345
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Electrodeposition of Zirconium from 1-Butyl-1-Methylpyrrolidinium-Bis(Trifluoromethylsulfonyl)imide: Electrochemical Behavior and Reduction Pathway

, , , , &
Pages 74-80 | Received 30 Aug 2014, Accepted 02 Jan 2015, Published online: 25 Jul 2015

REFERENCES

  • Xu, X.Y.; Chu, C.L.; Yin, H.; Pu, Y.P.; Chu, P.K. Cytocompatibility and haemocompatibility of Zr, ZrC and ZrCN films. Surface Engineering 2012, 28, 448–452.
  • Groult, H.; Barhoun, A.; Briot, E.; Lantelme, F.; Julien, C.M. Electrodeposition of Zr on graphite in molten fluorides. Journal of Fluorine Chemistry 2011, 132, 1122–1126.
  • Xiao, W.; Wang, DH. The electrochemical reduction processes of solid compounds in high temperature molten salts. Chemical Society Reviews 2014, 43, 3215–3228.
  • Chen, Z.; Li, Y.; Li, S. Electrochemical behavior of zirconium in the LiCl–KCl molten salt at Mo electrode. Journal of Alloys and Compounds 2011, 509, 5958–5961.
  • Wu, Y.; Xu, Z.; Chen, S.; Wang, L.; Li, G. Electrochemical behavior of zirconium in molten NaCl-KCl-K2ZrF6 system. Rare Metals 2011, 30, 8–13.
  • Groult, H.; Barhoun, A.; El Gallali, H.; Borensztjan, S.; Lantelme, F. Study of the electrochemical reduction of Zr4+ ions in molten alkali fluorides. Journal of Electrochemical Society 2008, 155, 19–25.
  • Gibilaro, M.; Massot, L.; Chamelot, P.; Cassayre, L.; Taxil, P. Investigation of Zr(IV) in LiF–CaF2: Stability with oxide ions and electroreduction pathway on inert and reactive electrodes. Electrochimica Acta 2013, 95, 185–191.
  • Guang-Sen, C.; Okido, M.; Oki, T. Electrochemical studies of zirconium and hafnium in alkali chloride and alkali fluoride-chloride molten salts. Journal of Applied Electrochemistry 1990, 20, 77–84.
  • Giridhar, P.; El Abedin, S.Z.; Bund, A.; Ispas, A.; Endres, F. Electrodeposition of niobium from 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide ionic liquid. Electrochimica Acta 2014, 129, 312–317.
  • MacFarlane, D.R.; Meakin, P.; Sun, J.; Amini, N.; Forsyth, M. Pyrrolidinium imides: A new family of molten salts and conductive plastic crystal phases. The Journal of Physical Chemistry B 1999, 103 (20), 4164–4170.
  • Endres, F.; El Abedin, S.Z. Air and water stable ionic liquids in physical chemistry. Physical Chemistry Chemical Physics 2006, 8, 2101–2116.
  • Mascia, M.; Vacca, A.; Mais, L.; Palmas, S.; Musu, E.; Delogu, F. Electrochemical deposition of Cu and Nb from pyrrolidinium based ionic liquid. Thin Solid Films 2014, 571, 325–331. doi:10.1016/j.tsf.2014.05.030.
  • Azaceta, E.; Chavhan, S.; Rossi, P.; Paderi, M.; Fantini, S.; Ungureanu, M.; Miguel, O.; Grande, H.J.; Tena-Zaera, R. NiO cathodic electrochemical deposition from an aprotic ionic liquid: Building metal oxide n–p heterojunctions. Electrochimica Acta 2012, 71, 39–43.
  • Tsuda, T.; Hussey, C.L.; Stafford, G.R.; Kongstein, O. Electrodeposition of Al-Zr alloys from lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride melt. Journal of the Electrochemical Society 2004, 151, C447–C454.
  • Fu, C.; Aldous, L.; Manan, N.S.A.; Compton, R.G. Electrochemistry of zirconium tetrachloride in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide: Formation of Zr(III) and exploitation of ZrCl4 as a facile ionic liquid drying agent. Electroanalysis 2012, 24 (2), 210–213.
  • Vacca, A.; Mascia, M.; Mais, L.; Rizzardini, S.; Delogu, F.; Palmas, S. On the electrodeposition of Niobium from 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide at conductive diamond substrates. Electrocatalysis 2014, 5 (1), 16–22.
  • Borisenko, N.; Ispas, A.; Zschippang, E.; Liu, Q.; El Abedin, S.Z.; Bund, A.; Endres, F. In situ STM and EQCM studies of tantalum electrodeposition from TaF5 in the air- and water-stable ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide. Electrochimica Acta 2009, 54, 1519–1528.
  • Randstrom, S.; Appetecchi, G.B.; Lagergren, C.; Moreno, A.; Passerini, S. The influence of air and its components on the cathodic stability of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide. Electrochimica Acta 2007, 53, 1837–1842.
  • Randstrom, R.; Montanino, M.; Appetecchi, G.B.; Lagergren, C.; Moreno, A.; Passerini, S. Effect of water and oxygen traces on the cathodic stability of N-alkyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide. Electrochimica Acta 2008, 53, 6397–6401.
  • Druschler, M.; Borisenko, N.; Wallauer, J.; Winter, C.; Huber, B.; Endres, F.; Roling, B. New insights into the interface between a single-crystalline metal electrode and an extremely pure ionic liquid: Slow interfacial processes and the influence of temperature on interfacial dynamics. Physical Chemistry Chemical Physics 2012, 14, 5090–5099.
  • El Abedin, S.Z.; Farag, H.K.; Moustafa, E.M.; Welz-Biermanny, U.; Endres, F. Electroreduction of tantalum fluoride in a room temperature ionic liquid at variable temperatures. Physical Chemistry Chemical Physics 2005, 7, 2333–2339.
  • Eshed, M.; Pol, S.; Gedanken, A.; Balasubramanian, M. Zirconium nanoparticles prepared by the reduction of zirconium oxide using the RAPET method. Beilstein Journal of Nanotechnology 2011, 2, 198–203.
  • Pletcher, D.; Greff, R.; Peat, R.; Peter, L.M.; Robinson, J. Instrumental Methods in Electrochemistry; Woodhead: Cambridge, UK, 2011; 443 pp.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.