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Section 2: Chemistry of Phosphorus Compounds in Particular Coordination Bonding

Transformation of Phosphaalkynes into 1H- and 2H-Phosphirenes1

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Pages 341-344 | Published online: 04 Oct 2006

References

  • Regitz , M. 1989 . Chem. Rev. , 89 Unusually coordinated phosphorus compounds, part 42. For part 41, see:, in press.
  • Wagner , O. , Maas , G. and Regitz , M. 1987 . Angew. Chem. Int. Ed. Engl. , 26 : 1257
  • The P/C double bond lenght of the tungsten carbonyl complex is shortened to 1.634 A in comparison to other free or complexed phosphaalkenes.
  • Regitz , M. and Binger , P. 1988 . Angew. Chem , 100 : 1541 Angew. Chem. Int. Ed. Engl. 1988, 27, 1484.
  • Wagner , O. , Ehle , M. and Regitz , M. 1989 . Angew. Chem. , 101 : 227 Angew. Chem. Int. Ed. Engl. 1989, 28, 225
  • The angle between the phosphorus and the chlorine amounts about 70°. The phosphorus chlorine bond is lengthened to 2.166 A in comparison to normal phosphorus chlorine single bonds

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