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Short Communication

Pd(acac)2/Xantphos: A highly efficient and readily available catalyst for regioselective hydrosilylation of allenes

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Pages 349-352 | Received 12 Aug 2020, Accepted 30 Oct 2020, Published online: 19 Nov 2020

References

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  • (a) Miller, Z. D.; Li, W.; Belderrain, T. R.; Montgomery, J. Regioselective Allene Hydrosilylation catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium. J. Am. Chem. Soc. 2013, 135, 15282–15285. DOI: 10.1021/ja407749w. (b) Tafazolian, H.; Schmidt, J. A. R. Highly Efficient Regioselective Hydrosilylation of Allenes using a [(3IP)Pd(allyl)]OTf Catalyst; First Example of Allene Hydrosilylation with Phenyl- and Diphenylsilane. Chem Commun. 2015, 51, 5943–5946. DOI: 10.1039/C4CC09804H. (c) Chen, J.-J.; Zeng, J.-H.; Yang, Y.; Liu, Z.-K.; Jiang, Y.-N.; Li, M.-R.; Chen, L.; Zhan, Z.-P. A Bithiophene-Promoted ppm Level Palladium-Catalyzed Highly Regioselective Hydrosilylation of Terminal Allenes. Adv. Synth. Catal. 2020, 362, 2360–2366. DOI: 10.1002/adsc.201901552.

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