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Original Articles

Grafting density of oligo-bottle-brushes on silicon surface: effect of mole fraction of RAFT agent-functionalized alkenes in mixed self-assembled monolayers

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Pages 479-487 | Received 19 Sep 2019, Accepted 29 Jan 2020, Published online: 10 Feb 2020

References

  • Sheiko, S. S.; Sumerlin, B. S.; Matyjaszewski, K. Cylindrical Molecular Brushes: Synthesis, Characterization, and Properties. Prog. Polym. Sci. 2008, 33, 759–785. DOI: 10.1016/j.progpolymsci.2008.05.001.
  • Zhang, M.; Müller, A. H. E. Cylindrical Polymer Brushes. J. Polym. Sci. A Polym. Chem. 2005, 43, 3461–3481. DOI: 10.1002/pola.20900.
  • Morsch, S.; Schofield, W. C. E.; Badyal, J. P. S. Tailoring the Density of Surface-Tethered Bottlebrushes. Langmuir 2011, 27, 14151–14159. DOI: 10.1021/la201967f.
  • Lecommandoux, S.; Checot, F.; Borsali, R.; Schappacher, M.; Deffieux, A.; Brulet, A.; Cotton, J. P. Effect of Dense Grafting on the Backbone Conformation of Bottlebrush Polymers: Determination of the Persistence Length in Solution. Macromolecules 2002, 35, 8878–8881. DOI: 10.1021/ma0203344.
  • Huang, W.; Kim, J.-B.; Bruening, M. L.; Baker, G. L. Functionalization of Surface by Water-Accelerated Atom-Transfer Radical Polymerization of Hydroxyethyl Methacrylate and Subsequent Derivatization. Macromolecules 2002, 35, 1175–1179. DOI: 10.1021/ma011159e.
  • Huang, K.; Rzayev, J. Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers. J. Am. Chem. Soc. 2009, 19, 6880–6885. DOI: 10.1021/ja901936g.
  • Juhari, A.; Mosnacek, J.; Yoon, J. A.; Nese, A.; Koynov, K.; Kowalewski, T.; Matyjaszewski, K. Star-like Poly (n-Butyl Acrlate)-b-Poly (α-Methylene-γ-Butyrolactone) Block Copolymers for High Temperature Thermoplastic Elastomers Applications. Polymer 2010, 51, 4806–4813. DOI: 10.1016/j.polymer.2010.08.017.
  • Snijkers, F.; Cho, H. Y.; Nese, A.; Matyjaszewski, K.; Pyckhout-Hintzen, W.; Vlassopoulos, D. Effects of Core Microstructure on Structure and Dynamics of Star Polymer Melts: From Polmeric to Colloidal Response. Macromolecules 2014, 47, 5347–5356. DOI: 10.1021/ma5008336.
  • Durmaz, Y. Y.; Kumbaraci, V.; Demirel, A. L.; Talinli, N.; Yagci, Y. Graft Copolymers by the Combination of ATRP and Photochemical Acylation Process by Using Benzodioxinones. Macromolecules 2009, 42, 3743–3749. DOI: 10.1021/ma900360s.
  • Gao, H.; Matyjaszewski, K. Synthesis of Molecular Brushes by “Grafting onto” Method: Combination of ATRP Andclick Reactions. J. Am. Chem. Soc. 2007, 129, 6633–6639. DOI: 10.1021/ja0711617.
  • Naderi, A.; Iruthayaraj, J.; Vareikis, A.; Makuska, R.; Claesson, P. M. Surface Properties of Bottle-Brush Polyelectrolytes on Mica: Effects of Side Chain Andcharge Densities. Langmuir 2007, 23, 12222–12232. DOI: 10.1021/la701716t.
  • Vogt, A. P.; Sumerlin, B. S. An Efficient Route to Macromonomers via ATRPand Click Chemistry. Macromolecules 2006, 39, 5286–5292. DOI: 10.1021/ma0610461.
  • Iwasaki, Y.; Akiyoshi, K. Design of Biodegradable Amphiphilic Polymers: Well-Defined Amphiphilic Polyphosphateswith Hydrophilic Graft Chains via ATRP. Macromolecules 2004, 37, 7637–7642. DOI: 10.1021/ma049043g.
  • Zhai, G.; Kang, E. T.; Neoh, K. G. Inimer Graft-Copolymerized Poly(Vinylidene Fluoride) for the Preparation of Arborescent Copolymers and “Surface-Active” Copolymer Membranes. Macromolecules 2004, 37, 7240–7249. DOI: 10.1021/ma048894l.
  • Li, X.; Jazeyi, H. S.; Pesek, S. L.; Agrawal, A.; Hammouda, B.; Verduzco, R. Thermoresponsive PNIPAAM Bottlebrush Polymers with Tailored Side-Chain Length and End- Group Structure. Soft Matter 2014, 10, 2008–2015. DOI: 10.1039/c3sm52614c.
  • Radzinski, S. C.; Foster, J. C.; Matson, J. B. Preparation of Bottlebrush Polymers via a One-Pot Ring-Opening Polymerization (ROP) and Ring-Opening Metathesis Polymerization (ROMP) Grafting-through Strategy. Macromol. Rapid Commun. 2016, 37, 616–621. DOI: 10.1002/marc.201500672.
  • Zhou, D.; Mastan, E.; Zhu, S. Termination of Surface Radicals and Kinetic Analysis of Surface-Initiated RAFT Polymerization on Flat Surfaces. Macromol. Theory Simul. 2012, 21, 602–614. DOI: 10.1002/mats.201200043.
  • Perrier, S.; Takolpuckdee, P.; Mars, C. A. Reversible Addition − Fragmentation Chain Transfer Polymerization Mediated by a Solid Supported Chain Transfer Agent. Macromolecules 2005, 38, 6770–6774. DOI: 10.1021/ma0506886.
  • Yildirim, E.; Cimen, D.; Zengin, A.; Caykara, T. Synthesis of Poly(N-(2-Hydroxypropyl) Methacrylamide) Brushes by Interface-Mediated RAFT Polymerization. RSC Adv. 2016, 6, 45259–45264. DOI: 10.1039/C6RA04189B.
  • Kursun, T. T.; Cimen, D.; Caykara, T. Synthesis and Stability of BODIPY-Based Fluorescent Polymer Brushes at Different pHs. J. Polym. Sci. Part A: Polym. Chem. 2014, 52, 3586–3596. DOI: 10.1002/pola.27426.
  • Zengin, A.; Karakose, G.; Caykara, T. Poly(2-(Dimethylamino)Ethyl Methacrylate) Brushes Fabricated by Surface-Mediated RAFT Polymerization and Their Response to pH. Euro. Polym. J. 2013, 49, 3350–3358. DOI: 10.1016/j.eurpolymj.2013.07.005.
  • Paragkumar, T.; Edith, D.; Jean-Luc, S. Surface Characteristics of PLA and PLGA Films. Appl. Surf. Sci. 2006, 253, 2758–2764. DOI: 10.1016/j.apsusc.2006.05.047.
  • Vorobii, M.; Pereira, A. S.; Georgievski, O. P.; Kostina, N. Y.; Emmenegger, C. R.; Percec, V. Synthesis of Non-Fouling Poly[N-(2-Hydroxypropyl)Methacrylamide] Brushes by Photoinduced SET-LRP. Polym. Chem. 2015, 6, 4210–4220. DOI: 10.1039/C5PY00506J.
  • Andrade, P. O.; Grinet, M. A. V. M.; Costa, M. M.; Santo, A. M. E.; Marciano, F. R.; Lobo, A. O. Poly(Lactic Acid) Fine Fibers Containing a Low Content of Superhydrophilic Multi-Walled Carbon Nanotube Graphene Oxide Hybrid as Scaffolds for Biological Applications. Macromol. Mater. Eng. 2018, 303, 1800317. DOI: 10.1002/mame.201800317.
  • Strohalm, J.; Kopecek, J. Poly [N-(2-Hydroxypropyl) Methacrylamide].IV.Heterogeneous Polymerization. Angew. Makromol. Chemie 1978, 70, 109–118.
  • Patton, D. L.; Advincula, R. C. A Versatile Synthetic Route to Macromonomers via RAFT Polymerization. Macromolecules 2006, 39, 8674–8683. DOI: 10.1021/ma061382h.
  • Buriak, J. M. Organometallic Chemistry on Silicon and Germanium Surfaces. Chem. Rev. 2002, 102, 1271–1306. DOI: 10.1021/cr000064s.
  • Buriak, J. M. Organometallic Chemistry on Silicon Surfaces: formation of Functional Monolayers Bound through Si–C Bonds. Chem. Commun. 1999, 1051–1060. DOI: 10.1039/a900108e.
  • Wayner, D. D. M. Organic Modification of Hydrogen Terminated Silicon Surfaces. J. Chem. Soc. Perkin Trans 2002, 2, 23–34. DOI: 10.1039/b100704l.
  • Israelachvili, J. N.; Gee, M. L. Contact Angles on Chemically Heterogeneous Surfaces. Langmuir 1989, 5, 288–289. DOI: 10.1021/la00085a059.
  • Bain, C. D.; Evall, J.; Whitesides, G. M. Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Head Group, Tail Group, and Solvent. J. Am. Chem. Soc. 1989, 111, 7155–7164. DOI: 10.1021/ja00200a39.
  • Bain, C. D.; Whitesides, G. M. Formation of Two-Component Surfaces by the Spontaneous Assembly of Monolayers on Gold from Solutions Containing Mixtures of Organic Thiols. J. Am. Chem. Soc. 1988, 110, 6560–6561. DOI: 10.1021/ja00227a044.
  • Linford, M. R.; Chidsey, C. E. D. Alkyl Monolayers Covalently Bonded to Silicon Surfaces. J. Am. Chem. Soc. 1993, 115, 12631–12632. DOI: 10.1021/ja00079a071.
  • Boukherroub, R.; Morin, S.; BenseBaa, F.; Wayner, D. D. M. New Synthetic Routes to Alkyl Monolayers on the Si(111) Surface. Langmuir 1999, 15, 3831–3835. DOI: 10.1021/la9901478.
  • Wei, F.; Zhao, X. S. The Capacitance of Mixed Alkyl Monolayers on Si(111) Surface. Thin Solid Films 2002, 408, 286–290. DOI: 10.1016/S0040-6090(02)00136-0.
  • Song, B.; Zhou, Y.; Schönherr, H. Optimized Model Surfaces for Advanced Atomic Force Microscopy Studies of Surface Nanobubbles. Langmuir 2016, 32, 11179–11187. DOI: 10.1021/acs.langmuir.6b01776.
  • Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben, K. D. In X-Ray Photoelectron Spectroscopy. Chastain, J., (Ed.). Perkin-Elmer: Eden Prairie, MN, 1992.
  • Beamson, G.; Briggs, D. High-Resolution XPS of Organic Polymers: The Scienta ESCA300 Database: John Wiley: Chichester, UK, 1992
  • Barsbay, M.; Güven, O.; Stenzel, M. H.; Davis, T. P.; Kowollik, C. B.; Barner, L. Verification of Controlled Grafting of Styrene from Cellulose via Radiation-Induced RAFT Polymerization. Macromolecules 2007, 40, 7140–7147. DOI: 10.1021/ma070825u.
  • Turan, E.; Demirci, S.; Caykara, T. Synthesis of Thermoresponsive Poly(N-Isopropylacrylamide) Brush on Silicon Wafer Surface via Atom Transfer Radical Polymerization. Thin Solid Films 2010, 518, 5950–5954. DOI: 10.1016/j.tsf.2010.05.103.
  • Luzinov, I.; Julthongpiput, D.; Malz, H.; Pionteck, J.; Tsukruk, V. V. Polystyrene Layers Grafted to Epoxy-Modified Silicon Surfaces. Macromolecules 2000, 33, 1043–1048. DOI: 10.1021/ma990926v.

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