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Original Articles

Enantioselective Recognition for Carboxylic Acids by Novel Chiral Macrocyclic Polyamides Derived from L-/D-tartaric Acid

, , , , &
Pages 507-513 | Received 29 Jan 2006, Accepted 16 May 2006, Published online: 01 Feb 2007

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  • Crystals suitable for X-ray analysis were obtained by recrystallization from acetonitrile at room temperature. Crystallographic data for the structure of compound 3 has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC-290467 These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif . Crystal data of 3: C27H36N4O4, M = 480.60, Monoclinic space group P2(1), a = 15.7369(18) Å, b = 8.8210(10) Å, c = 18.390(2) Å, β = 90.652(2)°, V = 2552.6(5) Å3, D = 1.251 g/cm3, μ = 0.085 mm− 1, F(0 0 0) = 1032, Z = 4, R1 = 0.0429, ωR2 = 0.0630. Data collection for the crystal structure determination was carried out on the Bruker APEX2 CCD area detector using MoKα radiation (λ = 0.71073 Å) at a temperature of 273(2) K. Of the 16671 reflections measured in the 2.22 ≤ θ ≤ 27.49 range, 10942 reflections were unique and 5389 reflections with I>2σ(I) were used in structure solution and refinement. Rint = 0.0533, M calc , where . The structure was solved by direct method using SHELX-97. All of the nonhydrogen atoms were refined by full-matrix leastsquares methods using anisotropic displacement parameters
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