Fate and Potential Environmental Effects of Methylenediphenyl Diisocyanate and Toluene Diisocyanate Released into the Atmosphere

References

• International Isocyanate Institute, Manchester, U.K. Private communication, 2002.
   Google Scholar
• MDI and TDI: Safety, Health and the Environment; Allport, D., Gilbert, D.S., Outterside, S., Eds.; Wiley and Sons: London, 2003, in production.
   Google Scholar
• Maddison, P.; Vangronsveld, E. III European Emission Project: Stack Emissions from Rigid Polyurethane Foam Production Lines; III Report No. 11357; Huntsman Polyurethanes: Manchester, U.K., 2000.
   Google Scholar
• Chapman, J.F. Emissions from Flexible Polyurethane Foam Moulding Operations in Europe; III Report No. 11374; Gilbert International Ltd.: Manchester, U.K., 2001.
   Google Scholar
• Maddison, P.; Merckx, E.M.B. Responsible Care Programmes; Forestry & Forest Prod. Int. 1996, 107-110.
   Google Scholar
• Middleton, P. Modeling MDI Emissions; Science and Policy Associates, Inc.: Boulder, CO, 1998.
   Google Scholar
• Chapman, J.F. III European Emissions Project. Phase 1(A)—Gas Emissions Study—A Rationale; III Report No. 11157; Gilbert International Isocyanates: Manchester, U.K., 1994.
   Google Scholar
• Tu, D.; Fetsch, R. Emissionen von luftverunreinigenden Schadstoffen bei der Herstellung und Verarbeitung von Polyurethanprodukten. Forschungsbericht 104 08 144; University of Stuttgart: Stuttgart, Germany, 1980.
   Google Scholar
• Vermeire, T.G.; Jager, D.T.; Bussian, B.; Devillers, J.; den Haan, K.; Hansen, B.; Lundberg, I.; Niessen, H.; Robertson, S.; Tyle, H.; van der Zandt, P.T. European Union System for the Evaluation of Substances (EUSES): Principles and Structure; Chemosphere 1997, 34, 1823-1836.
   Google Scholar
• Roffman, A.; Rivkin, C.H. Dispersion Deposition Study of MDI Stack Aerosols; 2 Vols; III Report No. 11191; Dow Environmental Inc.: Pittsburgh, 1995.
   Google Scholar
• Yakabe, Y.; Henderson, K.M.; Thompson, W.C.; Pemberton, D.; Tury, B.; Bailey, R.E. Fate of Methylenediphenyl Diisocyanate and Toluene Diisocyanate in the Aquatic Environment; Environ. Sci. Technol. 1999, 33, 2579-2583.
   Google Scholar
• Holdren, M.W.; Spicer, C.W.; Riggin, R.M. Gas-Phase Reaction of Toluene Diisocyanate with Water Vapor; Am. Ind. Hyg. Assoc. J. 1984, 45, 626-633.
   Google Scholar
• Brorson, T.; Skarping, G.; Renman, I.; Sango, C. Test Atmospheres of Diisocyanates with Special Reference to Controlled Exposure of Humans; Int. Arch. Occup. Environ. Health 1989, 61, 495-501.
   Google Scholar
• Sepai, O.; Schütze, D.; Heinrich, U.; Hoymann, H.G.; Henschler, D.; Sabbioni, G. Hemoglobin Adducts and Urine Metabolites of 4, 4′-methylenedianiline after 4, 4′-Methylenediphenyl Diisocyanate Exposure of Rats; Chem.-Biol. Interactions 1995, 97, 185-198.
   Google Scholar
• Skarping, G.; Brorson, T.; Sango, C. Biological Monitoring of Isocyanates and Related Amines. III. Test Chamber Exposure of Humans to Toluene Diisocyanate; Int. Arch. Occup. Environ. Health 1991, 63, 83-88.
   Google Scholar
• Butler, R.; Snelson, A. Kinetics of the Homogeneous Gas-Phase Hydro-lysis of CCl3 COCl, CCl2 HCOCl, CH2 ClCOCl and COCl2 ; J. Air Pollut.Control Assoc. 1979, 29, 833-837.
   Google Scholar
• Duff, P.B. Fate of Toluene Diisocyanate in Air: Phase II Study. In Paper, The Magic of Polyurethane: Proc. SPI 29th Ann. Tech./Marketing Conf., Reno, NV, Oct 23–25, 1985; pp 9-14.
   Google Scholar
• Gilbert, D.S. Fate of TDI and MDI in Air, Soil and Water; J. Cell. Plast. 1988, 24, 178-192.
   Google Scholar
• Atkinson, R. Gas-Phase Tropospheric Chemistry of Organic Compounds: A Review; Atmos. Environ. 1990, 24A, 1-41.
   Google Scholar
• Becker, K.H.; Bastian, V.; Klein, T. The Reactions of OH Radicals with Toluene Diisocyanate, Toluenediamine and Methylenedianiline under Simulated Atmospheric Conditions; J. Photochem. Photobiol., A: Chem. 1988, 45, 195-205.
   Google Scholar
• Carter, W.P.L.; Luo, D.; Malkina, I.L. Investigation of the Atmospheric Ozone Formation Potential of Para-Toluene Isocyanate and Methylene Diphenylene Diisocyanate; University of California; Final report to the Chemical Manufacturers Association Diisocyanates Panel, March 8, 1999. Available from ftp://ftp.cert.ucr.edu/pub/carter/pubs/mdirpt.pdf (accessed Jan 14, 2002).
   Google Scholar
• Montzka, S.A.; Spivakovsky, C.M.; Butler, J.H.; Elkins, J.W.; Lock, L.T.; Mondeel, D.J. New Observational Constraints for Atmospheric Hydroxyl on Global and Hemispheric Scales; Science 2000, 288, 500-503.
   Google Scholar
• Carter, W.P.L.; Luo, D.; Malkina, I.L. Investigation of the Atmospheric Ozone Formation Potential of Toluene Diisocyanate; University of California; Final report to the Society for the Plastics Industry, Inc., December 2, 1997. Available from ftp://ftp.cert.ucr.edu/pub/carter/pubs/tdirpt.pdf (accessed Jan 14, 2002).
   Google Scholar
• Carter, W.P.L.; Lurmann, F.W. Evaluation of the RADM Gas-Phase Chemical Mechanism; U.S. Environmental Protection Agency final report; EPA-600/3-90-001; U.S. Government Printing Office: Washington, DC, 1990.
   Google Scholar
• Carter, W.P.L.; Lurmann, F.W. Evaluation of a Detailed Gas-Phase Atmospheric Reaction Mechanism Using Environmental Chamber Data; Atmos. Environ. 1991, 25A, 2771-2806.
   Google Scholar
• Yakabe, Y.; Hiromatsu, K.; Kawahara, K.; Nakahara, M. Determination of 1-Octanol/Water Partition Coefficients of Isocyanate Compounds by an HPLC Method; Toxicol. Environ. Chem. 2000, 77, 199-206.
   Google Scholar
• International Uniform Chemical Information Database; 2000. CD of all data can be ordered from Office for Official Publications of the European Communities, Luxembourg.
   Google Scholar
• Hellpointner, E.; Dehner, D. Determination of the Quantum Yield and Assessment of the Environmental Half-Life of the Direct Photodegradation of 4, 4′-Diaminodiphenylmethane in Water; III Report No. 11265; Bayer AG: Leverkusen, Germany, 1997.
   Google Scholar
• Hellpointner, E.; Hoffend, F.J. Determination of the Quantum Yield and Assessment of the Environmental Half-Life of the Direct Photodegradation of 2,4-Diaminotoluene in Water; III Report No. 11266; Bayer AG: Leverkusen, Germany, 1997.
   Google Scholar
• Cowen, W.F.; Gastinger, A.M.; Spanier, C.E.; Buckel, J.R.; Bailey, R.E. Sorption and Microbial Degradation of Toluenediamines and Methylenedianiline in Soil under Aerobic and Anaerobic Conditions; Environ. Sci. Tech. 1998, 32, 598-603.
   Google Scholar