References and note
- Mizuhata, Y.; Fujimori, S.; Sasamori, T.; Tokitoh, N. Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion. Angew. Chem. Int. Ed. Engl. 2017, 56, 4588–4592. DOI: 10.1002/anie.201700801.
- Fujimori, S.; Mizuhata, Y.; Tokitoh, N. Heavy Phenyllithium and -Sodium: Synthesis and Characterization of Germanium Analogues of Phenyl Anion (‘Germabenzenyl Anions’). Chem. Lett. 2018, 47, 708–710. DOI: 10.1246/cl.180170.
- Mizuhata, Y.; Fujimori, S.; Noda, N.; Kanesato, S.; Tokitoh, N. Generation of Stannabenzenes and Their Monomer-Dimer Equilibration. Dalton Trans. 2018, 47, 14436–14444. DOI: 10.1039/C8DT02994F.
- Fujimori, S.; Mizuhata, Y.; Tokitoh, N. Stannabenzenylpotassium: The First Isolable Tin-Containing Benzene Derivative . Chemistry 2018, 24, 17039–17045. DOI: 10.1002/chem.201804858.
- Fujimori, S.; Mizuhata, Y.; Tokitoh, N. Ru-Complexes of an Anionic Germabenzenyl Ligand. Chem. Commun. 2018, 54, 8044–8047. DOI: 10.1039/C8CC02845A.
- Crystallographic data for 5: Empirical formula C39H70Ge3Si2, Mr = 812.90, 103(2) K, triclinic, P-1 (#2), a = 10.9515(4), b = 12.7244(5), c = 15.9909(7) Å, α = 83.301(3), β = 75.642(3), γ = 75.399(3)°, V = 2085.55(15) Å3, Z = 2, Dcalc = 1.294 Mg/m3, μ = 2.230 mm−1, Crystal size 0.050 × 0.050 × 0.010 mm3, 1.657 < = θ < = 25.250°, Reflections collected 18052, Independent reflections 7476 [R(int) = 0.1099], Completeness to θ = 25.242° 99.0%, Goodness-of-fit on F2 0.978, R1 = 0.0612 [I > 2σ(I)], wR2 (all data) = 0.1402, largest diff. peak and hole 1.281 and –0.622 e.Å−3. CCDC 1993292.
- Frisch, M. J.; Trucks, G. W.; Schlegel, H. E.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; et al. Gaussian 16. Gaussian, Inc., Wallingford CT, 2016.