Reduction of phosphogypsum to calcium sulfide (CaS) using metallic iron in a hydrochloric acid medium

References

• Ghisellini, P.; Cialani, C.; Ulgiati, S. A Review on Circular Economy: The Expected Transition to a Balanced Interplay of Environmental and Economic Systems. J. Cleaner Prod. 2016, 114, 11–32. DOI: 10.1016/j.jclepro.2015.09.007.
   Web of Science ®Google Scholar
• Luhar, S.; Cheng, T.-W.; Nicolaides, D.; Luhar, I.; Panias, D.; Sakkas, K. Valorisation of Glass Waste for Development of Geopolymer Composites–Mechanical Properties and Rheological Characteristics: A Review. Constr. Build. Mater. 2019, 220, 547–564. DOI: 10.1016/j.conbuildmat.2019.06.041.
   Web of Science ®Google Scholar
• Tayibi, H.; Choura, M.; López, F.-A.; Alguacil, F.-J.; López-Delgado, A. Environmental Impact and Management of Phosphogypsum. J. Environ. Manage. 2009, 90, 2377–2386. DOI: 10.1016/j.jenvman.2009.03.007.
   PubMed Web of Science ®Google Scholar
• Oumnih, S.; Gharibi, E.; Yousfi, E.-B.; Bekkouch, N.; El Hammouti, K. Posphogypsum Waste Valorization by Acid Attack with the Presence of Metallic Iron. J. Mater. Environ. Sci. 2017, 8, 338–344.
   Google Scholar
• Tsioka, M.; Voudrias, E.-A. Comparison of Alternative Management Methods for Phosphogypsum Waste Using Life Cycle Analysis. J. Cleaner. Prod. 2020, 266, 121386. 2020 DOI: 10.1016/j.jclepro.2020.121386.
   Web of Science ®Google Scholar
• Ennaciri, Y.; Bettach, M.; Cherrat, A.; Zegzouti, A. Conversion of Phosphogypsum to Sodium Sulfate and Calcium Carbonate in Aqueous Solution. J. Mater. Environ. Sci. 2016, 7, 1925–1933.
   Google Scholar
• De Ridder, M.; De Jong, S.; Polchar, J.; Lingemann, S. The Hague Centre for Strategic Studies (HCSS). Rapport No 17 | 12 | 12 ISBN/EAN: 978-94-91040-69-6, 2012.
   Google Scholar
• Mar, S.-S.; Okazaki, M. Investigation of Cd Contents in Several Phosphate Rocks Used for the Production of Fertilizer. Microchem. J. 2012, 104, 17–21. DOI: 10.1016/j.microc.2012.03.020.
   Web of Science ®Google Scholar
• U.S. Geological Survey, Mineral commodity summaries 2012: U.S. Geological Survey, 2012, 198 p.
   Google Scholar
• Cooper, J.; Lombardi, R.; Boardman, D.; Carliell-Marquet, C. The Future Distribution and Production of Global Phosphate Rock Reserves. Resour. Conserv. Recycl. 2011, 57, 78–86. DOI: 10.1016/j.resconrec.2011.09.009.
   Web of Science ®Google Scholar
• Walan, P.; Davidsson, S.; Johansson, S.; Höök, M. Phosphate Rock Production and Depletion: Regional Disaggregated Modeling and Global Implications. Resour., Conserv. Recycl. 2014, 93, 178–187. DOI: 10.1016/j.resconrec.2014.10.011.
   Web of Science ®Google Scholar
• Hammas, I.; Horchani-Naifer, K.; Férid, M. Solubility Study and Valorization of Phosphogypsum Salt Solution. Inter. J. Miner. Process. 2013, 123, 87–93. DOI: 10.1016/j.minpro.2013.05.008.
   Google Scholar
• Amrani, M.; Taha, Y.; Kchikach, A.; Benzaazoua, M.; Hakkou, R. Recycling: New Horizons for a More Sustainable Road Material Application. J. Build. Eng. 2020, 30, 101267. DOI: 10.1016/j.jobe.2020.101267.
   Web of Science ®Google Scholar
• Chernysh, Y.; Yakhnenko, O.; Chubur, V.; Roubík, H. Phosphogypsum Recycling: A Review of Environmental Issues, Current Trends, and Prospects. Appl. Sci. 2021, 11, 1575. DOI: 10.3390/app11041575.
   Google Scholar
• Geraldo, R.-H.; Costa, A.-R.-D.; Kanai, J.; Silva, J.-S.; Souza, J.-D.; Andrade, H.-M.-C.; Gonçalves, J.-P.; Fontanini, P.-S.-P.; Camarini, G. Calcination Parameters on Phosphogypsum Waste Recycling. Constr. Build. Mater. 2020, 256, 119406. DOI: 10.1016/j.conbuildmat.2020.119406.
   Web of Science ®Google Scholar
• Wu, S.; Yao, X.; Ren, C.; Yao, Y.; Wang, W. Recycling Phosphogypsum as a Sole Calcium Oxide Source in Calcium Sulfoaluminate Cement and Its Environmental Effects. J. Environ. Manage. 2020, 271, 110986. DOI: 10.1016/j.jenvman.2020.110986.
   PubMed Web of Science ®Google Scholar
• Sfar Felfoul, H.; Clastres, P.; Carles-Gibergues, A.; Ben Ouezdou, M. Propriétés et Perspectives D'utilisation du Phosphogypse. L'exemple de la Tunisie. Cim., Bétons, Plâtres, Chaux 2001, 849, 186–191.
   Google Scholar
• Murat, M.; Sorrentino, F. Effect of Large Additions of Cd, Pb, Cr, Zn, to Cement Raw Meal on the Composition and the Properties of the Clinker and the Cement. Cem. Concr. Res. 1996, 26, 377–385. DOI: 10.1016/S0008-8846(96)85025-3.
   Web of Science ®Google Scholar
• Silva, M.-V.; de Rezende, L.-R.; dos Anjos Mascarenha, M.-M.; de Oliveira, R.-B. Phosphogypsum, Tropical Soil and Cement Mixtures for Asphalt Pavements under Wet and Dry Environmental Conditions. Resour. Conserv. Recycl. 2019, 144, 123–136. DOI: 10.1016/j.resconrec.2019.01.029.
   Web of Science ®Google Scholar
• de Rezende, L.-R.; Curado, T.-D.-S.; Silva, M.-V.; Mascarenha, M.-M.-D.-A.; Metogo, D.-A.-N.; Neto, M.-P.-C.; Bernucci, L.-L.-B. Laboratory Study of Phosphogypsum, Stabilizers, and Tropical Soil Mixtures. J. Mater. Civ. Eng. 2017, 29, 04016188. DOI: 10.1061/(ASCE)MT.1943-5533.0001711.
   Web of Science ®Google Scholar
• Zeng, L.-L.; Bian, X.; Zhao, L.; Wang, Y.-J.; Hong, Z.-S. Effect of Phosphogypsum on Physiochemical and Mechanical Behaviour of Cement Stabilized Dredged Soil from Fuzhou. China. Geomech. Energy Environ. 2021, 25, 100195. DOI: 10.1016/j.gete.2020.100195.
   Web of Science ®Google Scholar
• Oumnih, S.; Bekkouch, N.; Gharibi, E.-K.; Fagel, N.; Elhamouti, K.; El Ouahabi, M. Phosphogypsum Waste as Additives to Lime Stabilization of Bentonite. Sustainable Environ. Res. 2019, 29, 1–10. DOI: 10.1186/s42834-019-0038-z.
   Web of Science ®Google Scholar
• Harrou, A.; Gharibi, E.-K.; Taha, Y.; Fagel, N.; El Ouahabi, M. Phosphogypsum and Black Steel Slag as Additives for Ecological Bentonite-Based Materials: Microstructure and Characterization. Minerals 2020, 10, 1067. DOI: 10.3390/min10121067.
   Web of Science ®Google Scholar
• Rutherford, P.-M.; Dudas, M.-J.; Arocena, J.-M. Trace Elements and Fluoride in Phosphogypsum Leachates. Environ. Technol. 1995, 16, 343–354. DOI: 10.1080/09593331608616276.
   Web of Science ®Google Scholar
• Romero-Hermida, M.-I.; Flores-Alés, V.; Hurtado-Bermúdez, S.-J.; Santos, A.; Esquivias, L. Environmental Impact of Phosphogypsum-Derived Building Materials. Int. J. Environ. Res. Public Health 2020, 17, 4248.ijerph DOI: 10.3390/17124248.
   Web of Science ®Google Scholar
• Xu, P.; Li, H.; Chen, Y. Experimental Study on Optimization of Phosphogypsum Suspension Decomposition Conditions under Double Catalysis. Materials 2021, 14, 1120. DOI: 10.3390/ma14051120.
   PubMed Web of Science ®Google Scholar
• Miao, Z.; Yang, H.; Wu, Y.; Zhang, H.; Zhang, X. Experimental studies on decomposing properties of desulfurization gypsum in a thermogravimetric analyzer and multiatmosphere fluidized beds. Ind. Eng. Chem. Res. 2012, 51(15), 5419–5423 DOI: 10.1021/ie300092s.
   Google Scholar
• Bhawan, P.; Nagar, E.-A. Hazardous Waste Management. Ministry of Environment & Forests: Delhi, 2012.
   Google Scholar
• Marty, M. Analyses-diagnostics du potentiel de résilience d’une organisation. Doctoral Dissertation. École Polytechnique de Montréal, 2014.
   Google Scholar
• Wheelock, T.-D.; Boylan, D.-R. Reductive Decomposition of Gypsum by Carbon Monoxide. Ind. Eng. Chem. 1960, 52, 215–218. DOI: 10.1021/ie50603a023.
   Google Scholar
• Zheng, M.; Shen, L.; Feng, X.; Xiao, J. Kinetic Model for Parallel Reactions of CaSO4 with CO in Chemical-Looping Combustion. Ind. Eng. Chem. Res. 2011, 50, 5414–5427. DOI: 10.1021/ie102252z.
   Web of Science ®Google Scholar
• Kühle, K.-D.; Knösel, K.-R. Process for the production of cement clinker and waste gases containing sulphur dioxide éd: Google Patents, 1988.
   Google Scholar
• Yan, B.; Ma, L.; Ma, J.; Zi, Z.; Yan, X. Mechanism Analysis of Ca, S Transformation in Phosphogypsum Decomposition with Fe Catalyst. Ind. Eng. Chem. Res. 2014, 53, 7648–7654. DOI: 10.1021/ie501159y.
   Web of Science ®Google Scholar
• Wheelock, T.-D. Simultaneous Reductive and Oxidative Decomposition of Calcium Sulfate in the Same Fluidized Bed. U.S. Patent No. 4,102,989. Washington, DC: U.S. Patent and Trademark Office. 1978.
   Google Scholar
• Smith, L.-L.; Fortney, M.-L.; Morris, C.-E.; Wheelock, T.-D.; Carrazza, J.-A. Resource Recovery from Wastewater Treatment Sludge Containing Gypsum. In Eleventh National Waste Processing Conference and Exhibit, 1984, p. 19.
   Google Scholar
• Nengovhela, R.-N. The Recovery of Sulphur from Waste Gypsum. Doctoral Dissertation, University of Pretoria, Pretoria, 2009.
   Google Scholar
• Aagli, A.; Tamer, N.; Atbir, A.; Boukbir, L.; El Hadek, M. Conversion of Phosphogypsum to Potassium Sulfate: Part I. The Effect of Temperature on the Solubility of Calcium Sulfate in Concentrated Aqueous Chloride Solutions. J. Therm. Anal. Calorim. 2005, 82, 395–399. DOI: 10.1007/s10973-005-0908-y.
   Web of Science ®Google Scholar
• Oumnih, S. Étude de valorisation du phosphogypse par désulfuration et par ajout à la stabilisation des sols gonflants. Doctoral Dissertation, Université Mohammed Premier, Oujda, Maroc and Université de Liège, Liege, Belgique, 2020.
   Google Scholar
• Wu, S.-Y.-H.; Tseng, C.-L.; Lin, F.-H. A Newly Developed Fe-Doped Calcium Sulfide Nanoparticles with Magnetic Property for Cancer Hyperthermia. J. Nanopart Res. 2010, 12, 1173–1185. DOI: 10.1007/s11051-009-9734-7.
   Web of Science ®Google Scholar
• Allen, D.; Hayhurst, A.-N. Reaction between Gaseous Sulfur Dioxide and Solid Calcium Oxide Mechanism and Kinetics. Faraday Trans. 1996, 92, 1227–1238. DOI: 10.1039/ft9969201227.
   Google Scholar
• Shobhana, E. Optical Characterization of Calcium Sulphide (CaS) Thin Films by Chemical Bath Deposition. Int. J. Sci. Res. 2015, 4, 1696–1701.
   Google Scholar
• Wu, S.-Y.-H.; Yang, K.-C.; Tseng, C.-L.; Chen, J.-C.; Lin, F.-H. Silica-Modified Fe-Doped Calcium Sulfide Nanoparticles for in Vitro and in Vivo Cancer Hyperthermia. J. Nanopart Res. 2011, 13, 1139–1149. DOI: 10.1007/s11051-010-0106-0.
   Web of Science ®Google Scholar
• Louvain, N.; Fakhry, A.; Bonnet, P.; El-Ghozzi, M.; Guérin, K.; Sougrati, M.-T.; Jumas, J.-C.; Willmann, P. One-Shot versus Stepwise Gas–Solid Synthesis of Iron Trifluoride: Investigation of Pure Molecular F2 Fluorination of Chloride Precursors. CrystEngComm 2013, 15, 3664–3671. DOI: 10.1039/c3ce27033e.
   Web of Science ®Google Scholar
• Sürer, M.-G.; Arat, H.-T. State of Art of Hydrogen Usage as a Fuel on Aviation. Eur. Mech. Sci. 2017, 2, 20–30. DOI: 10.26701/ems.364286.
   Google Scholar
• Odom, J.-M. Industrial and Environmental Activities of Sulfate-Reducing Bacteria. In The Sulfate-Reducing Bacteria: Contemporary Perspectives. New York: Springer-Verlag, 1993. pp. 189–210.
   Google Scholar
• Gou, Z.; Chang, J.; Gao, J.; Wang, Z. In Vitro Bioactivity and Dissolution of Ca2(SiO3)(OH)2 and β-Ca2SiO4 Fibers. J. Eur. Ceram. Soc. 2004, 24, 3491–3497. DOI: 10.1016/j.jeurceramsoc.2003.11.023.
   Web of Science ®Google Scholar
• Petrosyan, A.-M.; Ghazaryan, V.-V.; Fleck, M. On the Infrared Spectrum of L-Lysinium (2+) Sulfate. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2011, 79, 2020–2022. DOI: 10.1016/j.saa.2011.04.077
   PubMed Web of Science ®Google Scholar
• Kugel, R.; Taube, H. Infrared Spectrum and Structure of Matrix-Isolated Sulfur Tetroxide. J. Phys. Chem. 1975, 79, 2130–2135. DOI: 10.1021/j100587a014.
   Web of Science ®Google Scholar
• Naushad, M. Surfactant Assisted Nano-Composite Cation Exchanger: Development, Characterization and Applications for the Removal of Toxic Pb2+ from Aqueous Medium. Chem. Eng. J. 2014, 235, 100–108. DOI: 10.1016/j.cej.2013.09.013.
   Web of Science ®Google Scholar
• Zhang, G.; Qu, J.; Liu, H.; Liu, R.; Wu, R. Preparation and Evaluation of a Novel Fe-Mn binary oxide adsorbent for effective arsenite removal. Water Res. 2007, 41, 1921–1928. DOI: 10.1016/j.watres.2007.02.009.
   PubMed Web of Science ®Google Scholar
• Qi, Z.; Wang, Y.; He, H.; Li, D.; Xu, X. Wettability Alteration of the Quartz Surface in the Presence of Metal Cations. Energy Fuels 2013, 27, 7354–7359. DOI: 10.1021/ef401928c.
   Web of Science ®Google Scholar
• Athinarayanan, J.; Jaafari, S.-A.-A.-H.; Periasamy, V.-S.; Almanaa, T.-N.-A.; Alshatwi, A.-A. Fabrication of Biogenic Silica Nanostructures from Sorghum bicolor Leaves for Food Industry Applications. Silicon 2020, 12, 2829–2836. DOI: 10.1007/s12633-020-00379-4.
   Web of Science ®Google Scholar
• Corno, M.; Busco, C.; Civalleri, B.; Ugliengo, P. Periodic ab Initio Study of Structural and Vibrational Features of Hexagonal Hydroxyapatite Ca10(PO4)6(OH)2. Phys. Chem. Chem. Phys. 2006, 8, 2464–2472. DOI: 10.1039/B602419J.
   PubMed Web of Science ®Google Scholar
• Ulian, G.; Valdrè, G.; Corno, M.; Ugliengo, P. The Vibrational Features of Hydroxylapatite and Type a Carbonated Apatite: A First Principle Contribution. Amer. Miner. 2013, 98, 752–759. DOI: 10.2138/am.2013.4315.
   Web of Science ®Google Scholar
• Barrett, E.; Fern, G.-R.; Ray, B.; Withnall, R.; Silver, J. UV Photoluminescence from Small Particles of Calcium Cadmium Sulfide Solid Solutions. J. Opt. A: Pure Appl. Opt. 2005, 7, S265–S269. DOI: 10.1088/1464-4258/7/6/002.
   Google Scholar
• Sharma, G.; Patil, K.-R.; Gosavi, S.-W. Synthesis and Luminescence of Graphene-Nano Calcium Sulphide Composite. Mater. Chem. Phys. 2014, 147, 57–64. DOI: 10.1016/j.matchemphys.2014.04.006.
   Web of Science ®Google Scholar
• Castro, M. E.; Rivera, D. U.S. Patent No. 8,945,494. Washington, DC: U.S. Patent and Trademark Office. 2015.
   Google Scholar
• Izawa, M.-R.-M.; Applin, D.-M.; Mann, P.; Craig, M.-A.; Cloutis, E.-A.; Helbert, J.; Maturilli, A. Reflectance Spectroscopy (200–2500 nm) of Highly-Reduced Phases under Oxygen-and Water-Free Conditions. Icarus 2013, 226, 1612–1617. DOI: 10.1016/j.icarus.2013.08.014.
   Web of Science ®Google Scholar
• Nnabuchi, M.-N.; Okeke, C.-E. Characterization of Optimized Grown Calcium Sulphide Thin Films and Their Possible Applications in Solar Energy. Pac. J. Sci. Technol. 2004, 5, 72–82.
   Google Scholar
• Li, H.; Zhang, H.; Li, L.; Ren, Q.; Yang, X.; Jiang, Z.; Zhang, Z. Utilization of Low-Quality Desulfurized Ash from Semi-Dry Flue Gas Desulfurization by Mixing with Hemihydrate Gypsum. Fuel 2019, 255, 115783. DOI: 10.1016/j.fuel.2019.115783.
   Web of Science ®Google Scholar
• Wu, S.; Uddin, M.-A.; Nagamine, S.; Sasaoka, E. Role of Water Vapor in Oxidative Decomposition of Calcium Sulfide. Fuel 2004, 83, 671–677. DOI: 10.1016/j.fuel.2003.10.027.
   Web of Science ®Google Scholar
• Song, Z.; Zhang, M.; Ma, C. Study on the Oxidation of Calcium Sulfide Using TGA and FTIR. Fuel Process. Technol. 2007, 88, 569–575. DOI: 10.1016/j.fuproc.2007.01.014.
   Web of Science ®Google Scholar
• Seidel, G.; Huckauf, H.; Stark, J. Technologie des ciments, chaux, plâtre: Processus et installations de cuisson. Éditions SEPTIMA, 1980
   Google Scholar
• EPA. Toxic Release Inventory. U.S. Environmental Protection Agency: Washington, 1995.
   Google Scholar