymanowski , J. , Cote , G. , Sobczyúska , A. , Firgolski , K. and Jakubiak , A. 1994 . Interfacial activity of decyl pyridinemonocarboxylates . Solvent Extraction Ion Exchange , 12 : 69
  • Rosen , M. J. 1974 . Relation of structure to properties in surfactants. II. Efficiency in surface or interfacial tension reduction . J. Am. Oil Chem. Soc. , 51 : 461
  • Aratono , M. , Uryu , S. , Hayami , Y. , Motomura , K. and Matuura , R. 1983 . Mixed adsorbed film on dodecylammonium chloride with decylammonium chloride at water/air interface . J. Colloid Interface Sci. , 93 : 162
  • Uryu , S. , Aratono , M. , Yamanaka , M. , Motomura , K. and Matuura , R. 1983 . Adsorption of dodecyltrimethylammonium chloride-decylammonium chloride mixtures at the water/air interface . Bull. Chem. Soc. Jpn. , 56 : 3219
  • Uryu , S. , Aratono , M. , Yamanaka , M. , Motomura , K. and Matuura , R. 1984 . Mixed adsorbed film of 2-(octylsulfinyl)ethanol with decylammonium chloride at water/air interface . Bull. Chem. Soc. Jpn. , 57 : 967
  • Motomura , K. , Matsukiyo , H. and Aratono , M. 1986 . “ Thermodynamic study of the surface adsorption and micelle formation of mixed surfactants ” . In ACS Symposium Series 311 Phenomena in Mixed Surfactant Systems , Edited by: Scamehorn , J. F. 163 Washington, D.C. : American Chemical Society .
  • Prochaska , K. Interfacial tension for systems containing mixtures of 2-hydroxy-5-alkyl-benzophenone oxime and α-acyloin oxime . J. Colloid Interface Sci. , in preparation

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